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By Peter Faust, Jeremy Zorne, Timothy Siegel, Diane Fiorelli

Professional sport venue construction follows a very simple rule. Once the decision has been made to move the team to a new place, construction shall begin immediately, so that not more than one or two seasons pass by stuck in the old home. Such tight construction schedules require a different approach than traditional design-bid-build contracts. Design is mostly done on the fly, the construction schedule becomes a main risk factor and an early contractor involvement is desired. As specialty contractors become more and more sophisticated, owners, their construction managers or the general contractor have realized the value of ideas and modern technology they can bring to the table for a successful and fast project completion. Local knowledge and experience in a variety of solutions play a key role in the specialty contractor’s ability to provide added value to the project. This is also true for the specialty foundation contractor, who needs to understand the complexity of such modern structures from its integrate foundation, over the delicate concrete structure to a potentially fancy movable stadium roof. Not to mention all the modern high tech equipment which shall make such a place a great customer experience. His expertise shall enable him to propose the most suitable foundation element for the given ground condition and application. Rather to build what others have designed, his strength is to propose alternate concepts which will be faster and (hopefully) more cost effective. This paper highlights different value engineering (VE) input a specialty foundation contractor had on 3 major sports arena projects in California. Together with the entire team from owner to GC, including the Geotechnical (GEOR) and the Structural Engineer of Record (SEOR), the most efficient and best performing foundation solution can be found every time. But such an approach also requires the open mind of the owner to entertain last minute changes when the permit drawing set has already been submitted for approval.

Jan 1, 2018

By S. W. Hazen

The use of operations research and computer techniques continued to expand during 1967. A number of mining companies either obtained computers or were experimenting with their use through service bureaus. This trend was also evident in the Canadian mining industry. Although the annual Symposium and Short Course on Computers and Operations Research in Mineral Industries was not held in 1967, technical periodicals like MINING ENGINEERING, Mining Congress Journal and Engineering and Mining Journal stepped up their coverage on the subject. The annual AIME meeting had eight papers in two sessions and one session on Operations Research was held at the SME Fall Meeting in Las Vegas.

Jan 2, 1968

By Mario A. Terceros H., K. Rainer Massarsch

"ABSTRACTThe Expander Body (EB) technology has been used successfully to increase the pile toe capacity of bored piles in loose to medium dense soil. An important advantage of the EB system is the ability to monitor the EB expansion process, which provides important information regarding soil strength and soil stiffness. This information, obtained for each installed pile, can be used to determine the actual shape and pile toe area. The expansion pressure can be used to design the pile base capacity.The Expander Body system has been recently improved by incorporating the possibility of post-grouting of the soil below the expanded pile toe. This improvement measure provides additional strength and stiffness to the pile toe and reduces pile settlement.The shaft bearing capacity of bored piles can be increased by using a soil displacement auger, which avoids soil decompression and increases lateral soil stress. This paper describes the principle of the EB system. During the past 20 years, a large number of EB piles have been installed in Bolivia and elsewhere, providing a sound database. Results from field loading tests are presented. A comprehensive study of test piles with and without EB base has been carried out which demonstrates the improvement effects that can be achieved by the EB pile system and the combination with the displacement auger pile method. A design concept for the EB pile system with the full displacement auger pile is presented. A high degree of quality control can be achieved by monitoring the entire pile installation process, including the displacement pile and the Expander Body.1. IntroductionIn many regions of South America, soil deposits consist often of predominantly loose to medium dense sands and silts, often with high groundwater table. In the Santa Cruz area in central Bolivia, such soils are frequently quaternary sediments, deposited by the river Piray. The city of Santa Cruz is located at the right bank of the river.The most common deep foundation method during the last 30 years has been cast in situ piles, augered and concreted under support of bentonite slurry. The design of such piles has been based on SPT results. However, SPT is often performed without quality control and the reliability of geotechnical data is therefore often poor. Traditional methods of pile installation with simple well drilling equipment of insufficient capacity are frequently used. Such methods lack basic requirements of quality control. Such piles have usually low toe resistance and work mainly by shaft resistance . Although the construction process and materials are cheap, the final product has variable and limited capacity. However, the most serious deficiency is that actually achieved pile capacity and pile settlement can be erratic and difficult to predict, leading to uncertainties with regard to actual foundation performance."

