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By Arthur S. Coffinberry, Ralph Hultgren

We have studied the gold-aluminum system by X-ray diffraction and by the microscope over the entire range of composition for temperatures between 300° and 500° C. Results obtained are shown in Fig. 1, combined with the work of Heycock and Neville1 at higher temperatures. The diagram differs in important details from that given by Hansen2 in his critical compilation of the literature of binary alloy systems. This work was undertaken both because of the intrinsic value of a knowledge of the phase diagram of this system and because of the need of theoretical metallurgy for precise and accurate data, particularly X-ray diffraction data. Systematic studies of equilibrium diagrams, particularly by Hume-Rothery,3 have shown regularities that yield a certain insight into the nature of alloying forces. It has been shown, for example, that solid solubility depends on the concentration of free electrons in the alloy, on the relative radii of solvent and solute atoms, on the forces of attraction between atoms, and on the relative stability of intermediate phases. The well-known Hume-Rothery rule states that the crystal structures and compositions of many intermediate phases depend on the electron-to-atom ratio. This has been confirmed and extended by wave mechanical calculations.4 A knowledge of the forces between atoms in alloys, even an imperfectly developed empirical one, should be a valuable guide in the preparation of technological alloys of desirable properties. Furthermore, such information is basic in such problems as rate of diffusion, age-hardening, phase transformations, and others. The most valuable data for this purpose are furnished by X-ray diffraction studies. Unfortunately, work has been

Jan 1, 1938

By C. M. McCulloch

The methane content of virgin bituminous coalbed can now be measured accurately in the field with exploration core samples from vertical boreholes. The gas content of the coal per unit weight can be used either to design a mine ventilation system or to determine if degasification of the coalbed will be necessary before mining, and to determine the gas resources in the coalbed. The equipment necessary to conduct the test costs less than $50. The gas con-tent of the coal in place in the ground is determined by summing the gas lost from coring, gas measured during desorption, and the residual gas in the coal. Upon removal from the borehole, the core sample is placed in an airtight container and des orbed for several weeks until the desorption rate is below 0.05 cm3/g for 5 consecutive days. The gas lost from the core while it was being cored and the residual gas are estimated by a new graphical method. The amount of gas remaining depends upon whether the coal is friable or blocky. Friability appears to relate to the depth of the sample below the surface, fixed carbon percentage, Hardgrove grindability index, and proximity to tectonic disturbance. Friable coals emit nearly 96 pct of the total gas during desorption whereas a blocky coal emits only 60 pct of its total gas. Coalbeds that are ill defined as to their blocky or friable nature must be tested in the laboratory for unambiguous analysis.

Jan 1, 1975

By R. L. Morse

The thermodynamic program is similar to previous mine ventilation programs but has been expanded to consider the compressibility of air. The thermodynamic program does consider: 1) air density variations, 2) humidity changes, 3) intake, exhaust, and underground fans, 4) heat transfer between rock and air, 5) refrigeration of heating plants, both surface and underground, and 6) heat generated by equipment, both diesel and electric. 110st of the compressibility factors are handled in the branch calculations. The field survey necessary to supply-data for this program is quite similar to the basic base and leap-frog pair of stations method used with most incompressible mine ventilation programs. The thermodynamic program is a complete package of ventilation network analysis which can provide mine management with good operational control and planning of mine ventilation systems.

Jan 1, 1977

By Analy Flores, Victor Camavilca, Danny Valencia

Desde el punto de vista social, el Empleo Local es uno de los temas más sensibles que hay manejar durante la vida de un proyecto minero. Su abordaje conllevará necesariamente a implementar estrategias que a la vez garanticen “la preferencia en la contratación de mano de obra local” y “candidatos que cumplan los perfiles de puesto requeridos por la operación”. Ambos aspectos, pueden contraponerse en algún momento debido a las presiones comunales o a las urgencias operativas.

