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As a kind of collector, Xanthates are generally used to make sulfide minerals hydrophobic in flotation process. Xanthate adsorption on a galena surface has been widely studied experimentally. In this paper, DFT methods were employed to investigate the local adsorption interactions about the collectors,such as ethyl xanthate (CH3CH2OCS2?, EO) and ethyl trithiocarbonate (CH3CH2SCS2?, ES), absorbing on two different PbS clusters. From the results, it can be easily found that, on the edge or at the apex, both collectors, with two S atoms bidentate coordinating on the clusters, have surprising interaction energies, while on the surface, its interaction is relatively weak in the form of monodentate ligand. NBO analysis results reveal that there is at least a covalence bond with sulfur atom about 10% and lead atom about 90% when the absorbed lead is on the lattice edge or at apex, but, if the absorbed lead is on the lattice surface, no covalence band would be found. Meanwhile, the S-Pb bond, formed by the absorbed Xanthate and galena lattice, seems to have much more covalence characteristic than that formed in the PbS lattice inner. Furthermore, those data also imply that the difference of the collecting effect between the EO and the ES may be not notable, because of the similar distance and the interaction energy for the same interaction mode.

Jan 1, 2014

The mining industry worldwide is currently facing a significant restructuring process. In most underground mines, widespread mechanization of the mining processes increases production while reducing staff numbers. At the same time, mining depths as well as the lateral spread of the mine workings are increasing. This ever-changing mining environment requires sophisticated solutions for the design and operation of underground mines. In fact, a reduced number of mining engineers is taking responsibility for everincreasing mine operations. This applies not only to the excavation of the minerals, but also to all other aspects of the mining operation, including health and safety, disaster management, and mine rescue organization. Most mining engineering graduates entering the industry lack experience in mine emergency management. Young engineer trainees must learn mine emergency management and rescue work in addition to their normal training experience on the job. Often, and unfortunately, emergency and rescue training at different mining companies is not carried out to the highest level and standard and with the best possible training outcomes. The tasks and challenges a young engineer faces while being trained in a new position do not leave much room for additional training in mine rescue and emergency management. At the same time, experienced, ?old hands? are retiring and cannot easily be replaced due to limited graduation numbers. Strategies are being developed at mining universities worldwide to train mining engineering students in handling mine emergency situations and to provide hands-on experience for managing potential accident and disaster scenarios underground. Two of these strategies, from the USA and from Central Europe, are presented in this paper. These specific strategies have to be seen under special consideration of the local and regional boundary conditions, but might serve as case studies for mining schools and universities in other countries.

Jan 1, 2014

By J. L. Deutsch

Block model estimates are commonly calculated by the well-established technique of kriging. The mathematics are well established, but implementation details require site-specific considerations. Checking and measuring the performance of the estimates is important to ensure the block model is suitable for its intended purpose. There are different criteria for long-term planning and short-term planning. The implementation of kriging should be checked with cross-validation and assessed for conditional bias and departure from theoretical optimality with the calculation of kriging efficiency. A new expression of kriging efficiency, which compares the kriging variance with the theoretically optimal kriging variance, is developed to aid in this assessment. The assessment tools presented here can be applied in a number of situations; however, ordinary kriging with a reasonably large search performs well in most cases.

Jan 1, 2014

By William Skinner, Ishmael Quaicoe, Jonas Addai-Mensah, Ataollah Nosrati

To date, intractable ore specific operational challenges such as poor heap geotechnical stability, permeability and high acid consumption rates associated with low grade (~1 wt%) nickel (Ni) laterites still makes the adoption of heap leaching processing unattractive. This paper presents some highlights of drum agglomeration, column leaching and characterization studies undertaken to foster the understanding and knowledge of some of the desirable product attributes of -2 mm and -15 mm, low grade saprolitic (SAP) and goethitic (G) Ni laterite feed ores and their blends (SAP/G). For column leaching, 5-40 mm agglomerate beds were continuously irrigated with 200 g/dm3 H2SO4 solution at 8.5 dm3/m2/h rate over 100 days. Ni, Co, Fe, Al and Mn extraction rates, free acid concentration, agglomerate bed slump and structural changes were determined as a function of time. The results show that at equivalent feed masses, except -15 mm G which displayed slower, pseudo-layering based behaviour, all the feeds (single and blends) displayed coalescence controlled agglomeration behaviour at varying binder dosages. Whilst the agglomerate compressive strength of the G ore was markedly higher than that of SAP ore, those of the blends were substantially similar. At fixed column leaching conditions, the Ni/Co extractions and acid consumption were higher for SAP ore whilst the agglomerate bed slump was lower than those for G ore. The bed of agglomerates produced from -2 mm G/-15 mm SAP blend was more stable than that for the -2 mm G/-2 mm SAP blend agglomerate, the latter experiencing blockage within 24 h of acid irrigation due to agglomerates breakdown. The Ni/Co extractions and acid consumption rates obtained for agglomerates of -15 mm G/-2 mm SAP blend were lower than expected based on the ratios of the SAP and G ores within the blend composition. The findings suggest that judicious saprolitic and limonitic ores’ blending could reduce acid consumption rate, improve the agglomerate bed robustness and enhance bed percolation behaviour under prolonged acid irrigation periods during heap leaching of lateritic ores of variable mineralogy.

Jan 1, 2014

By R. Weber

Methane explosions in underground coal mines are a major concern across the mining industry. After the Pike River disaster, Arnot Coal became even more aware of the explosion risk. To determine whether Arnot has adequate precautions against a methane explosion, such as the one that led to the Pike River disaster, a literature survey covering the causes of the incident and what preventative measures should have been in place was conducted. Many different methane explosion prevention methods were evaluated, as well as codes of practice. Based on the findings, Arnot?s measures to prevent conditions favourable for a methane explosion were evaluated.

Jan 1, 2014

By Fredrik Sarvell, Leo-Ville Miettinen, Veli-Matti Uotinen

"Abstract The continued concentration of building activities in cramped areas of city centres means more underground construction and facilities. Demand to minimize execution time and any kind of disturbance to business, general traffic, people and nearby technical structures is increasing. To answer these challenges foundation business has to develop schedule-wise and technically reliable deep excavation and foundation solutions in vulnerable surroundings and challenging soil conditions.Drilled pipe pile wall – RD-pile wall – is a combination of Ruukki drilled steel pipe piles and interlocking sections. Individual RD piles, typical diameters between 219 mm to 610 mm, are connected to each other with interlocks welded to the piles on the automated welding line at the workshop. The matching dimensions of the drilling system and interlocking sections allow the installation of RD piles through stones and boulders and even into the bedrock, if necessary, in a single operation. Installation is done by a down-the-hole hammer (DTH) using the centric drilling system and oversized ring bits or a drilling system consisting of a pilot bit and reamer wings.RD-pile walls have been used as permanent and temporary retaining walls for different kinds of demanding excavations and structures, such as bridge foundation, as quay wall and as sealing structure in rehabilitation of an existing dam. Rigidity and watertightness of the lower end of the RDpile wall is being researched as well as fire design issues examined. One of the most fascinating RDpile wall solution is to utilize the wall as a permanent underground basement wall. Reliable and rigid connection to bedrock decreases the bending moment and deflection of the wall and good fire resistance in addition to large variety of pile dimensions and steel grades gives possibilities to design and execute a cost-efficient basement wall and foundations without temporary retaining wall works. 1. IntroductionIn northern Scandinavian soil conditions, installation of sheet pile walls, or even secant pile walls, is often problematic due to the existence of hard and large boulders in the overburden, and especially when the retaining wall structure should penetrate to or into the hard bedrock. On the other hand, an efficient and reliable piling technique suitable for the demanding soil conditions described above, percussion drilling, has been developed since the 1960’s, and especially from the mid-1990’s, when the concentric drilling method with the ring bit and pilot was introduced. A new retaining wall application, the RD pile wall was developed by combining that drilling method with the widely used retaining wall solution based on steel pipe piles and welded interlocks (a pipe pile wall normally installed with vibratory or impact hammers)."