Jan 1, 2014

By J. Klemenic

This paper presents an analysis of gold production and prices over an extended period. Production patterns are provided for the world as a whole and for the five major producing countries. Gold prices as a function of interest rates, as measured by municipal bond rates, are given for the period 1947 to the present. World gold production has had a phenomenal increase since 1980, with the exception of South Africa, all major producing nations participated in this increase, even though the price of gold generally has been decreasing since the high level attained in 1980.

Jan 1, 1993

By R. I. Rodriguez

Since the 1973 energy crisis, high fuel oil costs have been eroding the economics of the Nicaro and Punta Gorda Plants that employ the Caron Process for laterites processing. Since 1995, Cuban crude oil production has growth dramatically, with progressive utilization in power generation, cement and nickel plants. This paper shows how Nicaro and Punta Gorda plants have been able to shift from expensive Bunker C Fuel Oil to heavy but cheaper Cuban Crude Oil of high Sulfur content and achieve a significant reduction in operating cost. Problems related to the high sulfur content of the Cuban crude oil have demanded extensive investigations of the process chemistry and novelty solutions are proposed, with corresponding changes in process conditions. Innovative options are shown that will allow further cost reductions in the future. Keywords: Cuban Crude Oil, Sulfur, Ammonia.

Jan 1, 2004

By I D. Hair

A numerical groundwater model was used to predict the nature of interactions between heavy mineral sands mining operations and the groundwater regime at North Stradbroke Island, Southeast Queensland. North Stradbroke Island is formed mainly of massive vegetated Cainozoic aged dune sands. Since the 1950s, a number of operations have mined rutile, zircon and ilmenite on North Stradbroke Island. In such mining operations, a dredge and an associated processing plant are floated in a pond either above or below the prime groundwater table The numerical model was based on the North Stradbroke Island Groundwater Management Model, developed in 2001 by the Department of Natural Resources and Mines (NR&M). This model was constructed using the modular, cell-centred, finite-difference groundwater flow model, MODFLOW, developed by the United States Geological Survey (USGS). The NR&M model was refined to improve model resolution and detail for simulating dredge mine paths. Of particular interest were: water table fluctuations induced by mining for the identification of slope stability risk; the optimisation of sand spear arrays supplying mine make-up water requirements; inflow and outflow rates to the dredge pond for overall mine water balance; and interactions with Eighteen Mile Swamp and water supply bores controlled by the Redland Shire Council (RSC). Depending on the water level in the dredge pond compared with the surrounding groundwater table, water either flows out of the dredge pond into the groundwater regime or from the groundwater system into the dredge pond. The MODFLOW river package (RIV) was utilised for the modelling study. Dredge pond movement was simulated using specialised software developed by Watermark Numerical Computing (WNC) to interpolate pond positions and map the dredge path to the model grid both spatially and temporally. As tailings placement affects the groundwater system through increased recharge, the MODFLOW recharge package (RCH) was utilised to simulate different recharge efficiencies. Long-term model predictions were made for the period from July 2002 to May 2021. Results of the modelling showed that exchanges of flow between mining operations and the groundwater regime could be effectively managed. The study provided valuable information which was used to develop an appropriate mine water management plan.

Jan 1, 2003

By Yixian Zhao

Although many ultimate pit limit design algorithms have been developed for the past one- quarter century, only the well known Lerchs-Grossmann's (LG) algorithm is capable of producing a truly optimum ultimate pit limit today. This paper presents a graph theory oriented algorithm for optimum ultimate pit limit design. This algorithm produces a true optimal solution and maximizes the total undiscounted net profit for a given 3-D block mine model. The algorithm performs much better than the well known LG algorithm, in terms of the reduction in computation time and computer memory requirements. More importantly the new algorithm is easier to understand and implement than the LG algorithm. Specifically, this paper discusses: 1) the computer representation of arcs and the rules of arc generations which dictate the formation of trees in the graph, 2) the mechanism of joint support and re-allocation, 3) the properties, the general procedures of the algorithm, and the suggested specific steps to implement the algorithm, 4) comparison between the new algorithm with LG algorithm, and 5) some experience in implementation of the algorithm and two case study results.

