Search Documents

By K. Wangerud, B. S. Caruso

A water balance model with deterministic and stochastic components was developed and used for the Gilt Edge Mine Superfund Site, South Dakota, to evaluate risks of contaminated runoff discharging to surface waters based on assumed water treatment plant (WTP) rates for different remedial alternatives. The objectives of the modeling were to use a stochastic approach for analysis of precipitation based on historic records, and for probabilistic estimation of annual and monthly runoff from primary disturbed/mining activity areas that currently requires, or will need, treatment at the WTP, water storage and changes in a major pit, and risk of contaminated water bypass of the WTP to a downstream drainage. Subareas/source areas generating contaminated runoff requiring treatment were delineated. A simple water balance model was used based on precipitation inputs and evapotranspiration and groundwater losses. Annual and monthly precipitation records for Lead, South Dakota were used to estimate precipitation at the mine site. A lognormal distribution was estimated for monthly precipitation. The stochastic software package/Excel add-in “@Risk” was used to generate random monthly precipitation values using a Monte Carlo method based on the distributions. The average annual and monthly distribution of pan and lake evaporation, and groundwater losses were also estimated for the site. Stochastic outputs from the model for the end of each month and year included contaminated runoff requiring treatment, water storage in mine pits and the risk of WTP bypass given different assumed WTP rates. The probability of the time required to dewater the pits was also modeled.

Jan 1, 2002

By K. Wangerud, B. S. Caruso

A water-balance model with deterministic and stochastic components was developed and used for the Gilt Edge Mine Superfund Site in South Dakota. The model was developed to evaluate the risks of contaminated runoff discharging to surface waters based on assumed water treatment plant (WTP) rates, for different remedial alternatives. The objectives of the modeling were to use a stochastic approach for the analysis of precipitation based on historic records and to make a probabilistic estimation of annual and monthly runoff from disturbed/mining activity areas that now require, or will need, treatment at the WTP, water storage and changes in a major pit, and risk of contaminated water bypass of the WTP to a downstream drainage. Subareas/source areas generating contaminated runoff requiring treatment were delineated. A simple water-balance model was used based on precipitation inputs and evapotranspiration and groundwater losses. Annual and monthly precipitation records for Lead, South Dakota, were used to estimate precipitation at the mine site. A lognormal distribution was estimated for monthly precipitation. The stochastic software package/ Excel add-in "@Risk" was used to generate random monthly precipitation values using a Monte Carlo method based on the distributions. The average annual and monthly distribution of pan and lake evaporation and of groundwater losses were also estimated for the site. Stochastic outputs from the model for the end of each month and year included contaminated runoff requiring treatment, water storage in mine pits and the risk of WTP bypass given different assumed WTP rates. The probability of the time required to dewater the pits was also modeled.

Jan 1, 2003

Project developent proceeds by increasingly detailed studies addressing overall project returns through an analysis of the substance, risks and costs associated with the following elements: ò Reserves ò Mining ò Processing ò Infrastructure ò Environmental Impact ò Product Market Computer-based expertise has a potential to ò Capture perishable expertise, making this available for shared access and so reducing the cost of human experience ò Consolidate know-how for optimising process operations, bringing consistency of judgement and advice to decision- making by making the rules, facts and preferences explicit ò Allow assignment of the basis and authority of decisions, so experts can pass routine expertise down the line, freeing their time to generate more. ò Force a review of expertise when creating the knowledge base.

Jan 1, 1989

By M Araos, I Onederra

A novel explosive formulation that substitutes the use of ammonium nitrate (AN) with hydrogen peroxide (HP) as the main oxidising agent has been developed and tested as part of an Australian Coal Industry Research Program (ACARP) project. The main objective was to provide a step-change solution that has the potential to completely eliminate NOx fumes in blasting. The development of this HP/fuel-based explosive started with a comprehensive detonation characterisation program, consisting of unconfined velocity of detonation (VOD) measurements of samples at different diameters, densities and void sensitisation techniques. VOD results showed that the HP/fuel-based explosive mixtures behaved similarly to non-ideal commercial explosives; in that way mixtures could be tailored to achieve specific detonation performance targets. The next stage of testing in this development involved preliminary confined tests to evaluate the rock breakage potential of the HP/fuel-based explosive mixtures. Fully instrumented single-hole tests were conducted in a limestone quarry. Results from these preliminary trials confirmed the rock breakage performance of HP/fuel-based explosive mixtures. The confined VOD measured in one of the tests was 5100 m/s in a 102 mm diameter blasthole at a density of 0.96 g/ml. The corresponding borehole pressure measurement of this HP charge was 2.61 GPa with a detonation temperature of 2921°C. Based on near-field accelerations, both HP and ANFO charges displayed similar attenuation characteristics in the test conditions. Post-blast observations indicated that the breakage performance of the HP mixtures clearly reflected the in-hole detonation performance measurements obtained, confirming the ability of these explosive mixtures to both fragment and effectively displace the rock mass under evaluation. Further research work continues with the future commissioning of a prototype mixing and delivery unit, the successful completion and analysis of data from multiple-hole trials, and further characterisation work associated with product stability, reliability and performance under different geotechnical conditions.CITATION:Onederra, I and Araos, M, 2015. Detonation and breakage performance of a hydrogen peroxide-based explosive formulation, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 565–574 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By Y. Hirosaki, H. Hamashima, Y. Itoh Kato, S. Tanaka

The emulsion explosives show non- ideal detonation behavior, and its detonation velocity can be controled by selecting the size and adjusting the quantity of voids involved. To establish the technology to control the detonation characteristics of the emulsion explosives, some experiments have been carried out using resin balloons of five different sizes ranged from O.OSmm to 2.42mm in the average diameter. Detonation velocities of the emulsion explosives containing resin balloons of different size and quantity were determined for the charge diameter of 20-50mm. The detonation velocity at infinite charge diameter was compared with calculated ideal detonation velocity. The emulsion explosives containing large (0.5mm or larger) balloons showed big discrepancy between the measured and calculated detonation velocities, and the fraction of ammonium nitrate reacted in the reaction zone was estimated to be significantly low. It was shown that the reaction zone length was proportional to the size of voids involved. The critical charge diameter was determined for the emulsion explosives containing different resin balloons at the various explosive densities. It is large for the emulsion explosives containing large voids, and it was shown that the critical diameter is proportional to the distance between the void surfaces, not to the void spacing, the distance between the centers of the voids. The reaction rate of the bulk emulsion matrix seems to be the major factor that affects the critical diameter than the specific surface of voids. Good relationship between the critical diameter and the reaction zone length was observed.

Jan 1, 2000

By James A. McGrath

"The predominant key word associated with all commercial blasting methods is “safety”. Safetyshould take precedent over all other aspects of the entire explosives industry which on a wholehas had an excellent track record as to number of injuries per unit of hours worked at all blastsites throughout our country."

Jan 1, 1999

By B. Winterberg, C. Lewis, M. Starkel, C. Johnson

Non-electric systems, specifically shock tube, have become the pyrotechnic detonator of choice over electric due to their safety regarding accidental initiation from stray radio signals. Typically, the best practice when hooking up shock tube systems is to have direct contact to ensure initiation. When gaps are introduced to the explosives chain, there is potential for detonation to come to a halt. It is understood that direct coupling is required between the various elements in the explosive chain to ensure detonation. This holds true whether tying in non-electric detonators, loading holes in a mining related blast, or priming a block of C-4. Poor contact and gaps in the explosives chain can lead to detonators firing out sequence, leading to increased vibration, air overpressure, and other undesirable blast results. Furthering work conducted in previous experimentation, a new study was conducted at the Missouri University of Science and Technology’s Experimental Mine in Rolla, Missouri to observe the initiation potential of an air gap and fragmentation on non-electric shock tube. A series of small test blasts were conducted using 50 grain detonating cord and fragments from a blasting cap to initiate a non-electric shock tube across an air gap of varying distances. The data collected in the high-speed imagery was used to analyze the velocity of the pressure fronts and blasting cap fragments used to initiate non-electric shock tubes across an air gap. It was found that the shock tube was sensitive to 50 grain det cord at a 5cm (1.97in) distance while parallel and 10cm (3.94in) when perpendicular as well as sensitive to frag from the electric cap out to 2.4m (7.87ft).

Jan 1, 2024

By I Onederra

A better understanding of the detonation performance of an explosive charge can be gained by directly measuring pressure, temperature and velocity of detonation (VOD). This is particularly important with explosives used in the mining industry because their performance is directly influenced by the degree of confinement given by the borehole diameter and the surrounding rock mass. A project funded by the Australian Coal Association Research Program (ACARP) was initiated in early 2009 with the view to design and build cost-effective prototype instrumentation to measure the relative differences in detonation pressures and temperatures of commercial mining explosives. The project’s primary focus was on low-density explosives. Low-density (also referred to as low shock) explosives have been available in various forms for nearly 20 years. There have been significant advances in the availability, reliability and flexibility of these explosives, which now offer a range of densities and degrees of water resistance. Their detonation performance is not well understood and cannot be accurately predicted with current ideal and non-ideal detonation codes. It was therefore viewed as important to be able to directly measure pressure and temperature during the detonation process of these complex mixtures in production blastholes. Identifying the pressure release patterns of both conventional and low-density explosives under different geotechnical conditions should provide the necessary information to both validate detonation codes and better define input parameters for breakage and fragmentation models. This paper gives a general description of the prototype instrumentation developed and reports on the results obtained to date in full-scale conditions.

Nov 8, 2011

By Richard H. Granhom

Detonation pressure, or Chapman-Jouguet pressure, is an intrinsic property of an explosive, and like detonation velocity, is an indicator of explosive performance. Pressure and velocity are also important for calibrating computer codes and for other calculations such as the stress imparted to rock or metal by an explosive. The detonation pressures, P~cj, of many "ideal" explosives have been measured indirectly by recording some hydrodynamic flow variable other than pressure, with P~cj being inferred from hydrodynamics and the assumed Chapman-Jouguet equations. One such method is the difficult and expensive "aquarium technique''.] Commercial explosive manufacturers generally rely on estimates of P~cj generated by computer codes not explicitly designed for non-ideal explosives typically used in commercial applications. Over the last decade, U.S. national and government laboratories have developed in-situ gauge techniques such as the manganin gauge, for direct measurement of detonation pressure. Manganin is an alloy of copper, manganese and nickel, and is ideally suited for use as a pressure transducer because its electrical resistance changes with pressure, but is nearly constant with changes in temperature. A simplified manganin gauge technique adapted for use at a commercial test site is described and some initial results from measurements on commercial emulsion explosives are presented.

Jan 1, 1991

By Martin Langenderfer, Sergii Chertopalov, Catherine Johnson, Vadym Mochalin, William Fahrenholtz

