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By H. Polat, Q. Hu, M. Polat, S. Chander

"The electrostatic charge on spray droplets of ionic surfactant solutions and coal particles was measured and the results were correlated with the dust collection efficiency. When various surfactant were added, the magnitude of the droplet charge increased significantly and it was observed to be a function of surfactant type and concentration. The concentration of maximum droplet charge coincided with surfactant concentration where maximum collection efficiency was observed for these surfactants. Particles of coal also carried substantial amount of charge magnitude of which seemed to be a function of coal rank.Based on the results presented in this paper, it was concluded that ionic surfactant primarily act as a strong electrostatic charge inducer for droplets. Due to interactions between these highly charged droplets and naturally charged particles, the efficiency of droplet-particle collisions play a primary role when compared to the wetting and engulfment phenomenon which could only follow a successful collision. INTRODUCTIONWater spray are widely used to suppress airborne dust in mine atmospheres (Walton and Woolcock, 1960; Kobrick, 1970; Hamilton, 1974; Jayaraman et al., 1986). Several investigators have considered the use of surfactants to enhance the effectiveness of water sprays especially for difficult to wet particles such as those of coal (Glanville and Wightman, 1979). The capture of dust particles by water droplets involves droplet-particle collisions, adhesion of particles to droplets, and engulfment of particles into droplets. Surfactants affect these sub processes through their influence on droplet charge, surface tension, and wetting. The last two mechanism have been thoroughly studied in recent years (Walker et al., 1952; Cohen and Rosen, 1981; Glenville and Haley, 1982; Chander et al., 1988; 1991). However, little attention has been paid to the role of electrical charge on particles and droplets on the collision and adhesion of spray droplets and dust particles."

Nov 1, 1995

By Mark Rybak

On August, 31, 2006, Tropical Storm Ernesto hit the City of Richmond, Virginia. The Battery Park area was hit particularly hard, as flooding forced an evacuation of the area. A large sinkhole collapsed a sewer line in the Battery Park area, blocking the pipe and causing more serious flooding. This case history describes the fast track design, bidding, and construction of an emergency tunnel to bypass the collapsed sewer. Innovative value engineering, tunneling and shaft sinking methods, and final lining design all contributed to the success of this project. The storm inundated Richmond, Virginia with up to twelve inches of rain in some areas causing widespread flooding and damage. One of the hardest hit areas of Richmond was Battery Park. A major trunk sewer in the Battery Park area collapsed causing local combined sewer and storm-water flooding. The collapsed sewer was an 8'-3" wide by 9'-6" high arch sewer that was constructed in the nineteen twenties and later filled over with municipal solid waste and a soil fill cap to current elevations. A sinkhole was created in the area of collapse approximately sixty feet deep and one hundred feet in diameter causing the existing arch sewer to become blocked. As a result of this blockage contaminated flood waters reached depths in low lying areas in excess of twenty five feet. [ ]

Jan 1, 2008

By J. -W. Kim, Y. -B. Kang, H. -G. Lee

The effect of SiO2addition on the decomposition of Li2CO3was investigated at temperatures up to 1000ºC. It was found that addition of SiO2greatly enhanced the decomposition of Li2CO3. The main decomposition reaction started at around 600ºC, and completed just above the melting point of Li2CO3. The major decomposition product was Li2O?SiO2irrespective of the Li2CO3to SiO2mixing ratio while both reactants were available. It was ascertained that a liquid layer betweenLi2CO3and SiO2particles formed and facilitated the decomposition reaction. The governing reaction of the decomposition was the one between the dissolved Li2CO3and SiO2in the liquid layer to form Li2O?SiO2. The decomposition rate was independent of the Li2CO3/SiO2mixingratio until either one had been completely exhausted. When excess Li2CO3existed, it further reacted with the initial product of Li2O?SiO2to form 2Li2O?SiO2. When SiO2was found in excess, on the other hand, no further reaction took place. This is attributed to the fact that uponLi2CO3exhaustion there is no liquid phase available to facilitate further reaction. The apparent activation energy of the decomposition of Li2CO3in existence with SiO2is 198 kJ mol-1.

