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By Martha Gellner, Lutz Wuschke, Hans-Georg Jackel, Urs A. Peuker

"Electric vehicles are an alternative to the existing combustion engine driven cars. According to the EU Battery Directive a substantial recycling rate of at least 50 wt.-% has to be met for aged batteries since 2006. Existing recycling techniques are based on energy intensive pyro- and hydrometallurgical process, which are not able to recover all components. Aluminum and lithium for instance are slagged. The EU-Project “ABattReLife” investigated possibilities for a mechanical processing in order to create a sustainable process and a closed material loop from grave to cradle. After a sufficient liberation of the Li-ion batteries, components like the doped carbon black fraction (mainly lamination of electrode foils), the separator foil and the housing material can comparatively easily be separated from the other components by screening and air sifting. The remaining mixture consists of anode and cathode foils which have a similar free-settling ratio and are more difficult to separate from each other. A second comminution and compaction step modifies the particle size and shape as well as the degree of delamination. These changes influence the density of the electrode foils in order to improve the separation efficiency. Yield and purity of the generated metal concentrates were parameters to show if the separation was successful. The specific energy consumption for the different methods of processing was estimated in order to benchmark the cost-benefit ratio for each one.The studies have been accomplished with a zig zag sifter (model TUBAF), a hammer mill (model HM 340 Jehmlich) and with a Petkus-Sifter. Finally a process flow sheet was developed for a Li-ion battery recycling plant in pilot scale."

Jan 1, 2016

By Ranklin W. J

The mechanism and rate-limiting step of carbonaceous reduction of zinc from slags was investigated in the laboratory. Disks of graphite were rotated in ZnO-containing slags at various speeds for fixed periods at 1250 to 1325¦C. The mass loss was used as a measure of the amount of ZnO reduced. Application of the Levich equation indicated that at rotation speeds at which it is valid, the reduction was chemically controlled with an activation energy of 27 kcal/mol. At zero rotation speed the reduction of ZnO by carbon appeared to be slag-phase mass transfer controlled with an activation energy of 38 kcal/mol. An increase in the FeO content of the slag increased the rate of reduction while an increase in sulphur content decreased the rate of reduction. When FeO was present in the slag, reduction appeared to occur by a combination of indirect reduction of ZnO by carbon and by reduction by FeO with reduction of Fe203 back to FeO by carbon. The effect of sulphur was consistent with a surface blockage mechanism due to the surface active nature of sulphur in slags.

Jan 1, 1993

By Lee W. Saperstien

At the heart of the mining process are a number of basic and fundamental tasks whose regular and repeated performance constitute the mining cycle. As will be discussed presently, these tasks are the basic components of the mining system. Section 9, Production Operations, provides the mine designer and engineer with an understanding of these tasks and with sufficient design principles to allow this person to create an efficient mine system. This section is meant to be an introduction and adjunct to subsequent sections that describe specific mining systems. However, sufficient design information is included here for the independent design of mine systems that may not be described elsewhere or for subsequent verification of existing designs. For the purposes of this section, mining subsumes excavation; thus this material applies to any excavation process. Accordingly, this section is written in general enough terms to include both surface and underground mining. It may be used also for civil engineering excavations that often involve the same steps. Obviously, the actual procedures undertaken in any specific mining system will appear to be very different from those taken in any other system. This is certainly true when comparing surface with underground methods. Yet the fundamental principles are often the same. This segment is written to explicate the basics. Wherever appropriate, the section will suggest the differences between the application process to surface or to underground mining.

Jan 1, 2008

By H. C. Rickaby

Introduction The township of Swayze, from which the Swayze gold area derives its name, is in the Sudbury mining division, approximately 150 miles northwest of Sudbury. The gold area may be regarded as situated at the southwest corner of a triangular area whose northeast and southeast corners are at Porcupine and Shiningtree, respectively, and whose sides are between 70 miles and 90 miles in length. On a geological map, it would be found that belts of Keewatin greenstones and sediments form the sides of this triangle, and that they surround a large granite mass. Prior to the summer of 1931 the Swayze corner of this triangle had probably been less prospected than the other parts and comparatively little was known of it from the standpoint of gold mining possibilities. The extensive belts of iron formation to the south and west of Swayze received some attention about the year 1909, and during the years 1927 and 1928 some prospecting was done in the townships of Greenlaw and Cunningham, south of Swayze, but chiefly for base-metals- copper, zinc, and lead. In the summer of 1931 a very promising discovery of gold-bearing quartz was made by J. G. and J. L. Kenty, working for the Brett-Trethewey Mines, Ltd., in association with Northern Canada Mining Corporation, and Northland Prospectors, Ltd., and this property, now known as the Kenty Gold Mines, Ltd., has been actively developed with very encouraging results. Following this discovery a6d during the summer of 1932 much prospecting took place in the area, as a result of which a number of other discoveries of gold were made, chiefly to the west of the original find. They are distributed over a wide area, which includes the townships of Rollo, Raney, Swayze, Denyes, Halcrow, and Greenlaw.

Jan 1, 1933

By D. M. Thayer, P. B. Linkson

High intensity wet magnetic separation methods have received much attention in the search for alternative and effective methods to treat weakly magnetic minerals. This paper examines the incorporation of such techniques in the beneficiation of a non-sliming specular Michigan Hematite. The dependence of separation efficiency and beneficiation of specular hematite on various parameters controlling the operation of such a device is investigated experimentally. Particular attention is focused on particle size limitations imposed in these separations. In light of these data, metallurgical balances are presented and an attempt made to rationalize the various models suggested in the literature.

Jan 1, 1982

By C. S. Yust, J. W. Smith, J. R. Walsh, R. E. Simpson

This paper presents the results of a complete reservoir studv designed to determine a sound economic program for the conservation of oil and gas in the Pickton field, Hopkins County, Texas. The Pickton field produces from the Bacon Lime with all indications of the study being that production is predominately by dissolved-gas drive. Calculations of the total ultimate recovery to be expected under primary operations indicated only 16.7 per cent of the oil originally in place would be recovered. This unusually low recovery is due to the type of drive operating and the extremely high dissolved gas-oil ratio and shrinkage. Results are presented for six plans of returning gas to the reservoir, evaluated to determine (1) comparative recoveries and economics of (a) returning gas at a constant rate by supplementing Pickton gas with extraneous gas during the early portion of the operation, and (b) conventional gas-return operations without using extraneous gas, and (2) the optimum size of compressor plant for each type of pressure maintenance. The over-all economic program considers, for either type pressure maintenance operation. a gasoline plant to process the unusually rich casinghead gas. Since pressure maintenance will disturb equities, pooling of royalties is in the case of Pickton a prerequisite to conservation of oil by this type of operation, both from an economic and legal standpoint. In the event pooling of royalties cannot be achieved, the study considers a gasoline plant to operate under a modified primary production operation which will make the conservation of gas possible. INTRODUCTION The Pickton field, located in Hopkins County, Texas. was discovered in November, 1944. by the completion of Humble's C. D. Nichols 1, in the Bacon lime of the Lower Glen Rose formation, through perforations from 7,888 to 7.896 feet. The well initially produced 50.2 API gravity oil with a gas-oil ratio of 1,350 cubic feet per barrel. Subsurface samples of the reservoir fluid obtained soon after completion of the discovery well showed that the Pickton crude is unique in that it has an extremely high dissolved gas-oil ratio and is subject to very severe shrinkage. Calculations of the future behavior of the Pickton reservoir indicated that ultimate oil recovery by primary operations would be 3,269,000 barrels, representing only 16.7 per cent of the oil in place (19,577,000 stock-tank barrels), and that recovery could be substantially increased by returning the produced gas. The cumulative production of 1,382,694 barrels on November 1: 1947, amounted to 42.3 per cent of the estimated ultimate oil recovery from primary operations. The purpose of this study is to determine and evaluate the optimum program for conservation of oil and gas in the Pick-ton field, including the desirability of conducting gas-return operations and of installing a gasoline plant. LOCATION AND DESCRIPTION Pickton Field, The Pickton field, as shown in Fig. 1, is located in southwest Hopkins County, Texas, 12.5 miles southwest of the New Hope field, 2.7 miles northeast of the Coke field, 16 miles southwest of Sulphur Springs, and 8 miles northwest of Winnsboro, Texas.

Jan 1, 1949

By S. Sumski, M. B. Panish, R. T. Lynch

The liquidus isotherms in the gallium-rich corner of the Ga-Al-P phase diagram have been determined from 1000" to 1200°C and at I100°C the corresponding solidus isotherm was obtained. A simple thermody-namic treatment which permits calculation of the solidus and liquidus isotherms is discussed. A technique which was previously used for the growth of GaxAl1-xAs was used for the preparation of solution epitaxial layers of GaxAl1-xP and ALP. An approximate value of 2.49 i 0.05 ev for the band gap of Alp at 300°K was obtained and the ternary phase data were used to estimate a value of 36 kcal per mole for the heat of formation 0f Alp at that temperature. The Gap-A1P crystalline solid solution is one in which there exists the possibility of obtaining crystals with selected energy gaps, within the limits imposed by the energy gaps of Gap and Alp. Such crystals are of considerable interest because of their potential value for optoelectronic and other solid-state devices. Furthermore, it has been amply demonstrated for GaAs and GaP,'-7 that device, or bulk materials grown from gallium solution generally have more efficient radiative recombination than materials prepared in other ways. This presumably due to the lower gallium vacancy concentration in such material.= Small crystals of GaXAl1-xP and A1P have been grown from solution,8-10 and A1P has been grown from the vapor," but neither have previously been grown by liquid epitaxy. In this paper we present the ternary liquidus-solidus phase diagram of the Ga-A1-P system in the region of primary interest for solution epitaxy, and discuss the thermodynamic implications of that phase diagram with particular reference to the liquidus and solidus isotherms in the gallium-rich corner of the GaxAl1-xP primary phase field and to the A1-P system. Several measurements of the absorption edge of GaxAl1-xP crystals have been made and the width of the forbidden gap of A1P has been estimated from these measurements. EXPERIMENTAL The differential thermal analysis technique used to determine the liquidus isotherms and the optical measurements used in this work are similar to those described previously12 for the Ga-Al-As system, ex- thermocouples in the thermopile for added sensitivity. The materials used were semiconductor grade Ga, Gap, and Al+ The composition and temperature range at which DTA studies could be done was quite restricted. The upper temperature was limited by the chrome l-alumel thermopile to about 1200°C, and the highest aluminum concentration to about 5 at. pct by low sensitivity caused by the reduced solubility of Gap with increasing aluminum concentration in the liquid. DTA studies were not possible at 1000°C and below because of the low sensitivity caused by low solubility of Gap in the Ga-A1-P system. The cooling rate for these studies was about 1°C per min. No heating studies were done because of limited sensitivity. Supercooling probably does occur, but our experience with other 111-V systems indicates that it is no greater than about 10 to 15.c. Solid solubilities were determined by analyzing epitaxial layers of GaxAl1-xP grown from the liquid, with an electron beam microprobe. The layers were grown on Gap seeds by a tipping technique in which the layer is grown over a short-temperature range (20" to 50°C) on the seed from a solution of known composition. The tipping technique reported by Nelsson1 for GaAs could not be used, particularly for solutions containing appreciable amounts of aluminum, because of the formation of an A1203 scum on the liquid surface. A system was therefore designed, which would effectively remove the oxides mechanically, so that uniform wetting and crystal growth could occur. This tipping technique has already been described in detail." The best control over the composition of the re-grown layer was obtained when the tipping was done at a temperature which corresponded to the temperature of first formation of solid for the solution being used. Generally, therefore, a solution was prepared by adding the amounts of Ga, Gap, and A1 required to yield a solution which would be completely liquid above the tipping temperature with solid precipitating below that temperature. For most of the work reported here, the 1100°C isotherm of the ternary was used. It was generally necessary to heat the solution to 50" to l00. C above the tipping temperature to dissolve all of the Gap in a reasonable length of time. The epitaxially grown layers were used both for optical transmission measurements to aid in the estimation of the way in which the absorption edge changed with aluminum concentration, and for the electron beam microprobe analyses to provide data for the determination of the solid solubility isotherm. RESULTS AND DISCUSSION Liquidus Isotherms in the Ga-A1-P Ternary Phase Diagram: Thermodynamic properties of the system. The only thermal effect studied in this work was that

