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By F. Khomamizadeh

In this study the effect of solidification rate, T6 and T7 heat treatments on thermal fatigue resistance of A319 aluminum was investigated. Increasing of the solidification rate improved the thermal fatigue resistance of the alloy by refinement of the microstructure. The most sensible areas for thermal fatigue crack growth were the eutectic zones, T6 and T7 heat treatments improved the thermal fatigue resistance of the alloy by enhancing of the matrix resistance against the crack propagation. The slight reduction of the thermal fatigue resistance after T7 heat treatment is attributed to coarsening of the precipitates which reduces the matrix resistance.

Jan 1, 2005

By D. L. Martin, E. R. Parker

IN a previous paper, one of the authors observed that the rate of cooling from the anneal prior to testing greatly influenced the life of copper under sustained load at 200°C. Furnace-cooled bars of oxygen-free copper (with, and without silver) had a life four to twenty-five times that of the water-quenched specimens. The addition of 0.054 per cent silver to the oxygen-free copper increased the life at a stress of 20,000 lb. per sq. in. from about 2 hr. to 50 hr. Fractures in these bars were intercrystalline. An explanation was advanced to account for the profound influence of cooling rate on the rupture properties at 200°C. The suggestion offered was that at the high annealing temperature the minor constituents are distributed at random. By water quenching, this condition is maintained at room temperature, whereas furnace cooling permits some segregation at the grain boundaries. The higher concentration of the minor constituents in the grain boundaries results in a strengthening, so that a longer life at a given stress and temperature results. Small amounts of cadmium or manganese have also been found to increase the life of copper at 200°C., and to a much greater extent than silver .2 The increase in the long-time strength of copper resulting from small additions of cadmium or silver appears to be related, indirectly at least, to the higher softening temperatures of such alloys. The elements, such as silver or cadmium, which greatly increase the rupture life of copper also cause large increases in the softening temperature. As little as 0.05 per cent of cadmium or silver is sufficient to raise the softening temperature more than 100°.3,4 The effects of cooling rate and of minor constituents on the rupture properties are of considerable fundamental as well as practical interest; therefore a more detailed study of their nature was conducted and is reported in this paper. EXPERIMENTAL PROCEDURE Materials The materials studied in this investigation may conveniently be classified in two groups: one consisting of a wide variety of commercial coppers, and the other composed of special high-purity, laboratory-prepared coppers. The commercial materials were tested to determine whether or not the effect of cooling rate occurred with all coppers, whereas the high-purity coppers were investigated in order to establish a basis for evaluating the effect of minor constituents on the rupture properties. In Table I are given the analyses of the coppers tested. The samples I to 6 are commercial materials and were obtained for the most part from stock supplies.*

Jan 1, 1943

By Ari Jokilaakso, Junjie Shi, Zhuo Chen, Pekka Taskinen, Xiang Gao

The amount of copper flash smelting slag has increased during the recent years along with an increasing slag-to-metal ratio. During slag tapping, some copper sulfide is mechanically entrained. As a result, it is necessary to recover copper matte from the slag by suitable methods. At present, the most common way is slow, controlled cooling in a transfer ladle. However, research on the detailed effects of slow cooling and the function of slag modification is rare. This paper described experiments that were performed at different cooling rates (0.5, 1.5, 3, and 7 °C/min), with and without additive. A detailed characterization of the copper-rich phase and its particle size was subsequentlymade using SEM-EDSmicrographs and image analysis software.With a decrease in cooling rate, the particle size of the copper-rich matte phase became larger. The addition of gypsum and carbon as a slag modifier affected the size of the copper-rich phase slightly, and its chemical composition was modified compared with the experiments without additive.

Jul 31, 2020

By Gülhan Özbayoglu, Yusuf Ziya Akgök

The effect of cooling rate on the flotation behaviour of copper slags of flash smelter plant in Samsun was investigated. Fresh molten slag was solidified in laboratory scale in three different ways. All the samples were characterized by chemical and mineralogical analyses. The chemical analyses showed that samples prepared from fresh slag had 0.9 to 1 % Cu with 40 % Fe and 30 to 32 % SO2. Old pit slag samples contained between 1 to 3% copper. Microphotographs showed that rapidly cooled slags showed fine size distributions, e.g. the copper grains in granulated slag had sizes in 1-2 microns. On the other hand, the size of copper grains in slowly cooled slags increased above 40 microns. Flotation tests carried out by using potassium amyl xanthate and Flotanol-C showed that slowly cooled slag reduced the copper losses in the tailing and improved the grade of concentrate. Under the light of laboratory investigation, the pit dimensions of Samsun Plant have been modified which resulted in a pronounced improvement of the grade and recovery of concentrate produced at Samsun slag flotation circuit.