Jan 1, 2004

By R Frew, E Wong, G Ferguson

The Chang Jiang Tunnel and Bridge Project, when completed, will provide a fixed link between ShanghaiÆs rapidly developing Pudong District and Chong Ming Island, situated in the Yangtze River delta. The link includes 7.5 km of bored tunnel from the Pudong to the intermediate Changxing Island from where the link comprises viaduct and a cable stayed bridge. The bored section comprises twin 13.7 m internal diameter segmentally lined three-lane highway tunnels. At its deepest point the tunnel will be 55 m below the river. Cross passages will link the two bores for passenger evacuation. Tunnel boring commenced in October 2006 and is scheduled for completion in mid-2009. The paper describes the key features of the design and construction of the bored tunnel by two 14.53 m diameter slurry TBMs and eight cross passages using ground freezing techniques in alluvial sediments. A decision to include light rail below the road deck was taken after the completion of the detailed design. This posed a number of design challenges including passenger evacuation to the road deck, and the redesign of the low point sumps. The various options considered are discussed together with those adopted for construction.

Jan 1, 2008

By K Broadley

Risk and dispute resolution are linked. Dispute resolution techniques are brought to bear on a dispute - which is an outcome of a risk being wholly or partially realised. There has been an increasing awareness by business of risk as a component of doing business. There is an accompanying awareness of the need to manage risk - including legal risk. Many companies have undertaken a systematic review of their potential risks and endeavoured to put in place systems to help to avoid or manage risks. A legal risk management program will not prevent disputes arising. However, such a program should prescribe how that dispute will be managed. The management of the dispute will involve consideration of the dispute resolution procedure to be adopted. The most appropriate processes will take into account the practical, personal and commercial considerations surrounding the dispute and be as efficient, cost-effective and user friendly as achievable in the circumstances for the benefit of all the parties. Carrying on business in South East Asia, whether as an explorer or a mining operator, brings additional considerations to bear in legal risk management and the dispute resolution process. A significantly different perspective is required due to the varying nature of the legal systems in many South East Asian jurisdictions. These jurisdictions often have relative uncertainty as to the law. This impacts on the dispute resolution processes and also raises further timing and cost issues. The authors contend that this is all the more reason to endeavour, as practically as possible, to adopt a legal risk management and dispute resolution profile which will provide business with the greatest prospects of maintaining control of the dispute resolution process. This presents a greater chance of a successful outcome to the dispute. In these times of increasing pressures on profitability because of low mineral prices, all costs of a minerals business are being reviewed. In such times, a significant legal dispute may have even greater potential to adversely impact on the companies concerned, together with the careers of the people involved. In this paper possible approaches to managing disputes and a case study a legal dispute in which Freehill Hollingdale and Page were involved are discussed. The dispute concerned an international mining company developing a gold mine in Indonesia and one of its contractors in Indonesia. Described is how that dispute was resolved. This achieved a very satisfactory result for the client - all things considered. Given the æadditionalÆ problems associated with ascertainment and enforcement of ærightsÆ in South East Asia, the longer the parties can retain control over their dispute the better off they will be. For this reason, the authors set out in this paper the main additional dispute resolution tools available - that are appropriate for use throughout South East Asia.

Jan 1, 1999

By David Cooper, Susan Robertson, William Wiehagen, Launa Mallett, Charles Vaught, Joan Dickerson, Richard Conkle, ROBERT PETERS, Mike Brnich, Charles Urban