The high temperature and high pressure of an explosive detonation can be used for the production of nanomaterials. The controlled detonation of explosive compositions along with the collection and characterization of reaction products encompasses a process known as detonation synthesis. The primary advantage of the method of detonation synthesis is the possibility for producing monocrystalline nanoparticles with diameters of less than 10 nm. In order to successfully synthesize nanomaterials via the detonation process, it is necessary that the explosive detonation is conducted in a sealed environment. This environment when pulled to a vacuum or purged with inert gas such as argon will reduce the oxidation of detonation reaction products. Detonation synthesis testing is currently being conducted in a 1.8 cubic meters (m3) (64.3 cubic feet (ft3)) ellipsoidal pressure vessel consisting of two interlocking half shells. The testing involves the controlled detonation of cast mixtures of Cyclotrimethylene-trinitramine (RDX) and 2,4,6-Trinitrotoluene (TNT) in conjunction with siliceous compounds to produce nanocrystalline diamond and silicon carbide. Alternative detonation environments including the presence of a cooling medium such as water or dry ice to absorb residual, post detonation, thermal energy and enhance the stability of the materials being produced have improved yield. Modifications to the explosive charge composition have an effect on the type and quantity of materials that can be produced. Doping of explosive charges with various organic and inorganic compounds has shown promise in the synthesis of materials that are difficult or uneconomical to produce through other methods. This paper outlines the process development of detonation synthesis facilities. Preparation of the pressure vessel to create a suitable detonation environment for the production of nanomaterials is examined. Formulation of explosive charge compositions and considerations involving test charge initiation are discussed in detail. Experimental results and analysis from initial testing as well as plans for future research are also evaluated.

Jan 1, 2018

By Ronald R. Rollins

A continuous propagation velocity measurement probe has been utilized to determine velocities of slurry explosives, whole prills, crushed prills, aluminized crushed prills, in bulk and plastic screw tubes.

Jan 1, 1984

By Fumihiko Sumiya, Yukio Kato, Yoshikazu Hirosaki

Secluential blasting is one of the most popular methods in blasting. tiowever, it is well known that an emulsion explosive can be dead-pressed by dynamic pressure generated by the previous detonation. It is difficult to gain the expected blasting performance due to tb.e malfunction of explosive caused by deadpressing and shock desensitization. Such malfunction of an explosive is undesirable for safety blasting operation. Voids in the emulsion explosives will considerably affect the performance of explosives such as sensitivity, detonation velocity (DV), pressure-resistance and so on. To clarify the detonability and the performance of precompressed emulsion explosives, the DV was measured. Three types of microballoon or micro bubble ; two types of glass microballoon(GMB), resin microballoon@MB) and chemical gas bubble ; were used as sensitizers for the sample emulsion expiosives. The underwater explosion test was carried out to load dynamic pressure into the sample explosives. The dynamic pressure was generated by the detonation of a donor explosive, and the DV of the sample explosives as acceptor was measured by ionized gap terminals. The dynamic pressure level and initiation interval for the donor and the acceptor were chosen as experimental factors. The detonability was carefully investigated at short initiation intervals taking into consideration the interaction between same delays caused by the deviation of the ignition time of the electric detonators. From these experiments, the following results were obtained ; A) The DV of precompressed emulsion explosives was low compared with that of uncompressed emulsion explosives in all pressure conditions. B) The decrease of DV in the sample explosives sensitized by GMB s was larger than that of DV in the sample explosives sensitized by RMBs or chemical gas bubbles. C) The recovery of the detonability occurred rapidly in the sample explosives sensitized by RMBs and chemical gas bubbles. However, a long period was needed for the recovery of detonability in the sample explosives sensitized by GME! s. It was concluded that the type of microballoon and micro bubble significantly influenced the detonability of precompressed emulsion explosives.

Jan 1, 2002

By Alex C. Smith, Michael J. Sapko

A series of explosive detonation experiments was conducted in NIOSH’s Bruceton and Lake Lynn Experimental Mines to evaluate low level (<6 psig) detonation wave propagation behavior in single and multiple entry configurations. Entry cross-sectional area varied from 5 to140 m2 and explosive weights of Pentolite ranged from 0.24 to 2.4 kg. Behavior of the detonation wave was evaluated through recording of the pressure as a function of time and distance from the explosive detonation in single and multiple entry interconnecting tunnels. Peak pressure from detonation of an explosive in an underground mine maintains magnitude for a greater distance than is the case on the surface and is shown to follow the simple scaling rela-tionship P = 702.8(W/Vt)0.514(0.65)n, where P is the peak detonation pressure in kPa, W is the weight of the explosive charge in kg, Vt is the total volume in m3, and n is the number of splits, n = 0, 1, 2, …n. The total energy, or impulse, I, generated by these detonations can be expressed as I = 1.34(W/A)0.64n, where W is the weight of the explosive charge in kg, A is the area of the main tunnel in m2, and n is the number of side en-tries, n = 0, 1, 2, …n.

