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By Sato S, Kawaguchi T

The granulation and bed-permeability of sinter raw materials depend on interactions between the properties of various iron ores and water. The properties of individual iron ores are controlled by their particle size distribu- tion and surface characteristics, which can be described by representative particle size and wettability, respectively. Added water may be absorbed, affect granulation or lower bed permeability. These effects were experimentally studied as a function of properties of the iron ores. A mathematical model was developed in order to calculate the granulated particle size and permeability using the known blend of sinter raw materials. The calculated results were in good agreement with the observed values.

Jan 1, 1980

By Takahide Wakamatsu, Yoshiaki Numata, Charn Hoon Park

INTRODUCTION A technique is needed to apply the flotation method successfully to apply the flotation method successfully to low grade and complex ore bearing hard-to-float oxide minerals. Thus it is necessary to find a new selective, powerful collector or to develop a new flotation process. Some attempts to use two or more kinds of collectors combined in flotation have been made but the principle of the reaction between the collectors used and the surface of mineral as well as the effect of combined collectors on flotation has not yet been fully understood. As part of the study on the improvement of selective collection in flotation, we have been investigating the flotation of minerals using two kinds of organic reagents, one of which is a conventional collector. We found xanthates were able to adsorb even onto the surface of oxide mineral, with the help of another organic reagent, e.g. a chelate compound (1). Furthermore, a notable effect of combined reagents such as the xanthate-amino acid combination (2) was found on the reagent adsorption phenomena and the collection phenomena, depending on the combination of reagents. The present study was carried out to clarify the effects of adding two kinds of collectors to the collection of mineral in flotation in the following two cases: (1) joint use of xanthate and di-alkyl dithiophosphate for galena collection and (2) joint use of a cationic collector with xanthate for scheelite collection.

Jan 1, 1980

The world is getting flatter through internet, mobile phone technology, relatively low cost travel, massive outsourcing of manufacturing to China and the transfer of company backroom operations to India. In the iron and steel industry, however, things will remain relatively the same with slow gradual improvements in technology; only the geographic location of plants may change over time. Or will it? The blast furnace smelting process has remained largely unchanged since 1828 when James Neilson came up with the idea of preheated air being delivered to the tuyeres. Likewise, oxygen steelmaking that takes molten iron from such blast furnaces has remained conceptually unchanged since Sir Henry Bessemer invented an air-based system in 1856. These two processes are the core of integrated steel mills that we know today. Typically such mills consist of coke ovens, sinter plant, blast furnace, oxygen steelmaking, continuous caster, rolling mills and metal coating lines. In the intervening 150 years the only real disruptive technology to the integrated steel mill has been the minimill. Based on the use of the electric arc furnace (EAF), in conjunction with a continuous caster and rolling mill, the term minimill is used because steel products are produced at down to one-tenth the scale required for economic operation of an integrated mill, with the EAF producing molten steel using largely scrap steel as its feed, as against transforming coal to coke (coke ovens), iron ore, coke and limestone into molten iron (blast furnace) and molten iron to steel (oxygen steelmaking). There are, however, a number of technologies in development that may cause a paradigm shift in the way steel products are produced and perhaps push the evolution of the minimill as a disruptive technology. Two examples are direct iron smelting, where iron is produced in a matter of seconds by injection of ironmaking feed materials into a molten bath, and thin strip casting, where molten steel is cast into 2 mm strip or less, in similar time. Both have Australian connections. A leading iron smelting technology is the HIsmelt« process, which has its first commercial application at Kwinana, Western Australia, where a joint venture of international parties, consisting of Rio Tinto and the Nucor, Mitsubishi and Shougang corporations, are in the stage of ramping up commercial production. The leading strip casting technology is the Castrip« process that arose from development work done by then BHP Steel, with IHI of Japan, at Port Kembla, New South Wales in the 1990s. Nucor followed this work up, building the first commercial plant for the technology at its Crawfordsville site in Indiana in 2001 and has recently announced an intention to build a second plant in the USA. While both technologies are only into the early stages of commercialisation they are likely to change the face of iron and steelmaking as we know it over the next 20 years. This paper elaborates on the technology of the two processes, why they could change the face of the iron and steel industry forever, what might drive the rapid change and what the changes may look like.

