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By Segnit ER, Jensen G

The decoppering of soft and hard leads was investigated by stirring in an open pot, using sulfur or sulfur plus pyrites, or sulfur plus pyrrhotite, as reagents. Lead samples taken during the process were analysed for copper. Dross samples were examined by optical micro- scope, SEM and XRD. Soft lead containing silver can be decoppered satisfactorily by stirring with 0.1% S at low temperatures - close to 330¦C. Soft lead, whether containing silver or not, can be decoppered satisfactorily at higher temperatures by stirring with 0.1% S plus 0.4% pyrites. Then CuFeS2, Cu5FeS4 and PbS are formed, instead of Cu2S, CuS and PbS when using S alone. Hard lead containing tin can be decoppered satisfactorily by stirring with 0.1% S at temperatures from 320-400¦C. When stirring with 0.1% S plus 0.4% pyrites, reversion of copper from dross to lead on prolonged stirring does not occur. Hard lead without tin can be decoppered with S plus pyrites better than with S alone, but the presence of antimony hinders the decoppering, which is less effective on lead with 5.5% Sb than with 2.3% