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Apart from the general cooperation received in many quarters, the Unitization Committee desires to make specific acknowledgment to the following individuals for assistance rendered in the study to this time. California.—Committee members: Joseph Jensen, chairman, L. L. Brundred, E. M. Butterworth, H. Norton Johnson, D. B. Myers, W. R. Wardner; others who contributed: C. R. McCollom, F. C. Merritt, E. B. Noble, Ralph Arnold, J. R. Pemberton, Roy R. Morse, T. F. Stipp, John R. Roberts, R. D. Bush, Alexander Anderson, J. A. Taff, F. 0. Martin, J. E. Van Gundy, E. K. Parks, A. C. Rubel, Lew Suverkrop, W. L. McLaine, Gerard Henny, Walter Stalder, Lester C. Uren, Hoyt S. Gale, W. L. Walker. Rocky Mountain.—Fred E. Wood, chairman, J. G. Bartram, C. E. Dobbin, Wilson B. Emery, Charles E. Erdman, R. D. Hawley, E. W. Krampert, Foster Morrell, W. T. Nightingale, K. B. Nowels, C. M. Rath, Earl Shoenfelt, J. W. Steele, E. T. Wilson, J. J. Zorichak. Kansas-Oklahoma.—Committee members: C. E. Beecher, chairman, A. W. Ambrose, R. C. Hauber, Clyde Alexander, R. F. MacArthur, C. R. Swarts, M. M. Valerius, E. H. Griswold, G. 6. Rollin, L. Murray Newman, David L. Trax, Richard K. Huey, Marvin Lee, Harry Johnson; others who contributed: E. A. Carr, Paul S. Ache, K. C. Slater, R. S. McFarland, J. R. McWilliams, Joseph Chalmers, Henry A. Ley, Dorsey IIager, H. C. George, W. K. Whiteford, L. G. E. Bignell, L. E. Smith, George E. Burton. Texas, Louisiana, Arkansas, New Mexico.—Frederic H. Lahee, chairman, Donald C. Barton, C:. E. Beecher, Olin G. Bell, G. E. Campbell, Paul Wagner, John West, Robin Willis, J. M. Forgotson, E. J. Gorman, P. S. Haury, Marvin Lee, C. F. Lytle, L. H. McBee, T. F. Petty, C. C. Pope, F. S. Prout, J. C. Stewart, J. R. Suman, L. P. Teas, W. C. Thompson, A. F. Truex, R. B. Campbell, M. G. Cheney, P. C. Dean, F. W. DeWolf, Dugald Gordon, B. A. Hardey, F. E. Heath, J. F. Lucey, George C. Matson, W. H. Perot, T. W. Pew, W. A. Price, W. A. -Reiter, R. C. Stewart. Eastern United States and Foreign Fields.—H. H. Hill and E. L. Estabrook, chairmen; Dr. Richard Ambronn, Gottingen, Germany; Arthur R. Andrew,

Jan 1, 1930

By Ann Barron

For millions of people, cold weather is a fact of line – and one that can make a major challenge out of just getting to work. But for those working in the blasting industry, a number of obstacles are created when old man winter blows in. In addition to the obvious concerns regarding personal protection, Mother Nature can throw some very nasty weather at the blasting crew trying to travel with explosives products from the magazine site to the job site. As such, divers need to be familiar with cold, ice, and snow driving conditions both on and off the blast site. It’s critical to know what to expect before you leave. Keep informed of the latest weather and road conditions as they change often; it will help you make the right choice in clothing and driving habits. Remember bridges and overpasses will freeze first even in temperatures above or near the freezing mark due to the effects of wind chill. Plan to take extra time to and from the job site.

Jan 1, 2004

By Thys B. Johnson

The mine system analysis and evaluation study presented in this report was part of the U. S. Bureau of Nines' Tertiary channel project conducted under the Heavy Metals program. The Badger Hill pit, located on the west end of the San Juan Ridge area, near Nevada City, California, was the site of the Bureau's field work. The objectives of this study were: (1) Determine potential alternative mining systems for some of the large tertiary channel gold-bearing gravel deposits, and (2) Identify areas of technology where further investigation would be merited because of their potential inclusion in a mining system for such deposits, The study involved the development of a mineralized block inventory, an economic block inventory, determination of optimum ultimate mining limits and a preliminary economic mining system evaluation. Computer programs were developed and utilized for each of the study phases stated above. The sampling program conducted at Badger Hill by the Bureau Delineation Group together with confidential drill hole data provided by the San Juan Gold Co. formed the basic gold values and distribution information from which a deposit model was developed. The deposit was divided into minable block units and net economic values were assigned to each block for various configurations of both open-pit and underground mining methods based on cost and performance data provided by the various Bureau of Mines Research Centers. A number of controllable variables such as: (1) Mining method (open-pit and underground), (2) depth of mining cut, (3) production rate and (4) equipment type and capacity were evaluated. The prime measures of effectiveness on which the mining systems where judged were discounted cash flow rate of return and maximum utilization of natural resources. The analysis showed that underground mining of the Six-Mile Tertiary channel gold-bearing gravel deposit under consideration was uneconomical and did not permit maximum recovery of the resources within the channel. It was also apparent that mining the Six-Mile Deposit for gold alone is uneconomical or at best marginal at a gold price less than $80 per ounce. The analysis showed that the potential for an economic mining operation within the Six-Mile Deposit exists when the gravel resources of the channel are considered together with the gold. It was determined that the highest rate of return would be realized with a 20-year open-pit mining operation yielding 745,000 ounces of -gold and 55 million cubic yards of usable gravel.

Jan 1, 2012

By D. W. Taylor, I. W. Farmer, N. Mojtabai

Rittinger's and Bond's descriptions of rock crushing relate the energy input required to fracture rock and the surface energy required to form new fractures to the change in specific surface area of feed and product during comminution. The potential applicability of this approach to blasting is illustrated, using the results of data from bench blasting tests on Pinal schists and production blasting of Carboniferous limestones. The approach contributes to understanding of the mechanisms involved in blasting and to the design of test blasts. A modified form is presented of the relationship between blasting energy, specific surface area of the muckpile and a rock energy constant related to the discontinuity structure of the rock. The modified equation fits observed data and offers a simple basis for further experiments

Jun 19, 1905

By Frank C. Greene

The results of drilling in Missouri in 1938 are overshadowed by the leasing activity in northern Missouri, which began about the middle of the year. Nothing like it has ever been witnessed by the oil industry. With no production except a minor amount of gas, and with no drilling except in Clay, Platte and Marion Counties, a leasing campaign has embraced most of the counties north of the Missouri River and spread into southern Iowa, southeastern Nebraska and northeastern Kansas. It is reported that nearly all farms that could be leased without payment of a bonus have been leased, mostly on 10-yr. contracts, and at the end of the year a policy of bonus paying is in effect. Many of the major oil companies are leasing in the area and at least 15 of them are represented by scouts. Similarity to the Illinois Basin, low-priced leases and low drilling costs are among the reasons advanced for the leasing activity. Drilling activity in Missouri increased nearly two-thirds over 1937, with a total of 164 completions. The main activity was the extension of the "shoestring" of the so-called Bartlesville gas pool in Jackson County. It now seems that this sand is probably at the horizon of the Burbank sand. A new Squirrel sand oil pool was discovered in Jackson County. Cass County had five oil wells, with 63 bbl. initial production, four gas wells with 542,000 cu. ft. initial open flow, and 15 dry holes. Jackson County had three oil wells, with 24 bbl. initial production, 56 gas wells with 52,021,168 cu. ft. initial open flow and 57 dry holes. In Vernon County seven oil wells, with about 36 bbl. initial production, and two dry holes were completed. The oil production dropped off very quickly. In counties where wildcatting was carried on, new production was found. Clay County had seven dry holes, Hickory and Marion one each; Platte, four and St. Clair, two.

Jan 1, 1939

By G. T. Fisher

A continuous process is used at Phelps Dodge Sierrita Inc. to produce copper sulfate pentahydrate via a solution extraction ? crystallization approach to supply the animal feed market. A review of the fundamental concepts of the process and unit operations is presented. Improvements in the process are aimed at achieving a controlled size distribution of product crystals (-40+80 mesh) with minimization of fines by primary nucleation and crystal breakage. An independent temperature control design was implemented for the heat transfer medium (water) in each crystallizer, albeit using common headers in and out of the chiller. This design was developed to maintain a controlled degree of supersaturation in each vessel while preventing localized spontaneous nucleation of fines and reducing encrustation of the heat transfer surfaces in each crystallizer. A model was developed to calculate the heat load and heat transfer coefficient of each crystallizer along with the saturation copper tenor as a function of temperature and free acid.

