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By Madhu. P, Srinivas. K

Measurement of thermal properties like thermal conductivity, thermal resistivity, heat capacity and thermal diffusivity for materials, it plays a crucial role in a wide range of various civil and electrical engineering projects, and many field applications like building’s basement, power generation, underneath soil heating, wastes from nuclear as well as thermal plants, and buried cables. Thermal conductivity of soil depends upon various geotechnical parameters such as type of soil, moisture content, particle size distribution, density, and compaction characteristics. Earlier studies, the measurement of thermal conductivity of soil by incorporating the heat source methods. Thereby expensive and time taken to conduct in laboratory as well as field measurements. The thermal conductivity is determined by fabricated probe and used in this work. Fabricated probe was calibrated with glycerin. The thermal conductivity of the soil increases as the water content and density increase because these factors are majorly influencing and water has a higher thermal conductivity than soil minerals, and grain to grain contact increases as density increases. therefore, Thermal conductivity is higher in coarser soils than in finer soils. The details regarding of this work as explained in this paper.

Sep 1, 2022

By Ümit Yasar Onder, Tevfik Prof. Dr. Güyagüler

This paper describes the results of an investigation done to determine thermal properties and heat emission of coal measure rocks in Karadon district of Zonguldak Coal Colliery. In Karadon District, depth of working level is about -600 m where the heat problem arises. In the near future, workings will be at deeper levels and working conditions will be more difficult due to high heat emission. At the beginning of the paper the importance of wall rock heat emission in underground mine have been explained and then the amount of heat emission to the ventilating air has been calculated. It has been found out that the strata is the main source of heat in the mine. Therefore, geothermal gradient of the region has also been determined simply by measuring the virgin rock temperatures in different levels of the mine. All other data directly related with heat emission from different sources has been collected and has been analyzed by using a special computer package. As a conclusion, total heat and moisture content in ventilating air and heat balance has been determined for Karadon Coal Mine. In addition, some recommendations and suggestions have been made for the future works when the mine workings go to the deeper levels.

Jan 1, 1995

A method for the detection and analysis of tin in cassiterite ores is discussed. An empirical relationship was established between the tin content of an ore sample and the percentage absorption that this sample produced in a Mossbauer experiment. The time taken to complete an assay with this method is much less than with any of the methods currently in use. The equipment can be adapted readily for use in the field.

Jan 1, 1969

A method is proposed for the analysis of tin in cassiterite ores. Tin is volatilised by heating with ammonium iodide. The tin iodide so formed is extracted with hydrochloric acid and the concentration is measured by atomic absorption spectroscopy using an air-hydrogen flame.It is considered that a more efficient extraction of tin and faster reproducible results are obtained than by any other known method.

