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"Chairman: Professor J. de V. Lambrechts Rapporteur: Mr R. HempPapers:Computer-aided design of a flash smelting installation by M. A. T. Cocquerel, R. T. Gates and L. A. GreenPlanning of mine ventilation by E. U. Reuther and A. DohrnenCoal mine ventilation systems in the U.S.A. by R. Stefanko and R. V. Ramani Heat flow models in ventilation planning by A. J. Dickson and A. M. StarfieldThe first of the papers in the session dealt with a flash smelter installation, while the remaining three papers dealt with mine ventilation. In view of this the Chairman proposed that the paper on flash smelting be introduced and discussed first, after which the remaining three papers would be introduced followed by discussion on all three.Dr Cocquerel, who presented the first paper, used some typical flow diagrams to illustrate the process and stated that the program considered only steady-state operations and did not take into account the dynamical changes. Subjective judgment was necessary for the preparation of input data and some degree of user appreciation was required.Dr Cocquerel said that no work bad yet been done on an optimization program, but that this was being considered. Such a program would require a large amount of physical and chemical data which were not yet available. The variables to be optimized were the energy and material consumptions and the loss of metal in the slag.The Chairman opened the discussion by asking Dr Cocquerel if he could give a brief description of the flash smelting process for the benefit of those not familiar with the subject. Dr Coquerel replied that in the Outokumpu process con¬centrates were injected directly into the furnace, and that the process was somewhat analogous to flash distillation or evaporation processes, but was perhaps closer to the burning of pulverized fuel.The process had two distinct advantages. First, the heat evolved in the smelting reaction was used to heat the furnace, which resulted in less fuel consumption, and, second, the effluent gases were cheaper to treat than the effluent gases from other pyrometallurgical processes. This was important particularly in view of the current interest in pollution problems.Mr P. Marais thought that the authors had done themselves an injustice by not including details of the very complex processes taking place in the furnace."

Jan 1, 2014

By Luis Bergh, Juan Yianatos, Luis Vinnett

"Process automation as an engineering discipline is more than control systems since it includes industrial instrumentation, such as sensors, transmitters and actuators, as well as control and supervision systems, collection and transmission of data and real-time software applications to supervise and control the operation of plants or industrial processes. In the last several decades, accelerated technological development has provided a variety of software and hardware tools to aid development, maintenance and continuous improvement of automated systems. These developments however seldom reach their full potential in real plants. There are many factors to be considered, among them human capital specific training and the organization model. In this paper, a methodology for training engineers in advanced control and supervision of flotation plants is presented based on study of the application of these technologies in hybrid pilot plants. Since experimentation in real plants may present undesirable risks and costs, and simulation studies are usually limited to some unrealistic conditions, a laboratory where on-line measurements of the hydrodynamic behaviour of a pilot plant is mixed with phenomenological models has been created. In this form, an environment as close as possible to a real plant can be recreated. A flotation column and a circuit of three pneumatic cells are fully instrumented and connected to a PLC and PC network. In the control room, students learn applications of classical PID control in a DCS environment, advanced predictive control, on-line process operation diagnosis, fault analysis, virtual sensors and expert-fuzzy systems. Several undergraduate and graduate courses and theses are supported by this Process Control Laboratory infrastructure. Examples of these applications are discussed."