Sep 1, 2017

By B. S. Kim, Y. D. Kim, T. S. Kim, T. B. Kim, H. J. Chae

"The Nd-Fe-B scrap was placed in Fe crucible with pure Mg in an Ar atmosphere, and the scraps were melted using an induction heating method. The effects of experimental parameters such as melting temperature (range of 993K to 1073K) and holding time (15min-600min) on the ability of extraction were investigated. The microstructure and diffusion layers were analyzed by Scanning Electron Microscopy (SEM) and Energy Dispersive Spectroscopy (EDS), and the constituent phases were characterized using XRay Diffraction (XRD). Diffusion of Nd through the Nd-Fe-B scrap into liquid Mg was described, and the diffusion coefficient of Nd in liquid Mg was estimated.INTRODUCTIONNd-Fe-B magnets are usually produced either from comminuted melt-spun ribbons as bonded magnets or hot pressed bulk magnets, or by sintering in conjunction with prior green compaction in an applied magnetic field (Sagawa et al., 1984). These magnets have been widely used for various electromechanical and electronic devices such as voice coil motors (VCMs) and magnetic resonance imaging (MRI) (Samardzija et al., 2012; Matsuura et al., 2006). The production of the Nd-Fe-B magnets is increasing by about 20% per year because of their excellent magnetic properties. However, the expansion of Nd-Fe-B magnet market induced a concern for the scarcity of Nd at the aspect of natural resource. Therefore, the development of an effective recycling process for Nd-Fe-B magnet scraps is an extremely important issue from the viewpoint of resource and energy conservation. Several recycling processes for the Nd-Fe-B magnets have been proposed (Uda et al., 2002; Lyman et al., 1993]. It has been reported that the best separation of rare-earths from the Nd-Fe-B magnets is obtained by sulfuric acid dissolution followed by precipitation of recyclable rare-earth salts. However, this process can make a large amount of waste water including dangerous solutions. Recently, (Xu et al., 2000) have reported a technique to extract Nd from 18Nd-72.4Fe-0.9B-1.82Pr-5.3Dy (wt.%) magnet scrap by using liquid metal extraction (LME) processing. However, these techniques seemed to be difficult for application, because the scraps consist of an infinitesimal amount of other minor elements (Pr, Dy, Cu, Al and Tb), and these minor elements can make a new intermetallic compounds with Mg. Also, some oxides or the plated Ni metal can be preventable to reaction between solid-liquid (S/L) interfaces. For these reasons, the substantive reaction mechanism between Mg and Nd-Fe-B scrap is not clear. In this study, the simple composition of 33Nd-66Fe-1B (wt.%) magnet scraps were prepared using an induction melting process. The effects of the experimental parameter on the diffusion properties between Mg and scraps were investigated to determine whether these methods could be used in industrial application in a liquid metal extraction (LME) process."

Jan 1, 2012

By S. Ramachandran, L. A. Vazquez, N. L. Grauerholz

A novel process is described for the selective flotation of scheelite from low-grade (- 0.5% W03) tungsten ores having appreciable quantities of calcareous and siliceous gangue minerals. Specifically developed for the Tempiute, Nevada facility of Union Carbide, the process yields tungsten concentrates exceeding 15 percent W03 with at least 85 percent recovery. This condition was not achieved through conventional processes. This process consists of conditioning the ore pulp with judicious amounts of lime, followed by soda ash and sodium silicate as modifiers. The scheelite is then floated using a mixture of oleic and naphthenic acids as collector. Contrary to the common observation as to the deleterious effects of calcium in fatty acid flotation systems, lime addition is found to be beneficial in achieving satisfactory results. The process has also shown excellent results on a Brazilian scheelite ore.

Jan 1, 1976

By W. A. Bruce

This paper covers the theory and present state of development of an apparatus for the nonmathematical analysis of complex problems of reservoir and well behavior. At the present stage of development of this apparatus, it is capable of solving the water-drive problem of any reservoir performance for which a mathematical solution has been presented in the literature, either on the basis of steady or unsteady-state flow analysis. The theory is presented for the extension of the scope of this analyzer along the lines of the present development. The resulting apparatus should be able to solve reservoir-performance problems previously thought too difficult for practical solution by mathematical means. As an illustration of its operation and present scope, the analysis of a reservoir problem and synthesis of expected performance is presented. Introduction In this method† of analyzing problems of petroleum-reservoir and well behavior, the porous continuum of the reservoir is assumed to be divided into small blocks, or units. Each block is assumed to be small enough so that for a material balance on the fluids in the block an average pressure for the block can be used. In analyzing reservoir behavior from this point of view by mathematical means, a set of simultaneous difference equations would be obtained (two for each block), which must be solved or combined into a partial differential equation. In the method to be described here, instead of solving these sets of equations analytically, electrical units are constructed, which will behave in respect to the flow of electricity exactly as the reservoir units behave under various conditions of fluid flow. The electrical units are then wired together in the same way that the reservoir units are connected naturally by virtue of their geometrical locations and shapes. Fluid-Flow Equations Consider a block in a reservoir. Assume that reservoir fluid (or fluids) is flowing in at one face and out at the opposite face, and that the block is small enough so that at all points the stream lines are within one degree of perpendicular to the face. Furthermore, assume that the pressure, pi, at the upstream face (Fig, I) is not more than one per cent greater than P2 the pressure at the downstream face. A material balance will show that the mass of fluid flowing out less the mass of fluid flowing in will equal the change in density times the fluid volume. This is expressed in the equation:

Jan 1, 1943

By I. D. Shah

The copper-nickel ore of the Duluth Gabbro Complex in northeastern Minnesota is a large potential domestic resource of cobalt and platinum-group metals. However, because of the low grade of the primary metal values (0.5 pct Cu, 0.15 pct Ni), the private sector has assigned a relatively low priority to the development of technology for processing this ore, anticipating that mining probably would not begin until the mid-1990's. Furthermore, preliminary processing flowsheets considered by the mining companies centered on the primary metal values. As part of an effort to help provide the basis for technology to recover critical and strategic minerals from domestic resources the Bureau of Mines is investigating methods to recover all of the mineral values, in the Duluth Gabbro material, with particular attention to the byproduct critical minerals. A key step in this process is the removal of a relatively large amount of iron present in the bulk sulfide flotation concentrate to permit subsequent extraction of mineral values. This report describes a direct smelting method that removes most of the iron and produces a copper-nickel-cobalt matte, an intermediate product from which the metal values subsequently are separated. Copper, nickel, and cobalt grade and recovery data are presented for the direct smelting method. Test results showed that under certain conditions some of the mineral values reported to the slag, requiring slag cleaning to recover them.

Jan 1, 1983

By J. M. Pugliese

The U.S. Bureau of Mines is developing designs and estimating costs for vertical in situ copper mining wells as part of its in situ mining research program. Conceptual designs and estimated costs for "deep" 1100 m (3600 ft) recovery and injection wells in an undisturbed copper ore zone are presented. Within a single in situ copper mining well, multiple perforated well completions and associated costs are discussed for two ore zones between depths of 370 m (1200 ft) and 550 m (1800 ft). The order of well specifications for designing these wells is explained.

Jan 1, 1995

By Chang Chia -Fu

The generic structure of our bimesogens is shown in and for a typical blue-phase mixture of the type we describe here. We use mixtures of the ratio 33.4% (n =2.6), 34.1% (n =6.57), 36.6% (n= 11.15) with of the high twisted power (HTP) agent BD H1381(available from Merck Chemicals and described in ref. We then studied the electric-field dependency of the selective reflection in BP I* at 20.7 °C by applying increasing and the decreasing pulsed alternating current (a.c.) electric fields (100 Hz).

Jan 1, 2006

By M Brady

"It has long been recognised that the barometer infl uences areas of underground coal mines that havebeen sealed off from the current, or active, mine workings but it appears litt le formal research hasbeen done on how the barometer aff ects the goafstream sample point. Based on statistical analysis of samples from a number of mines from Queensland and New South Wales it can be concluded that there is a direct correlation between the barometer and oxygen concentration at a goafstream sample point. To help mitigate some of the high consequence hazards within the underground coal industry and protect the health and safety of the persons within that environment, many monitoring tools are utilised. A control recognised in management plans prescribed under New South Wales and Queensland legislation is the need to conduct monitoring to identify the early warning signs of spontaneous combustion. One of the monitoring tools utilised involves a bagsample being collected from a goafstream sample point then returned to the surface for analysis.When the sample is incorrectly collected, the resultant analysis from a gas chromatograph provides litt le value to the persons charged with the obligation of operating the coal mine at an acceptable level of risk. This, therefore, increases the probability of spontaneous combustion leading to a loss of equipment, mine and in the worst case, life. When the sample is collected correctly, the analysis presents early warning signs of low level oxidation allowing corrective action to be taken, to prevent the oxidation accelerating to spontaneous combustion. The eff ect the barometer has on this sample point should be recognised and the knowledge imparted to persons who conduct sampling to remove a variable in the bag sample collection process. This will ensure the persons operating the mine have a bett er understanding of what is happening within their longwall goaf."

Jun 1, 2012

By X. T. Zeng, X. Z. Ding, W. R. Chen, L. R. Zhao

The effect of deposition defects in metal nitride coatings on erosion behavior is presented. AlCrN, AlTiSiN, TiSiN and TiSiN:MoS2 coatings were fabricated by reactive cathodic arc evaporation and unbalanced magnetron sputtering processes. The microstructure and mechanical properties of the coatings were characterized by X-ray diffraction, scanning electron microscopy and nanoindentation, and the erosion property was assessed by solid particle impingement testing. The erosion characteristics on the coating surface and cross section were analyzed and correlated to the defects, which played an important role by promoting formation of erosion pits.

Jan 1, 2006

By Upali Siriwardane, Tushar V. Kudale, Naidu V. Seetala

"Cellulose acetate (CA) membranes with 25% triethyl citrate (TEC) as plasticizer were prepared with varying thickness for CO2 gas separation from water-gas-shift (WGS) reaction products. The AFM analysis of the CA membrane showed that the uniform coating had fewer and smaller pores as the film thickness increased, and corroborated by gas permeability studies. The CO2 permeability has decreased faster than CO permeability with the CA/TEC membrane thickness, and findings support that the CA membrane could be used to entrap CO2. Several CA/TEC membranes were also staked to increase the separation efficiency. Positron Annihilation Lifetime Spectroscopy (PALS) was used to estimate the nano-porosity (pore size and concentration) changes of CA/TEC films. PALS results show a decrease in pore size with increasing CA-TEC concentration in acetone, while the pore concentration increases. The PALS results are correlated with the CO2/CO permeability variations as the CA-TEC concentration change.IntroductionHydrogen is one of the main energy sources available for the future advancement of clean fuel technologies especially for fuel cells. Generation of hydrogen and CO2 from Water Gas Shift (WGS) reaction mixtures of CO and H2O is of interest to many researchers since it allows a large scale production of hydrogen [1, 2]. Once hydrogen is produced using the WGS reaction, the output products contain mixture of CO, CO2, H2, and water vapor. Metallic membranes have been used as hydrogen separation membranes [3-6]. As H2 is separated from the mixture using the metal membranes, we need to separate CO2, and find ways of sequestration of CO2 to avoid environmental problems by greenhouse gasses. Polymeric Membranes have been used for CO2 separation [7]. Plasticizer can control the micro-structural properties such as pore size and concentration of polymer membranes [8], which influence the size/molecular weight dependent diffusion rates of the gas molecules. We have used cellulose acetate with triethyl citrate as plasticizer to separate CO2 from the WGS reaction products. Positron annihilation lifetime spectroscopy (PALS) is very sensitive and able to identify different kinds of defects and their agglomerates such as vacancies, vacancy loops, and voids [9, 10]. PALS has been successful in determining the free volume in polymers that influence the properties of the polymers [11, 12]. Microscopic properties of the free volume obtained from PALS have been correlated to macroscopic properties [13, 14]. We used PALS to study the nanoporosity (pore size and concentration) and fractional free volume changes of CA/TEC films, and used to understand the variations observed in the CO2/CO permeability as the CA-TEC concentration in the membranes change."

Jan 1, 2014

By Maurice C. Fuerstenau, Bruce R. Palmer, R. E. Johnson, B. R. Palmer, G. W. Warren

The environmentally sound processing of metal-bearing chloride solutions plays a key role in the extraction, plating, recycling, finishing and surface preparation of metals. Additionally, many chloride-bearing waste streams must be processed to obtain environmentally acceptable products. This paper reviews the technologies used for processing aqueous metal-chloride solutions and describes the challenges that have been overcome in application of these technologies.

Jan 1, 1993

Stuart Manwaring Buck, a member of the Institute from the first year of its existence, and one of its Managers from 1883 to 1885, died at his home in Bramwell, West Va., on July 16, 1921, at the age of 79 years. He was the son of David and Matilda S. Ruck of Boston, and was educated at Williams College, at the Massachusetts Institute of Technology and at the School of Mines at Freiberg, Germany. Mr. Buck was one of the pioneers in the development of the coal fields of West Virginia. From 1872 to 1877 he was connected with the Kana-wha and Ohio Coal Co. as engineer and as lessor; from 1877 to 1888 he was general manager of the East Bank Coal and Coke Co.; from 1888

Jan 1, 1922

By Yin J, Sun H

A new technology has been introduced - the use of the High-Water Solidifying Material for providing pumped roadside supports to maintain a roadway for re-use in longwall retreating. As a gob edge support, its initial use at Hebi No. 1 Colliery was successful, providing acceptable performances in support and control of convergences and lateral closures of the gob-edge roadways. This acceptability applied to both first use and re-use when the roadway became a gateroad for the adjoining longwall, remaining stable throughout the associated loadings and convergences. The technology promises economic and social benefits.