Jan 1, 2007

By E. E. Thurlow

The Geology Div. of Northern Pacific Railway Co. has adapted to its exploration efforts field procedures for geochemical sampling and semi-quantitative analysis which have been developed through research by the U. S. Geological Survey. The sampling is done in conjunction with reconnaissance geologic mapping on aerial photographs or during field checking of maps which have been prepared largely by photo-geologic interpretation. Stream sediment or soil samples are taken and readily soluble combined heavy metals are extracted with ammonium citrate followed by colorimetric titration with dithizone at the sample site. The effectiveness of this approach has been demonstrated both in positive and negative results, thereby assisting in the elimination of large areas of land from further immediate attention and in providing targets for followup exploration. An occa sional sample is submitted for spectrographic analysis as a check on the possible presence of other elements of economic significance. Field laboratory procedures are also being implemented for determining molybdenum, mercury, and other metals which may be valuable in themselves or useful as pathfinder elements in outlining mineralized areas. A lead-zinc occurrence in Oregon and a copper deposit in Montana were readily detected and outlined by stream sediment and soil sampling and a heavy metal anomaly that lacks obvious interpretation has been found in northwestern Montana. Detailed mapping and additional sampling are followed by other exploration techniques if warranted. Northern Pacific's program of reconnaissance mineral evaluation of company-owned lands and adjoining areas was outlined in a paper presented at the American Mining Congress meeting in Las Vegas four years ago. That report included policies and procedures with respect to mineral development on Railway Co. lands and may be referred to for information on these matters.1 In a sense this paper is a progress report on the use of geochemical prospecting in Northern Pacific's continuing mineral evaluation program. At this time there are positive results but as yet there is no real success story in the form of a minable ore body. GEOCHEMICAL PROSPECTING PROCEDURES The decision to use geochemistry as a reconnaissance exploration tool must be followed by research into sampling and analytical methods and into the interpretation of results. Various analytical methods were tried and evaluated by the Geology Div., including hot and cold acid extraction with and without fusion of the sample, panning and magnetic separation followed by dithizone testing of the magnetite, and cold aqueous extraction of metallic ions followed by indicator tests. Samples were first sent to the laboratory for analysis; later field laboratories were established and now virtually all testing is done at the sample site. It was concluded that, where applicable, the quickest dependable methods for reconnaissance use are the dithizone field tests for readily extractable heavy metals. This involves the simultaneous treatment of a sample, usually of soil or stream sediment, with two immiscible liquids; one a cold aqueous extractant (ammonium citrate) and the other a solution of dithizone in toluene or xylene.2 Dithizone is a colorimetric indicator that reacts quantitatively with copper, lead, zinc, and several other metals to form colored complexes in organic solvents. Results may be expressed in ml of 0.001 pct dithizone that are required to reach the blue end point, or calibration of the test results can be carried out with standard solutions of zinc; conversion factors would then be expressed in ppm, zinc equivalent. Calibration of dithizone solution with zinc standards indicates that 1 ml of 0.001 pct dithizone is equivalent to approximately 0.25 ppm of zinc. An authoritative report on dithizone field tests authored by H. E. Hawkes in the June-July 1963 issue of Economic Geology* states "The appeal of these techniques has been the simplicity and speed of the determinations as compared with more tedious laboratory determinations of trace metals in weathered rocks, soils, or plant materials. This obvious appeal, however, has often been more than matched by misuse of the method in such a manner that the results are

Jan 1, 1964

A mining engineer from South Africa, whose research has taken him to some of the world?s deepest gold mines, is the winner of the St Andrews Prize. Daniel Limpitlaw, 27, picked up a cheque for $25,000 for his dissertation on reversing the damage done by early mining technology, which he claims is partly responsible for blighting the urban environment in many South African cities. Launched in October 1998 by the University of St Andrews and international energy company Conoco, the St Andrews Prize sought practical solutions to environmental problems. It attracted interest from 450 individuals and groups from countries as diverse as China, Pakistan, Canada, New Zealand, Germany, the UK and the United States.