Jan 1, 2014

By Tomohide Takeyama, Yuki Yoshida, Masaki Kitazume

"Abstract A series of centrifuge model tests was conducted to investigate the failure pattern and stability of cement treated clay ground having an unsupported vertical slope. The model ground was subjected to monotonically increasing centrifugal acceleration until it failed due to the enhanced self-weight. The test results were compared with the numerical analyses in which the treated soil was simulated by the Smoothed Particle Hydrodynamics (SPH) method. In the simulation, the Dracker- Prager model is employed as the constitutive model. In order to simulate the brittle behavior of the cement treated soil, it is assumed that the unconfined strength is gradually reduced to a certain value which corresponds to the residual strength due to accumulated plastic strain. It was found that the simulation by using SPH method can express the brittle failure observed in the centrifuge model tests.IntroductionBecause of economical and environmental concerns it has become more difficult in recent years to obtain enough soil to construct reclaimed land for airports, electric power plants, manufacture plants and so on. On the other hand, it has become difficult to find and construct disposal sites for waste subsoil or dredged soil. These circumstances have encourage geotechnical engineers at present to use these poor quality materials as filling materials more than they were used one or two decades ago. Several soil admixture methods have been developed to improve their properties and to manufacture high quality fill materials.The deformation and strength characteristics of cement treated soils have been investigated in Japan, which have revealed that the treated soil is characterized by a brittle behavior with quite high compressive strength and quite small strain at failure, and the treated soil with relatively high strength shows tensile failure instead of shear failure. Regarding to evaluate the stability of structures adjacent to or buried in the treated ground, Kitazume (1998) and Kitazume et al. (2003) investigated the earth pressure of cement treated ground by the centrifuge model tests. And they emphasized that the failure pattern of the cement treated ground was much different from that of ordinary ground. After the Hyogoken- Nambu earthquake in 1995, many design codes for the seismic stability were revised in Japan, so that seismic stability must be evaluated more precisely. The dynamic earth pressure of ordinary grounds is usually calculated by a pseudo-static limit equilibrium method based on the Mononobe- Okabe’s method (Okabe, 1924; Mononobe and Matsuo, 1929). This calculation method is also applied to the cement treated ground, although its applicability has not been thoroughly clarified."

Jan 1, 2014

By V. Nasri, S. Rashidi

The Baltimore Red Line Project is a proposed 22.7-km (14.1-mile) long east-west light rail transit (LRT) line envisioned to connect the areas of Woodlawn, Edmondson Village, West Baltimore, downtown Baltimore, Inner Harbor East, Fells Point, Canton and the Johns Hopkins Bayview Medical Center Campus. The Red Line LRT System has two tunnel segments - the Cooks Lane Tunnel (CLT) and the Downtown Tunnel (DTT). The CLT segment is roughly 1,920-m (6,300-ft) long. It commences at the west portal located at the highway ramp for I 70 (to be removed) and terminates at the east portal that is at the intersection of Edmondson Avenue (U.S. Route 40) and Glen Allen Drive. This segment of the project consists of the following construction components: approximately 1,458 m (4,786 ft) of tunnels, 143 m (469 ft) of cut-and-cover tunnel, and 318 m (1,045 ft) of retained cut (U) section. The approximate horizontal alignment for the Red Line LRT Project is shown in Fig. 1.

Jan 1, 2014

"Chairman: Professor J. C. Griffiths Rapporteur: Mr J. P. G. PRETORIUSPapers:Mine-mill production scheduling by dynamic programming by R. J. Roman Optimization of a large mining venture by J. C. Paynter, B. K. Loveday and C. G. Robinson Economic surface mining of multiple seams by T. V. Falkie and W. E. PorterIn introducing his paper, Mr Roman said that whereas in manufacturing plants the yearly production levels were usually chosen to produce the largest annual cash flow, in a mining operation, the raw materials (ore) were exhaustible so that the production had to be scheduled to maximize the total net present worth of the operation. This optimum production schedule could be determined by using dynamic programming. The required information was readily available to management at most mines. The 'possible operating range' of production rates lay between the rate with the highest profit per ton. and that with the highest profit per year. The optimum production rate started typically at the top of this range and decreased slowly as the deposit was depleted.Dynamic programming was used to determine several production schedules for a hypothetical mine-mill complex. The effects of changes in the ore grade estimates, size of deposit and acceptable rate of interest on the production schedule were taken into account. Apart from the fact that the net present worth of the overall profits was larger than that obtained by conventional methods, it appeared from the cases studied that the amount of metal recovered was also greater.Dr it P. King commented that this was a very interesting application of dynamic programming. He pointed out, however, that the market price of the metal was likely to vary significantly and randomly during the life of the mine, and he suggested that the problem should, therefore, be reformulated as a stochastic dynamic programming problem.If the price of the metal rose to abnormally high levels, a much higher than normal production rate could be expected. The results of analyses given in Table 5 showed that the production rate was a function of market price. In his view the stochastic problem could be solved just as easily as the deterministic problem.In reply to a question by Dr King as to whether the function relating recovery to production rate (Table I) was based on real data, the author replied that it was based on the results of an analysis conducted at the Union Carbide Corporation's Pine Creek tungsten mine in California.Dr D. M. Hawkins stated that costs were incurred when the production rate was altered, for example, in appointing or laying off staff, and that in practice it may be necessary to take these costs into account in finding the optimum production rate. Mr Roman replied that, while normal administrative costs were accounted for, the additional costs incurred in appointing and laying off staff were not taken into account."