Jan 1, 2014

By Kilian Neubert, Wotruba. Hermann, Lars Weitkämper

Metallurgical slags are produced in large quantities all around the world as a result of smelting, refining or alloying processes applied to metals, ores and recycling material. The slag phase serves different purposes in metallurgical processes. It prevents heat losses and protects the metal phases from contaminations and absorbs gangue and extracted impurities. Due to achievable metallurgical efficiencies certain amounts of valuable metal contents always remain in the residual slag. Recycling of these metallurgical slags has several positive effects, such as optimized ecological and economical compliance of the producing industry. If recycled metal contents can be reintroduced into existing processes, required inputs of raw material can be lowered. High metal prices enable the economic recovery of metal contents in metallurgical slags by applying different non-metallurgical processing methods. Conventional processing of metallurgical slags utilizes processes such as hand picking, selective comminution, screening and magnetic separation. Those state of the art processing techniques have limitations in terms of achievable metal recoveries and required energy demand. The approach for an optimized processing of metallurgical slags targets enhanced metal recoveries in combination with lower specific treatment costs. Processes such as coarse and ultrafine density separation, as well as sensor-based sorting as a pre-concentration stage are used to enable an efficient recovery of metal contents in slags. By applying these methods a completely dry working process is possible. This paper reviews the commonly used methods and describes approaches for innovative processing of metallurgical slags to enhance metal recoveries. Focus of this paper is laid on sensor-based sorting as well as on processes for dry density separation.

Jan 1, 2014

By H. H. Li

Reverse flotation is usually used for hematite/silica or bauxite/clay flotation separation in which the silica or clay is floated and rejected. Some properties of these silicate minerals such as particle size and surface characteristics have significant effect on their flotation behaviours. Firstly, the silicate mineral particles (especially clay minerals) generally have fine particle size (< 5 microns) in their natural states or due to overgrinding and they display poor flotation kinetics, consequently having low flotation recovery. Secondly, the wettability difference on different particle basal planes influences the affinity for adsorptions of different types of chemicals such as collectors or macro-molecule. Common polyacrylamide (PAM) flocculants can be used to minimize the exposure of the most hydrophilic planes of clay particles via hydrogen bonding but they can not efficiently enhance the overall particle surface floatability due to the hydrophilic properties of this type of macromolecules. A novel method to improve both flotation kinetics and surface wettability of silicate minerals has been developed and studied. That is to use a temperature-sensitive polymer, poly (N-isopropyl acrylamide) (PNIPAM), as a process aid in the flotation of silicate minerals. Unlike PAM polymers, PNIPAM can induce a hydrophilic/hydrophobic transition on the particle surface when the temperature is changed to be lower or higher than its critical solution temperature (CST). At a lower temperature, the PNIPAM adsorbs on the particle surface via hydrogen bond similar to PAM. It induces strong hydrophobic aggregation when the temperature is increased above the CST. Thus, both floc size and mineral floatability are greatly increased. The flotation results show very good flotation performance and the addition of conventional flotation collector was no more required because the increased particle surface hydrophobicity induced by PNIPAM. Contact angle measurements explained the role of PNIPAM in manipulating particle surface hydrophilic/hydrophobic transition.

Jan 1, 2014

By Tetsuya Uda, Sakae Shirayama

"With the aim of producing nickel (Ni) metal directly from acidic aqueous solution containing cobalt (Co) and other impurities, selective reduction of Ni was examined. As a preliminary experiment, sodium hypophosphite monohydrate (NaH2PO2·H2O) was selected as a reductant, and reacted with aqueous solution containing 0.1 mol L-1 nickel sulfate (NiSO4·6H2O) and 0 ~ 0.05 mol L-1 cobalt sulfate (CoSO4·7H2O) for 3 hours at 90 °C. As a result, it was revealed that Ni was selectively reduced and separated from Co in the acidic region (pH= 4.8). In this study, differences of reduction behavior between Ni and Co were investigated, and the feasibility of Ni I Co separation by the selective reduction of Ni was discussed.IntroductionEfficient Ni condensation and separation from Co are essential in nickel hydrometallurgical processes. Currently, the hydrometallurgical production of Ni from oxide ore is mainly carried out by acid leaching at elevated temperature, followed by the removal of impurities using neutralization, and condensation of Ni and Co into intermediate products such as hydroxides and sulfides. Then, the intermediate product is dissolved in acid aqueous solutions, and Ni I Co separation is conducted by solvent extraction. Finally, Ni and Co are recovered by electro-winning. This complicated process consumes large amounts of alkali, hydrogen sulfide (H2S), and organic solution in a multiple-staged process'. To reduce the consumption of these chemicals, it is important to recover Ni more efficiently from acidic aqueous solution containing impurities."

