Search Documents

By Steven I. Baskin

Cyanides are utilized in many industrial applications including preparation of chemical intermediates, electroplating, and' mining, Cyanide has been utilized in chemical warfare operations as well Cyanide is also synthesized and found in plants and animals including man where it is thought to perform multiple functions. A variety of enzymes are known to detoxify cyanide under different conditions. These include rhodanese, 3-mercaptopyruvate-sulfur transferase, thiosulfate reductase, cystathionaseand albumin. Cyanide appears tQ exert its toxic effect primarily by inhibiting cytochrome oxidase? although other enzymes are also inhibited. Therapeutic antagonist categories to treat cyanide include methemoglobin formers such as nitrite, sulfane-sulfur donors such as thiosulfate, metal salts or complexes such as cobalt and cyanohydrin-forming compounds such as dihydroxyacetone or alpha keto-glutaric acid. Advantages and disadvantages of each category will be discussed. Newer compounds under development have been found that may allow for prophylactic therapy for cyanide poisoning with minimal side effects; In addition, portable co-oximetry devices may provide real-time measurement of cyanide in field units.

Jan 1, 1998

O.F.S. Branch, Welkom Minutes of a Committee Meeting held in the V.LP. Lounge of the Welkom Club on Tuesday, 26th June, 1973, at 5.00 p.m. Present Mr C. J. Isaac (in the Chair), Mr D. A. Smith, Mr G. Young,

Jan 1, 1974

By P Hanna

Following the Busang fiasco, more detailed guidelines were appended to the latest revision of the JORC Code released in September 1999 (JORC, 1999). Although the definitions and terminology essentially remained unchanged, the additional information in the guidelines has highlighted a number of issues for consideration by geologists undertaking computer-based resource estimations. The three main issues are:Data Integrity û details such as drilling and logging techniques, sampling procedures, assay tests, site visits, data recording and aggregation methods need to be considered. Geological Interpretation û is the Competent Person applying the appropriate software interpretation to the deposit in accordance with the regional setting. Are the correct computer-based tools being applied and are they producing the desired result (without compromise) to the satisfaction of the Competent Person? Modelling Technique û the importance of the relevant experience of the Competent Person not only in regard to the geology, but also with respect to the modelling algorithms and resource calculation methods of the computer software system involved. At the end of the day, it is essential that the Competent Person undertake a reality check on the resource estimation itself. They should also check that the borehole spacing is in accordance with the level of continuity for each critical parameter (such as structure, grade, impurities, etc) for which the resources are categorised.

Jan 1, 2000

By N. Shi, T. G. Joseph

ABSTRACT Before any large plant is moved onto an oil sands dominated surface, particularly those surfaces encountered in-pit, it is imperative that the ground be evaluated for bearing capacity. A 2230 tonne mobile in-pit hopper/crusher facility designed for operation in the Canadian oil sands was modeled. This evaluation focused on track and outrigger pad versus ground interactions as the key performance indicators of appropriate ground performance below the unit in both operating and repositioning propel modes. A study of cyclic oil sand behaviour was also inferred from laboratory cyclic plate load data as an extension of the simulation model indications.

Jan 1, 2013

By Andreas H. Vassiliou

Organic materials are major constituents of the ore in several uranium deposits. Some of these deposits have been described as "urano-organic" because, the organic materials are believed to have provided the dominant control for the accumulation and deposition of uranium and are directly and intimately intermingled with the uranium. The nature of these urano-organic deposits has been problematic in terms of (a) the origin of the associated organic materials and (b) the specific form of' occurrence of uranium. The organic materials in urano-organic deposits have been genetically related to both coal and petroleum or their progenitors or deriva-tives. Analytical data presented here (infrared, chemical. D.T.A.) suggest that coaliferous materials or related plant derivatives represent the main source of the organic fractions in practically all major urano-organic ores analyzed from the Colorado Plateau and other areas. Recognition of the specific form of occurrence of uranium in urano-organic deposits has been problematic mainly because the uranium is usually in an extremely fine-grained and disseminated state in the organic matrix. Electron microprobe and X-ray diffraction analyses presented here show that fine-grained uranium minerals, specifically uraninite or coffinite. are disseminated in the organic matrix as the predominant form of uranium in most major deposits; however. the presence of true organo-uranium compounds is also suggested for some deposits.