Jan 1, 1967

By Niels Jonassen

INTRODUCTION The occurrence of the radioactive element radium, [2gg~a], often in trace amounts, in the crust of the earth gives rise to a flux of the daughter product radon, ['ii~n], across the earth-air interface. This so-called exhalation process has been studied by many investigators [KO 45, Kra 64, Pe 66, Wi 741] over several decades. In the earlier investigations the exhalation process was studied in a purely geophysical context, but over the last 20 years it has been realized, that under certain conditions the exhalation may be intense enough to also have radiological implications. This is for example the case where relatively radium-rich wastes or by-products, like uranium mill tailings and phospho-gypsum, are stored in larger quantities. In order to be able to predict the radiological impact on the environnent it is necessary to know the rate of exhalation of radon from the surface of the exhaling material. Usually the determination of these exhalation rates has been done by measurements in situ directly upon the accumulated material [~le 74, Ha 791. Although such field measurements have the obvious merit of dealing directly with the full scale problem, the results are often lacking in generality, making predictions for other situations difficult or even impossible. The present paper describes some results of an investigation where it is attempted from laboratory measurements on samples of limited size to obtain material parameters, which are suited for extrapolating and predicting the radiational behaviour of larger accumulations of the material. THEORY Let us consider a sample of a radon exhaling material enclosed in a container with a dead space volume, Vd, and initially containing radon free air. If the total exhalation rate (number of atoms per unit time) is c, the radon concentration (number of atoms per unit volume) N will initially grow with the time t according to the equation [ ] where [R] is the decay constant of radon. As the concentration (or activity) in the container grows, the net exhalation rate will slow down because of back diffusion, and, furthermore, radon atoms may be removed from the container, not only by radioactive decay, but also by diffusion leakage [JO 81 ]. If, however,only the initial. part of the activity growth curve is considered, the total exhalation rate, c, is given by [c = r•Vd(2) where r is the initial activity growth rate in the container. Let the container be cylindrical with an inner cross-section S and filled to a height L with a radon exhaling material with the specific mass p, the porosity E, the radon pore production rate f and the diffusion length i. When the container is left open,i.e. the radon exhalation takes place into a virtually radon free room, the radon area exhalation rate, E, can be written [Jo 80] E = Ef?t tanh L.R (3) assuming the exhalation only takes place in one direction, towards the surface of the material. It appears that for values of L > 2•ithe area exhalation rate becomes E a = Efi (4) independently of the sample dimensions and the total exhalation rate c is then c = E •S (5) For L ;~ 0.5•i, tanh P _ k and equation (3) may be written E ~ EfL (6) then c = EfL•S = p•m= Em •m (7) where m is the mass of the sample and Em = P (8) is the mass exhalation rate. It thus appears that the radon exhalation rate from a given amount of material may often be conveniently expressed by c = E •Sfor L z 2•I (5) a orc = Em •mfor L0.5•i (7) where S is the total exhaling area and m the total exhaling mass, E and E the area and mass exhalation rates respectively defined by equations (4) and (8).]

Jan 1, 1981

By Yousef Mohassab, Feng Chen, Hong Yong Sohn, Mohamed Elzohiery

The determination of reduction degree in a DR process is sensitive to the total iron in the ore and DRI. An accurate and high throughput analysis method for total iron has been developed. Titration of the solution after tin(II) chloride reduction of ferric ion is a widely used method for iron analysis. However, it is a multistep method that requires many chemical reagents and much time. In this work, an ICP-OES analysis method with higher or equivalent accuracy compared with the titrimetric method was developed. This method has much higher throughput and demands fewer chemical reagents compared with the titrimetric method. In this paper, a comparison of the two methods is presented.

Jan 1, 2016

By Hiroshi Ono

"By newly developed ICP method, trace amounts of As(III), As(V) .,Sb(III) and Sb(V) were precisely determined within accuracy of sub ng/ml. As(III) and Sb(III) were separated from As(V) and Sb(V) by extracting into ·xylene as diethyldithiocarbamate complexes using diethylammonium diethyldithiocarbamate (DDDC), and then back-extracted into nitric acid for a quantitative determiruition by ICP-AES equipped with hydridegeneration system The recoveries of As(III) and Sb(III) were satisfactory throughout the extraction with 0.04mol/l DDDC in xylene from lmol/l hydrochloric acid solution and the back-extraction with 7 mol/l nitric acid. As(V) and Sb(V) were reduced to As(III) and Sb(III) by ascorbic acid and potassium iodide, and their quantities were determined as mentioned above. The detection limits were found to be 0.58ng/ml for As(III), 0.63ng/ml for Sb(III) using 50ml of a sample. The proposed method was applied to analysis of the real sample.Introduction In drain, arsenic(AS) concentration is prescribed below 0.lmg/l, so As must be removed. As is existed at .the form of As(III) or As(V) in solution. For t1Jeir difference of chemic;µ property, it is not easy to remove As in solution. So it is an urgent necessity to develop for determining concentration of As(III) and As(V). Antimony( Sb) has resemblance .chemical property to As. So Sb was experimented the same as As.The separation and determination of As(III) and As(V) have been carried out using several methods, such as ICP after copreclpitating separation, HPLC, direct hydride generation atomic absorption. However these methods have some problems. One of main problems is that HPLC and direct hydride generation atomic absorption methods are influenced by coexisting elements."

Jan 1, 2000

This method determines tellurium at concentrations down to 0·01 p.p.m., with geochemical accuracy. Tellurium is volatilized from the rock at 800°C in the presence of sulphur from decomposing pyrite, condensed, dissolved, and finally determined by atomic absorption in a long tube burner. The distribution of Te is shown near some gold lodes at Kalgoorlie. Lastly, a method of synthesizing Te-free pyrite from sulphur and ferrous sulphate is described.