Jan 1, 2014

By Kaustubh Joshi, Pradip, Beena Rai, Venugopal Tammishetti

"Rapid depletion of high grade iron ores coupled with the increasing demand for the blast furnace grade iron ore in recent times has shifted the research focus on the development of appropriate technologies for the utilization of low - grade alumina rich iron ore slimes. These slimes are currently being dumped into tailing ponds owing to their high alumina content. Typical constituent minerals present in the Indian iron ore slimes are hematite, goethite, gibbsite and kaolinite. Considering the fine particle size distribution (<37 microns) in the slimes, selective dispersion-flocculation seems to be one of the most appropriate process which has been explored by us. We present our successful results on a natural iron ore slime sample obtained from one of the mines in India. We have been able to achieve a concentrate assaying >67% Fe, and <3% Al2O3 and 2.8% loss on ignition (LOI) from the slime sample assaying 60.4% Fe, 7.7% Al2O3 and 5.45% LOI with an Fe recovery of 62-69% simply by adjusting the pulp pH. We have scaled up the process to a semi batch scale as a prelude to commercialize it for the beneficiation of low grade iron ore slimes."

Jan 1, 2014

The primary (sulphide) resources at Aphrodite are refractory in nature, requiring an oxidation process stage to be introduced to facilitate extraction of the gold. The company is investigating the use of pressure oxidation (POX) as the oxidation method for processing of high grade gold bearing concentrate it plans to produce at Aphrodite. POX has been used extensively around the world for the past 30 years and continues to be the favoured option for a number of refractory gold plants currently in the design and construction stages. Initial pressure oxidisation testing investigated the effect of temperature, pressure and grind size on a bulk flotation concentrate prepared from Alpha lode material. The concentrate averaged 47.3 g/t gold and was prepared from a composite of core samples averaging 1.49 g/t gold. Sub-samples of the concentrate were subjected to POX for 1 hour resulting in rapid oxidation during this very short period. Testing undertaken showed that there was a significant increase in sulphide oxidisation at higher temperature (220°C) and pressure (2,500 k/Pa) for the two grind sizes (75 and 20 microns) evaluated. The proposed flowsheet, OPEX and CAPEX are critical aspects for project development.

Jan 1, 2014

By D. W. Fuerstenau

Understanding how cationic surfactants affect the interfacial behavior of quartz is important in mineral processing and environmental engineering. This paper presents the results of a study of the effect of the molecular structure of cationic surfactants on the interfacial behavior of finely ground natural quartz. Most of the experimental work involved the determination of zeta potentials and the stability of quartz suspensions. Some measurements of induction times and the flotation response of coarser particles are also included. How these surfactants affect interfacial behavior is discussed in terms of adsorption mechanisms. The molecular structure (number of hydrocarbon chains, type of ionic head group, number of ionic head groups on the molecule) of these reagents was found to significantly affect their surface activity.

Jan 1, 2014

By Bern Klein, Givemore Sakuhuni, Libin Tong

The use of continuous discharge centrifugal concentrators introduced in the early 1990’s for recovery of gold associated with sulphides has introduced a novel application niche for gravity concentration which could not be realized with the low mass yield batch and semi-continuous concentrators. A typical application is scavenging gold associated with sulphides from flotation tails which has potential to increase productivity by reducing gold loss to tailings and lower grinding cost by using a coarser grind. However, the full potential of this technology has not been fully exploited partly due to the lack of reliable small sample procedures to demonstrate applicability. This paper introduces a bench-scale procedure developed to characterize the Knelson Continuous Variable Discharge concentrator (CVD) for scavenging gold from flotation tails. The procedure code named gravity release analysis was derived from standard flotation release analysis. It is a modification of the gravity recoverable gold and gravity amenability test in order to best simulate continuous centrifugal concentration. Based on this iterative procedure, a gravity release index similar to the flotation rate constant, for measuring individual mineral gravity susceptibility for an ore is introduced which can be a useful quantitative measure to both predict application of centrifugal concentration and for plant design. The gravity release analysis procedure was tested on a polymetallic flotation plant tailing at Myra Falls, BC, Canada and results show that it can predict CVD performance. The gravity release index for gold was observed to decrease with each successive cleaner stage showing that the initial stages recover liberated gold whilst successive runs recover gold associated with sulphides and or gangue. The difference in magnitude of the gravity release index for different mineral species shows the species separable by centrifugal concentration.

Jan 1, 2014

By C. Y. Sun

China is a country with abundant resources of tungsten, taking one of the world?s top-positions regarding both the total reserve and the amount of industrial production. China?s tungsten resources occur mostly in multi-metallic deposits rather than in single-metallic deposits. China?s multi-metallic tungsten ores have the characteristics of coexistence with other valuable components such as molybdenum, bismuth, copper, sulfur and fluorite. These ores are usually low in grade and difficult to process. The technological challenge in mineral processing lies in separation of multi-metallic components in these complex ores and a comprehensive utilization of natural resource. Several cases of industrial practice of processing China?s typical multi-metallic tungsten ores are presented.

Jan 1, 2014

By Isabel C. B Rodrigues, Flávia D. Reis, Versiane A. Leão, Rosa M. F. Lima

Attention has been focused in recent decades upon the precipitation of metal sulphides from acid mine drainage (AMD) and pregnant leach solutions, due to the advantages of the sulphide precipitation process over traditional methods employing hydroxides. The aim of this work was thus to explore technologies for copper precipitation using either Na2S or biogenic sulphide. The recovery of copper sulphide was improved when the initial pH of the solution containing each metal was 4 or excess sulphide was employed. In such, a condition the removal efficiency was 99.9%, corresponding to a residual level of 0.1mg/L for copper in solution. Kinetic parameters for precipitation were determined from the particle size distributions using the method of moments, where the growth and nucleation rates, as well the agglomeration kernel, were calculated. The biogenic sulphide was a suitable alternative to sodium sulphide for copper removal as either sodium sulphide and biogenic sulphide can be utilized to precipitate such a metal allowing the effluent to be compliant with environmental legislation.

Jan 1, 2014

By Zachary D. Jones

"Construction projects involve a great many risks. The risk that material prices will increase during construction or that the work under construction will be destroyed by fire, storm or some other act of God are just a few examples. In tunneling or other underground projects, one of the most significant risks is that the subsurface conditions encountered during construction will differ from what is expected. Each of these risks must be accounted for, managed and, ultimately, the duty of one party or the other to bear. The primary tool used to allocate the risks among the parties is the construction contract.How construction contracts allocate the risk that subsurface conditions will differ have changed substantially over the past century. Today, construction contracts typically allocate the risk through a series of provisions. The first is the differing site condition or changed condition clause. That clause, when included, typically provides that the owner bears the risk that the subsurface conditions will differ from what is indicated in the contract documents or what is reasonably expected. The second clause is one that provides that the contractor must conduct a reasonable site investigation and bear the risk of any conditions that such an investigation would reveal. The third provision includes disclaimers that are often included in geotechnical data provided by the owner (or the owner’s engineer) to the contractor which attempts to limit the information on which the contractor can rely. Because these risk-allocating devices seem to be somewhat conflicting, a brief discussion of each provides critical insight in understanding how the modern construction contract allocates the risk of differing site conditions.At the start of the 20th century, construction contracts looked substantially different than they do today. For example, one contract for the construction of a public water tunnel in Chicago, IL, drafted around 1895 contained the following clause:The contractor must take the work entirely at his own risk. No extra allowance will be made for quicksand, hardpan or boulders."

Jan 1, 2014

By L. Y. Feng

The percentage of leached zinc in massive zinc oxide ores (11.7% Zn, >2 mm) is up to 73.3 % in 120 days. Alternatively, crushed to -0.154 mm, mixed with cement 5% (wt), pelletized and solidified. The diameters of the pellets obtained are between 5 mm to 8 mm. When the pellet solidification periods are 3 days, 10 days and 45 days respectively, the alkaline leaching rates of zinc in the pellets are up to 95.8%, 89.1% and 76.4% respectively. Decreasing the solidification time can re-duce reaction time, increase dissolution of zinc in pellets and lower the effect of initial zinc concentration on leaching rate. The experiment results show that the minimum solidification time is three days, and the kinetic study indicates that alkaline leaching of the low grade zinc oxide pellets is controlled by the diffusion of the leach liquor through the gangue layer in the whole leach process, and the apparent rate constants are 3.33×10-2 day-1, 9.18×10-3 day-1, 5.82×10-3 day-1 respectively.

Jan 1, 2014

By V. I. Lakshmanan

Rare earth elements and yttrium (REEs+Y) are being used in the making of hybrid electric cars, catalytic converters, wind power generators, LEDs, hard disc drives, flat panel displays, and portable electronics. Currently China produces more than 95% of REEs+Y, which has made REEs+Y a critical strategic resource. Process Research ORTECH Inc. (PRO) has developed the innovative mixed-chloride (HCl+MgCl2) solvent extraction processes for recovery of REEs+Y from their ores. The HCl leaching system provides the opportunity to regenerate the acid, while the presence of MgCl2 in the lixiviant enhances the activity of the hydrogen ion by orders of magnitude, making the lixiviant very aggressive and resulting in high recoveries of REEs+Y. Solvent extraction steps are used for separation and purification of REEs+Y from other value metals or impurities including iron, zirconium, hafnium, uranium, thorium, niobium, tantalum and titanium. Direct individual separation of REEs+Y in a mixed chloride system allows avoiding the additional process steps of precipitation and dissolution in HCl. The resulting process has a simplified flow sheet that is closed-loop and environmentally friendly.

Jan 1, 2014

By S. S. Lu

In sodium oleate and salicylhydroxamic acid systems, sequence of floatability of three sulfate minerals is: barite>celestite>gypsum, in lauryl amine system is: gypsum>celestite>barite. XPS and infrared spectrum analysis are used to find that it is chemical reaction between sodium oleate and three minerals, physical adsorption on the surface of minerals for lauryl amine, and it is chelating reaction between salicylhydroxamic acid and three minerals possibly. Theoretical calculation on chemical bonds in crystal structures of three minerals is carried out, finding that breaking degree of Mn+?O2- in crystal structures of three sulfate minerals is closed related with floatability.

Jan 1, 2014

At times the phosphate industry, in Florida, encounters phosphate rock that gives lower than expected P2O5 recovery in the rougher plant section. The drop in recovery is typically 10% and as much as 30% or more. Variations in feed quality from day to day, shift to shift and even from drag-line to drag line, represent a challenge to the beneficiation plant operators and reagents? suppliers. Therefore, this characterization study has been initiated to identify the reasons for the differences in flotation behavior of such feeds. The study involves many samples to cover such variations. The characterization work includes: ? Mineralogical and chemical analysis; ? Size, shape, surface roughness and porosity analysis; ? Surface charge and surface contamination with other phases (minerals); ? Clay content and its relationship to phosphate and silica particles. The results correlated with flotation data and adsorption density measurements clearly establish the statistically significant variability in characteristic features that influence flotation response. This article discusses results from the above listed studies. On the basis of the obtained data, recommendations of practical approaches to overcome the problem of feed variability in phosphate flotation plants are delineated.

Jan 1, 2014

By Kjell Karlsrud

"Abstract New semi-empirical design procedures for the determination of ultimate shaft friction and load-displacement response of axially loaded piles in clay are proposed. Hereunder also prediction of how the capacity will build up with time following the pile installation, primarily as result of reconsolidation. A main basis for developing the new procedures was detailed review and re-assessment of results from a series pile load test programs published over the past 30 years on piles well instrumented to monitor soil- and pore pressures as well as load distribution along the pile shafts. Two new alternative procedures are proposed for predicting the ultimate shaft friction; a-approach using the normalised undrained strength based on direct simple shear tests as a main correlation parameter, and ß-approach using the overconsolidation ratio, OCR. Both approaches include the effects of the plasticity index of the clay, Ip, which is shown to have an especially large impact on the correlations when Ip<25. It is recommended to use both methods in design practice, and select design values for the ultimate shaft friction that represents an average for the two methods. Pile diameter, length or stiffness, or whether the pile is open- or closed-ended seem to have little impact on the shaft friction. However, a moderate effect of pile length or flexibility on the total ultimate pile capacity comes out of the proposed t-z curves, which include some post-peak reduction. The proposed procedure for predicting the time for set-up is based on linear radial consolidation theory. The main input parameters are the insitu permeability and virgin modulus number (or virgin compression index) of the undisturbed clay. The same basic formula and correlations are applicable to both open and closed-ended or partially plugging piles.IntroductionThe design procedures presented herein are primarily based on observations and data collected in connection with “fully instrumented” pile testing programs that the author has been responsible for or has become involved with over the past 40 years, or that have been found in the literature.It was a pre-requisite for the test programs included that there were sufficient high quality soil data available to give a reliable determination of the true in-situ strength and compressibility characteristics of the clay deposits. The soil conditions range from soft NC clays with undrained shear strength down to about 15 kPa, to very stiff clays with undrained shear strength up to about 500 kPa and OCR up to 25. The plasticity index of the clays mostly lies in range 12 to 60 %."