Jan 1, 1995

By Ho-Jung Shin

The influence of cooling rate from 1873 to 1473 K on the size and morphology of austenite grains was studied using a Fe-O.I5 % C-I.5 % Mn alloy. The experiments were carried out at three different cooling rates of O.33KJsec, O.67KJsec and air-cooling. The austenite grain showed an isotropy at 0.33KJsec but maximized anisotropy at O.67KJsec and become much less. anisotropic. In order to account for these phenomena, a model was developed for estimating the size and morphology of austenite grains as a function of cooling rate. The driving force for the )( phase formation from 0 phase is caused by undercooling degree due to cooling rate and energy barrier is restricted to the misfit strain energy which is caused by mismatch between )( phase and 0 phase. The )( phase from 0 phase could be formed on not random orientation index systems but specific orientation systems depending on cooling rate.

Jan 1, 2001

By Dan Wang, Qian Li, Yong-bin Yang, Tao Jiang

"Thiosulfate is one of the most promising non-cyanide lixiviants for gold leaching. However, the undesirable reaction between thiosulfate and copper (II) gives rise to increased reagent consumption, which results in high cost and huge limit to its development. This paper presents study on the effect of ammonia, copper (II) and Cu(NH3)l+ ions on the oxidative decomposition of thioulfate. It shows that the presence of copper (II) and Cu(NH3)l+ can significantly increase the thiosulfate oxidation, while ammonia is relatively unaffected. The oxidation of thiosulfate by copper(II) in the absence of ammonia is fast at first and then decreases as time increased within a certain time, which can postulate that an intermediate product is responsible for the decreased consumption. The effect of ammonia is depended on the interaction with copper (II), which was found to significantly affect the consumption of thiosulfate.IntroductionFor over one century cyanidation is widely used in industrial production of gold, due to its simplity of process and low cost of production. However, cyanide is a highly toxic chemical reagent used dangerously and brings serious environmental pollution. What's more, cyanidation has slow speed of leaching gold and poorly leaching effective for refractory ores. With the exhausting of free-milling gold ores and promoted environmental protection requests, the disadvantage of cyanidation becomes a growing problem. In recent years, more and more research activities have been focused on alternative processes using non-cyanide lixiviants. Among the non-cyanide lixiviants, thiosulfate is considered as the most promising one[l-5].Compared to cyanide, thiosulfate is an inexpensive, nontoxic and less-pollution reagent, which can form complexes with many metal ions. Thiosulfate leaching of gold has an acceptable leaching rate and is insensitivity to impurities. Moreover it presents advantage on the treatment of refractory gold ores such as carbonaceous gold ores, copper gold ores, complex arsenic and sulfur gold ores, and so on[6]."