Jan 1, 1999

By M. J. McPherson

Having worked on the thermodynamics of air/liquid-water mixtures passing through the surface fans of deep mines, I find this paper of great interest and congratulate the authors on producing it. There are two matters, however, deserving discussion. First, the authors have described the classical theory of fog formation with fogging occurring at "supersaturation." In fact, the process of fog formation begins well below 100% humidity. The more strongly hygroscopic nuclei in the atmosphere will attract water molecules and begin to grow at a relative humidity perhaps as low as 70%. The process is a dynamic one with both condensation and evaporation taking place throughout the mixture on microscopic liquid surfaces. As saturation is approached, the rate of condensation accelerates rapidly producing the familiar reduction in visibility. Hygroscopic nuclei are present in all natural atmospheres and under the appropriate conditions of pressure and temperature, will produce clean fogs. However, if the air is polluted by particulates from combustion or other processes then the resultant coagulation with growing liquid particles may produce dense (and sometimes photochemical) smogs. It is this process that is likely to occur in underground mines when moist air is cooled below dew point. Second, the authors have summarized very well the individual measures that might alleviate the problem. In particular, I agree that neither heating nor refrigerating the air, by themselves, provides a satisfactory solution. However, there is a combination of these that provides a neat and effective control of fog formation. This involves a small, self-contained refrigeration unit within a duct but without the usual external heat rejection facility. The air is cooled below dew point and, hence, dehumidified on passing over the cold evaporator coils. The heat from the condenser is rejected back into the air down-stream from the water eliminator, as shown in [Fig. 1]. The duct configuration can be designed to create good mixing at the outlet.

Jan 1, 1984

By Ihsan B. Tulu, David F. Gearhart, Gabriel S. Esterhuizen

"Ground deformation and support response was monitored in a longwall gateroad as part of a research project into gateroad stability under changing loading conditions. In this study, instrumentation was installed in a gateroad located between two active longwall panels. The first panel to pass was the second panel in the district, and the second panel to pass the instrumentation sites was the third panel in the district. All of the panels in the district were right-handed. All of the instrumentation was installed in the number one entry, the tailgate, the second panel to pass the instrumentation sites at a mid-pillar location, and at an outby intersection location under about 600 feet of cover. The instrumentation included roof extensometers, cable bolt load cells, hollow inclusion cells, borehole pressure cells, standing support load cells, and convergence sensors, and a multipoint borehole extensometer. The roof extensometers measured roof convergence and sag. The cable bolt load cells measured the roof load applied to the cable bolts in the secondary support array. Hollow inclusion cells measured the magnitude and direction of the principal and shear stresses. The borehole pressure cells measured the stress on a pillar in the entry nearest to the second panel to pass the instrument site. The instrumented wood cribs in the entry nearest the second panel recorded the closure and load on the cribs, and the multipoint borehole extensometer in a pillar closest to the second panel recorded the location and width of cracks that occurred and total expansion of the pillar. This paper describes the effects of the changing stress caused by the first panel as it approached and passed the locations of the instruments on the opposite side of the gateroad system and the later effect caused by the second panel as it approached and passed the mid-pillar instrument location. The first panel passing caused significant loading at the mid-pillar instrument location, but not at the intersection location, while the second panel had passed the mid-pillar location and just arrived at the intersection location when the dataloggers needed to be removed."

Jan 1, 2017

By A. J. Kauffman

The alluvial deposits of the Pacific Northwest have been investigated and worked with varying degrees of intensity since about the middle of the 19th century. Earlier efforts, of course, were centered about the placer-gold content of the deposits; later, the Oregon beach sands were exploited for their chrome content, and, still more recently, deposits in Idaho were worked for their content of monazite, a rare-earth mineral which also contains significant quantities of thorium. The composition of alluvial deposits seems to depend mainly upon the nature of the source rock from which the detrital material was derived and upon the resistance of the individual mineral grains to the agencies of weathering and transportation. The processes of crushing and concentration used in ore dressing are applied in a leisurely but nonetheless effective manner when exposed rock masses are eroded by natural forces. Weathering effects a continuous disintegration and chemical decomposition, wherein resistant minerals are set free as individual grains and new minerals are formed. Erosion carries these detrital products down the slopes into natural waterways, where a mechanical separation of heavy particles from light is accomplished by the running water. The accumulation of such resistant, heavy particles through the ages has resulted in formation of the black-sand deposits. In addition to the associated gangue minerals, heavy sand deposits in the Pacific Northwest may contain the following constituents of possible economic value: Gold, platinum, chromite, ilmenite, magnetite, garnet, zircon, monazite, columbite-tantalite, and radioactive blacks.

