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By C Simpson, J Market

The process of sampling blasthole cones utilising personnel to manually shovel material into sample bags is a long-standing industry accepted process. However, this method has several drawbacks, including the safety issues around having personnel performing manual sampling in a harsh environment and the variability involved in getting a human to repeatedly get a ‘shovel full of dirt’, and make it always representative. Geophysical blasthole sampling, or utilising a Downhole Assaying Tool (DHAT) has been tested and has now begun implementation at many iron ore sites throughout the Pilbara region, Western Australia. This method uses a geophysical tool to capture data within blastholes, and together with a semi-autonomous logging platform to minimise risks around manual handling, delivers a multielement proxy-assay which can be utilised by the mine geology team to accurately domain the orebodies. Logistically, the combination of a specially designed tool and semi-autonomous truck are the way forward for a safer and more data-robust blasthole sampling practice. The method utilises a neutrongenerating geophysical tool and linked elemental spectroscopy sensor, which measures the response of the material surrounding an open hole. This delivers results at submetre intervals. These results are then utilised, similar to blasthole sample results, to map out areas within the blast pattern that are ‘ore’, ‘waste’, or ‘other suitable grade’. This paper outlines a project that has been in ‘proof of concept’ at selected Fortescue sites over the last few years with testing of these tools carried out on reverse circulation (RC), diamond drill and blastholes. The method is now being implemented at operational hematite mine sites. Fundamentally, the method adds more than enough value to justify its implementation. The aim is that these learnings will enable the greater industry to adapt, implement and improve their mining practices. Ultimately, the outcome will be greater value in mining for the industry by having a larger volume of good quality data to make reliable decisions on material movements, minimising ore-loss and dilution, and maximising the value of our current and future orebodies.

Nov 8, 2021

By D McB Martin, A Piechocka, M Jessell, M Lindsay, E Ramanaidou

The Hamersley Basin of Western Australia, approximately 500 km long by 200 km wide, is recognised globally for its rich endowment of iron ore resources. Two types of bedded iron ore mineralisation are recognised: the Proterozoic hypogene martite-microplaty hematite ores; and the more recent Cenozoic supergene martite-goethite ores. Exploration strategies depend on the style of mineralisation being targeted; however, stratigraphy and structure are fundamental controls on both ore types. Therefore, the ability to visualise the 3D geology of the entire basin is critical for the understanding of iron ore occurrences and their relationship to ore genesis of bedded iron ore mineralisation. However, due to the large size of the basin, generating a 3D geological model of the regional stratigraphy and structure has not been possible, or prioritised, primarily due to software limitations. Recent advances in implicit automated geological modelling presents an ideal opportunity to develop a 3D model of the entire Hamersley Basin. The innovative Loop software was used to model open source geological data (ie geological mapping, outcrop orientation data, and fault data) sourced from the Geological Survey of Western Australia. In addition to generating a 3D geological model, information such as stratigraphic thickness and fault offset information was extracted using the map2loop module and demonstrated its application to exploration targeting. This study demonstrates how a basin-wide 3D geological model was used to conduct a regional structural analysis of the Hamersley Basin. The results of this study provide opportunities for other prospective regions to be rapidly modelled in order to enhance the understanding of the geology and improve exploration targeting.

Nov 8, 2021

By H Rossiter, C Simpson, J Market, P Jeanneau

Downhole Assay tools are a geophysical method to collect an instigated response from the material surrounding a drill hole and deliver a multielement proxy-assay. They were first tested in the Pilbara at the turn of this century, however since 2011 they have seen a more focused testing and implementation regime with multiple companies across multiple Pilbara mine sites. The increase in the volume of data has led to advances in the measurements and significant improvements to the efficiency of the calibration process. Pulsed Fast and Thermal Neutron Activation Analysis (PFTNA) downhole assay tools collect gamma photon spectra which are characteristic of elemental signatures. One of the key components of the technique is calibrating the spectral signatures to lab assays. Each tool is slightly different due to the organic nature of the crystal detector and therefore responds slightly differently. Environment and hole conditions as well as ore characteristics are among other external influencing factors. Thus, a unique calibration is required for each tool. In addition, not all elements are measured directly, but some are actually characterised by proxy, meaning that if the signal-to-noise ratio for an element is small, it may be easier to identify the mineral or geology in which that element is found and thus infer the concentration of the element. These proxies may differ for each site or geology type within a site. There is a large advantage to build a unique calibration per tool at each site rather than a universal one to be used across the whole province. This then delivers the accuracy and precision of measurements that mining companies require for modern operations. Early work with the tool required several thousand metres of calibration data and several weeks of analysis to build each calibration. This process has now been streamlined to significantly reduce the amount of data required and the analysis time to make it much easier to introduce new tools to a site with an existing model or to create new models. This paper details the calibration process, illustrating the increasing accuracy of the models as training data are acquired as well as the methods for transferring a calibration from one tool to another.