This trainer’s guide is designed as a reference manual. The purpose is to offer information and examples to skills trainers to assist them in structuring training for new operators of Walk-Thru roof bolting machines. Trainers can use this manual as a resource for helping trainees learn, understand, and apply knowledge and skills. In this sense, the guide is not prescriptive. It is designed to offer information and trigger ideas on what might be done to accelerate learning to those who are new to the roof-bolting task. On-site trainers can modify this guide to fit their conditions, machines and equipment, and work procedures. They can integrate roof control plans, company policies and procedures, and operators’ manuals from the manufacturers of the original equipment into this guide. Every trainee is different and will come to the job with varying levels of relevant knowledge and skills. The trainer’s decisions on where to start, how to organize the on-the-job and classroom training portions, and when and how to offer different aspects of the training will be based on (1) a pretraining assessment of the trainee’s knowledge and skills and (2) the trainer’s experience in conducting skills training. The “Skill Check” section might be useful for deciding where training should start among miners who have underground experience but limited knowledge of roof-bolting techniques. Every job carries a learning curve and likely has a number of “teachable moments” where significantly new knowledge and skills can be learned. The videos on the DVD that accompany this guide can be shown at the beginning of training to give trainees an idea of what the job entails and related requirements. They can also be used within the training cycle (after the trainee has some experience in the job) to reinforce key points or as a trigger for eliciting questions about particularly difficult parts of the job. The video segments are meant to be visual models of good performance. They are designed to elicit discussion on good (lower risk) ways to do the job. In this context, they can be used very creatively at different times within the training cycle. The section on “Talking Points” offers a number of questions that can be used in the classroom to support and elaborate on certain aspects of the job duties. If the trainee has a fair amount of underground experience, some of the questions can also be used to support the pretraining assessment (i.e., skill check) of knowledge and skills. Likewise, some of the questions can also be used while teaching on the job to reinforce key points affecting safety, production, or maintenance. The section dealing with a mine’s roof control plan should be used at various times in the training cycle to make sure the trainee understands the plan and knows how to apply it in performing the job. The supplemental materials offer additional resources that can be used to support initial job training or follow-up. Learning continues well after an individual has been trained. The supplemental materials can help reinforce good operating skills and provide an opportunity for further discussion on better ways to do the job.

Jan 8, 2006

By Merih Celasun

The literature in operations research centered on mineral exploration has been comparatively limited in view of the significant implications of mineral discoveries upon the national economies in general and mineral industries in particular. Much of what has been published is of somewhat unsure academic nature, indicating to a certain extent the scarcity of industrial applications. Mineral exploration activities present quite difficult operational and conceptual problems. The purpose of this paper is to discuss the principal characteristics of decision problems encountered in planning an exploration program, to indicate an optimization approach to a certain class of allocation problems, and to suggest directions for future research effort.

Jan 1, 1962

By E. D. Dainty, B. E. Enga, D. L. McKinnon

Following considerable laboratory studies concerning particulate control systems for underground use, a program was commenced to develop practical real life implementation systems. This program covers the implementation in seven mines of particulate filter systems to 10 engine models from three engine manufacturers in 12 different vehicle types, a total of 24 vehicles. As the program ran, one mine had to drop out and a mutually agreed upon system could not be arrived at for another. Hence, the program included five Canadian mining companies. Several of the vehicles trialed at Brunswick Mining were trialed by Brunswick themselves. Nonetheless, the data is presented. This paper covers the work performed from the beginning to the end of the demonstration program. Data collected to properly select and design filter systems along with technical conclusions of the demonstration are presented. Also presented are the results of a survey that highlights the participating mines' acceptance of the technology.

Jan 1, 1991

By T. Mahlangu Mahlangu, T. Fungene, K. C. Sole

"Although oxygen is widely employed as the oxidant of choice in gold leaching by cyanide, its low aqueous solubility presents some drawbacks in practical application; hydrogen peroxide has therefore been considered as a possible alternative. The aim of this investigation was to study the catalytic decomposition of hydrogen peroxide, which generates an oxidizing intermediate species, and to understand its effect on cyanide destruction. Operating conditions that facilitated the effective decomposition of hydrogen peroxide were established by varying the pH and catalyst type and concentration. The oxidizing intermediate, detected using an indirect technique, was found to be the hydroxyl radical (OH?). OH? is commonly generated in acidic solutions, but this work demonstrated that it is also produced at the alkaline pH values necessary for cyanide gold leaching. The effects of free and complexed iron and copper catalysts on the oxidation and consumption of hydrogen peroxide and cyanide were also investigated. It was shown that the cyano complexes of Fe(II) and Cu(I) are also effective as decomposition catalysts. Hydrogen peroxide concentrations above 0.01 M decreased the free cyanide concentration, which was attributed to the probable formation of the cyanate anion (CNO-). Although cyanide consumption increased due to its oxidation in the presence of OH?, excessive cyanide consumption in the presence of copper was attributed primarily to its complexation by the unstable copper(I) cyanide species. Rate constants for the decompositions of H2O2 and cyanide by ferrocyanide and copper cyanide were calculated; the latter was identified as being a better catalyst. IntroductionLeaching of gold from its ores using cyanide has been employed for well over a century (Habashi, 2016). Addition of cyanide converts the gold into a cyanide complex (Au(CN)2 -) that is soluble in water (Wang and Forssberg, 1990). The leaching reaction can be represented as Equation [1]:"