Jan 1, 1969

By R. J. Sweigard, G. T. Lineberry, B. K. Slone, F. A. James III, D. S. Maggard

The depth at which it becomes more economical to use slope access instead of box-cut access for nearsurface coal reserves is termed the "transition depth." The transition depth can be established for a given coal property by considering cost estimates for those parameters that determine respective access methods. Fourteen parameters that influence access cost were identified, and ranges for these parameters were determined. A transitiondepth formula was developed to permit the determination of which is the better method of accessing a reserve, given information such as high wall slope, road width, total bench width, pit dimensions, road grade, belt component costs, pumping costs and the cost of overburden removal and reclamation. In most cases in Appalachia, especially in eastern Kentucky, the observed transition depth ranges from 20 to 30 m (66 to l00 ft). This indicates that actual practice is consistent with the analytical approach used.

Jan 1, 2002

By B. K. Slone

The depth at which it becomes more economical to use slope access as opposed to box-cut access for near-surface coal reserves, termed "transition depth," can be established for a given coal property by considering cost estimates for those parameters that determine respective access method. Fourteen parameters that influence access cost were identified and ranges determined. A Transition Depth Formula was developed to permit determination of the better method of accessing a reserve, given such information as highwall slope, road width, total bench width, pit dimensions, road grade, belt component costs, pumping costs, and cost of overburden removal and reclamation. In most cases, in Appalachia, studies indicate that the transition depth ranges between 20 and 30 m.

Jan 1, 1998

By Donald R. Williamson

Statistical studies at Cyprus Pima Mine indicate that samples from 22 blastholes are necessary for determining average copper grades, within a desired range of precision, for mine-model blocks by arithmetic averaging. The average number of holes in such blocks is 14. Many considerations show that more holes will not be drilled for sampling. A way to determine block grades more reliably than by" arithmetic averaging was sought. Thus far arithmetic averaging has proven to be the best procedure for the particular operation characteristics despite the small number of samples. It naturally follows that expenditure of great effort in sampling blasthole cuttings is unwise.

Jan 1, 1977

By A. Shakoor, A. M. Hirt

The compressive strength of coal, and its variation within and between seams, was determined for four Pennsylvania coal seams (Pittsburgh, Sewickley, Upper Kittanning and Lower Kittanning). Large coal blocks were obtained from 12 coal mines (three mines per seam) and cut into 50-mm (2-in.) cubes using a low-speed saw. The cubes were tested for compressive strength, with the results used to compute actual pillar strength. Using the tributary area approach, the pillar stress was determined. The pillar stress and strength data were used to calculate the factor of safety against pillar crushing for each mine. The cube strength was also correlated with various physical and chemical coal properties (density, percent absorption, percent ash, percent sulfur and percent carbon) to see if any strong relationships exist. The coal's mean compressive strength varies from 9.1 MPa (1326 psi) in the Lower Kittanning seam to 37.8 MPa (5480 psi) in the Pittsburgh seam. Between different seams the pillar strength varies from 29.5 MPa to 48.1 MPa (4282 psi - 6981 psi). Although coal strength appears to be weakly related to carbon content, no relationship was found between compressive strength and other physical or chemical properties. Since the values for the safety factor against pillar crushing generally exceed the recommended value of two, the existing pillars are mostly overdesigned. This implies that an accurate assessment of coal compressive strength could result in the use of smaller pillars and, thus, increased coal production.

Jan 1, 1993

By Toshihisa Adachi, Shosei Serata, Shunsuke Sakurai

Many different methods of measuring the in-situ stress field have been developed in recent years. They are all based on the assumption of elasticity without allowing any viscoelastic deformation. By using the high resolution strain-measuring technique recently developed in the laboratory at Serata Geomechanics, many rocks were found to be viscoelastic. The viscoelasticity of rock media was found to be dependent upon the resolution of the strain measurement. The higher the resolution of the strain measurement, the greater number of rocks could be identified as viscoelastic. All rocks eventually exhibit viscoelastic deformation under high stresses relative to the strength of the material. Therefore, the conventional methods of elasticity become less reliable with increase of ground stress. In deep underground formations, even hard rocks become viscoelastic. At the same time, many ground formations near the surface are actually viscoelastic. A new method was developed in the laboratory to determine the in-situ stress field in viscoelastic rock media. Rocks in general exhibit a small amount of viscoelastic creep whenever mean stress and octahedral shearing stress are changed substantially from their initial states. Such changes take place around a borehole immediately following the drilling although they are short-lived. We developed a viscoelastic method of determining the in-situ stress field by relating the time-dependent behavior of the borehole with the tensor properties and stress field of the underground. In developing the viscoelastic relation, only isotropic and homogeneous

Jan 1, 1970

By F. E. Senftle

Introduction The usual laboratory methods of uranium analysis are either tedious, time-consuming chemical procedures or elaborate physical methods requiring sensitive equipment. There is thus an urgent need for a method of estimating the uranium content of ore samples by approximate analysis in the field. When a new property is being developed, it is desirable to know, with the least possible delay, the uranium content of channel samples in order to guide the diamond drilling and digging operations. Prospectors, too, require approximate analyses of their hand specimens to evaluate their discoveries. To satisfy the demand for these types of analyses, several field procedures have been tried. Two general plans can be followed. One is fast but will yield only a rough estimate. The other is slightly longer but, if done carefully, will give an assay probably within 10 per cent of the true value. For field operation it is necessary to strip the more accurate laboratory methods of analysis of all refinements because of the limited equipment and skilled techniques at hand. Most of the corrections normally applied, with the exception of that for equilibrium, will not alter the gross analysis to any appreciable extent. When uranium atoms in pitchblende disintegrate, they break down into other radioactive elements, and eventually the number of elements being formed is equal to the number breaking down. The ore is then said to be in equilibrium. Certain geological processes, however, such as leaching, may selectively remove some of these elements and hence reduce the radioactivity of the ore sample. The ore is then said to be out of equilibrium. The field analysis may then be in error by as much as 50 per cent since the apparatus is calibrated with standards that are in equilibrium. However, such a large error due to loss of equilibrium is the exception, and in most cases uncorrected field types of analyr.is are justified.

Jan 1, 1949

By M. Rahmanpour

"Mine planning is a multidisciplinary procedure that aims to guarantee the profitability of a mining operation in changing and uncertain conditions. Mine plans are normally classified as long-term, intermediate-term, and short-term plans, and many factors affect the preciseness of these plans and cause deviations in reaching the objectives. Commodity price is the heart of mine planning, but it has a changing and uncertain nature. Therefore, the determination of mine plans in the presence of uncertain mineral price is a challenge. A robust mine plan reduces the risk of early mine closure. A procedure is presented to determine the value at risk (VaR) in any possible mine planning alternative. VaR is considered together with downside risk and upside potential in order to select the most profitable and least risky plan. The model is tested on a small iron ore deposit. IntroductionMining projects are normally evaluated with the objective of maximizing economic value, as measured by the net present value (NPV). The aim of mine planning is to develop a yearly extraction plan that guides the mining operation to the highest NPV (Dagdelen, 2007; Yarmuch and Ortiz, 2011). This plan considers the technical constraints such as blending requirements, block sequencing, and pit slope (Caccetta and Hill 2003). Thus, the mine plan affects the economics and the payback period of mining operations.Mine planning is a procedure based on which the profitability of the mining operation is guaranteed in changing and uncertain conditions (McCarter, 1992). However, conventional mine planning ignores the volatility and uncertainty of future commodity prices and does not allow for managerial flexibility. It is common practice to assume a deterministic and constant commodity price through the mine life. The problem with this approach is that the commodity price is the heart of the mine planning procedure and governs the profitability and feasibility of the operation; thus ignoring price volatility will result in a sub-optimal mine plan."

Jan 1, 2016

By B. A. Slaker

The ability to detect and quantify ground movements in underground mine workings is of the utmost importance to the safety of miners and continuity of operations. Rib sloughage is one of the most common forms of underground deformation. Remote sensing techniques, such as laser scanning, can be used to quantify this rib sloughage, by recording precise, timelapse point clouds of mine workings. In order to determine sloughage volumes and locations, two sets of laser scans were performed 42 days apart at a working section of an underground limestone mine. During this period, significant sloughing and scaling occurred, allowing for differentiation between the initial and final point clouds. Volumetric changes of 2.3-2.6 m3 were detected on rib faces during the time-lapse study. In addition, displacement in the mine roof was, as expected, not detected, suggesting well surveyed scans and an appropriate scan resolution.