Nov 8, 2021

By S Hapugoda, J R. Manuel, X Cao, B D. McDonald, N A. Ware, L Lu

Roy Hill is a large iron ore mining, processing, railing and port operation in the Pilbara region of Western Australia. Since delivering its first shipments to customers in December 2015, Roy Hill has quickly achieved a 60 Mtpa production rate of lump and fines products. The process plant, principally consisting of wet scrubbing, screening and de-sanding unit processes, was expanded from early 2020 to include operation of a Wet High Intensity Magnetic Separation (WHIMS) Plant. The WHIMS Plant treats tailings to recover approximately 4 Mtpa of ultra-fine (nominally -150 μm) high-grade hematitic concentrate which, after dewatering, is blended into the fines product. Unlike typical hematite concentrates, which consist largely of dense particles with smooth surfaces, the WHIMS concentrate is characterised by very finely microporous hematitic/goethitic particles, reflecting the overall characteristics of the Roy Hill deposit. Detailed test work has been conducted in collaboration with CSIRO to characterise the WHIMS concentrate in terms of its physical and mineralogical properties, and to determine its influence on the granulation and sintering performance of Roy Hill fines – from fundamental/lab-scale and sinterpot perspectives. The results demonstrate that blending of the high-grade hematitic Roy Hill WHIMS concentrate into the fines product can maintain overall sinter quality and positively influence granulation and sinter melt formation, as well as Fe grade.

Nov 8, 2021

By A Larsson, K Niiranen

The Palaeoproterozoic Leveäniemi iron oxide apatite (IOA) deposit of the so-called Kiruna type is currently mined by Luossavaara-Kiirunavaara AB (publ.), commonly known as LKAB. The mineralogy of iron oxides, ie magnetite, hematite, maghemite, and goethite is more complicated compared to the neighbouring and more famous IOA deposits of Kiirunavaara and Malmberget. Furthermore, the mineral chemistry of the iron oxides in the Leveäniemi deposit is also slightly different. Especially, the information about the deportment of titanium and vanadium in iron oxides and distribution in the deposit is essential since they can have an impact in the steelmaking process. For this study 50 samples were selected from exploration drill cores and investigated by optical microscopy, FE-SEM-EDS and EPMA at LKAB and the Geological Survey of Finland. Investigations revealed that magnetite is the predominant iron oxide mineral with secondary hematite being the second most abundant mineral. Primary hematite, maghemite, and goethite seem to be less abundant. It should be noted, however, that this investigation focused on magnetite which currently is the only mineral with economic value. Vanadium occurs as a substitution element in the crystal lattice of iron oxide minerals in the Leveäniemi deposit and not as discrete stochiometric vanadium minerals. In the investigated samples vanadium concentration in magnetite ranges from 0.12 to 0.32 wt per cent V2O3 with higher concentration in the southern part of the deposit. Contrary, titanium does not substitute for iron in the crystal lattice of magnetite or secondary hematite (less than 0.018 wt per cent TiO2). It either occurs as tiny inclusions of titanium oxide minerals or as exsolution lamellae of ilmenite in magnetite. The spatial distribution for titanium in the deposit, however, remains unknown. Furthermore, results of this study indicate that alteration of primary magnetite to secondary hematite has had no significant effect on the trace element chemistry of these minerals in the Leveäniemi deposit.

Nov 8, 2021

By J Caron, M Athayde, F Lavoie, R Joyce

Decarbonisation has become a major challenge for the global steelmaking industry, turning towards new technologies aimed at carbon footprint reduction, which on its own accounts for approximately 9 per cent global emissions. The iron and steel industry represents a ‘hard to abate’ sector, where much of efforts are currently being deployed into initiatives aiming to decarbonise the ironmaking through the use of green hydrogen, carbon capture utilisation and storage and state-of-the-art operation of current technologies, while little efforts being deployed to find carbon-efficient solution to iron ore burden preparation, where high-grade iron concentrate will increase in importance to ironmaking regardless of the chosen reduction route. Quebec Iron Ore (QIO), a subsidiary of Champion Iron Limited (Champion), produces high-grade hematite concentrate with one of the lowest carbon global footprints. Still, QIO is partnering with its clients to the development of burden solutions to minimise CO2 emission, in the seek for a decarbonised steel. In a strong technological partnership, Binding Solutions Limited (BSL) has developed a novel, coldbinding technology to provide a cleaner, more cost-effective alternative to induration. The technology allows miners and steel producers to reduce Capex significantly and reduce energy consumption and CO2 emissions by 90 per cent. QIO and BSL have partnered to adapt the disruptive cold binding technology developed by BSL to QIO’s concentrate to produce a high-quality low emissions iron ore agglomerate. This paper describes the efforts taken to further develop BSL’s cold binding technology and its application to QIO’s high-grade iron ore concentrate to produce a hematite cold bonded briquette (hCBB) showing comparable performances with high quality seaborne fired pellets.

Nov 8, 2021

By Y K. Leong

Iron ore tailings typically containing 40 to 50 per cent Fe can be beneficiated to iron ore products containing 54 to 60 per cent Fe. The impurities are comprised of clay, quartz, cristabolite and TiO2. Goethite and hematite are also present. At high concentrations of 55–60 wt% solids, the tailings displayed high yield stress and viscosity and cannot be pumped over long distances. Composite additives comprising of NaOH, phosphate-based additives and sodium metasilicate are found to reduce the viscosity and yield stress very significantly by a few orders of magnitude. The yield stress of 100 Pa can be reduced to almost zero. At this state, dilution of the tailings with its process water to 40 per cent solids causes the coarse and high-density iron ore particles to separate from the colloidal fractions located in the supernatant after a few minutes of sedimentation. Separation by decantation produces a sediment with an Fe content of 54 per cent from tailings with 47 per cent Fe. Another tailings sample with 48 per cent Fe was beneficiated to greater than 57 per cent Fe using NaOH-metasilicate-polyphosphate additives and employing an additional washing step. The use of other composite additives, NaOH and polyphosphates, increased beneficiated product Fe content to greater than 60 per cent from the same tailings. With the current iron ore spot price of more than US$180 per tonne, the cost of this treatment process even including a desalination step, if necessary, is relatively insignificant. This study has given tailings an economic value that should be exploited as soon as possible.

Nov 8, 2021

By E Bouchard March, F Lavoie, B Legare, K Bourassa

Quebec Iron Ore (QIO), a subsidiary of Champion Iron Limited (Champion), completed the restart of the Bloom Lake iron ore mine located in the heart of the Labrador Trough region of Northern Quebec, Canada in February 2018. Prior to its restart, the concentrator flow sheet underwent major upgrades which brought the iron recovery to the highest of all Labrador Trough operations. After two profitable years of production, QIO, supported by Soutex, started to look at technologies to improve its current performance and integrate into its expansion project flow sheet. From the lessons learned while optimising Phase 1, the addition of a scavenger-cleaner processing stage was identified as an improvement opportunity to increase recovery, produce a higher-grade product, and further improve the stability of concentrate quality. In 2019, the NI-43101 feasibility study for the Phase 2 expansion, aiming to double the production of high-grade iron ore concentrate, was published. Based on the metallurgical test work, the hydraulic classifier was selected to perform the scavenger-cleaning duty for its well-established performance and known behaviour at the cleaning step in the Phase 1 plant. To validate laboratory results, a pilot scavenger-cleaning hydraulic classifier was installed in Phase 1. Although the hydraulic classifier was selected for the feasibility study, metallurgical test work performed with the REFLUX® classifier showed interesting potential. It was thus decided to also install a pilot RC300 Reflux classifier at the scavenger-cleaning stage in Phase 1. Despite their apparent great similarities, the metallurgical performance was significantly different, and many dozens of sampling campaigns highlighted the different performance of both pieces of equipment considering the feed material particle size. This article presents the pilot plant results in terms of recovery, selectivity and stability for both the Reflux classifier and the hydraulic classifier operated in a scavenger-cleaner stage at the Bloom Lake iron ore concentrator.