Jan 1, 2013

By H. Yoshida, H. Hatta, T. Suzuki

"The effect of the copper and magnesium contents and quenching rate during quenching on the age hardening behavior of 2000 series aluminum alloys was investigated. For the higher copper-containing specimens as conventional alloys, like AA2024, precipitation of the stable phases increased as the quenching rate decreased under the as-quenched conditions. The maximum hardness after the artificial aging of air cooled(AC) specimens was much lower than that of the water quenched(WQ)specimens. On the other hand, for the lower copper-containing specimens, coarse precipitation did not increase even in the case of the AC. The age hardening behaviors of the WQ and AC were very similar such that the maximum hardness and aging rate were almost the same. Many parts of the fine precipitates that increased the hardness were thought to be the GPB zone or fine S’ phase for the WQ and relatively coarse S’ phase for the AC. From the calculated CCT(continuous cooling transformation)diagrams, the lower copper-containing specimens could maintain the copper and magnesium in the solid solution state during the AC, so they could be quenched at a rather slower quenching rate like the AC.INTRODUCTIONThe 2000 series aluminum alloys, containing copper and magnesium as the major chemical components, are some of the well-known heat treatable aluminum alloys. These alloys have a high quenching sensitivity, thus the age hardening ability of these alloys decreases with as low quenching rate. To prevent the decrease of the age hardening ability, quenching is done by a method such as water quenching, which is not very efficient in an industrial situation, because the method requires such large equipment. For these alloys, reducing the quenching sensitivity helps them to be produced in a rather convenient way. For example, 6000 series alloys such as A6063 have low quenching sensitivity, thus they could be quenched by only air cooling just after extrusion and they do not need water quenching. Based on these reasons, investigations of these alloys with high copper and magnesium contents have been conducted in the past to find a way to lower the quenching sensitivity by adding transition elements such as manganese, chromium and zirconium (Kanno, Suzuki, & Itoh, 1986; Suzuki & Itoh, 1986; Kanno, Sakuma, Muromachi, & Watanabe, 1988). However, very few studies have focused on the quenching sensitivity of the lower copper and magnesium containing alloys because of their usage for structural components with high strength, and most of the past studies have used only the fast quenching method like water quenching. On the other hand, from our recent results, there is a possibility to lower the quenching sensitivity of 2000 series alloys with lower alloying elements. In this paper, the effect of the copper and magnesium contents with lower alloying elements and quenching rate, especially in case of slower quenching rate than conventional quenching method, on the age hardening behavior of the 2000 series alloys is investigated by the hardness measurement, structure observation and thermal analysis."

Jan 1, 2018

By Robert I. Jaffee, Bruce W. Gonser

RECENT work by the authors1 established the constitutional diagram of the gold-germanium system. Of particular interest in the simple euctectiferous system was the eutectic alloy at 12 per cent Ge, which melted at the very low temperature of 356°C. and had an unusually fine eutectic structure. It was of interest to investigate the effect of third components on the melting point, microstructure, and strength of this alloy, and in this work the effect of copper is discussed rather completely, with less complete data on the effects of silver, platinum, nickel, and zinc. No reference in the literature has been found on ternary systems with gold-germanium. MATERIALS AND ALLOYING As in the work on the binary system, gold-germanium, the germanium used in this investigation was the cyanide-reduced, 99.9 per cent product, produced by the Eagle-Picher Co. Fine gold sheet from Handy and Harmon, pure platinum sheet from the American Platinum Works, copper magnet wire from Anaconda, nickel wire assaying 99.6 per cent Ni, and electrolytic zinc were used for alloying. To make the alloys, charges of the pure metals were put in a graphite crucible and melted in an atmosphere of pure hydrogen. The temperature was brought up to about 1050°C., and the metal allowed to freeze in the crucible. Except with alloys containing zinc, melting losses were consistently less than a few milligrams. When zinc was a component, weight losses up to half the weight of the zinc present were incurred, and the alloy compositions were calculated by assuming the entire weight loss to be that of zinc. In all other cases the composition of the alloys could safely be taken as that of the charge. The ingots, as solidified, were segregated, the heavier primary phases being at the bottom and sides of the ingots and the lighter primary phases at the top, but by sectioning the entire ingot vertically for microscopic examination, this factor could be evaluated. Ingots for microscopic examination weighed one gram, and those for thermal analysis weighed three grams. THERMAL ANALYSIS In this work, the eutectic line composition and thermal arrests were desired, and, after microscopic exploration had established the position of the eutectic line at a given percentage of the third component, a thermal analysis was run at that composition. The method of thermal analysis used in the work on the binary Au-Ge system,1 a method particularly well suited for a small quantity of material, was used in this work. Clearly defined arrests were obtained, although with some alloys containing platinum

Jan 1, 1946

By E. S. Leaver

THE presence of soluble base metals in precious-metal ores usually precludes cyanidation as the best method of treatment. The laboratory experiments described in this paper show the possibility of cyanidation of gold-silver ores containing less than 0.5 per cent, of cyanide-soluble copper and the effect of zinc in the cyanide solution. PART I.-COPPER IN CYANIDATION The proposed process of cyanidation of precious-metal ores containing copper is based on the regeneration of about 80 per cent., of the cyanide used in the dissolution of the copper. The method of regeneration involves a combination of the sulfide and the acid precipitation of the copper and silver. The resultant solution is made alkaline with lime, and the gold is precipitated with zinc dust. Solubility of Copper Minerals in Cyanide Solution In order to determine the solubility of copper minerals, including metallic copper, under the usual conditions for cyanidation, experiments were conducted with synthetic ores. Each ore sample was prepared by mixing the particular pure copper mineral with barren sea sand. Both the mineral and sand were ground to pass 100 mesh before they were thoroughly mixed. The percentage of copper in each head sample was determined by direct assay, excepting the metallic copper sample, which was computed on weights before mixing. Table 1 gives the results.