Jan 1, 1981

By R. Kerby, T. R. lngraham

The rates of cadmiuln cementation from buffered solutions were studied on both the cylindrical and circular faces of a rotating zinc disk. The activation energies are equivalent on both surfaces, but the rate is more rapid on the cylindrical face. At higher temperatures and at pH values above 6.4, the rate of deposition increases because of an increase in the cathodic area of the deposit. The rate may also be increased by decreasing the thickness of the diffusion layer by rapid stirring. The presence of small amounts of copper, cadmium, lead, iron, or aluminum in the zinc does not affect the cementation rate, but when srnall amounts of copper, cobalt, and arsenic were present in the solution cadmium deposition ceased shortly after it started. Small amounts of copper in solution become cemented with the cadmium to form a coarse deposit of Cd3Cu. When zinc ores containing cadmium are processed for electrolysis, the cadmium appears with the zinc in the leach liquors. Because of the discharge potential of the cadmium ion and the hydrogen overvoltage on metallic cadmium, the cadmium ion must be removed prior to zinc electrolysis to prevent its codeposition. Cadmium is usually removed from acidic zinc sulfate solutions by cementation on zinc. When zinc sheets are used with the appropriate conditions of pH and temperature, a finely divided, high-purity cadmium powder is obtained; it floats to the surface with attached hydrogen bubbles and, after careful washing, may be processed directly to a marketable product.' The reaction on zinc sheets is relatively slow because of the limited amount of exposed cathodic area on the sheets. A much more rapid reaction is obtained when zinc powders are stirred into the solution, but this procedure does have a potential disadvantage: some unreacted zinc may be trapped in the cemented cadmium and thus lower its grade.1 The equilibrium constant at 25°C for the displacement of cadmium by zinc is of the order of lo", which indicates that at equilibrium the displacement would be essentially quantitative and no back reaction need be considered. This indication is not entirely true, however, because in the presence of oxygen any loose cadmium which is out of contact with metallic zinc tends to redissolve after cementation.' The overall effect is much the same as that to be expected if the equilibrium constant were much smaller. Previous experimental work on cementation reac- tions3 is in general agreement that the rates of cementation usually follow first-order kinetics. The metal on which cementation occurs is considered to consist of anodic areas from which metal dissolves and cathodic areas onto which the reactive metal is cemented. For the reaction to continue, the cemented deposit must remain open and porous for the removal of ions. Usually, the deposited metal influences the rate of cementation; when it blocks the pores in the deposit, the rate of cementation will be decreased. Alternatively, when the cemented metal grows as den-drites or as coarse powder the cathodic area is correspondingly increased and the rate of cementation increases,3 Thus, it is only during the initial stages of cementation, prior to the development of deposit effects, that the kinetic behavior of the reaction may be studied without ambiguity. In this paper, experiments will be described for cementation of cadmium from dilute solutions onto the surface of a rapidly spinning zinc cylinder. The effects of ionic concentration, disk rotation speed, temperature, and impurities will be described. APPARATUS AND PROCEDURE The apparatus used for the experiments was described in a previous paper.4 It consisted of a 2-liter vessel in which the contents were protected, against oxidation, by a stream of prepurified nitrogen. The vessel was immersed in a water bath which controlled