Dec 1, 2018

By Edgar Stanfield

Since April, 1923, the Scientific & Industrial Research Council of Alberta has had an analyst, Mr. W. P. Campbell, steadily employed analyzing coal samples taken by the provincial Mine Inspectors. Mr. Campbell has also analyzed a number of coal samples taken by one of the Council's Geological Survey parties. We have thus, at the time of writing, over four hundred analyses of Alberta coal, made by the same analyst, and strictly comparable. These samples come from widely distributed points, some 88 townships being represented. The stream of samples is still flowing in, and it is hoped by the end of this year that the number of townships represented will be increased at least fifty percent. The time has arrived to publish some of the data collected; but it must be clearly understood that this is merely a progress report, subject to revision as further information is obtained. Three hundred and fifty-three coal mines in the province were operated during 1923. The production per mine varied from 5 up to 500,000 tons. With this number of mines to examine (and fresh mines are being opened every year) it is a large task to make even a proximate analysis of representative samples from every mine. Any chemist will appreciate the fact that to make ultimate analyses representative of even the larger mines will be a long and tedious task. It has seemed better to make a comprehensive survey by proximate analysis and determination of calorific value before beginning the more thorough survey by ultimate analysis. This paper, therefore, deals only with proximate analyses and calorific values; and, owing to limitations of time and space, does not deal with other chemical and physical characteristics of coal, such as storage quality and fusibility of ash, important though these are.

Jan 1, 1925

By Halet. R. A.

"The Quesabe Mine, owned by Brunston Mines Limited, is a gold deposit in the south central part of Duprat Township, northwestern Quebec, about 10 miles northwest of Noranda.It is one of the few gold mines in Canada developed since World War II. The occurrence of gold in the Quesabe fault structure has been known for many years, but serious exploration did not begin until 1945. By 1949, 15,000 feet of diamond drilling had been completed and a shaft sunk to a depth of 635 feet, with lateral development on the 450 and 600 foot levels. In 1949 and 1950 a new shaft was sunk to 1,050 feet, new levels were established at 800 and 1,000 feet, and ore was mined and shipped to the Noranda smelter. After November 1950 the ore mined was treated in the company's own mill. The grade of ore was marginal under existing economic conditions, and production was suspended in April 1952. The mine produced about 100,000 tons of ore with an average grade of approximately 0.25 ounces of gold per ton.GeologyThe bedrock formations are all Precambrian, and the general geology of the area has been described by W. G. Robinson (1). The rocks in the vicinity of the mine are acidic and basic volcanics of the Keewatin series (andesite, rhyolite, agglomerates, tuffs) invaded by the Flavrian Lake granite stock, and by dykes and irregular masses of intrusive felsite, quartz porphyry, syenite-porphyry, diorite, and lamprophyre.The mine workings are in andesite and felsite, about 2,500 feet west of the western margin of the Flavrian Lake stock.The principal structural feature of the area, from an economic point of view, is the Quesabe fault. This steeply-dipping fault cuts all the rock formations of the area, and has been traced for about 11 miles along a strike of north 65 degrees east from Lake Arnoux in the northeast corner of Dasserat Township to Duprat Lake near the east boundary of Duprat Township."