By Christopher Smith

The critical nature of detonator function in blast design and its effects upon performance and safety of a blasting operation are well documented. Numerous laboratory and field studies have shown dynamic shock waves, generated by the detonating explosives in a shot, to be detrimental to the performance of the explosive columns in the adjacent boreholes. Laboratory tests conducted in Japan have explored the possible effects of dynamic precompression upon cartridges of emulsion explosives, which had been sensitized with different hotspot void producing methods. These tests uncovered significant differences in the magnitude of the dynamic shock wave pressures measured inside the different emulsion explosive cartridges, and demonstrated these pressure differences by crushing detonator shells inserted inside the emulsion cartridge. Basically, the results of these tests clearly showed the magnitude of the compressive force applied to the detonator inside the primed explosive cartridge to be a function of the mechanism that had been used to sensitize the emulsion (i.e., glass microspheres, plastic spheres, chemical gassing). The current study was designed to further explore the actual detonator failure mechanism in these dynamic precompression tests using live detonators inside the emulsion cartridge as opposed to empty detonator shells. The testing involved inserting commercial delay detonators inside emulsion charges, which had been sensitized with common hotspot void producing agents, and subjecting the primed explosive cartridge to the dynamic pressure wave generated by an underwater donor explosive charge. The effects of variations in the emulsion’s sensitization method upon the damage inflicted to the detonator were studied. Depending upon the degree of detonator damage, detonator crushing can lead to varying degrees of detonator malfunctions, ranging from sympathetic initiation of the detonator, to a reduction in delay time accuracy, to reduced detonator output, to complete detonator failure. Each of these malfunctions can have serious detrimental effects upon the performance and safety of a blasting operation.

Jan 1, 2006

By James G. Stuart, Tassilo N. Baur

We will discuss the kind of procedure that we use to predict the no-fire (for safety) and all-fire (for reliability) current levels for any given type electric detonator. The basic idea is to expose several detonators to different levels of electric current, so we can estimate the probability of firing as a function of current. We call this a statistical firing test. But what about the uncertainty in measuring the current? Suppose we are not quite sure what stimulus level we apply? This is the question that we will consider here. This relates to both safety and reliability. Surprisingly enough, we will find that some uncertainty in measuring the levels during our statistical firing test improves our long-term safety and reliability

Jan 1, 2019

By R. Aubertin, G. Panneton, P. Donovan

The Detour Lake gold project is located in northeastern Ontario, approximately 300 km northeast of Timmins, within the Abitibi greenstone belt in the northwestern portion of the Archean Superior Province. Historically this greenstone belt has produced approximately 180 million ounces of gold, largely from narrow vein underground mining. The Detour Lake project is a site of extensive past exploration since 1974, as well as underground and limited open pit mining activity from 1983 to 1999. During this period, it produced 1.8 million ounces of gold. Underground mining focused on narrow vein conventional shrinkage and mechanized longhole stoping. After acquiring the property in January 2007, Detour Gold Corporation initiated a comprehensive drill campaign to define the potential for a large, open pitable, low-grade gold deposit. From 2007 to present, Detour Gold has completed over 500,000 metres of diamond drilling. A technical report completed in March 2011 defined an open pit mineral reserve of 14.9 million ounces of gold, which is Canada&apos;s largest undeveloped gold reserve. The Detour Lake project is currently in development and infrastructure construction of the mine facilities started at year-end 2010, after all the necessary Provincial regulatory permits were received. Gold production is expected to commence in early 2013. Gold mineralization at Detour Lake is associated with a large scale deformation zone (Sunday Lake Deformation Zone; "SLDZ") that occurs at the contact between the 2.72 Ga Deloro Group mafic metavolcanics and the 2.69 Ga Porcupine Assemblage metasedimentary and metavolcanic rocks. The bulk of the gold mineralization is found in the hanging wall of the SLDZ, which is associated with a stockwork of auriferous quartz veins that splay from a flexure along the deformation corridor. The mineralization forms a 200-350 metres wide auriferous corridor defined over 3 kilometres along the strike of the mafic metavolcanic assemblage, from surface to at least 1,000 metres depth. The richest gold mineralized zones are commonly associated with quartz veins with a strong biotite alteration and local zones of pyrrhotite-chalcopyrite-pyrite-gold enrichment formed during the deformation of the quartz vein system.