Jan 1, 2006

By Donald A. Bruce

Pin Piles are small diameter, bored, cast-in-place piles used to underpin structures. They were first employed over 40 years ago in Italy, and have been used in the U.S. since the late 1970's. However, it is only in the last few years that their full potential in terms of load holding capacity has been exploited: whereas 100 kip working loads typified former practice, ultimate loads approaching 700 kips have recently been recorded for Pin Piles founded in sand. In order to better understand the actual performance of these piles, fundamental research has been conducted by a consortium of industry and academia. This paper describes the advances made in the laboratory and full scale field testing programs. In particular, the extensive field tests have been conducted in a variety of materials in which different pile configurations have been cyclically tested to failure. By using this test method, the elastic performance of the piles has been examined and so the progressive interfacial debonding phenomenon has been studied. This has led to the development of the Elastic Ratio concept which is proving extremely useful in analyzing and predicting Pin Pile performance. Data are provided from the full scale Test Pile Programs conducted at Mobile, AL and Port Vancouver, WA. Given that Pin Piles are usually installed in areas of low headroom or restricted access, and through difficult, occasionally contaminated soils, the paper also describes key aspects of construction.

Jan 1, 1993

By Dave Tahija

"Many investigations are being performed with the goal of removing carbon dioxide from the atmosphere and permanently storing it in geologically stable settings. At the same time, carbon dioxide in the form of dissolved carbonate is steadily accumulating in the world's oceans. Both carbon dioxide sequestration and oceanic accumulation are constrained by the aqueous thermodynamics of the carbonate system. These constraints are illustrated using the STABCAL computer model to generate potential-pH and aqueous distribution diagrams of seawater in contact with various pressures of carbon dioxide gas. STABCAL diagrams and titration simulations are also used to model some potentially useful cation-carbonate sequestrationsystems.IntroductionAtmospheric carbon dioxide concentrations have risen dramatically in the past couple of centuries and are rising still, primarily as a result of human activities, especially the burning of fossil fuels. Increased atmospheric carbon dioxide concentrations have been implicated as a main cause of global warming but have other effects as well.Rising levels of atmospheric carbon dioxide result in increased concentrations of dissolved carbonate complexes in water, including the oceans. These dissolved carbonates interact with other dissolved substances, altering overall seawater chemistry, most noticeably causing lowered pH levels.Some of these chemical changes are observed directly, for instance the general drop in oceanic pH, [1], while others can be inferred and predicted using thermodynamic modeling. The chemistry of dissolved carbonate in seawater is not especially intricate, as such chemical systems go, but neither is it simple enough to be worked out on the back of an envelope. Interactions between the several simple carbonate species and all the major dissolved cations in seawater should be considered, as well as the effects of competing anions, especially chloride and sulphate, since they are much more abundant than carbonate in seawater."

Jan 1, 2011

By Stephanie Trant

Montana Tech has been engaged in fundamental research on the processing of critical materials for more than a decade. Efforts include examining novel reagents for the flotation of Rare Earth Minerals (REMs). For this paper, research results on a collector, salicyl hydroxamic acid (SHA), are presented. Various REMs were examined and include the rare earth oxides (REOs), carbonates (RECs), and phosphates (REPs) of a suite of Rare Earth Elements (REEs). Differences are attributed to solution and surface chemistry, coordination number, and ionic diameter. SHA adsorption follows an ion-exchange process that leads to chemisorbed and surface-precipitated states, depending mostly on pH. Many effects are directly attributed to lanthanide contraction. Results should also be applicable to other REM/collector systems and further suggest that REM flotation should consider dual collectors.