Jan 1, 1949

By Yonghun Jong, Chungin Lee

The main purpose of this study was to apply the artificial neural network (ANN) models to determine optimal powder factors and predict peak particle velocities, based on a series of observations and input parameters. The used blasthole pattern was V-cut. The locations of blastholes and ignition patterns remained almost constant. The input parameters were 14 geological conditions (i.e., dip, dip direction, spacing, separation, and persistence of 2 discontinuity sets, tunnel orientation, rock strength, RQD, and RMR) and 4 blasting conditions (i.e., distance between blasting points and measuring points, charge weight per delay, drilling length, and blasting efficiency). Data for the ANN application in this study were recently collected in a highway tunnel under construction in Korea. The main rock type in the site was biotitic granite. An optimum ANN model was determined by training models with collected data. The trained model was used to evaluate the prediction capability of the optimum model. It was shown that the ANN model could predict the powder factor and the peak particle velocity depended upon the selected input parameters. Particularly, the ANN model predicted more accurate peak particle velocities than those obtained by the blasting vibration equation. Moreover, the more dominant factors among the input parameters could be determined by analysis of the relative strength effect.

Jan 1, 2002

By Dickson B. L

Groundwater geochemistry is controlled by chemical interactions with aquifer rocks, and offers a powerful geochemical exploration technique for locating concealed mineral- isation. Techniques are applied for identifying constituents of aquifers using the compositions of their groundwaters, collected from the surface through drill holes, water bores or springs. Even slowly moving groundwaters have passed through large volumes of rocks which surround any sample site. Products from these rock-water contacts modify the groundwater. By relating water composition to the minerals from which the dissolved species may have been derived, geochemical exploration information is obtained for a significantly larger zone than is represented by drill hole rock samples. In this paper we describe some solution chemical tech- niques we are applying in mineral exploration, particularly in areas of Australia where ground- waters are highly saline and contain enhanced concentrations of trace metals. EQUILIBRIUM MODELS FOR SALINE GROUNDWATERS Central to our technique is the assumption that in low rainfall regions, aquifer rocks and contained groundwaters are in chemical equili- brium. Solubility calculations then allow us to predict upper limits to the soluble products of groundwater interaction with aquifer rocks and to identify minerals with which the groundwater is saturated. Whilst equilibrium calculations require input of concentrations of all dissolved species, they are actually based on "activity" of dissolved species rather than the analysed concentrations. Unless waters have very low ionic strengths (a measure of total dissolved solids), activity of a solute is not equal to its analytical concentration but equals concentration multiplied by an "activity coefficent". Several methods exist for calculating mineral solubilities. The ion-association model, commonly used in programs such as WATEQ (Truesdell and Jones, 1974) and later deriv- atives such as MINTEQ, assume the formation of complex ions such as MgSO4(0), CaCl+, which are described by formation constants. Activity coefficients are obtained by the extended Debye

Jan 1, 1988

By Mauritz Kotze, Jason Furtney, Ewan Sellers, Sandy Etchells, Tom Szendrei

The development of a simple model for gas flow and burden movement has driven the need to improve our understanding of burden breakage mechanisms for single hole blasts and the interaction between multiple holes in solid and jointed rock masses. Conventional analytical understandings of the burden breakout using the elastic-tensile fracture model were studied and found to provide a breakout angle that is independent of burden in contradiction to experimental data. By considering rock fracture in terms of Mohr-Coulomb plasticity using analytical expressions from the field of cavity expansion analysis an improved relationship between breakout angle and burden is derived until the point of critical breakout at which the angle of breakout suddenly changes from between 90 degree and 100 degrees to zero. This suggests that the critical burden occurs at about 0.6 times the radial fracture zone calculated from the analytical solutions.