Nov 8, 2021

By C S. Kelsey, J R. Kelly

Australia is presently enjoying the fruits of a booming iron ore market. Expectations are that market strength will be supported in the short to medium term by increasing feedstock demands from steel mills, as world economies rebuild post-Covid-19. However, as cost and environmental pressures increase the longer-term market outlook will be dominated by product quality. The ‘flight to quality’ will place increasing demands on direct shipping ore miners as they compete to maintain their standing in the iron ore marketplace. China will progressively disengage from its dependence on Australian imports, leaving miners under increasing pressure to boost product quality and diversify outlets globally. Australia has vast deposits of low-grade magnetite ores located mainly in remote and arid regions of the continent. This paper proposes a dry grinding and magnetic separation process to produce premium concentrate grades from the low-grade ores, to assist in meeting future product quality demands. The premium grade concentrates could be either blended with lower quality direct shipping ores or marketed separately. The proposed dry concentration process involves the pairing of Vertical Roller Milling (VRM), a mature technology widely used in the cement industry, and Planar Magnetic Separation (PMS), a new methodology, which has been developed to the threshold of commercialisation by the private Australian company Cyclomag P/L. Two laboratory prototype planar magnetic separators with field strengths of 1800 gauss and 6000 gauss have been built and tested on a range of magnetite ore types over the past three years. In each case, following grinding to liberation sizes, a combination of roughing and cleaning operations has produced pellet grade concentrates. Vertical roller milling has competed successfully with conventional media milling in grinding cement clinker, limestone and blast furnace slags. A key advantage of dry VRM/PMS processing is its potential adaptability to stepwise modular development, which can minimise initial capital investment, while generating early revenue streams to cope with unpredictable market volatility.

Nov 8, 2021

By D Giles, A C. Bailey

In the first 20 years of the 21st century, just over 20 per cent of Australian mineral exploration expenditure was dedicated to iron ore, totalling >A$8 billion and >30 million metres of drilling (Australian Bureau of Statistics, 2021). Improvements in the cost, efficiency, safety, reliability and data quality of drilling have the potential to deliver significant productivity improvements, increasing the probability of discovery and reducing the time from discovery to mining. Currently in its third year of research, Mineral Exploration Cooperative Research Centre (MinEx CRC) is focused on a new set of exploration tools and new ways to deploy those tools which recognise the fundamental importance of collecting quantity and quality data from the subsurface, to enable exploration success for all minerals, including iron ore. MinEx CRC is focused on developing more productive, safer and environmentally friendly drilling methods to discover and drill-out deposits. This includes pioneering work on Coil Tube (CT) drilling technology and innovations in Diamond and Reverse Circulation (RC) drilling techniques aimed at improved drilling optimisation and automation. In parallel, MinEx is developing new technologies for collecting data whilst drilling. This is being undertaken in four separate industry-led projects utilising geophysical, seismic, downhole analytical and 3-dimensional (3D) modelling improvements. A National Drilling Initiative (NDI) is also underway, with two drilling programs completed in 2020. The NDI is a world-first collaboration of Geological Surveys, researchers and industry, which undertakes drilling in under-explored areas of potential mineral wealth in Australia and provides a test-bed for new mineral exploration technologies.

Nov 8, 2021

By P Dean, M Elmouttie, Y Duan, X Luo

Slope instability is one of the major concerns in open pit mining operations. A significant collapse of the pit wall can result in injuries, damage to machinery and interruptions to production. A broadband microseismic monitoring technique has been developed for diagnosing the healthy condition of a target slope area. This technique has been successfully applied to an open pit mine in Chile. Our research has found that this microseismic monitoring technique can be used in open pits for tracking and locating a falling rock that is rolling on a slope, if a dedicated seismic sensor network has been established. In collaboration with other monitoring techniques (radar, laser scan, aerial photography), more accurate determination of rock rolling trajectories can be obtained. In this paper, an example of using the CSIRO microseismic monitoring technique at an open pit mine is presented. Results from an experiment where we used the microseismic technique for determination of the trajectory of a rockfalling on a slope are also presented.