Jan 1, 1970

By D. J. M. Farnsworth

Since the 1.940's, the bulk of the ore production from the Sullivan Mine has come from pillars. These pillars, located from 100 to 2000 feet below surface, have been subjected to considerable ground pressure. Mining techniques were adopted to minimize the problems of deteriorating ground conditions. These techniques included an orderly sequential blasting of pillars along a retreat front, stage blasting of tall pillars in horizontal slices and utilization of broken pillars as "buffers". The latter two techniques involved leaving substantial tonnages of broken ore in place for as long as 4 years. Rapid oxidation of metal sulphides, with attendant heat and noxious gas generation, had occurred in a few very localized areas of the mine associated with a major water course. However, in a very short period starting in 1972, sulphide fires spread to several of the large blocks of broken ore that had been left inactive for lengthy periods. There proved to be no feasible method of extinguishing these fires, except by complete removal of the burning ore. The attendant problems of handling large tonnages of burning ore have had considerable negative impact on the mine operation. The chemical reactions involved in these sulphide fires have been studied by the mine staff to determine the conditions necessary for' initiation and propagation of the tires. Techniques to safely and efficiently handle hot ore have been implemented and refined. Lastly, and most important, mining methods at the Sullivan Mine have been revised to ensure that additional fires do not occur.

Jan 1, 1977

For the past five years the University of Queenslandhas, through its various workshops, been preaching to Australia that there was a potentially hazardous situation from earthquakes for urban Australia. A few people outside The University accepted this, but largely the warnings fell on deaf ears.The 1989 Newcastle earthquake changed that per-ception. The most important lessons to emerge from Newcastle were (i)the realization that in continental areas small earthquakes cause widespread damage:(ii)the local geology of an area is of great importance in the damage done by an earthquake.These two factors clearly indicate that, in the future, we must take far greater account of the "Urban Geology" of an area. This paper discusses the need for urban geology and its impact on seismic risk and compares that with the traditional methods of assessing seismic risk.

Jan 1, 1990

By Eric Westman

Ground control problems caused by multiple-seam interaction frequently sterilize coal reserves. Interaction mechanisms differ for overmining and undermining and are controlled by mining, spatial. and geologic conditions at each site. A multiple-seam interaction analysis software program, UGLY (Uppersearn Gateroad Longwall Stability), has been used to evaluate sterilization of coal reserves due to overmining at three locations. Four case histories were reviewed to determine the effectiveness of improved ground control in mitigating interaction effects.

Jan 1, 1997

By Thomas M. Barczak

The performance characteristics of Mobile Roof Supports (MRS's) were evaluated through full-scale testing in the Strategic Structures Testing Laboratory at the National Institute for Occupational Safety and Health, Pittsburgh Research Center. Safety issues pertaining to the operation and design of these supports for pillar extraction during retreat mining are examined. A unique load frame, called the mine roof simulator, provided a realistic simulation of mining conditions by inducing vertical, horizontal, and lateral loading on the support. The purpose of these experiments was to determine the capabilities and limitations of the supports and to investigate factors that influence the measurement of loading and loading rate. An evaluation of the support design and load conditions that can cause support failure or loss of support capacity are discussed relative to the laboratory tests. In general, lateral loading perpendicular to the longitudinal axis of the canopy is most severe, although horizontal loading in the direction of the long axis of the canopy can also produce critical loading in some cases. The experiments indicate that both setting force and leg pressure measurements are influenced by the staging of the leg cylinders. The implications of these factors on load rate measurement are evaluated. A comparison of MRS capacity and stiffness characteristics is made to conventional timber supports.

Jan 1, 1997

By Tad S. Golosinski, R. Larry Grayson

Online education is not new. During the last decade, it has reached the stage where many universities offer a variety of courses, degrees and programs without any associated residency requirements. The most successful of the online universities, University of Phoenix, offers hundreds of accredited programs for close to 100,000 students throughout the world (www.phoenix.edu). Online education is considered to be a valid equivalent to traditional, classroom-based education. It is best suited to the needs of mature students with full-time jobs and a desire to deepen their knowledge. While most of the e-business has experienced severe setbacks during the last two years, e-education shows no signs of slowing down. On the contrary, the number of students and institutions offering online education keeps growing. The value of e-education associated expenditures was expected to reach $300 billion in 2001 (Sanoff,2001), making it a serious and mature industry.

Jan 1, 2002

By Edwards A. B

A table concentrate obtained experimentally by the New Occidental Gold Mines N.L. has unusual interest on account of the presence in it of abundant coated or "black" gold. The concentrate was obtained from ore from the New Cobar mine, Cobar, New South Wales, by feeding the oversize product from a "Dorr Bowl classifier to a Card table.Its assay value was 129 oz. of gold and 52 oz. of silver per ton, yet practically no free gold could be seen on panning.When, however, the concentrate was digested in hydrochloric acid fine rusty gold could be obtained by panning.The following chemical analysis was carried out by the mining company on a similar sample of concentrate.