Jan 1, 2013

By T Gibbons, M Korte, C Brent, K Runge

The Barrick Osborne concentrator has gone through a number of upgrades since commissioning and steadily increased production from the original 119 t/h design capacity to 265 t/h milling throughput in 2008. This was achieved incrementally over several years, by maximising operating efficiencies, in order to minimise capital expenditure, and take advantages of economies of scale; but more importantly it was reached with no measurable loss of recovery. Osborne currently processes a blend of under- ground with open pit material from the nearby Trekelano deposit. Following primary/secondary crushing, the material is processed through a rod/ball mill grinding circuit ahead of rougher/scavenger flotation that produces a copper concentrate.Osborne was seeking a further increase in plant throughput of the order of 15 per cent, but at more sustainable levels of secondary crusher plant utilisation. In early 2008, Osborne contracted Metso Minerals Process Technology Asia-Pacific and South America (MMPT) to review the entire process from run-of-mine feed to final copper concentrate. This review would be done concurrently, with surveys of both the crushing/ grinding and flotation circuits being performed at the same time. The outcome would be a steady-state model of the complete flow sheet allowing the crushing/grinding model to interact with the flotation circuit model such that overall process optimisation was possible. Two key outcomes for the operation are exploration of the operating limits of the currently installed plant, and projection of the logical next stage of potential capital plant expansions. This paper covers Part B or the flotation component of the project. A separate paper discussing Part A or crushing and grinding is also being presented at this conference. Surveys of the Osborne flotation circuit were performed along with a comprehensive review of the cell characteristics including measurements of the gas and froth phases of individual flotation cells. These data resulted in a size-by-size floatability component model of the complete circuit. This circuit model was then used to perform steady-state simulat- ions to evaluate options to improve both overall circuit and individual cell performance. The grinding circuit model discussed in a separate paper or Part A of this project was then used interactively with the flotation circuit model to recommend the best operating regime to maximise overall efficiency. For example, the balance between increased crushing and grinding costs versus higher copper recovery and final concentrate grade. Due to changes in market conditions in the fourth quarter of 2008, the focus was shifted to prioritising operational changes rather than capital expansion modifications, in order to improve circuit performance.

Jan 1, 2009

By J. G. Kirby

According to the annual Bureau of Mines survey of refinery capacity, there were 343 petroleum refineries in the United States as of January 1, 1953, with a total daily crude-oil throughput capacity of 7,638,661 barrels. Compared with the previous year, this represents a decline of 7 in the total number of refineries, but a gain of 305,776 barrels in daily crude-oil throughput capacity. The capacity of the average refinery to process crude oil increased to 22,270 barrels, a gain of 1,319 barrels during 1952. All refining districts reported increases in installed capacity for the year, with Texas Gulf Coast accounting for 28 percent of the increase; California, 21 percent; and the Indiana-Illinois-Kentucky district, 18 percent. Additional crude-oil capacity under construction January 1, 1953, was 60 percent greater than at the beginning of 1952. The total reported, 509,721 barrels daily, is a record high for refinery expansion. In addition to the new facilities under way, facilities for 127,755 barrels daily are being installed to replace those that are obsolete. Four new refineries were under construction at the beginning of the year, and three of these are now in operation. Plans for five' new refineries have been announced, but actual construction has not been started.

Jan 1, 1953

By C. J. Thompson

This Bureau of Mines study describes the preparation of sulfur compound concentrates boiling from 225° to 400° C, and reports the sulfur types detected in these concentrates by low-voltage mass spectrometry (LVMS). Existing LVMS methods were extended; the procedures described should be generally applicable to high-boiling petroleum distillates and concentrates as a preliminary means of narrowing the number of factions to be considered for more detailed separation and identification studies. The following major sulfur compound constituents of petroleum are indicated by the data: benzothiophenes, dibenzothiophenes, naphthanothiophenes, naphthenobenzothiophenes, and homologs and isomers of these. Cyclic and chain sulfides comprise a significant portion of the gas-oil range sulfur compound types. The presence of some classes of sulfur compounds containing two sulfur atoms per molecule was indicated.