Jan 1, 1929

By E. S. Leaver

THE presence of soluble base metals in precious-metal ores usually precludes cyanidation as the best method of treatment. The laboratory experiments described in this paper show the possibility of cyanidation of gold-silver ores containing less than 0.5 per cent. of cyanide-soluble copper and the effect of zinc in the cyanide solution. PART 1.-COPPER IN CYANIDATION The proposed process of cyanidation of precious-metal ores containing copper is based on the regeneration of about 80 per cent. of the cyanide used in the dissolution of the copper. The method of regeneration involves a combination of the sulfide and the acid precipitation of the copper and silver. The resultant solution is made alkaline with lime, and the gold is precipitated with zinc dust.

Jan 1, 1929

By Y. -H. Cho, J. -M. Lee, J. -G. Jung

The effects of copper on the microstructure and mechanical properties of ultrasonic melt treated Al-xCu (x=0, 4) alloys were investigated. The densities of alloys were increased and their grain sizes were decreased by UST. The hardness and electrical resistivity measurements revealed that the amount of solute Cu within Al matrix was increased by UST. Both the yield and tensile strengths of Al-4Cu alloy were increased by UST. The improved mechanical properties of Al-4Cu alloy by UST were probably due to the reduced amount of casting defects (e.g. pore), grain refinement, and enhanced solid-solution hardening of Cu.

Jan 1, 2014

By A. G. Doll

The Bond low energy impact (crushing) work index test is specified to be performed on rock specimens between 50 mm and 75 mm in effective diameter. NQ-diameter drill core, frequently used in mineral exploration programs does not meet that specification, it being 45 mm diameter or less. This paper reports the effect of performing the impact test on contiguous sections of HQ diameter and NQ diameter core, exploring the hypothesis that the contiguous intervals give equivalent results in spite of the core diameter difference.

Jan 1, 2012

By R. Phillips, A. G. Doll, D. J. Barratt

"The Bond low energy impact (crushing) work index test is specified to be performed on rock specimens between 50 mm and 75 mm in effective diameter. NQ-diameter drill core, frequently used in mineral exploration programs does not meet that specification, it being 45 mm diameter or less.This paper reports the effect of performing the impact test on contiguous sections of HQ diameter and NQ diameter core, exploring the hypothesis that the contiguous intervals give equivalent results in spite of the core diameter difference."

Jan 1, 2012

By HASSAN E. EL-SHALL, AYMAN A. EL-MIDANY, KERRI-ANN A. HUE

Modifying the hydrophobicity of clay is necessary to accommodate large mycotoxin molecules such as zearalenone (ZEN). In this study, tricaprylmethylammonium (TCMA) chloride and common corn oil were used to modify clay. The results indicate that more than 90 percent of ZEN could be removed using clays modified by TCMA and corn oil at acidic and neutral pH due to the expansion of intergallery spacing as a result of TCMA surfactant intercalation within the clay-forming layers. The removal percentage depends on the pH and amount of clay used. Complete removal can be achieved at acidic pH and small clay amount.

By Ayman A. El‑Midany, Hassan E. El‑Shall, Kerri‑Ann A. Hue

Modification of clays is necessary for the zearalenone (ZEN), as long-chain mycotoxins, removal. The organic-cations were usually used to modify the clay hydrophobicity to accommodate the large mycotoxin molecules. In this study, tri capryl methylammonium (TCMA) chloride and common corn oil were used in clay modification. Several characterization techniques such as XRD, FTIR, and TGA were used to identify the d-spacing changes after modification either by TCMA or corn oil. The results of applying the TCMA-corn oil-modified clays in ZEN removal indicated a noticeable improvement where more than 90% of ZEN could be removed in vitro at acidic and neutral pH values. The success of eliminating a high percentage of ZEN molecules is due to the expansion of intergallery spacing as a result of TCMA surfactant intercalation within the clayforming layers. The removal percentage does not depend only on pH but also on the amount of clay used. In addition, the ZEN removal in the presence of corn oil is better at acidic pH and small clay amount where the ZEN can be fully removed.