Jan 1, 1992

By M. Katzer, R. Klimpel, J. Sewell

The effect of using selective dispersants as wet grinding aids for ores is demonstrated on laboratory scale batch and continuous grinding equipment. A complete characterization of behavior is performed on a given ore to demonstrate correlations involving torque, % solids, net production rate, and slurry weight and volume loading. The relationship between such laboratory data and industrial scale testing results is very consistent.

Jan 1, 1982

By Y. J. Wang

Stall or aerodynamic stall of axial-flow fans has long been recognized as an important operational problem in mine ventilation. To develop a technique for characterizing fan stall in multiple-fan ventilation networks, a research project was initiated through the Generic Mineral Technology Center for Mine Systems Design and Ground Control. Considering that fan stall is related to multiple operating points, this paper discusses a numerical model for multiple-fan ventilation networks, design of the experimental setup for two-and three-fan ventilation networks, and numerical methods for solving multiple networks solutions. It is hoped that the results of this project will lead to an innovative method of ventilation network analysis and simulation, thus preventing stall.

Jan 1, 1991

By W. S. Landers

In contrast to the large fund of information available on the carbonizing properties of Eastern U.S. coals, the experimental data available for most Western U.S. and foreign coals are meager. To supply some self-consistent data, the Bureau of Mines conducted 220 low-temperature carbonization assay tests at 500° C. in a laboratory-scale carbonization apparatus. The results are included in this report. The U.S. coals tested are from Alaska, Arizona, Colorado, Illinois, Montana, New Mexico, North Dakota, Pennsylvania, Ohio, Texas, Utah, and Wyoming. Assays were also made on coals from Canada, Ecuador, France, Greece, India, Mexico, the Philippine Islands, Thailand, and Yugoslavia. In addition, one assay of pine sawdust and one assay of a peat from Ireland are reported. Prediction equations were developed relating the yield of products of carbonization obtained at 500° C. in the assay unit to the proximate and ultimate analyses of the coals. The equations for predicting the yields of tar plus light oil, char, and gas, and the heating value of the gas, are considered good, each equation having a multiple correlation coefficient of 0.90 or higher. The equation predicting volume of gas obtained upon carbonization is considered as fair, with a multiple correlation coefficient of 0.84. A reproducibility study of the assay made on 10 replicate samples of a subbituminous coal indicated that the standard deviation of the individual products was 0.31 percent or less.

Jan 1, 1961

By Levent Ozdemir, Charles Merguerian

Between 1996 and 1999, a high-performance Robbins TBM [235-282] excavated a 5 mile long, 23´2? wide, and ~700´ deep tunnel through the subsurface of southwestern Queens. Low penetration rates (~6´/hr [actual] vs. ~9´/hr [anticipated])resulted from changed rock mass conditions mostly attributable to high-grade metamorphism of the rocks. Over a three-year period, as-built circumferential geologic mapping (scale 1?=10´) and digital imagery of the tunnel, fracture and fault analysis, structural, lithologic, and petrographic studies have shown that the rocks of the Queens Tunnel consist of orthogneiss of mesocratic, leucocratic, and mafic composition. These metaigneous rocks developed coarse-grained fabrics during Grenvillian (~1.0 Ga) granulite facies metamorphism, and retained their nearly anhydrous, poorly foliated character during subsequent high-grade Ordoviciande formation. Lacking a penetrative foliation, the coarse granoblastic rock texture and extraordinary garnet content (up to 50% in some zones) together proved animpediment to efficient chip production and resulted in bimodal production of blocks and excessive fines. TBM excavation of the Queens Tunnel was also hindered by geological conditions that included unexpected lithology and rock fabric orientation, a zone of crosscutting hypabyssal rhyodacite dikes, and unanticipated extent of brittle faults. The dikes and brittle faults produced blocky ground conditions and a collapsing face condition that produced cutter damage and decreased utilization. Such fundamental textural, mineralogic, and lithologic control over hard-rock TBM penetration can be predicted by careful pre-bid geological analysis. To determine the causes of lower than anticipated TBM performance, a detailed investigation was carried out that included analysis of operational data from the TBM data logger and an extensive laboratory test program on cores retrieved from tunnel walls. Integrated laboratory testing included punch, point load, tensile strength, Cerchar abrasivity, and linear cutting tests, independent petrographic analysis and machine performance analysis. These allied investigations have provided quantification that the rock mass exhibited an unusually high degree of toughness and rock directional properties and established geological causes for decreased TBM penetration rates.

Jan 1, 2003

By R. P. Agarwala, M. S. Anand

Using residual activity technique, the diffusion of palladium, silver, cadmium, indium, and tin in alunzinum has been studied in the temperature range of 400" to 630°C. The diffusivities (in units of square centimeters per second) have been expressed as: IMPURITY diffusion in aluminum,1-9 silverand lead5 for cases of low solid solubility of the impurity in the host metal has yielded frequency factors in the range of l0-6 to l0-9 sq cm per sec whereas the activation energy is practically half the self-diffusion activation energy value. From the observed values of frequency factor, activation energy, and entropy of activation, it has been suggested' that these solutes are not diffusing by vacancy or interstitial mechanisms but by a mechanism which should be consistent with such low values of the diffusion parameters (Do and Q). However in spite of extensive work on these types of systems, the mechanism of diffusion is still not well understood. The present investigation on the diffusion of palladium, silver, cadmium, indium, and tin in aluminum has been carried out to throw further light on the diffusion mechanism in systems, where the solid solubility is very low (except for the case of silver). The results are discussed on the basis of solid solubility and the structural changes involved owing to the presence of the solutes in aluminum solid solution. An attempt has also been made to apply the existing theories of charge5-8 and size8 difference between the solute and the solvent. EXPERIMENTAL PROCEDURE Specimens (1/2 in. diam by 3/8 in. high) were machined out of pure aluminum (99.995 wt pct) rod obtained from Johnson Mattheys. They were sealed under vacuum in quartz tubes and annealed at 620° C for several hours; the grains thus developed were sufficiently large to eliminate the possibility of diffusion along the grain boundaries. The flat ends were prepared carefully after polishing as described previously,10 Radioactive nitrates of cadmium, indium, and tin and chloride of palladium containing, respectively, cd115, 1n114, sn113, and pd103 were dissolved in distilled water and mixed with 30 pct acetone. By means of a micropipet a drop of this solution was placed on a smoothly polished and lightly etched surface of the specimen. Due care was taken to see that the solution spread uniformly on the surface of specimen without trickling down its sides. Radioactive silver was elec-trodeposited using a AgCN-KCN bath. The amount of sample deposited in all the cases was not more than 0.1 µ thick. The samples were then sealed in quartz tubes in vacuum. The cadmium samples were sealed in a purified argon atmosphere to avoid evaporation. The samples were then diffusion-annealed. The temperature of annealing varied between 400° and 630°C and was controlled to ±5°C. On heating to -400°C,the deposits of cadmium, indium, and tin, which were of the order of 0.1 p in thickness, were converted to their respective oxides. The contribution of oxygen present in the lattice of aluminum due to these oxides has been calculated and found to be less than 10 ppm in all cases. Oxide method has already been used by other workers11'12 in diffusion studies without any controversy on the issue. However, in some of these investigations, metallic deposition was also tried. The diffusivities calculated from these measurements were found to agree very well with the diffusivities obtained by using the oxide method. Thus it is assumed that the measured diffusivities represent true diffusion coefficients. Since palladous chloride decomposes at about 500°C, the deposited samples which were to be diffusion-annealed below 500°C were heated in vacuum for a very short time at 500°C to allow the decomposition of palladous chloride to palladium metal. Time taken in decomposition of nitrates to oxides and chloride to metal was negligibly small as compared to the period of the diffusion anneals. The residual activity technique13 was used to study the diffusion profiles where thin layers from the specimen surface were removed by grinding it parallel to a flat surface on a 600-grade carborundum paper. The specimen was washed, dried, and weighed, the differ -ence of the weight being the measure of the thickness of the layer removed. After each such abrasion and weighing, the total residual activity on the surface of the specimens was measured by counting 0.656, 0.94,