Jan 1, 2011

By E N. Sajin

The final arsenic bearing waste products at the majority of metallurgical and chemical enterprises are cakes in which arsenic is present in the form of calcium arsenate. Burial of cakes demands construction of special burial sites and does not guarantee reliable protection from arsenic penetration into the ground and surface waters. Under laboratory conditions we developed technology for processing calcium arsenate cakes with obtaining low toxic products suitable for long-term storage, meeting environmental requirements. The investigations have shown that thermal processing of briquetted mixtures of cakes containing 15 - 20 per cent weight of pyrite under the temperature of 873 - 923¦K during 45 - 60 minutes gives briquettes sufficiently hard for transportation and long-term storage. Arsenic, under high sulphidisation temperature is bonded into low solubility non-volatile iron sulphide bearing compounds having chemical properties similar to the natural arsenic compounds. Solubility of the obtained products in neutral, acid and alkaline media was investigated during long period of time (three to 12 months). It was determined that arsenic content in the solutions did not exceed the norms for cultural and welfare basins and fish-ponds.

Jan 1, 2002

By Wenjie Zhu

Chromite ore processing residue (COPR) is a hazardous waste containing high concentration of chromium. We describe here a pioneer trial of detoxification of COPR in column reactor with an indigenous chromate reducing bacterium Leucobacter sp. Ch1, which showed high chromate reducing ability at high pH. Under the optimum conditions, at 30°C and pH 10.0, pH of leachate decreased from 10.3 to 8.3, and Cr(VI) concentration in solution decreased to zero mg L-1, and 76.4% of Cr(VI) was removed from COPR samples. The leaching toxicity of detoxified residue was 1.1 mg L-1 that was lower than national standard of China.

Jan 1, 2008

By A. Griffiths

The? use of hydrogen peroxide to detoxify gold mill waste waters containing cyanide and other toxic substances is already an established technology. Recent advances have extended the range of application of hydrogen peroxide treatment to include the removal of complex iron cyanides, the simultaneous removal of cyanide and toxic metals down to very low levels and treatment of barren bleeds, CIP&apos; pulps and tailings pond discharges. Three treatment plants are described here. Each was installed at a gold mine in North America in 1987 and each illustrates a different application of hydrogen peroxide. The need for individual design of the detoxification plant to fit particular requirements is shown by the examples chosen.

Jan 1, 1988

By M. Quamrul Ahsan, Andrew Griffiths, Edward P. Jucevic

Heap leaching of precious metal ores using the cyanide process is extensively used in the Western U.S.A. for extracting gold. Consequently, the impact of cyanide in the spent heap is closely examined by environmental agencies and permitting authorities. Currently, many states require that all decomnissioned heaps be detoxified before abandonment. This paper describes a case study for detoxification of spent heaps at the ACH-Dayton Project using hydrogen peroxide. The chemistry of cyanide detoxification by hydrogen peroxide, together with simplicity of a detoxification operation, is discussed.

Jan 1, 1989