Jan 1, 1970

This project was started 8 June 1971. As set forth in our Proposal of 28 April 1970, responding to the RFP of 30 March 1970, the plan was twofold: 1) choose fluids and develop techniques for measuring coat porosity, and 2) construct a porosimeter for making such measurements, By the time plans for the porosimeter had been drawn up, the picture had changed; and it was found more advisable to do further researches on porosity rather than build the equipment. This development arose from a meeting with Dr. Fred N. Kissell on 14, 15 October 1971, annotated in our letter of 19 October 1971, and was contracted for 6 December 1971. The technical effort of the project was completed 7 May 1972. From the beginning it was realized that the ratio of 'hole volume to the whole volume' might be too simplistic a definition for coat porosity and that its measurement might be confounded by complications which were not yet known, We were hopeful that an exploration of fluids and techniques would provide early feedback on both these points which could be used in subsequent developments. This turned out to be the case.

Jan 1, 1972

By Masami Nakamoto

Controlled thermolysis of gold(I) thiolate complex, [C14H29(CH3)3N][Au(SC12H25)2], at 180 °C for 5 h under an N2 atmosphere produces novel gold nanoparticles passivated by alkyl groups derived from the precursor complex, the TEM photograph of which shows spherical particles with average diameter 26 nm. Since Brust et al. reported the two-phase reduction of AuCl4 - by NaBH4 to afford monodispersed gold nanoparticles passivated by alkanethiolate ligands (1), plenty of preparative investigations on gold nanoparticles (2,3) and its surface modification (3,4) have appeared, because of their potential applications in microelectronics (5). However, those preparative methods generally involve the reduction of AuCl4 - by reducing agent NaBH4 in the presence of suitable organic stabilizers such as alkanethiol (1-4), phosphane (5), quarternary ammonium salts (6), surfactants (7) or polymers (8). On the other hand, O?Brien et al. recently reported the preparation of organically capped gold nanoparticles at 190 °C, where tri-n-octylphosphine oxide and/or n-octadecylamine are used both as a reaction medium and as a passivating ligand (6), but this procedure also needs NaBH4 as reducing agent. Our strategy of novel preparative method of gold nanoparticles is the combination of reductive elimination of thiolate ligands and simultaneous attachment of organic moiety on the growing nuclei. Gold(I) thiolate complexes with ammonium cations were useful for our preparative method. We now report the controlled thermolysis of gold(I) thiolate complexes, [R(CH3)3N][Au(SC12H25)2] and [R(CH3)3N][Au(SC6H4-p-R?)2] (R= C14H29, C12H25; R?= C8H17, CH3), under an N2 atmosphere, where the powder of gold(I) thiolate complexes completely melts to afford the precursor liquid and then the liquid gradually decomposes. In spite of no use of reducing agent and solvent, reduction reaction is thermochemically induced to afford novel gold nanoparticles passivated by alkyl groups rather than by alkanethiolate ligands. Figure 1a shows a typical transmission electron microscopy (TEM) image of gold nanoparticles prepared by thermolysis of [C14H29(CH3)3N][Au(SC12H25)2] at 180 °C for 5 h, indicating a controlled growth of spherical gold nanoparticles. As shown in Fig. 1b, these spherical gold nanoparticles display the size distribution ranging from 5 to 50 nm. Although the particle size is larger than that of thiol-derivatized gold nanoparticles (less than 5 nm) prepared by NaBH4 reduction (1-3), the aggregation of gold nuclei is smoothly regulated and the growth of core gold is limited to be 26 nm in average diameter in spite of thermal procedure.

Oct 1, 2003

By Hajime Miki, Michael J. Nicol

Relatively simple techniques have been developed which enable the electrochemistry of sulfide minerals to be studied with particles varying in size from above 100 pm to less than 1 pm. Both oxidative and reductive processes have been studied wing the minerals pyrite, arsenopyrite and chalcopyrite. It has been shown that it is possible to completely oxidise or reduce the minerals during a single voltammetic sweep. The resulting voltammogram produces peaks which are characteristic of each mineral and can be used to qualitatively identify the minerals. In the case of chalcopyrite, it has been demonstrated that the charge involved in the anodic oxidation can be quantitatively related to the amount of copper dissolved. Quantitative information can be obtained using peak fitting techniques. Interesting differences in the behaviour of the minerals in sulfuric and hydrochloric acids have been observed, particularly in the case of pyrite for which a second major peak is obtained which has been attributed to the oxidation of elemental sulfur in the presence of chloride ions. The technique offers the possibility of providing mineralogical information of individual particles based on an electrochemical voltammetic finger print.

Jan 1, 2005

By Jun Xiao, Yucai Zhou, Yanhong Dong, Daixiong Chen

"In this article research on the mineralogical characteristics and beneficiation process for a copper molybdenum deposits in Heilongjiang province of China has been carried out. Chemical analysis, X-ray diffraction(XRD) and Quantitative Evaluation of Minerals by SCANning electron microscopy (QEMSCAN) were conducted on samples. The bulk analysis results showed that: (1) Comprehensive recovery and separation of molybdenum & copper minerals was feasible by the flowsheet of first copper-molybdenum mixed flotation after grinding the ore samples to 61.88% -74µm and then separation flotation of copper and molybdenum after regrinding the Cu-Mo mixed concentrate to 83.26% -38 µm. The results highlight relationship between mineralogical characteristics of ore and comprehensive benefication method. (2) the combination of "" Sodium sulphide and sodium thioglycolate "" reagents are effective inhibitors of copper-molybdenum mixed concentrate, their selectivity performance is better than that of single reagent. Good flotation indexes were gained that might be directive experience to similar cases. KEYWORDS Mineralogical characteristics; molybdenite; chalcopyrite; flotation separation; inhibitor INTRODUCTION Copper and molybdenum metals are widely used in the field of metallurgy, aerospace, national defence, etc. Copper –molybdenum sulphide ore is an important source of copper and molybdenum metals. At present flotation is still the preferred methods to deal with the copper-molybdenum sulphide minerals (Yin, Z., Sun, W.et al. 2017; Ansari, A., & Pawlik, M. 2007; Hirajima, T., Miki, et al. 2017). Copper and molybdenum sulphide ores usually have the similarly good nature floatability(Miki, H., Matsuoka, et al. 2017), meanwhile most molybdenum sulphide ore has tiny grained-size(Castro, S., & Laskowski, J. S. 2015.) and closed relationship with other sulphide and gangue minerals which result in the coper and molybdenum separation problem. Base on the nature of the ore and flotation properties of the individual minerals contained in the ore, there are two methods are usually used to deal with the copper – molybdenum ore, including bulk molybdenum/copper flotation followed by separation of copper and molybdenum minerals, sequential molybdenum/ copper flotation(Liu, G. Y., Lu, et al. 2012). The latter method has the shortcoming of hard to activate the depressed copper minerals in the previous molybdenum flotation process, which may result in a large loss of the copper from concentrate, this disadvantage would avoid while adopting the former method. bulk flotation followed by separation process is to get the copper-molybdenum concentrate from raw ore first then separate flotation the molybdenum and copper minerals, benefit from the excellent floatability of both molybdenum and copper minerals ( Malhotra, D., Rowe, R. M., & Bhasin, A. K. 1986; Cao, Z., Yue, et al. 2017 ), it really easy to obtain the mixed concentrate. In order to get the high quality copper and molybdenum concentrate, the key technologies and difficulties are to realize the separation of the copper and molybdenum minerals which have the very similar natural floatability (Raghavan, S., & Hsu, L. L. 2015; Nakhaei, F. 2014)."

Jan 1, 2018

By Osvaldo Bascur, Laurent Garrigues, Nouna Kettaneh, Svante Wold

The chemical, oil, semiconductor, mining, and paper and pulp industries, as well as most other modern industries, are rapidly expanding the range of measurements used to characterize raw materials, process steps, intermediates, and final products. In addition, process variables such as temperature, pressure, and flow become more and more numerous, providing extra information on the state of the process. However, no matter how many sensors are added, the underlying sources of variations that drive the process behavior remain constant. On the other hand, the measuring frequency of these data has increased from once a day or once an hour to once, ten, or even hundred times a minute. This gives masses of data that are swelling in both directions (more variables and more observations). These data need to be properly stored, managed, and analyzed to provide diagnostics about the state of the process as well as an understanding of the relationships between different parts of the process and the product properties. Projection methods such as PCA (principal components analysis) and PLS (projection to latent structures) compress process data to informative summaries of the original variables. These can be shown on line, providing an efficient, graphically oriented suite of diagnostics regarding the "health" and performance of the process. The power of these methods is illustrated by two examples of industrial data in the mining industry.

Jan 1, 2000

By Y. Nakada, E. J. Fasiska, A. S. Keh, L. Zwell

DURING an investigation of solid-solution hardening of nickel by carbon,' we found that there were no reliable data on the dilating effect of dissolved carbon on the unit cell of nickel. Bernier2 reported an increase in lattice parameter of nickel (3.523A) when an unknown amount of carbon was introduced into solid solution (3.536A). Similarly KG, Tsien, and Misek3 found an increase from 3.523 to 3.531A when nickel was carburized. strong4 studied the variation of nickel lattice constant as a function of dissolved carbon. However, in his case carbon was introduced into nickel by solidifying the melt at 65 kbar. Therefore, his carbon concentrations were much above the highest equilibrium solubility limit5 (2.7 at. pct C at 1 atm). Knowledge of the lattice mismatch between solute and solvent is essential in understanding the mechanism of solid-solution hardening. Therefore, we decided to determine the dilation of the nickel lattice by carbon under the more usual conditions of atmospheric pressure. The material used was Inco Electrolytic Nickel of 99.95 pct purity, as specified by the supplier. The impurity contents in wt pct were: Fe, 0.01; Cu, 0.01; Co, 0.03; 0, 0.005; C, Si, S, N, trace. To this base material various amounts of AUC-grade high-purity carbon were added during vacuum induction casting. Ingots, 2 in. in diam, were heated in a muffle furnace at 1000°C for i hr., hot-rolled to 1/2-in. thickness, and quenched into brine. All ingots with carbon concentration greater than 0.98 at. pct were enclosed in a cast iron box during the heating to minimize decar-burization. Small pieces were then either swaged down to 0.028-in.-diam wire or cold-rolled to 0.010-in.-thick sheets. After the final cold reduction in area of 50 pct, the specimens were recrystallized by heating in evacuated capsules at 1100°C for 60 to 80 sec and then quenched into brine. The final grain size was 50 to 100 µ. The carbon contents of the alloys, Table I, were determined by a combustion method

Jan 1, 1969

In conjunction with steady increases in production levels, longwall operators have applied greater quantities of ventilating air and spray water in an effort to control respirable dust and/or methane. Air velocities greater than 7.6 m/s (1,500 )fpm) have been measured on longwall faces. Operators have expressed concern over the potential entrainment of respirable dust at these high velocities. The greatest likelihood for entraining dust into the high-velocity airstream may occur as shields are advanced, allowing relatively dry particles to fall from the shield canopy directly into the airstream. Laboratory tests to simulate dust liberation during shield movement were conducted at the Pittsburgh Research Laboratory of NIOSH at velocities ranging from 2.0 to 8.2 m/s (400 to 1,600 fpm). Airborne dust samples were obtained with personal impactors to quantify the size distribution and concentration of the dust entrained at the various air velocities. Statistically significant increases in both total and respirable dust concentrations were measured as test air velocities were increased.