Jan 1, 1956

By S R. Grano, M Vera

This paper deals with two separate case studies investigating the froth phase performance and characterisation of two industrial rougher/ scavenger flotation circuits. Froth phase performance was quantified using a mass balance approach to estimate froth zone recovery. Measured characteristics of the froth phase included frother solution concentration determined by gas chromatography, and the time taken for an equilibrium froth sample to decay to one-half of its original froth height. The latter measurement is referred to as the æfroth half-lifeÆ and is strongly linked to froth stability. Special methods and techniques developed to preserve frother in solution and to measure froth half-life are briefly described. The frother type in the first case study was a mixture of straight and branched alcohols, whilst the frother type in the second case study was a mixture of alcohols, aldehydes and triethoxybutane. The first case study focussed on a flotation circuit treating a low-grade ore containing only a small fraction of floatable copper sulfide minerals, while the second case study focussed on a flotation circuit treating a higher grade complex sulfide ore containing significant quantities of chalcopyrite, galena, sphalerite and pyrite. It was found that froth zone recovery of valuable mineral generally decreased down-the-bank of the two industrial rougher/scavenger circuits. Moreover, decreases in froth zone recovery significantly limit the overall cell recovery of valuable mineral achievable from the plant scavenger cells. However, the decrease in froth zone recovery could not be linked to the removal of frother from the pulp solution to the concentrate product in the preceding rougher flotation stages. Measurements of residual frother in solution suggested that, approximately, only five to ten per cent of the added frother was removed into the rougher/scavenger concentrate, with the remainder appearing in the scavenger tailings. This finding suggested there was apparently adequate frother in solution in the scavenger stages.

Jan 1, 2005

By R. Stenne

This paper deals with a complementary soil investigation which being part of the contract helped understand the behavior of a softened clay and adjusted the design of a retaining structure accordingly. The investigated softened clay proved to have lost its original strength but had maintained some characteristics of its stress history and in particular high horizontal stress. Pressuremeter tests and flat dilatometer tests were of interest to estimate the at rest earth pressure. A design consisting of a T-shaped slurry wall in conjunction with transverse walls was the most effective solution to cope with high active pressures and low passive pressures.

Jan 1, 2000

By A. G. Starliper

Research was conducted by the Bureau of Mines to determine feasible roasting methods for the removal and the recovery of germanium, cadmium, and lead as enriched fractions from sphalerite concentrates. The two types of roasting processes studied were: (1) Batch, with a stationary bed, and (2) continuous, with a suspended bed, Results indicated that either method gave satisfactory metallurgical recoveries} but the continuous process is recommended because of inherent advantages. Final products were enriched fractions that could be treated by conventional methods for production of metallic germanium, cadmium, and lead. In the batch process, the concentrates were placed in a large tube furnace and heated at 1,080° C, an average of 3 hours. During the heating period, inert, reducing} or sulfur-laden gases were passed over the stationary charge to convey the sublimed metal sulfides from the hot portion of the tube to a lower temperature condensing zone at the end of the tube, where the metal sulfides were collected on baffles and recovered. In the batch and fluidizing roasting processes alike, the gases passed over or through the charge and served only as carriers for the sublimates and as suspension media in fluidization roasting. Since both processes depended on the volatilization, at relatively high vapor pressures, of the sulfides of germanium, cadmium, and lead, it was imperative that very little oxygen come in contact with the charge to alter the sulfide minerals. Germanium has a high affinity for oxygen, but in this instance it was buffered by being in solid solution in zinc sulfide.

Jan 1, 1961

By Gregory B. Poole

As part of a $3.5 billion program to improve the antiquated waste water system in the city of Atlanta, the Nancy Creek Tunnel is being constructed across the northwest portion of the city. This tunnel is over eight miles long and is being constructed using Tunnel Boring Machines (TBM) for the majority of the tunnel and conventional drilling and blasting for three shafts, starter and tail tunnels and four connecting tunnels, totaling 2400 feet in length. An extensive public relations program was developed for this project. A group effort by the owner, engineer and contractor produced a public relations program that both informed and educated the public of the anticipated perceptions and effects of the blasting and TBM activities.

Jan 1, 2005

By W. E. C. Eustis

1st. THE fine iron ore is mixed with a sufficient proportion of fine coking coal, and is coked in any of the ordinary methods for making coke. The effect of this is to convert the iron oxide into sponge in such a shape that the usual trouble of oxidation is avoided. 2d. The resulting mixture of coke and sponge is melted down in an ordinary cupola, the coke furnishing more than sufficient fuel for that purpose. I may briefly point out here that in the first place the iron is sponged, and this sponge, as is well known, contain-, no phosphorus or silicon when the reduction takes place at a low temperature; and in the second place this sponge is melted down in a cupola in which there is no zone of reduction for phosphorus or silicon, and that con¬sequently the resulting iron should be free from both of these impu¬rities. 3d. The liquid sponge, now carburized, is run into an open-hearth furnace, where the requisite degree of hardness or softness is obtained by adding some of the fine ore, and the usual dose of ferronmanganose. I have merely given above the rough outlines of the process, but it is my intention, as early as possible, to bring the process more fully before the Institute.

Jan 1, 1881

By R. B. Porter

Bench-scale tests were performed by the Federal Bureau of Mines on lignite and subbituminous coal at pressures to 1,000 p.s.i.g. (pounds per square inch gage) in atmospheres of hydrogen or nitrogen to obtain information concerning the influence of pressure on carbonization of normally noncaking coals. The distribution of gaseous, liquid, and solid products as a function of processing pressure was determined. Except for special experiments, the carbonization was at 940° F. In a hydrogen atmosphere above 400 p.s.i.g., agglomeration of the solid residue (especially with lignite) became noticeable and increased directly with the processing pressure. Although in some instances the solid particles fused together, the mechanical strength of the agglomerate was always low. On the basis of visual inspection, the coals agglomerated in the following order of decreasing intensity: (1) Steam-dried lignite; (2) lignite; and (3) subbituminous coal. Addition of lignite tar in quantities to 25 percent by weight of charge did not increase agglomeration or change the carbonization characteristics of the coal.

Jan 1, 1961

By Bill Parnell

"Friction winders and double drum winders have been used in the vertical shaft mining industry for over 100 years. In that time, there have been many changes made in the electronic and mechanical fields of hoisting, but few changes made in the manufacturing and performance of steel wire rope, until recently.In the past ten years, with the advent of high polymer thermoplastics, the industry has seen some major advancements in steel wire rope. By incorporating a polymer with steel, improvement of rope life and reduction of costly maintenance downtime has been accomplished.IntroductionThe Williams Mine is Canada's largest gold producer with an annual production of some 500 000 ounces of gold from 2.2 million tonnes of ore. The Williams Mine is situated in the Hemlo area of northwestern Ontario, approximately 40 Ian east of the town of Marathon. It is operated by the Williams Operating Corporation which is owned equally by Teck Corporation and Homestake Canada Inc. It is one of three adjacent properties forming the Hemlo gold camp."

Jan 1, 1995

By R Barritt

Remedial options for a waste rock dump (WRD) were considered as part of closure planning studies at an active mine in Western Australia. To minimise the impact of any seepage from the landform it was determined that placement cover system utilising the moisture ‘store-and-release’ concept was appropriate. The purpose of the cover system was to:•Reduce net infiltration of meteoric water to attenuate peak concentrations for contaminants of concern in natural receptors to levels that can be assimilated without adverse impact to the surrounding ecosystem; •Provide a growth medium for establishment of a sustainable vegetation canopy; and •Improve current quality of surface water runoff from waste storage areas.The project comprised several phases of work: materials characterisation, numerical soil-plant-atmosphere (SPA) modelling and finally cover system construction and monitoring equipment installation.CITATION:Barritt, R, 2018. Conclusions from long-term cover system performance monitoring – a case study, in Proceedings Life-of-Mine 2018, pp 101–105 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 25, 2018

By Stephan A. Jefferis

I presume that the questioner is not asking about the reduction of sulfate in groundwater to hydrogen sulfide as a result of biological activity promoted by organics in the grout hardener and that the question relates to sulfate attack on cementitious grout systems. For the project in Spain presented in my paper, we used a very high pulverized fuel ash (PFA) content in the cementitious material. This gives good sulfate resistance and indeed the chemical interaction will actually cause the permeability to drop for about 50 years without any question of sulfate attack and damage to the whole thickness of the grout - of course there will be attack at the exposed face of the grout where it is in contact with the contaminated groundwater. The mix had over 75% PFA, and also a very high overall cementitious content. The mix was the contractor's design and showed excellent behavior in laboratory proving trials. In grouts as distinct from concrete, PFA gives significantly better sulfate resistance than ground granulated blast furnace slag which is often used in Europe as a component of bentonite-cement mixes for slurry trench cut-off walls.

Feb 10, 2003