Jan 1, 1941

By M. Royker

Gold has been demonstrated as a possible catalyst for oxidation reactions. Some evidence for a possible promotion effect of platinum has also been recorded. The influence of platinum as promoter for Au/?-Al2O3 prepared via anionic ion-exchange for the oxidation of glycerol was investigated in a batch reactor at 60°C. It is inferred that the addition of platinum reduces the catalytic activity and the rate of deactivation, resulting in an overall higher final conversion of glycerol with increasing platinum loading. The addition of platinum to the catalyst favours the formation of the desired product, glyceric acid.

Jan 1, 2012

By W. B. Potter

There is probably no more interesting group of mineral fuels to be found in any country than that occurring within the limits of the new State of Colorado. The supplies are so abundant, and the occurrence and distribution are so favorable for easy development and transportation to the future manufacturing centres of the State, that they are destined to play a very important part in the material growth and prosperity of the region, the more so because of the rich and varied stores of ores awaiting metallurgical treatment, and the comparative scarcity of timber for fuel. From a purely scientific point, also, these lignitic coals form an interesting and important series. An examination of their geological occurrence and relations opens up new and important questions regarding the comparative value of various kinds of geological evidence, while a study of the character and composition of this class of fuels, which forms a connecting link, as it were, between the lignites and the true bituminous coals, may lead to a more thorough and accurate classification of mineral fuels. The analyses here presented are from samples, of not less than fifty pounds each, obtained by myself during the summer of 1875, and may be regarded as representing very fairly the average run of

By Royston D

Victoria has an extensive brown coal resource, 202,000 Mt, of which 43,300 Mt is regarded as readily recoverable. This brown coal is located principally in the Latrobe Valley as thick seams and is being extracted at low cost primarily to support base-load electrical power generation. The high moisture content of the coal is partially off-set in many applications by the high reactivity of the coal and the generally low levels of potential pollutants such as ash, sulphur and nitrogen in the coal. Large scale development of this brown coal resource began in the 1920's. In addition to electricity generation, it is used for briquette production, carbonisation of briquettes to char and was gasified for town gas supply to Melbourne (1956 - 1969). The BCLV coal to oil pilot plant at Morwell is a major new initiative in the use of Victorian brown coal. Many other new developments are in place and emerging in the utilization of low rank coals. Examples of these developments are, the large-scale gasification of lignites in the USA, and value-added products such as bulk chars, solid fuels, activated carbons and coal-water mixtures. The Government of Victoria has created the Coal Corporation of Victoria to promote current sales of briquettes and to encourage further new industrial developments based on the State's brown coal resources, in particular the Loy Yang coalfield. The Coal Corporation also has a vigorous product and process oriented research and development Programme.

Jan 1, 1987

The Bayswater seam of the Singleton Coal Measures is discussed in relation to its field occurrence and related li~hotype profiles. The seam is correlated throughout widely separated areas of the Hunter Valley with the Farrells Creek seam at Howick, Broke seam at Broke, and Saddlers Creek seam at Mt. Arthur. The unusual features of composition of the seam in relation to adjacent seams is dealt with in terms of the seam environment, particular attention being given to the sandstone at the base of .the seam. Petrographic and other data are used to support the arguments submitted.

Jan 1, 1973

By Meakins R. L, Talaska A, Kenny D, Haycraft J. A, Dickson B. L

A vehicle-mounted radiation detector interfaced to a microprocessor called PRAM (programmable radioactive analyser mobile) has been developed to provide grade control for selective mining of a soft rock uranium ore. The grade of ore over which the vehicle passes is determined and indicated by several coloured lights to a pegman who walks behind the vehicle. Coloured pegs are then laid out to mark the uranium grade ranges on the floor of the mine pit. Comparison between grade ranges determined by the PRAM and by prior drilling and downhole logging at the Yeelirrie deposit, Western Australia indicate good agreement. Use of the PRAM decreases the cost, manpower and time required to grade extensive areas of a mine pit floor.