By M Jones

The past 100 years the mining industry can be characterised by a focus on increasing financial returns often to the detriment of social, human, manufactured and environmental capitals. Despite the sustainable development principles promoted by the International Council on Mining and Metals (ICMM), the Equator Principles and the African Mining Vision, which should have enhanced project promoters’ ‘licence to operate’ within a host community or nation, the industry has often failed to integrate proven innovations and best practices that enhance sustainability outcomes for mineral resource projects. This failure has led to delays, the abandonment of projects, with value destroyed for promoters, governments, host community and investors.The paper will outline the application of proven innovations, Enterprise Optimisation (EO), and Sustainable Operations (SUSOP®), during the pre-feasibility phase of a project. By determining the value of each capital before and after the application of proven innovations, the presentation will outline how and where value can be created across all five capitals over the life of a project or operation.The paper will demonstrate how the application of proven innovations significantly transforms the value-proposition of a mineral resource project or operation by generating additional value across all of the five capitals, reducing project risk, thus generating value for all stakeholders.CITATION:Jones, M, 2015. Fundamentally transforming the economic and sustainability signature of mining assets, in Proceedings Third International Future Mining Conference, pp 169–180 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 4, 2015

By C. Anderson, H. Huang, P. Miranda, E. Dahlgren, I. Chandra, M. Jeffrey

The latter part of the 20th century saw great advances in the treatment of refractory gold ores coupled with increased reliance on the use of cyanide for gold processing. Now, in many parts of the world, there is social pressure to limit or eliminate the use of cyanide. As well, treatment of some refractory ores or concentrates which have excessive cyanide consumption, gold cyanide pregrobbing or significant sulfide content remain difficult. This paper will outline the history of the development of alkaline sulfide leaching as an ancillary process to nitrogen species catalyzed (NSC) pressure leaching. Electrochemical fundamentals and the applicable thermodynamics of the alkaline sulfide hydrometallurgical system will be outlined. As well, examples of refractory gold recovery with alkaline sulfide hydrometallurgy such as an arsenopyrite gold concentrate application, a chalcopyrite gold concentrate application, a pregrobbing gold ore application, and a cyanide consuming gold ore application will be delineated in this paper.

Jan 1, 2005

By ANDREW HOBERT, Maoming Fan

Low-cost and environmentally friendly green froth flotation modifiers of plant origin, such as guar gum, carboxymethyl cellulose (CMC) and starch, have been used in the flotation of some sulfide and nonsulfide minerals. This paper discusses the fundamentals, current applications and potential new applications of guar gum, CMC and starch in minerals flotation. In this study, improved flotation performance was achieved using some green modifiers in flotation columns.

By ANDREW HOBERT, Maoming Fan

Low-cost and environment-friendly green froth flotation modifiers of plant origin, such as guar gum, carboxymethyl cellulose (CMC), and starch, have been used in flotation of some sulfide and non-sulfide minerals. Certain green modifiers may be used as dispersants, flocculants, depressants, or activators. The functions of green modifiers in froth flotation highly depend on their molecular composition, flotation slurry chemistry, hydrodynamic conditions, etc. This paper will discuss the fundamentals, current applications, and potential new applications of guar gum, CMC, and corn starch in valuable minerals (phosphate, potash, and iron ores) and the unwanted gangue minerals (silica and clay minerals) flotation. In this study, improved flotation performance was achieved using some green modifiers in flotation columns with the more plug-flow environments than in conventional flotation cells approaching perfectly mixed conditions. This is because the hydrodynamic cavitation-generated ultrafine bubbles could help bridge ultrafine particles to form aggregates, promote the formation of flocs, and increase the stability of flocs.

Jan 6, 2022

Despite the research interest on non-cyanide gold lixiviants over the past three decades all the non-cyanide gold processes are still at the developmental stages with limited understanding on solution and pulp chemistry in some cases. This is partly associated with:the difficulties in measuring reliable equilibrium data for various gold(I/III) complexes with non-cyanide ligands; the lack of knowledge on mixed-ligand complexes; and different kinetic stabilities of gold(I) complexes with respect to disproportionation. This paper presents reliable equilibrium data for complex formation, dissolution, precipitation, hydrolysis and disproportionation reactions of gold(I/III) compounds with a range of non-cyanide ligands: S2-, HS-, S2O32-, SO32-, SCN-, SC(NH2)2, OH-, NH3, Cl-. Solubility of gold(III) compounds with non-cyanide ligands follows the order: Cl- > NH3 > OH-. In the case of gold metal the solubility order at a given temperature is MgS > Fe(III) or Cu(II) / Cl- > Cu(II)/NH3 > NaOH, but the solubility increases with increasing temperature. Rate of gold oxidation with different non-cyanide lixiviants depends on the oxidant, ligand and temperature and follows the general order of oxidants: Fe(III) or Cu(II) > X2 or OX- > O2 (X = halogen). In the case of metal ion oxidants oxygen is required to reoxidise Cu(I) or Fe(II). Some of the reported data on chloride and thiosulfate leaching of gold are presented to highlight the effect of additives and the copper, silver and sulfur contents of the starting material on the success of non-cyanide leaching processes.