Jan 1, 1966

By P. E. Busby, C. Wells

FURTHER study of data used in determinations of 1—rates of diffusion of boron in austenite and 2—solubilities of boron in the a and phases of iron and steel' has provided an equation for the diffusion of boron in a iron. In brief, the previously published data were accumulated from the results of deboron-izing (and decarburizing) experiments carried out in the range of 700° to 1300°C. Diffusion coefficients (D?) for boron in austenite were calculated using the Grube solution of Fick's law. However, only solubility values were estimated from the discontinuous concentration-penetration curves, Fig. 1, which are characteristic of diffusion in two phases. Dr. Carl Wagner' has recently provided a solution for calculating D values from penetration curves of this type as follows: Cl1.1 —C8/C8- C11.1 = vp ? e ? erf (?) and D = ?/4?2 t where C11,12, C8, C11, and E have the values shown in Fig. 1. D is the diffusion coefficient, sq cm per sec; t is time of deboronizing anneal, see; and ? is a di-mensionless parameter. For a given diffusion experiment, the value of ? can be readily obtained by graphical solution from a plot of y vs the right-hand part of Eq. 1. D may then be evaluated from Eq. 2. The avplication of this solution to previously re-ported results, of which excerpts are given in Table I, permits the calculation of diffusion coefficients for boron in a iron. On the basis of these meager data, it is tentatively concluded that the diffusion of boron in a may be represented by the equation Da = 1011 e-92,900/RT where R is the gas constant, cal X 0C-1 X mol-1; and T is the absolute temperature, OK. Although the frequency factor, 106 sq cm per sec, is admittedly several orders of magnitude higher than expected, the value of Q, 62,000 cal per mol, appears reasonable and is, in fact, very similar to that for the self-diffusion of iron. It is pertinent to mention at this point that the value of Q obtained for the diffusion of boron in austenite by means of the Wagner solution is 19,000 cal per mol and is in excellent agreement with the value previously reported1 in the equation DT = 2xl0-3 e-21,000/RT [4] which was determined by the application of the Grube solution to other data. The fact that determined constants A and Q in the equation D? = A e-Q/RT were practically the same, independent of whether the Wagner or Grube solutions were used in determinations of D values, strengthened the authors' belief that the computed values of D (Table I) using the Wagner solution are reliable. The relative values in Eqs. 3 and 4 for the diffusion of boron in the a and ? phases, respectively, suggest that boron forms a substitutional solid solution in a iron and an interstitial solid solution in ? iron. The same tentative conclusion has been reached by McBride et al.3 on the basis of relative solubilities, atom diameter, and the size of the interstitial hole in a and ? iron. In connection with the data for test 14 listed in Table I, it is of interest to calculate the solubility of boron in a iron using the D value given by Eq. 3. As might be anticipated from the small movement of the interface in test 14, proper substitutions in Eqs. 2 and 1 give a low value, approximately 0.0004 pct B, at 850°C. Apparently at 835°C (test 13) it is possible to obtain 0.0018 pct B, and at 850°C only 0.0004 pct B into solution in the a phase before a second phase appears. These observations are consistent with the Fe-B constitution diagram proposed by McBride, Spretnak, and Speiser.3 References P. E. Busby, M. E. Warga, and C. Wells: Diffusion and Solubility of Boron in Iron and Steel. Trans. AIME (1953) 197, p. 1463; Journal of Metals (November 1953). 'W. Jost: Diffusion in Solids, Liquids, Gases. (1952) pp. 69-71. New York. Academic Press Inc. "C. C. McBride, J. W. Spretnak, and R. Speiser: A Study of the Fe-Fe2B System. Trans. ASM (1954) 46, p. 499.

Jan 1, 1955

By P Murthy, Z Guan, P Townson

In this paper, we introduce a methodology to optimise mining equipment operation in terms of the conflicting concerns of productivity and availability. We also introduce the concept of damage points and equipment dutymeters. These provide the mine management with tools to monitor the success of such optimisation. Since we have quoted the results of an on-going Australian Coal Association Research Program (ACARP) project, the apparent focus of this article is on draglines. However, the concept is equally applicable to other equipment. Mining is the type of business that requires a large investment in capital infrastructure and equipment to produce a product that is sold at a relatively low unit cost. In such a business, the key to competitiveness lies in achieving the full realisation of capital investment ie sustained production at high levels. Some of the concepts outlined in this paper are essential components of this picture.

Jan 1, 2000

By Kent D. Peaslee

When supersonic oxygen jetting is used in electric furnace steelmaking, the lance jet axis is typically inclined at larger angles to the vertical than is used in basic oxygen steelmaking. The supersonic jet is important not only for refining the steel, but for sustaining the foamy slag in the electric furnace. Physical modeling was carried out using a room temperature, two-dimensional slice apparatus in which mercury represented the metal and water-glycerol the slag. High speed video photography with image analysis was used to study the effects of the angle of inclination on the slag/metal bath. Mathematical modeling using FLUENT provided a method of predicting flow patterns and the trajectories of drops injected at various points in the flowfield. A one-half scale water model of the system, in which lance heights, angles, and flowrates simulated those encountered in steelmaking operations, was used to provide a better understanding of some aspects of the oxygen blowing process in electric furnace steelmaking.

Jan 1, 1994