Sep 27, 2021

By Satyajeet Ghosh, Edward F. Glynn

Many of the proposed techniques for calculating the reliability of rock slopes utilize Monte Carlo simulation. Monte Carlo approaches are attractive because they provide means of solving probabilistic problems with deterministic algorithms. One disadvantage shared by all simulation-based stability analyses is that they assume all the random variables are independently distributed. The paper focuses on the independence assumption and examines the effect of correlation on the probability of failure. In particular it considers the influence of possible (albeit hypothetical) correlation between joint attitudes [(8)] and joint friction angles [($)]. The study indicates that neglecting correlation can introduce significant errors into the reliability computations. With a modest positive correlation between [8] and [$] the error can lead to a 100% overestimate of the probability of failure.

Jan 1, 1982

By Zhan Zhang, Hiromi Nagaumi, Zhen Li

"Recently, the remarkable strengthening effect of ??-Al(Mn, Fe) Si dispersoids at both ambient temperature and elevated temperature were found by several researches. A large amount of dispersoids can be formed by applying special heat treatments and within a suitable range of chemical composition of AA3xxx alloys. In the present work, the influences of Cr addition on the mechanical properties and microstructures of the Al-Mn-Mg-Si alloys were investigated. The mechanical properties at ambient and elevated temperatures were evaluated by micro-hardness and yield strength. Moreover, the microstructures in as-cast and heat-treated conditions were quantitatively analyzed by optical and electron microscopes. Results revealed that Cr also had effect on the number density and volume fraction of dispersoids. Micro-hardness and yield strength at ambient temperature increased with the increasing content of Cr, and the Cr addition increased the yield strength at elevated temperature as well. Moreover, the creep resistance at 300°C improved dramatically with the increasing content of Cr.INTRODUCTION Traditionally, AA3xxx aluminum alloys were widely used in packaging, automobile and architecture industries, because of its good formability, excellent corrosion resistance and weldability. And AA3xxx alloys were considered as non-heat-treatable alloys. However, the strengthening effect of dispersoids in AA3xxx alloys was discovered recently (Li & Arnberg, 2003;Li, Muggerud, Olsen, & Furu, 2012; Li, Zhang, & Chen, 2016; Liu & Chen, 2015).Alarge amount of dispersoids could precipitate by a proper heat treatment.In order to further improve AA3xxxalloys, the composition of the alloys should be optimized. A few previous studies were reported to investigate the influence of compositions on AA3xxx alloys. Adding Mn element could enhance the precipitation of ??-Al(Mn, Fe)Si dispersoids and improve the yield strength(Muggerud, Mørtsell, Li, & Holmestad, 2013), as long as the concentration of Mn was under the solid solution limit. Fe decreased the solubility of Mn and accelerated the precipitation rate of ??-Al(Mn, Fe)Sidispersoids(Li & Arnberg, 2003), the yield strength and creep resistance at elevated temperature could increase with an optimized content of Fe(Liu & Chen, 2016). Mg element would affect the nucleation process of ??-Al(Mn, Fe)Sidispersoids by forming metastable Mg2Si(Hirasawa, 1975; Li, Zhang, & Chen, 2017a; Lodgaard & Ryum, 2000), metastable Mg2Si precipitated during heating process and promoted the precipitation of ??-Al(Mn, Fe)Sidispersoids, moreover, Mg provided solid solution strength for AA3004 alloys(Li et al., 2016). Si increased the volume fractionof ??-Al(Mn, Fe)Sidispersoids(Muggerud et al., 2013)and decreased the size of ??-Al(Mn, Fe)Sidispersoids(Li, Zhang, & Chen, 2017b). With the addition of Mo, the size of dispersoids became finer with a higher volume fraction, the volume percentage of dispersoid free zones was reduced. Elevated temperature yield strength and creep resistance improved due to Mo addition (Liu, Ma, & Chen, 2017).However, the effect of Crelements on microstructure and mechanical properties of AA3xxx alloys were rarely reported."