Jan 1, 2004

By M. Stelter

Since the first years in copper electrorefining natural products have been used as so called "additives" in the electrolyte. Glue as one of these additives offers a lot of different reactions with the metal ions and also with other additives like thiourea in the electrolyte. For a deep understanding of the effect of these additives it is important to know the routes of possible reactions in the electrolyte as well as the basics of electrocrystallization. Using this knowledge the interpretation of nodulation or inclusions of electrolyte in the cathodes in copper electrorefining is easier than before. Setting up on physical and chemical properties of the electrolyte and the additives practical investigations of the effects of additives in copper electrorefining and their impacts on copper crystallization and cathode quality are presented in this paper. Chemical deposition of glue against time and temperature are only few of the effects that are mainly caused by the use of natural products. In fact parameters like anodic and cathodic polarization are strongly affected by the additives as well as the effects of the additives are strongly affected by current density. This second part of the paper presents results concerning interactions of the above mentioned parameters.

Jan 1, 2007

By K. Malysa

Bubble collisions with ore grains and a selective formation of the bubble-grain aggregates are necessary steps for flotation separation of useful and gangue components of an ore. For the attachment of valuable mineral grain to the colliding bubble a liquid film, separating the bubble and the grain needs to rupture during short time of their collision. High hydrophobicity of the grain surface is favorable because stability of the separating (wetting) film is much lower at such surfaces, that is, the film ruptures faster and at greater thickness. Simultaneously, it needs to be kept in mind and taken into consideration that high affinity to air is a typical feature of hydrophobic surfaces. Thus, when the hydrophobic surface is immersed into aqueous phase the air can stay attached to such surfaces and affect kinetics of the bubble attachment. The paper presents results and analysis of dynamic phenomena occurring upon the collision of the rising bubble followed by its attachment to hydrophobic (Teflon) plates of different roughness. The influence of the Teflon surface roughness, solution concentration, bubble size and impact velocity on bouncing of the colliding bubble, time of the three phase contact (TPC) formation and drainage time of the liquid film, formed between the solid and bubble surfaces, is described. High hydrophobicity, as showed earlier (Malysa et al, 2005), does not assure that each collision leads to the TPC formation and attachment of the colliding bubble. Roughness is the parameter of crucial importance for kinetics of the bubble attachment to hydrophobic surfaces (Krasowska and Malysa, 2007; Krasowska et al, 2009; Kosior et al, 2011). Enlarged roughness of the Teflon plate, from ca. 1 to 80µm, results in shortening the time of the TPC formation (bubble attachment) by over an order of magnitude - from 105 to a few milliseconds only. Higher surface roughness means that larger amount of air can be entrapped in bigger scratches and cavities of the Teflon plate during its immersion into aqueous phase. Results documenting importance of the air presence are showed and mechanism of the air facilitated TPC formation and bubble attachment to hydrophobic surfaces is described. Keywords: bubble collisions, hydrophobic surfaces, teflon plate roughness, TPC formation

Sep 1, 2012

By Robert Snow, Yingxue Yu, Howard Hanson, Patrick Zhang

One of the major current efforts by the Florida phosphate industry to reduce deep aquifer water consumption is to use 100% recycle water for flotation. This measure alone could save billions of gallons of deep well water annually. However, this also results in higher suspended solids (slimes) in flotation water, causing poor process performance particularly for amine flotation. Polymers could play a major role in allowing the industry to use high-turbidity recycle water for amine flotation without compromising its impact on the Florida economy. The enhancement of rougher flotation by polymers may also have potential. Most importantly, dramatic efficiency improvement may be realized by floating silica first. Adding polymer to flotation feed and/or water is perhaps the most economically viable way of reversing the Crago "double float" process, in order to reduce operating costs and increase phosphate recovery. This paper presents both laboratory and pilot flotation data showing the effect of different polymers on collector dosage and flotation recovery. There appeared to be an optimal range of polymer concentration beyond which the benefits do not offset the drop in phosphate recovery. The effect of poly mer is slime-level dependent. Pilot testing data show that the "Reverse Crago" process (floating silica first followed by phosphate flotation) can outperform the Crago process.

Jan 1, 1999

By King RP, Kientzler P

In recent years, ultrasonic comminution technology has been developed at the Utah Comminution Center. An ultrasonic grinding device was assembled and investigated. An ultrasonic transducer system has been significantly improved by using a special type of piezoelectric ceramic and preloading to 4.1 x le kPa to obtain maximum strength. The improved system provides constant and rapid vibratory promotion of fatigue fracture resulting in more effective breakage. The design principles for an ultrasonic mill are developed in this paper. Size reduction was successfully achieved in the ultrasonic nip-roll device for a variety of materials. Ultrasonic comminution has repeatedly demonstrated the capability of producing fine particles from a variety of materials. A comparison between ultrasonic grinding and dry ball milling of limestone showed that the ultrasonic device produced much narrower size distributions than the ball mill. This trend is especially obvious in the coarse size range where few particles remain, and in the fine size range where overgrinding is prevented. This behavior might have some interesting applications in areas other than mineral processing like powder metallurgy or material science where narrow and controlled product sizes are required for the successful elaboration of high-technology ceramics and glasses. Ultrasonic comminution has a significant advantage in the accurate control of the product size.

Jan 1, 1993

By Jeffrey C. Schuh, Logan Bloemer, Daniel P. Dietzler

Over the past 30 years, the authors have encountered numerous projects where recognizing the geology, soil properties and groundwater conditions, and considering alternative construction techniques have promoted efficient and cost-saving construction. The construction documents for these projects, produced by various engineering firms, provided basic information on geotechnical conditions. The authors became involved in each project either because there was a problem during design or construction or, as a contractor, won the project because they saw a value engineering opportunity to take advantage of the geologic setting of the project to design and build alternatives to what the designer depicted. Understanding the geologic setting is critical before planning and designing begins. Being able to work with the geology and the materials on site is preferred before specifying more costly and complex solutions, which often require the importing of materials and adherence to unnecessary and/or inappropriate specifications. Failing to understand the geology or not knowing all the techniques available for construction can lead designers to develop solutions that could be inappropriate. This paper presents several examples of value engineering and project performance enhancements developed through knowledge of basic soil mechanics and implementing innovative solutions. History and Background Most people attend DFI meetings, present their experiences, listen to others, and read articles and papers with the hope they can learn from others. Geotechnical engineers and contractors often interface with others in the execution of projects who have, at best, a rudimentary knowledge of geology and soil mechanics. Of course, there is a need for architects, bankers, and regulators, etc., but they typically do not have much interest in the nuances of geotechnical engineering, which relies on both art and science. Thus, significant time is spent educating counterparts in the need for comprehensive subsurface investigation programs and the intricacies of construction in the “dirt,” as they typically refer to soil and rock.