Jan 1, 1992

By Jorge Tramaglia

En la naturaleza existe elementos radioactivos naturales conocidos por las siglaS NORM ( naturally occurring radioactive material) que desde su origen en el reservorio, se movilizan acompañando al petróleo hasta las instalaciones de proceso en superficie. En ese sentido, el presente texto señala la radioactvidad de esto materiales, transporte y acumulación, procesos de separación, valores de contaminación, las formas de irradiación y la espectometría.

May 1, 2015

By Shan Mafi

he Broken Aro coal mine is located at the Woodbury Wildlife Preserve 11 km (7 miles) west of Coshocton, OH on State Route 541. Underground min¬ing at the 16-hm2 (40-acre) site took place during the 1910s. During the past five years, surface mining has occurred along the western and northern perimeters of the underground region. The Ohio Department of Natural Resources (ODNR), R&F Coal and American Electric Power (AEP) are involved in a project to remine the abandoned underground complex. The program also includes installing a mine seal made of fixated flue gas desulfurization (FGD) material. Previous mining activity in this area has resulted in an acid mine drainage (AMD) problem on portions of the reserve. In particular, a prominent AMD source is present in the Simmons Run drainage. The project goal is to eliminate or reduce the AMD that is discharging into the watershed. It was initially hoped that the Simmons Run drainage area could be economically mined. Accordingly, this area was included in the mine permit. However, experience with other previously mined areas on this reserve showed that the old mine workings were more extensive than originally thought. Old mine workings present several problems. The most significant are reduced coal recovery, poor coal quality and AMD liability. All of these problems increase mining costs. And the more extensive the old workings, the more significant the increase in cost. Based on R&F's experience with old mine workings in this area, it was decided that economic recovery of the Simmons Run drainage reserve was not possible. As a result, R&F excluded the Simmons Run drainage area from its early mine plans. Some time after it was decided not to affect the Simmons Run drainage area, R&F and ODNR's Division of Mining and Reclamation discussed the possibility of removing this area from the permit and attempting to correct the AMD problem as an Abandoned Mine Lands (AML) project. Specifically, the discussion centered around mining through a portion of the old mine workings to expose the mine openings in the highwall. Once exposed, the mine openings would be sealed using FGD material from the nearby Conesville power plant operated by AEP. In addition, there was interest in reclaiming the old tipple and associated gob pile located adjacent to Coshocton County Road 17 on the opposite side of Simmons Run. R&F attempted to eliminate the AMD problem by sealing the mine openings with FGD material. Once the seals were installed, they were covered with overburden. Monitoring wells were installed to determine the effectiveness of the seal and the inundation progress in the old mine workings as well as monitoring the quality of ground water. The project was jointly funded by revenue from the sale of the coal recovered during the project and AML funds. The FGD seal is expected to cause well water levels to increase above preseal elevations. However, the additional head pressure due to increased water depths in the underground mine may cause seepage through the bottom of the mine or out through the perimeter. The in¬creased water depth in the underground mine is expected to cause lower oxygen concentrations in the underground mine water. Since acidity is produced by oxidation of iron pyrites, less oxygen should result in better quality water. Monitoring wells will be installed before seal installation so that pre- and postseal water levels and well water quality can be determined. Surface sampling locations will be identified. These will be monitored before and after seal placement.

Jan 1, 1998

By Jerry Demchuk, Allan Flemming, Stephan Day

Luscar Ltd. is currently developing open pit mining plans for the Telkwa Coal Project. Most waste rock is predicted to be non-acid generating but a proportion (less than 20%) is potentially acid generating. The waste management plan includes in-pit and ex-pit disposal of blended and till-capped waste rock, segregation and in-pit encapsulation of strongly potentially acid generating materials, and in-pit underwater disposal of coarse and fine tailings. The paper will present the steps used to design the waste management plan including the development of geochemical design criteria using various tests and theoretical and practical knowledge of waste behaviour.

Jan 1, 2000

By J. le Grange, M. Tullmin, A. Strauss, F. P. A. Robinson, C. A. O. Henning

An experimental feritic stainless steel with a chromium content of 40 per cent was welded by laser and electron beam (EB) welding processes. These techniques were found to be particularly suited to the welding of this alloy in that the impact toughness of the weld metal and heat-affected zone (HAZ) of the laser welds compared favourably with those of the parent aloy. When the EB process was used, the impact toughness of the weld metal was over 180 J/cm2. Grain growth in the HAZ was minimal for welding with these two processes. Corosion tests, conducted in a solution consisting of 20 per cent sulphuric acid and 100 p.p.m. of potassium thiocyanate, and In a highly corrosive industrial solution, indicated that the laser and EB welds were free of sensitization effects, thus confirming the metalographic results.

Jan 1, 1989