Jan 1, 2002

By Miguel A. Cuba

Trends in the mean and/or variance are a longstanding challenge in mineral resource modeling. Geologic modeling and/or grade domaining are often employed to account for heterogeneities in mineral grades; however, this is only practical up to a certain point since the number of data available for reliable model construction can be severely reduced. In such cases, trends remain present in certain geologic/grade domains and directly impact the modeling methodology; the trend must either be handled explicitly or a suitable approach is adopted to implicitly account for it. This is highly dependent on understanding the source of the trend. We propose an approach that detects the source of non-stationarity, which is based on quantifying the impact of non-stationarity in the mean and the variance via the semivariogram. By expanding the methodof- moments approximation of the semivariogram, we decompose the experimental semivariogram is into three terms: 1) trend in mean component, 2) trend in variance component and 3) stationary component. We can then assess the source of trend by calculating the contribution of each component at every lag. Two cases are presented to illustrate this tool. Firstly, a synthetic reference model is simulated and different trend patterns are added; the influence of these patterns in the experimental semivariogram calculation are analyzed and discussed. Secondly, a real dataset is considered where the impact due to the presence of trends in the mean and variance are assessed. The results of this paper reveal the semivariogram to be a tremendously powerful tool in determining the source of the trend. This insight may be useful in the selection of a suitable modeling approach for resource estimation.

Oct 1, 2009

By S. Shapiro, G. Krauss

We will reply to Dr. Pitsch's discussion by 1) presenting in greater detail the single surface trace analysis which we performed on the reversed austenite plates in a single parent plate of martensite of known orientation, 2) relating the results of our analysis to the conclusions which Dr. Pitsch makes on the basis of our data, and 3) examining the validity of our selection of twenty-nine individual traces from the over 200 austenite plates which were observed in a surface of this single martensite plate. Fig. 7 shows a standard (001) projection of the martensite plate from which the austenite-martensite interface traces were taken. The traces are plotted on the projection as the small solid circles, and the great circles corresponding to the loci of plane normals which could contain each trace or could intersect the surface plane along the measured directions are also plotted. It can be seen that these great circles intersect at a point which corresponds to the normal of the surface plane on which the traces were observed. Also rate which occurred only at particularly low heating rates, see Figs. 1 and 3 in the paper.2 Since in this case the interpretation of Jana and Wayman is plausible and since we have no alternative to this interpretation, we would like to state only that the existence of a diffusion-controlled reversal at low temperatures seems to be not yet proved beyond any doubt. The author wishes to thank Professor G. Krauss for making available his manuscript prior to publication. It is also a pleasure to acknowledge the lively written discussions, which the author has had with Professors G. Krauss and C. M. Wayman prior to this communication. The financial support of the Deutsche For-schungsgemeinschaft for the work on which this communication is based is also gratefully acknowledged. plotted within small dotted circles which represent a i3 deg scatter in each of the twenty-four unit stereo-graphic triangles are our A and B poles7 and the pole P determined by Kessler and itsch.' The data presented in Fig. 7 permit a direct association of the measured traces and the various proposed habit plane poles for the reversed austenite plates in the martensite crystal. If the sample measurements do in fact

Jan 1, 1969

By R. O. Burt

The Tanco pegmatite is located in the Bird River greenstone belt of south-eastern Manitoba approximately 160 km northeast of Winnipeg (Figure 1). The orebody was discovered in 1929 and subsequently attempts were made to exploit it for tin by Jack Nutt Mines Ltd. and later in the middle 1950's by Montgary Oil Ltd., who extensively developed but did not produce from its lithium deposits. In 1966 systematic investigation of the pegmatite as a potential source of tantalum led to the founding of Tantalum Mining Corporation of Canada Ltd. (TANCO), and production of tantalum concentrates from the Bernie Lake mine commenced in 1969. Tanco's currently jointly owned by Hudson Bay Mining and Smelting Co., Cabot Corporation, and the Province of Manitoba.