Nov 8, 2021

By J Pan, Q H. Li, D Q. Zhu, C C. Yang, X Wang, Z Q. Guo

Al2O3 in natural iron ores generally occurs in goethite, kaolinite, gibbsite, hematite and iron carbonate. When the content of alumina in sinter increases from 1.11 per cent to 3.50 per cent, the reducibility of sinter decreases with the addition of four different types of alumina. When gibbsite and kaolinite are added, the low temperature reduction disintegration (RDI+3.15 mm) of sinter increases with the increase of Al2O3 content in the range of 1.5 per cent to 3.5 per cent. Furthermore, when adding pure reagent alumina, the increase of Al2O3 content in the range of 1.5 per cent to 3.0 per cent will increase the RDI+3.15 mm of sinter. The addition of ferric oxide–alumina spinel with the Al2O3 content in the range of 1.5 per cent to 2.5 per cent, also increases the RDI+ 3.15 mm of sinter. The influence difference is results from the change of the mineral composition and microstructure of sinter because of the occurrence state of Al2O3. Under the condition that Al2O3 content of sinter is 2 per cent, the porosity of sinter with kaolinite is 37.26 per cent, and the shape is irregular. When gibbsite and ferric oxide–alumina spinel are added, the porosity of sinter is about 16 per cent, and the pores are round. When pure reagent alumina is added, the porosity of sinter is 17.49 per cent, and the pores are regular and small. When kaolinite, gibbsite and ferric oxide–alumina spinel are added, platy calcium ferrite is mainly formed in the sinter, and some of it is columnar calcium ferrite. On the other hand, when pure reagent alumina is added, in addition to platy columnar calcium ferrite, acicular calcium ferrite is also formed in the sinter.

Nov 8, 2021

By T A. J Hopper, S Mukkisa, K-O Ott, D Palmer

RIG Technologies has developed new technology that can successfully acquire high quality natural gamma ray (GR) and hole deviations, downhole while drilling, on reverse circulation drills. This technology survives the hostile downhole environment with shocks of between 400–2500 g for 7– 10 days at a time. The Logging While Drilling (LWD) service eliminates the need to run in-rod surveys, either by the driller or by wireline trucks and crews. This time saving is in the middle of the drilling process, thus enabling drills to keep drilling and increase their productivity. Additional to the natural GR and directional survey, the downhole tool is equipped with sensors to measure the downhole dynamic response of the drilling system providing insights into rock hardness, density and potentially clay types. These parameters have never been acquired behind the hammer before and coupled with surface measurements from the drills themselves, form a rich data set for trainable machine learning algorithms shortening the time to receive advanced geophysical answer products from sometimes months, to live feeds directly from drills (Hopper, 2019). Alive, high speed, two-way data link between surface data acquisition systems and downhole geophysics tools has been established and incorporates calibrated surface measurements of dynamic forces directly on the drill string to match up with those measured downhole. Receiving live streams of natural GR and hole deviation surveys as the drill is drilling allows true remote decisionmaking with live data available anywhere in the world. The combined data from surface and downhole dynamics builds a data set that could begin to enable true optimisation of autonomous drilling processes.

Nov 8, 2021

By S Mundell, A Atkins, S van de Water

Geoscientific information management enables the capture, management and delivery of the original geoscientific observations and measurements of the earth’s natural resources. However, original observations and measurements are worth nothing if the quality and integrity of the data can’t be guaranteed. Geoscientific information is one of the fundamental assets enabling miners to make confident and accurate business decisions, whether that is defining a resource model, performing reconciliation, delivering ore reserve reports or meeting environmental compliance requirements. Without access to reliable, validated or verified data it increases the risk of miners using incorrect information for reporting and compliance. Industry codes, such as JORC, or government regulations, such as environmental compliance requirements, must be adhered to and companies should be able to confidently report to these standards. Without having a robust information management framework in place, it becomes a challenge to make trustworthy decisions, report confidently and reduce the risk of non-compliance. As a key initiative, good data governance should form one part of a miner’s information management strategy. Within the mining industry it is common for companies to only consider technology tools as the key focus for compliance whereas a mature information management focus will additionally consider people and process. All three pillars are critical for a miner to have confidence in their data driven decisions. This paper discusses an industry framework for best-practice geoscientific information management based on the observations gathered from analysing data management practices within the mining industry. It focuses on how the three pillars of people, process and technology are crucial elements to improve operational decisions and ensure companies are compliant.