Jan 1, 2014

By B. Jin

Removal of fluoride and chloride by alkaline washing from direct lead smelting dust which originated from an Ausmelt furnace is reported. The results show that the fluoride removal efficiency increases with an increase of alkaline concentration, alkaline washing temperature and time. The L/S ratio has little effect on fluoride and chloride removal efficiency. A new flow sheet for removal of fluoride and chloride from the dust was successfully proposed according to the results. Fluoride and chloride removal efficiencies are more than 53.68% and 63.18% respectively using the flow sheet under the optimum parameters of temperature 338 K, L/S ratio 3:1 and alkaline washing time of 1.5 h. The contents of fluoride and chloride in the alkaline washing residues can meet the standard of zinc purity as hydrometallurgical materials for zinc processing.

Jan 1, 2014

By C. Tokoro

Co-precipitation of dilute toxic anions with ferrihydrite is an important removal mechanism in wastewater treatment system. Although, numerous qualitative studies have been published on removal characteristic from wastewater of dilute anions by co-precipitation treatment, detail mechanism or quantitative characteristic is not well understood. This paper discussed the co-precipitation mechanism of As(V) and Cr(VI) with ferrihydrite by comparative experiments between co-precipitation and simple adsorption. In this study, co-precipitation experiments and simple adsorption ones were distinguished closely. In the former, precipitation of hydroxides and adsorption of anions develop simultaneously, but in the latter, anions adsorb onto prepared hydroxides. Although high affinity anions for hydroxides (e.g. As(V) for ferrihydrite) showed quantitative difference of removal ratio between co-precipitation experiments and simple adsorption ones, low affinity anions (e.g. Cr(VI) for ferrihydrite) showed quantitative agreement in spite of deferent forms of ferrihydrites between them, that is, amorphous ferrihydrite was formed in co-precipitation experiments, but goethite was formed in simple adsorption ones. In order to discuss the mechanism of co-precipitation phenomena, three experimental studies have been carried out: (i) adsorption isotherm measurement in the co-precipitation experiments of As(V) or Cr(VI) with ferrihydrite, (ii) zeta potential measurement of co-precipitated or simple ad-sorbed ferrihydrite with As(V) or Cr(VI), and (iii) XRD analysis of co-precipitated As(V) for ferrihydrite. All experimental results suggested the main mechanism in co-precipitation phenomena of As(V) was not only a surface complexation (simple adsorption) but also a surface precipitation.

Jan 1, 2014

By Tsvetan Damyanov, Nikolay Hristov, Evgeni Kostadinov, Lubomir Kuzev

"The process of grinding in drum mills is directly dependent on the dynamic forces occuring in the free movement of the grinding bodies in the volume. The subject of discussion are the potential impacts between grinding bodies having different shape and equal weight in a drum mill that has a diameter of 1200 mm. The study utilised ball grinding bodies having a diameter of 120 mm and tetraballpebs having a conditional diameter of 120 mm. The study was carried out using the Solid Works Simulation software. The following cases were examined: • Impact between two identical grinding bodies; • Impact between a grinding body and the shell surface. The study provided numerical values for impact force, kinetic energy of impact, linear speed of impact, linear displacment of the center of gravity and duration of impact deformation. The impact force of the balls is approximately 179000 N. The impact force of the tetraballpebs with typical vertices, edges and spherical surfaces depending on the area of impact is 177000 to 185000 N. Upon impact between two spherical surfaces of tetraballpebs, the contact area is 263.55 mm2, which is more than twice the contact area upon impact between two balls, which is 114.39 mm2. This determines better conditions for the transmission of kinetic energy by reducing opportunities for overgrinding."