Jan 1, 1968

By Lawrie Logan, Mike Wiggin

This paper will be in two parts, a discussion of the benefits available from benefit sharing as a concept followed by an examination of how this approach was applied at Mesa J Mine and what improvements were made. The first part is an outline of the ways that both parties in a benefit sharing agreement can uncover additional wealth by bringing a new approach to the relationships between mine and supplier. The paper describes a partnering agreement recently established between Robe River Iron Associates (RRIA) and Dyno Nobel Asia Pacific Ltd (DNAP) to access the wealth locked up by the usual explosives supply contracts in Australia and elsewhere. The partners are acting cooperatively to maximise the benefits to both parties from optimising blasting practices at the Mesa J Iron Ore Mine in the Pilbara region of Western Australia.

Jan 1, 2001

By Rob D. Morrision, Paul W. Cleary

"The best accepted method for design of autogenous and semi-autogenous mills is to carry out pilot scale test work using a 1.8 m diameter by 0.6 m long pilot scale test mill. The load in such a mill typically contains 250,000-450,000 particles larger than 6 mm, allowing correct representation of more than 90% of the charge. This scale of DEM model is now within the practical range of standard workstations running an efficient DEM code.This paper describes various ways of extracting collision data from the DEM model and translating it into breakage and wear estimates. Account is taken of the different breakage mechanisms (impact and abrasion) and of the specific impact histories of the particles in order to assess the breakage rates for various size fractions in the mills. These impact histories have the potential to be directly related to breakage as they most resemble the single particle breakage tests which are used by the JKMRC to calibrate more traditional population balance models for variations in ore behaviour. However, the specific impact histories also show a background of many low energy collision events within the mill. This Background may constitute what is usually regarded as “abrasion” breakage. As might be expected, high impact events are concentrated in the toe of the charge and near to the mill shell where the forces associated with the load bearing on each particle is more concentrated."

Jan 1, 2003

By Richard D. Hagni

The United States is dependent upon foreign sources for more than 93% of its bauxite and alumina supply. Domestic production of bauxite, which comes from Alabama, Georgia and Arkansas, is limited to those bauxite ores containing less than about l ½ % iron. Bauxites with higher iron contents are generally not utilized because they cause problems in bauxite calcining and especially because they produce undesirable brick discoloration and cracking. In order to improve beneficiation and expand the utilization of high-iron or ferruginous bauxites, a mineralogical and textural study has been conducted on selected samples from the Eufaula, Alabama, bauxite district. Reflected light microscopic, petrographic, and X-ray techniques have shown that a variety of iron minerals are present, including hematite, goethite, lepidocrosite, siderite, pyrite, marcasite, and ilmenite. Although the iron minerals may be locally concentrated into concretions and pisolites, most occur as very fine grains that are disseminated and show a variety of intergrowths. Mineralogical and textural observations indicate that the fine-grained iron mineral grains may be amenable to high gradient magnetic separation.

Jan 1, 1981

By L. P. Srivastava

Rock bolts have been used since long to enhance the shear strength response of jointed rocks in civil and mining engineering structures. However, the assessment of strength response of a rock mass reinforced with rock bolts remains an unresolved problem till date. In the present article, an attempt has been made to study, through physical model tests, the shear strength enhancement of a blocky mass due to provision of passive rock bolts. Direct shear tests were conducted on large specimens of size 750 mm x 750 mm x 900 mm of rock mass under a normal stress varying from 0 to 2.0 MPa. Concrete was used as a model material to simulate intact rock and, elemental blocks of size 150 mm x 150 mm x 150 mm were used to form the mass specimens. Steel bolts of 6 mm diameter with 2 mm thick grout were used to reinforce the mass. Three different configurations of bolts were adopted. Observations were made on shear stress, horizontal shear displacement, and dilation during the tests. Effect of normal stress and reinforcement on peak shear stress and shear stiffness was studied. It is observed that the rock bolts enhance the shear strength of the mass by preventing sliding along the shearing plane, and by inducing additional normal stress due to tension mobilized in the bolts. The rock mass, therefore, becomes stronger due to the high degree of interlocking produced by the bolts. Shear strength of the mass increases with increasing numbers of bolts. In the case of reinforced mass, the enhancement in shear strength due to provision of bolts decreases with an increase in normal stress. The provision of bolts improves the cohesion of joints substantially. The effect on friction angle is low. The shear strength enhancement depends on the area of the bolts, spacing of the joints, spacing between the bolts and the cohesion of the intact material. A correlation has been established using which the enhancement in shear strength due to the provision of bolts can be assessed.

Jan 1, 2015

By H. C. Chao, W. F. Hosford, L. H. Van Vlack

The negative "plastic Poisson's ratio" suggested in earlier studies of Mus deformation is analyzed, and the results are verified experimentally with NaCl crystals. In the early stages of deformation where the primary {110}(110) slip predominates, compression along. the [001] direction produces contraction along the lateral [011] direction plus a compensating expansion along. the [100] direction. With additional strain, the primary slip is supplemented by secondary {111}(110) slip so that the above contraction diminishes and a more typical deformation appears. THE shape change of bee and fee crystals deformed by compression or tension along [011] has been analyzed in some detail and shown to be responsible for the development of peculiar microstructures in [011] fiber textured polycrystals of these metals.1'3 This paper concerns the unusual shape change accompanying [011] compression of NaCl crystals. It is the direct outgrowth of an earlier investigation of the deformation of manganese sulfide inclusions in steel.3,4 In that investigation, cylindrical specimens of steel containing small oriented crystals of MnS were prepared by powder metallurgy and plastically compressed. The flow of the inclusions was determined relative to that of the steel by sectioning the composite and measuring the length-to-width ratio L/W of the inclusion and diameter-to-height D/H ratio of the steel cylinder on the plane of section. These L/W ratios, normalized by dividing by the initial LO/WO ratio of the inclusion, were compared with the normalized D/H ratio of the steel cylinder. Of particular interest here are the deformation characteristics of an inclusion oriented with [Oil] parallel to the compression axis. When measurements were made on sections parallel to the (100) plane of the inclusion, the L/IV ratios were only slightly in excess of unity, indicating a high apparent hardness of the [011] criented inclusion. However, measurements on a (011) plane of section resulted in L/W ratios which were much larger, Fig. 1. These observations prompted an analysis of the strains resulting from slip in an MnS crystal compressed along [011.]. CRYSTALLOGRAPHIC ANALYSIS Manganese sulfide has the NaCl crystal structure, and the predominant slip system is {110}(110). A secondary system, {111}(110), has also been reported.= {110}(110) Slip. When a crystal is subject to a uni-axial compressive stress 011 along [011], four slip systems, (101)[101.], (101)[101.], (110)[i10], and (110) [ 110], will be equally stressed with a shear stress t = 0.2 011 while the other two {110}( 110) systems will be unstressed. The normal strain En along any reference axis n resulting from slip is given by Schmid's law: en = S COS ?in COS in ?i 111 where ?in and +in are the angles between n and the i slip direction and n and the i slip plane normal, respectively, and where ?i is the shear strain on the i slip system, For the four active slip systems above, the cos ?in cos +in terms are all equal when the reference axes are the [011] compressive axis, [011] and [ 100]. Eq. [I.] therefore reduces to en - cos ?n cos +ny [2] where y =S?i for all slip systems. Substituting the appropriate angles, Eon = 0.25? 110 eon - 0.25y110 [3] €100 = -0.50y 110 The interesting feature of Eqs. [3] is that they predict that the strains in the [011] and [011] directions, resulting from {110}(110) slip, are equal and of the same sign. Thus when a crystal is compressed along [011], it will contract along the lateral [oil] direction

Jan 1, 1967

By C. P. Moore, G. W. Taylor

Vertically dipping lenses of nickel-copper ore at Dumbarton Mines Limited are being mined by a modified blasthole stoping method. The principal access to the mine is provided by a 15-degree decline, which, in conjunction with the use of ramps and declines for secondary access, maximizes the accessibility and mobility of trackless mining equipment. Sublevels are driven in ore on 80-foot vertical intervals and subsequently the ore, ranging in thickness from 15 to 30 feet, is slashed to its limits by a procedure of face sampling and test holing. Two longhole drill jumbos are used to drill off 40-foot vertical slices above and below these levels. Following blasting, the ore falls by gravity to the 500-foot horizon, where it is removed from drawpoints by load-haul-dump units and transported by truck to the main orepass. The rock is crushed to minus 3-4 inches and conveyed to surface by a 30-inch-wide wire rope suspended conveyor. This is achieved in two flights, a lower one of 290 feet and a main flight of 2260 feet. All aspects of the mining operation are discussed in the paper, including ventilation, services and safety.

Jan 1, 1973

By G. Purcell, S. C. Sun

The objective of the present study was to detennine the role played by double bonds in the flotation of a very pure mineral using 18-carbon unsaturated fatty acids as collectors. Streaming potential measurements were made on a plug of pure synthetic rutile in solutions of inorganic electrolytes and unsaturated 18-carbon fatty acid soaps. Experimental results from these tests are detailed in the paper. The collector effectiveness of oleic acid with one double bond, linoleic acid with two double bonds, and linolenic acid with three double bonds has been a matter of speculation for many years, and conflic- ting experimental evidence1-8 has not clarified the issue. The overall objective of the present study was to determine the role played by double bonds in the flotation of a very pure mineral using 18-carbon un-saturated fatty acids as collectors. Since zeta potential is dependent on adsorption and orientation of ions at the solid-liquid interface, its variation under different conditions of pH and collector concentration should throw some light on the behavior of unsatu-rated fatty acids in flotation pulps. Titanium dioxide, in the form of rutile, was chosen for the investigation because it is now available in a very pure, synthetic, crystalline state, and despite the fact that it is one of the most important synthetic inorganic chemicals in commercial use, its electro-kinetic properties have not been closely studied. Electrokinetic properties of rutile in various aqueous solutions are discussed in this paper. Adsorption information gained from the streaming potential measurements enabled the flotation resultsg to be explained in a qualitative way, thus providing a clearer

Jan 1, 1963

By John D. Sullivan

In leaching copper ores knowledge of the rate of dissolution of the copper minerals and of the impurities is desirable. With knowledge of these two factors and data as to what minerals are present in the ore the metallurgist has an excellent start on planning a leaching cycle to fit that ore. The rate of dissolution is rather difficult to predict, and the time required to leach a given ore may differ markedly from that required by another ore. The whole study as related to mixed oxidized and sulphide ores is one of relative rates of dissolution of the different copper minerals and the impurities in sulphuric aoid and in ferric sulphate. The aim of leaching is to choose a cycle and strength of solvents to extract a maximum amount of copper and a minimum of impurities. The consumption of reagents per unit of copper dissolved is a function of the strength of the reagents used and the relative rates of attack on copper minerals and impurities. An opportunity may exist of obtaining the kind of electrolyte wanted for electrolytic precipitation and yet of saving on the consumption of reagents by modifying the strength of ferric sulphate and of sulphuric acid during the cycle to fit the time needed for dissolving the sulphide and oxidized minerals present.

Jan 1, 1931