Jan 1, 1982

By Dong Maolin

A great amount of high temperature off-gas, whose maximum temperature is up to 2100?, is generated during the smelting process of electric arc furnace (EAF). The dust content, which is mainly iron oxide, of the off-gas is high and worthy of industrial recovery. The heat carried by the high temperature off-gas with dust is about 11% of the total energy input of EAF, and some even is as high as 20%. The high-temperature off-gas not only takes away a lot of heat but also places a huge burden to de-dusting system of EAF. It not only reduces the iron oxide dust recovery ratio, but also causes serious pollution problems. With the development of the iron and steel industry, the proportion of molten iron for EAF gradually increases, and even more than 30% in some cases. The increase of molten iron causes increases in the amount of EAF off-gas and heat waste. As a result the problem of dust removal is worsening [1-2]. How to sufficiently recover the sensible heat of the high temperature off-gas, create conditions for efficient dust removal, thus reduce operating costs of dust removal system and the production costs is a problem which EAF steel making companies must pay attention to.

Oct 30, 2017

By J. B. Mawdsley

"AbstractThe uraninite-bearing deposits in the Charlebois Lake area of northeastern Saskatchewan are unusual and important concentrations of uranium. They were first discovered in 1949 and preliminary development work to the end of the 1951 field season indicates the probability that this will become •another uranium producing district. The deposits are in zones bordering granite masses. These zones are of migmatite (mixed rocks) composed of calcium-rich meta-sediments intruded and replaced by a fine-grained white pegmatite. Locally this pegmatite is replaced by an end fraction which is relatively rich in fine-grained disseminated uraninite; it is these occurrences that constitute the bodies of economic interest.The fine-grained white pegmatite contains plagioclase feldspar more lime-rich than that in the granites of which it is an end differentiate. This extra lime, evidently derived from the intruded sediments, would result in the raising of the temperature of crystallization of the pegmatite-forming magma, thus consolidating it rapidly near the granite contacts as a fine-grained pegmatite. The end liquor containing uranium was evidently locally concentrated in minor fracture zones in these pegmatites. Where no lime sediments were present. the coarse-grained alkaline pegmatites were formed. Their crystallization would not be accelerated and the uranium would tend not to be localized in the pegmatite but to migrate and consolidate at lower temperatures with the end products, possibly in some instances as pitchblende veins."

Jan 1, 1952

By A M. Myrvang, B Nøst, N Q. Trinh, I S. B Bergh

The iron ore producer Rana Gruber AS is situated in northern Norway just below the Arctic Circle, and has been producing hematite and magnetite concentrates for more than 60 years. Since the late 1990s, the major part of the production comes from a sublevel stoping underground operation after many years of open pit mining. Despite moderate mining depth, the operations have experienced considerable rock stress problems due to quite high tectonic, horizontal stresses. To manage the problems, comprehensive rock mechanics investigations have been carried out by SINTEF, a major contract research organisation. This has included in situ rock stress measurements, laboratory investigations and numerical modelling. Based on this and practical experience, satisfactory design of vertical and horizontal pillars was achieved. At depth, the ore width increases from 30–40?m to more than 100?m. This, together with a major planned increase in production, called for a change of the mining method. After thorough investigations and considerations, it was decided to change to sublevel caving, very much like the LKAB system. The development of the new system has been closely followed up by rock mechanics measures, including 3D numerical modelling and comprehensive monitoring of deformations and rock stress changes. To achieve a satisfactory caving of the hanging wall, all vertical and horizontal pillars in the sublevel stoping area had to be removed. This has been a challenging task, and the development of the caving has been slow until recently. However, now the caving develops satisfactorily.CITATION:Bergh, I S B, Trinh, N Q, Myrvang, A M and Nøst, B, 2014. From sublevel stoping to sublevel caving at Rana Gruber, Norway – rock mechanical aspects, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference , pp 323–330 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 5, 2014