Jan 1, 2019

By H. R. Fife

AN extended study of dustproofing Freeport-seam coal has empha-sized several fundamental features in the successful treating of bituminous coals. The extent of the exposed surface area and its absorption proper-ties for the dust-retaining film were found to be the most critical factors affecting the efficiency of fly-dust prevention. From recently published screen data and specific surface-area measure-ments on United Kingdom coals, an approximation of the surface exposed by mine-run coal and by 1-in. slack was made. The total surface area exposed by an average ton of this mine-run coal was estimated at 3768 sq. yd., while a ton of 1-in. slack represents a total surface area of 8779 sq. yd. with no additions for porosity. It is important in coal treating to consider that in mine-run coal the fraction above 1/4 in. in size represents 79.5 per cent of the total weight, but only 4 per cent of the total surface, while the fraction below 150 mesh contains 47 per cent of the total surface and only 1.2 per cent of the total weight. Also, one should appreciate that, in a 1-in. slack, the domestic stoker fraction (1 in. to 8 mesh) contains 76.3 per cent of the weight and 8.2 per cent of the surface, while the fraction below 150 mesh represents 3.3 per cent by weight and 54.8 per cent by sur-face area. Wax extraction data on 1-in. to 0 slack from mine-run treated Free-port-seam coal showed that the coating was distributed uniformly as a function of exposed surface; hence, nonuniformly on a weight basis. This distribution of the coating on mine-run coal therefore limits the extent of treating that is desirable on bituminous coal at this point in the preparation. The treatment of Freeport mine-run coal before it reached the tipple gave a 70 to 80 per cent reduction of fly-dust in the tipple, a satisfactory treated commercial slack coal, and an indicated change in the trend of tipple degradation. The premium-treated domestic sizes required a supplemental treatment for complete dustproofness.

Jan 1, 1937

By Rainer Schmid-Fetzer

"Isothermal solidification can be used to form strong bonds at low temperature which remain solid at much higher temperatures. The exploitation of this principally known technique for new high temperature processing steps and applications in electronic assemblies is the aim of this study. Three basically different variants of this bonding process are given. A comprehensive metallurgical screening is performed and the feasibility of binary material systems is given on a quantitative scale. Very attractive systems are spotted that have never been studied before. Detailed examples for the realization of bonding with complex ternary and multilayer systems are given. A highly innovative example is the chip stack or wafer to wafer bonding of unmetallized Si or SiC at 250°C. The proposed bond remains stable above the melting point of Si and enables entirely new semiconductor manufacturing steps. An improved die bonding process was proposed and verified experimentally.1. IntroductionIsothermal solidification can be applied to form strong bonds at relatively low temperature which remain solid at higher temperatures. The general principle of this type of joining processes is illustrated in Fig. 1. An interlayer of a low melting component, Lo, is provided as a foil or a thin film coating between the high melting joint components, Hi. The assembly is heated under moderate pressure to the bonding temperature, T 8 , and a liquid filler forms, either because the melting point of Lo is exceeded or due to a eutectic reaction between Lo and Hi. This molten filler initiates a rapid interdiffusion or reaction diffusion between Lo and Hi and the subsequent approach to an equilibrium state results in isothermal solidification. The solid phases formed at T 8 in the joint region exhibit a remelt temperature above T8 •"

Jan 1, 1996

By S. M. Carpenter

In an ever increasing ?carbon? society; management and growth will be measured by one?s carbon footprint (or output). Industries, especially mining, are under an ever increasing scrutiny of carbon, water and environmental mandates. These mandates are measured by the emissions caused by the combustion of fossil fuels. The fundamental building-block for any business, strategic or management decision must be based on an understanding of one?s ?footprint?. The scrutiny is most stringent for the commodities producers, power producers & fuel suppliers in the energy market. An overview of currently acceptable standards, application of those standards and nuances experienced in collecting the data necessary to analyze and complete a company?s carbon footprint will be presented. A lack of regulation, the fear and expectation of new and ever constraining rules, regulation and a change in the federal administration is a recipe for uncertainty in the marketplace.

Jan 1, 2010

By Thomas M. Barczak, Christopher Mark

Roof supports can only be understood in conjunction with the rock structure that they support. The strength of the rock depends on geology, and the loads are applied primarily by the in situ and mining-induced stresses. Other factors, such as wider spans and retreat or multiple-seam mining, can also reduce the stability of mine openings. Roof supports are used to help stabilize these openings, but their performance characteristics must be properly matched to the loading environment and ground behavior if they are to succeed. Roof supports include both intrinsic supports, such as roof bolts, and standing supports. The key characteristics of any support include its maximum load-carrying capacity, stiffness, and residual strength. Other important factors are the timing of installation, the stability of the support as it is loaded, and the capability of the support system to provide skin control. This paper explains in practical terms how supports work and the important factors in ensuring that a good support design and application strategy are developed.

Jan 10, 2000