Nov 1, 2013

By B. Slaker

The ability to detect and quantify ground movements in underground mine workings is of the utmost importance to the safety of miners and continuity of operations. Rib sloughage is one of the most common forms of underground deformations. Remote sensing techniques, such as laser scanning, can be used to quantify this rib sloughage, by recording precise, time-lapse point clouds of mine workings. In order to determine sloughage volumes and locations, a total of 11 laser scans were performed 41 days apart at a working section of an underground limestone mine. During this period, significant sloughing and scaling occurred, allowing for differentiation between the initial and final point clouds.

Feb 27, 2013

By Jorge Lucas Carvalho Bechir

A usina de beneficiamento da Unidade Vazante da Votorantim Metais concentra zinco a partir de Willemita – Zn2SiO4 por flotação. Através desse processo, é possível obter elevadas recuperações metalúrgicas. Contudo, foi identificado que é possível aumentar ainda mais a recuperação de zinco através de redução de granulometria. Essa redução eleva os custos de energia de um circuito de cominuição, fato que torna fundamental a identificação da relação ideal entre ganho de recuperação e os gastos com maior consumo de energia. Grande parte das frações de Willemita mais grosseiras (acima de 0,15 mm) que passam pelo processo de flotação, vão para o rejeito. Isso ocorre devido a granulometria atual de moagem não atingir a liberação ideal do mineral de interesse, de forma que, grande parte da superfície das partículas ainda apresenta ganga que não é adsorvida pelo coletor especifico da Willemita. Em busca de elevar a recuperação metálica de zinco potencializando o seu aproveitamento, estudos de caracterização mineralógica foram realizados. O trabalho consistiu na utilização de MEV/EDS com MLA (Mineral Liberation Analyzer) e na realização de testes de flotação em escala de bancada e piloto para determinar a granulometria ideal para flotação do mineral Willemita. Através dos resultados obtidos, foi possível concluir que houve ganhos de recuperação de zinco com a redução da granulometria sem comprometer a qualidade do concentrado gerado.

Aug 17, 2017

By Cynara Christ Klippel

Devido às exigências de teores de fosforo cada vez menores no aço, o processo de desfosforação tem ganhado destaque nas indústrias. Para aproveitamento das melhores condições termodinâmicas a etapa mais eficiente para o processo de desfosforação ocorre no ferro-gusa. Esse trabalho utilizou quatro misturas iniciais de composição definida com base na literatura, juntamente com o ferro-gusa para ser simulado o processo de desfosforação. A simulação foi feita através do software de cálculos termodinâmicos FactSage e através dos resultados obtidos do programa foram feitos cálculos para avalição da eficiência do processo. Além disso, também foram feitos cálculos baseados na literatura para comparação de resultados e estudo mais aprofundado dos resultados. Os resultados obtidos comprovaram a teoria inicial de que menores temperaturas favorecem o processo.

Aug 17, 2017

By Rodrigo de Oliveira Pezzin

Devido ao fato que a exigência por menores teores de enxofre em alguns tipos de aços, torna-se interessante investigar a eficiência na dessulfuração dos materiais já conhecidos com matérias primas alternativas. Duas dessas novas matérias primas que podem ser utilizadas no processo de dessulfuração são o resíduo de mármore e a sodalita. Desta forma, o presente trabalho tem como objetivo avaliar a eficiência de dessulfuração em ferro-gusa por misturas contendo resíduo de mármore, sodalita e agentes dessulfurantes convencionalmente utilizados. Os testes foram realizados a 1400°C, em uma atmosfera inerte (Ar) com agitação constante. Os testes experimentais mostraram que 50 a 90% da dessulfuração ocorreu em até 15 minutos. As misturas contendo fluorita foram os que apresentaram maior eficiência de dessulfuração. A adição de sodalita ocasionou uma queda na eficiência de dessulfuração.

Aug 17, 2017