Jan 1, 1988

By F. Habashi

The changes that took place in China between 1984 and 2004 are remarkable. Visits were made to universities, research institutes, metallurgical industry, and many cultural centers within five trips during this twenty years period. The impressions of these visits are outlined.

Jan 1, 2007

By J. Edberg

"This article details the use of an alternative testing method to the 2004 "Post-Tensioning Institute (PTI) Recommendations for Prestressed Rock and Soil Anchors" manual’s recommendations for temporary and permanent rock anchors for applications in shafts and tunnels. This method was developed and used for the Black River Tunnel (BRT) project in Lorain, OH as a means to reduce testing time of rock bolts during shaft construction while maintaining a similar level of quality control and assurance. The following sections will detail the project background, subsurface characteristics, shaft construction, the 2004 PTI testing method and associated difficulties, the alternative testing method and conclusions reached.Project backgroundThe city of Lorain is located in north central Ohio on the south shore of Lake Erie, approximately 40 km (25 miles) west of Cleveland and 119 km (74 miles) east of Toledo. The city chose to build a large-diameter storage tunnel and pump station to meet its requirements to reduce sanitary sewer overflows to the nearby Black River. NTH Consultants Ltd. (NTH) was retained by the city’s prime consultant, Malcolm Pirnie Inc. (now the water division of Arcadis), to perform a geotechnical investigation, develop design and construction bid documents for the tunnel and shaft liner systems and ultimately provide oversight assistance during the construction phase of the project.The BRT is an approximately 1,700-m (5,560-ft) long, 7-m (23-ft) diameter rock tunnel to be lined with a 5.8-m (19-ft) inside diameter secondary concrete lining (Fig. 1). The tunnel is designed to accept flow at a new drop shaft (Shaft 3) located on the west side of the Black River, across from the city of Lorain Black River waste water treatment plant (BRWWTP). The tunnel will be dewatered at the south end by a large diameter pump station (Shaft 1) located in the existing Lorain Port Authority Public Boat Launch. Flow from the new pump station will be discharged into an existing shallow interceptor sewer and directed back to the BRWWTP."

Jan 1, 2014

By Yang Cui

The partition ratios of lead and antimony between liquid copper and MgO saturated Cu2O-CaO-SiO2 flux and their removal rate by using CuCl-based flux were measured between 1423 K and 1573 K. For Cu2O-CaO-MgOsatd. system, the partition ratio of Pb was not affected by the CaO content at 1573 K, while that of Sb increased with increasing CaO content. The maximum value was 160 at the CaO content of 15.4 mass%. For Cu2O-CaO-SiO2-MgOsatd. system, two liquid phases of calcium silicate rich phase and Cu2O rich phase were observed at 1573 K. The partition ratios of Pb and Sb between calcium silicate phase and liquid copper depended on the (mass%CaO)/(mass%SiO2) ratio. When the (mass%CaO)/(mass%SiO2) ratio increased, the partition ratio of Pb decreased and that of Sb increased. For CuCl flux, the removal of Pb from liquid copper at 1473 K was possible, and a relatively low concentration could be reached. Moreover, most of lead as metal chloride vaporized from flux. For the removal of antimony from liquid copper at 1423 K, it was difficult by CuCl flux, and the removal ratio was approximately 20% for 75 minutes. However, the addition of CaO or Na2CO3 to CuCl flux was relatively effective to remove antimony, and the concentration of antimony reached a relatively low value after 15 minutes by using CuCl-CaO or CuCl-Na2CO3fluxes. Moreover, a small part of antimony as chloride vaporized from flux.

Jan 1, 2006