Nov 8, 2021

By N J. Goodman

The HIsmelt technology was developed and proven in Western Australia (WA) after more than 30 years and several billion dollars of research and development. The HIsmelt technology was transferred to China and is now successfully operating at the Molong plant in Shandong Province, China using WA iron ore fines as the major feedstock. Several more plants are under construction in China, and the technology has been approved by the Chinese Government as an environmentally acceptable alternative to the blast furnace. The unique flexibility of the HIsmelt process offers multiple pathways to decarbonise the production of steel in the near future. These pathways include:  Use of sustainably grown biomass converted to Biochar to replace coal as the reductant.  Pre-reduction of iron ore fines using hydrogen or biomass to direct reduced iron (DRI) powder.  Capture of carbon dioxide from the HIsmelt off gas and geo-sequestration underground. These pathways are highly suitable for the Australian iron ore industry as they utilise:  The large areas of land and long growing season available in Australia for the production of large tonnages of sustainably grown biomass.  Coarse iron ore fines directly without the need for fine grinding and pelletising.  Existing oil, gas and other underground gas reservoirs to store carbon dioxide. The HIsmelt technology will allow Australia to transition from ‘Asia’s quarry’ to Asia’s supplier of low cost, low carbon and high quality metallics that are required to produce ‘green’ steel with net zero carbon dioxide emissions. In addition, HIsmelt pig iron can be converted locally into steel via electricarc or basic-oxygen steelmaking furnaces to supply all of Australia’s demand for green steel.

Nov 8, 2021

By M Grigorescu, J H. Hodgkinson

The expansive, open cut iron-ore mines in Western Australia typically experience few days of rain per annum, often amounting to less than 250 mm. Unlike mines where rainfall is frequent, they may be less prepared for extreme rainfall events. Such events can cause erosion, flooding and sedimentation, drainage alteration, spoil and stock heaps wetting and effect slope stability. Such impacts may threaten personnel safety, infrastructure, and production. The CRATER (‘Climate Related Adaptation from Terrain Evaluation Results’) framework collates and interprets a mine’s pre-existing data and semi-quantitative information to assess vulnerability to, and ultimately plan to avoid or minimise, flood-related hazard to infrastructure, people, downtime, environment and revenue. Outputs assist decision makers to design investment strategies for minimising mining operations’ vulnerability to climate. Previously developed for smaller, wetter mines in Queensland’s coal region, the outputs provide a hot-spot map, fault tree analysis and an assessment of the mine’s capacity to adapt. The multicriteria evaluation (MCE) within a geographic information system (GIS), equally suits iron-ore mines’ siteconditions (elevation, slope, drainage, soil and vegetation) to identify critical inundation areas. Hotspot results provide target zones for in-depth fault-tree analysis that, in turn, present a range of sitespecific adaptation options. Rainfall-intensity and the number of rain days since the 1970s have increased over central and eastern parts of the Pilbara Region. While tropical cyclones may become less frequent, they are projected to increase in intensity. Although some parts of the Hamersley Ranges receive more than 500 mm per annum, rainfall in the Pilbara is generally very low. Therefore, experience of the impacts of extreme rainfall events in the constantly changing topography of Western Australia’s iron ore region may be sparse. Minimising potential effects can be proactively assisted using CRATER.

Nov 8, 2021

By M I. Pownceby, M A. Rhamdhani, S Purohit, G Brooks

The use of concentrated solar flux for high temperature metallurgical applications is a wellresearched area with several reported literatures on solar calcination and metal oxide reduction. This paper presents two such processes with potential to reduce the carbon footprint from ironmaking through using concentrated solar flux. The first process involves solar flux incorporation to the recently developed lime-magnetite pellet (LMP) route of magnetite ore agglomeration. The second process is a hybrid solar-smelting route for iron ore-coal composite pellets that utilises solar flux to provide process heat. Both the concepts of solar agglomeration and solar smelting process were investigated using a solar simulator-hybrid reactor set-up at Swinburne University of Technology. Results from solar agglomeration experiments at 950°C suggested no change in the reaction mechanism of the LMPs under solar irradiation compared to electrical heating. The percentage and morphology of the primary phases (mainly CaFe3O5) appeared similar for both solar and electric heated LMPs. The solar-smelting of magnetite concentrate-lignite coal composite pellets at 1130°C showed a maximum metallisation of 55 per cent after 1.5 hrs of reaction. The solar-smelt process has about 25 to 35 per cent lower CO2 emission compared to the blast furnace ironmaking. Technoeconomic analysis of implementing a CST facility in an existing composite pellet process suggested a payback period of about ten years at a heliostat cost of $A100/m2 and natural gas cost of A$10/GJ. The economics of CST implementation can be further enhanced by decreasing the thermal losses from the heliostat field and reactor.