Jan 1, 2014

By Yagmur Sirinyurt, Ayhan Ali Sirkeci, Gülay Bulut, Mustafa Özer, Tuncer Acar

"The basic requirement of glass industry for the silica sand is at least 99% SiO2 content. On the other hand, coloring impurities such as Fe and Ti, must be removed. Flotation is the most widely used method for the purification of silica sands from impurities. In this study experimental studies were carried out to reduce Fe content of Mersin (Turkey) district silica sands by flotation. Silica sand sample with a d80 particle size of 1.85 mm was reduced below 0.5 mm in size. Then the size fraction -0.5 +0.106 mm was subjected to flotation tests. In flotation tests, sulfonate-type R801-R825, fatty acid based DER NA 7 (Produced by a Turkish company) and HA110-HA150 a blend of various chemicals produced by Mersin Cam-Is Mining Company (producer of glass raw materials) were used as collectors. Flotation tests showed that sulfonate type R801-R825 collectors provided much better results in acidic medium (pH: 3). The optimum pH value for DER NA, HA150 and HA110 collectors was found to be 7. It was observed that the addition of collector at once caused an increase in the amount of floated product that resulted in a loss of silica to the tailings. In the case of multistage addition of the collector much better selectivity was achieved. As a result of flotation tests conducted under best conditions, a concentrate assaying 0.046% Fe was obtained with a weight percentage of 93.4 when DER NA 7 was used as a collector. In the case of R801-R825 a concentrate was produced with 0.058% Fe content with a yield of 98.4%. On the use of HA150-HA110 the concentrate was produced with 96% weight recovery and 0.052% Fe content."

Jan 1, 2014

The present work aimed to verify the possibility of using froth flotation to separate the constitu-ent minerals of an alaskite rock waste having as the main minerals quartz and feldspar. Three stages of tests have been carried through. In the first stage was used an amphoteric collector for flotation, diaminedioleate, at pH 2 and, after analyzing the final products, a very poor selectivity was ob-served. During the second stage of tests, different collectors that are normally used for feldspar flo-tation as amines, sulfonates and soybean oil were employed. Once more, it was not possible to reach reasonably selective results. In the third stage, a salt of etheramine was used for collecting the feldspar and hydrofluoric acid was utilized for controlling the pH. A simulation of three flotation steps (rougher, cleaner and recleaner) permitted to attain a good selectivity in the flotation process. A concentrate with a silica content of 96.6% was obtained. The low concentrate content of alkalis totalizing 0.52% and a feldspar recovery of 96.5% to the tailings, represented by the high content of Na, K, and Al2O3 in the tailings, demonstrated that the concentrate was made up mostly of quartz.

Jan 1, 2014

By R. K. Dwari

The electrostatic beneficiation of coal is based on tribocharging characteristics of ash forming minerals and coal particles. The tribocharging of quartz, pyrite and coal particles contacted with various metals and polymeric materials have been measured and the charge acquisition is assessed through surface energy calculations from liquid contact angle data. The contact angles, before and after tribocharging of solids, are measured using Krüss tensiometer and Washburn?s method where the sample holders in tensiometer are specially constructed with tribocharger materials. The charge polarity and amount of charge acquired by quartz, pyrite and carbon with metal tribochargers were found in good agreement with the reported work functions of the contacting surfaces. The charge results with polymer materials differed from the work function values, presumably caused by surface contamination. The surface energy of quartz calculated by all the theoretical approaches in the literature showed that the tribocharging increases the surface energy. Both polar and non-polar components computed from Fowkes and Owens-Wendt-Rabel-Kaelble approaches dis-play that both these components increased after triboelectrification. However, the polar component divided into acid and base components, as in van Oss approach, manifest decreasing acid part and increasing base part. Since quartz charged negatively during tribocharging with metal surfaces and therefore accepted electrons, the determined acid and base surface energy components are consistent with charge transfer process. The results also elucidate an explicit correlation between the charges generated by powders and the surface acceptor (acid) and donor (base) electronic states and thereby the work functions. A novel fluidized bed tribocharger was designed and developed with internal baffle system for efficient contact electrification of mineral and maceral to produce high differential charging for efficient separation. The results achieved on coal with 45% ash content are presented and discussed.

Jan 1, 2014