Jan 1, 2014

By A. Tohn, K. Adham, R. Lu, D. Lemieux

"To remove sulphur, carbon and arsenic from the gold concentrates of Dundee Sustainable Technologies (DST), Hatch has designed a demonstration plant roaster using the fluid bed technology. The fluid bed was selected for its ability to maintain stable temperatures and uniform reaction conditions. Data points from a small pilot plant (operated by DST) were used for setting the parameters of the demo plant roaster.The DST demonstration plant is being built to further prove their patented gold extraction process at an industrial scale. Their gold extraction process is based on halogenation at atmospheric pressure and relatively low temperatures. Before the halogen leaching, most of the sulphur, carbon and arsenic should be roasted out of the feed concentrate.The Hatch fluid bed roaster design includes a moist feed introduction system, simple bed cooling for temperature control, and cyclone fines recirculation. The demonstration plant roaster is planned for construction in 2014, and the performance results will be presented in a future paper."

Jan 1, 2014

Calcium sulfate whiskers are considered to be a prosperous reinforced material in application due to their high mechanical properties. But the hydration occurs easily at moist atmosphere or in aqueous solution. The surface topographies of the calcium sulfate hemihydrate whiskers and the hydrates were analyzed by on-line observation and using XRD. The results indicated the transformation of the crystal type and shape of calcium sulfate hemihydrate whiskers and the reduction of whiskers? aspect ratio. The hydration process of the calcium sulfate hemihydrate whiskers and the effective parameters were further discussed based on FT-IR measurements. The conclusions were obtained that the hydration of calcium sulfate hemihydrate whiskers can be divided into the three phases, namely, initial hemihydration phase, dehydration phase, and coarsening, dissolving and the re-formation of calcium sulfate dehydrate crystal phase. In addition, it was found that in the hydration process of calcium sulfate hemihydrate whiskers the calcium sulfate dihydrate whiskers are formed at first and then converted into the calcium sulfate dihydrate with different crystal shapes, but in the hydration of gypsum hemihydrate the gypsum dihydrate is formed without transition products. The surface active site-calcium ion which has strong trend to react with H2O, the surface ?OH and the inner channels are considered to play important roles in the hydration process of calcium sulfate hemihydrate whiskers.

Jan 1, 2014

By Mike Daniel, Eric Wang

"Several new large copper and gold concentrators have been built and commissioned around the world in the past five to eight years. The success of the ramp-up from these very large concentrators has varied. CITIC SMCC Process Technology was engaged to assist some of these mines by gaining a better understanding of the factors that influence throughput capacity. As such, site-specific throughput forecast models that are influenced by SAG mill performance were developed. The forecast models are easy to interpret and modify and can greatly assist the mine management to make predictions and informed decisions for a range of site improvements. The models investigate the influence of SAG mill performance with respect to ore competency, derived from SMC Test® via the measured DWi model parameter. In some cases the benefits of blasting and from fine tuning milling operations are already incorporated into the "site-specific" forecast models. The methodology follows rigorous plant data analysis that is analogous to a "Mine-to-Mill®" optimisation project. The CITIC-SMCC model validation includes extensive data collection, which includes drill core analysis, ore characterisation and comprehensive comminution circuit operational data to assess the limitations within the comminution circuit within the operating mine. The results and models may be used to define the operating base lines of the processing areas and identify improvement opportunities upstream and downstream of the comminution circuit. The predictive capability of the models use logged production data and has enabled the user to differentiate between alternative circuit configuration options and identify optimum operating conditions. This approach minimises the ongoing requirement for costly plant surveys. The improvement strategy for each site, included the ongoing measurement of grindability, rock strength and via the Bond and SMC Test® respectively. Some commentary as to what other practitioners do with input data and their models is also presented as this highlights some of their shortcomings relative to the CITIC-SMCC methods."

Jan 1, 2014

By K. Rainer Massarsch, Bengt H. Fellenius

"Abstract Vibration limits for buildings with respect to ground vibrations from pile driving published in international standards are reviewed. At first, relevant vibration parameters are defined and the evaluation of vibration records is described. The sensitivity of structures to different vibration parameters (displacement, velocity and acceleration) is discussed. Most vibration standards relate to blasting activities, the dynamic characteristics of which can be significantly different to those from construction activities and in particular, pile driving. Several vibration standards are reviewed. The Swedish vibration standard is described in detail, as it is the only one accounting for several important factors, such as ground conditions, building material, and type of building foundation. Many standards limit the guidance to values based on the dominant vibration frequency and a wide scatter of frequency-dependent vibration limits exists. It is difficult to compare limiting values of ground vibrations proposed in different standards.1. INTRODUCTIONFor poor ground conditions, placing structures on piles is the most common foundation solution, while sheet piles are widely used to support deep excavations. Piles and sheet piles must often be installed in the close vicinity to buildings, structures or installations in the ground, which can be affected by ground movements and vibrations, (Massarsch and Fellenius, 2014). In many areas, environmental concerns with respect to noise and ground vibrations can restrict or even prohibit driving of piles or sheet piles or reduce the efficiency of installation. The design engineer must prescribe – often at an early stage of a project — the permissible levels of ground vibrations in order to minimize the potential risk of building damage. When seeking guidance from the literature, little or practically no applicable information can be found on how to assess permissible levels of ground vibrations."

Jan 1, 2014

By Cristian Rodriguez, Tom BoBo, Maria Rocha, John Kemeny

Blast fragmentation depends on many factors. First of all, it depends on the specific blast design, which includes the amount and type of explosive, the blasting pattern, the timing and sequencing, and other parameters. Secondly, it depends on the properties of the rock mass, including the uniaxial compressive strength (UCS), the rock mass elastic modulus (E), the rock discontinuity characteristics (as reflected in the GSI or RMR), and the rock density. Several fragmentation models have been proposed to predict blast fragmentation based on the blast design and the properties of the rock. These models include the Kuz-Ram model and variations of this model, as well as recent models by Kim and Kemeny (2011) and others. Fragmentation models are validated and calibrated by comparing the predicted fragmentation with actual post-blast fragmentation from image processing monitoring systems.

Jan 1, 2014

By Pengbo Chu, James Finch

Bubbles around 1 mm diameter provide the high interfacial area for capture and transport of hydrophobic particles in flotation. The formation of such fine bubbles is commonly achieved by addition of frothers that appear to simultaneously retard coalescence and promote break-up. High inorganic salt content in process water can substitute for frother. In this work we focus on the action of salt (sodium chloride) on formation of bubbles by break-up. An experimental setup that isolates break-up from coalescence was employed. A pocket of air is exposed to controlled mechanical turbulence to produce single bubbles by the induced deformation of the air and the events imaged. The presence of salt is shown to produce smaller bubbles than in water alone. Comparison with a similar study on frothers is made. The argument is advanced that the presence of frother and salt creates surface tension gradients at the air/water interface which add to the mechanical energy of the deformation and break-up process.

Jan 1, 2014

By M. F. He

The depression of pyrite in marmatite flotation by a new depressant Sodium Glycerine-xanthate (SGX) has been investigated through microflotation, zeta potential, and adsorption measurements in systems open to the atmosphere. The flotation tests of single mineral show that in the presence of SGX, marmatite can be activated by Cu2+ and shows good flotability, while pyrite can?t be activated and therefore shows poor flotability, as a result these two minerals can be separated using butyl xanthate as the collector. The depression mechanism of SGX on sulfide minerals is discussed based on Zeta potential and adsorption isotherm. Zeta potential experiments demonstrate that at the presence of Cu2+, SGX can strongly adsorb on the surface of pyrite, while it can?t adsorb on the surface of marmatite, thus the results are in accordance with those of flotation experiments; the results of adsorption isotherms show that the adsorption density of SGX on pyrite is greater.

Jan 1, 2014

By J. Z. Yuan

The purity of rectorite is only about 70% after preliminary mineral processing, which has limited its application. In this research, different pulp densities, different dispersants, different dispersing methods and purification flow sheets were used to purify rectorite. The results show that it is possible to obtain high pure rectorite clay with the purity above 90% and concentrate yield between 24.9% and 29.4% by the purification process with composite dispersants, stirred mill grinding dispersion and so on. The obtained high pure rectorite can be further used in rectorite nanocomposites.

Jan 1, 2014