Nov 8, 2021

By T B. T Nguyen, L Matthews, D O’Dea, T Honeyands, T Harvey

Productivity and fuel consumption of the blast furnace is driven by the quality of the iron ore sinter, which in turn is related to the sinter mineralogy. The sintering conditions including temperature and gas composition have a significant influence on the formation of melt and finally the mineralogy of the sinter. In this work, analogue sinter tablets were produced from iron ore fines in a laboratory furnace with tightly controlled temperature profile and oxygen partial pressure in the gas. The mineralogy of the sinters was analysed using reflected light microscopy. The results showed that increasing thermal enclosed area (area enclosed by heating and cooling curve above a reference temperature) reduces primary hematite and platy silico-ferrite of calcium and aluminium (SFCA) contents. This is attributed to increasing melt formation, leading to greater assimilation of the iron ore particles. Lower magnetite was found for tablets with greater median pore size, which is thought to be due to greater oxidation of magnetite to hematite during cooling in air. It was also found that higher alumina content was found to result in more SFCA formation under the same heating/cooling conditions, whereas tablets with higher goethite had higher assimilation and produced more secondary hematite on cooling. Finally, it is necessary to relate the enclosed area to the temperature at which the melt formation becomes significant which strongly depends on chemical composition of the ore studied.

Nov 8, 2021

By M I. Pownceby, S Hapugoda, H Han, V Nunna, L Lu

Charcoal produced from Syzygium Zeylanicum (local name: Yakada Maran = iron killer) trees were widely used in ancient Sri Lankan iron smelting practices. In this study, relict charcoal from Syzygium Zeylanicum tree trunks, branches and leaves were analysed for the first time. Unusually high concentrations of calcium oxalate (CaC2O4.H2O – CaOX) crystals were identified preserved in plant cell structures by optical mineralogy and SEM analysis. Thermogravimetric Analysis (TGA) of CaOX showed that it displayed three decomposition stages, releasing H2O at 177°C, CO at 493°C and CO2 at 750°C. Following the identification of CaOX in Sri Lankan charcoal, a series of reduction tests on a low-grade, high-P iron ore fine sample (high SiO2: 5 wt. per cent; Al2O3 4 wt. per cent; P: 0.135 wt. per cent) doped with CaOX were carried out at various temperatures. Samples were analysed by XRF, SEM and EPMA to determine the degree of reduction and the effect of reduction on the deportment of impurities, in particular P. Reduction tests at 800°C and 900°C with 5 wt. per cent CaOX showed that the reducibility increased to over 65 per cent. At temperatures above 900°C, P was located mainly within a fine, interstitial glass matrix suggesting that the CaOX flux enhanced removal of P from iron-rich pre-cursor phases to form glass. Preliminary magnetic separation tests to remove the P-rich interstitial glass were unsuccessful due to the fine grain size. Further complete reduction tests at temperatures above 1200°C with addition of coke to convert the iron oxides into Fem were conducted with samples doped with 10 wt. per cent CaOX, 10 wt. per cent CaCO3 and equivalent undoped samples. Results confirmed the preferential P-incorporation into a glassy matrix in the CaOX samples although some rare P incorporation into the metallic phase was noted. Experimental results, including comparisons with the CaCO3 fluxed and undoped samples, are discussed in view of the potential for CaOX flux for removing P (and potentially other impurities) from P-rich iron ores.

Nov 8, 2021

By T Takayama, R Muroi, M Matsumura

The steel industry occupies 14 per cent of CO2 emissions in Japan, and the sintering process is one of the major emitters. Since most of CO2 released from the sintering process comes from coke fine combustion, replacement of coke fines with biomass char as bonding agent is a potential countermeasure. In order to explore the effective use of biomass char, we chose char made from Palm Kernel Shell (PKS) as a sample. First, the char’s combustion behaviour was examined with varying the char’s particle size by means of admixing the char in alumina ball packed bed placed in an electric furnace. As a result, the finer the PKS char the faster the burning rate and reaching a higher temperature compared to coke fine. In addition, it is also concluded that the optimum size of PKS char was larger than coke fines. Next, the effect of different heat profiles on sinter structure was examined by sintering tablet made of chemical reagents. In this experiment, the chemical composition is designed based on sinter composition. By this sintering test, even at high temperature, rapid cooling is effective to make fine sinter matrix and fine pores, which has possibility for high sinter reducibility. Based on these two experiments, using PKS char as a sinter fine source has the possibility to improve sinter reducibility.

Nov 8, 2021