Jan 1, 2018

By Jian Li, J. Miles, P. Liu, W. Cook, W. Zheng, Alvin Qian

"High temperature corrosion resistance is one of the key challenges in water-cooled nuclear reactor material development. Iron based materials with low Cr content exhibits superior high temperature mechanical properties. However, due to the relatively low Cr content, their corrosion resistances under supercritical water (SCW) conditions are generally poor. High-Cr alloys, despite their much improved corrosion resistance, often suffer from embitterment due to the precipitation of sigma phase in the microstructure. In this study, corrosion resistance of an in-house produced high Cr steel (25%Cr) showed much better corrosion resistance compared to that of low Cr alloy (14%Cr). This high-Cr steel can potentially be used as a corrosion-resistant coating for structural materials in sew applications.INTRODUCTIONThe supercritical water-cooled reactor (SCWR) concept is one of the promising designs for the next generation nuclear reactor, in which the water coolant is designed to be at about 625°C and 25 MPa at the outlet of the reactor core. Under these relatively high-temperature and high-pressure conditions, the cooling water is at supercritical state. High-temperature mechanical properties, corrosion resistance and radiation damage are some of the key challenges. At present, no single commercial material can meet all the requirements of the severe SCWR in-core conditions. Canada supports research in several key areas of SCWR development, including materials selection. A major focus is on materials development, selection and evaluation for both in-core and out-of-core components.Allen et. al. [1] carried out a comprehensive study on the SCW corrosion resistance up to 600 °C on commercially available high temperature materials including Ni-based super alloys, various types of stainless steels and ferritic/matensitic steels. They concluded that ferritic steels develop a relatively thick but mechanically stable oxide layer, while austenitic alloys develop a thinner oxide layer that has been found to spall in some cases. Of the three types of alloys examined, the Ni-based alloys exhibited the lowest oxide thickness, however pitting was observed in the vicinity of intermetallic precipitates."

Jan 1, 2011

By Lifeng Yang, Xiang Zhang, Liang Yuan, Yonghui Wang, Bing Hou, Mian Chen, Rixing Zhang

Large-scale hydraulic fracturing technique has been widely applied to the development of shale gas reservoirs, where the interaction between natural fractures and critical fracture zones has substantial impact on the propagation of hydraulic fractures. Therefore, it is of significant importance to understand and experimentally verify such mechanism. To reach this end, tri-axial fracturing tests were implemented on 400mm×400mm×400mm block samples collected from Longmaxi shale outcrops. The interplay between hydraulic and natural fractures was investigated during the tests, factoring in the role of pump rate in affecting the created fracture network. Based on the experimental results, the critical fracture zone, defined as the weak formation zone nearby the wellbore created by staged pressure implementation that is observed rapid fracture propagation upon next stage of pressure increase, was thoroughly investigated. The analysis illustrates that given the high brittleness of the shale formation, abundant critical fracture zones are generated around natural fractures with pressure building up at a relatively low pump rate. As the pump rate increases, hydraulic fractures initiate and come into play with critical fracture zones, implying emergence of a large number of micro-cracks. A changing pump rate modifies the way of interaction between hydraulic and natural fractures and the subsequent formation of fracture network. Long term fracturing fluid injection with relatively low pump rate below the activation of critical zones is suggested. Also proposed is appropriate timing when applying a specific pump rate that will contribute to the improvement of hydraulic fracture propagation.

Jan 1, 2015

By P. N. Anyalebechi

The effects of a cross-hatched grooved mold surface topography, casting speed, and superheat on the morphology of solidifying shells of aluminum alloy 3003 have been characterized by a series of immersion tests. The cross-hatched grooves were 0.232 mm deep with wavelength or spacing between 1 mm and 15 mm. The shells solidified at casting speed of less than 10 mm/s on the 1 mm spaced cross-hatched grooved mold surface were fairly uniform with little or no localized variations in thickness. However, the propensity for non-uniform shell growth morphology was exacerbated by an increase in casting speed, melt superheat, and the wavelength of the cross-hatched grooves. This is provisionally attributed to their effects on interfacial heat transfer and wetting of the mold surface by the molten metal.

Jan 1, 2008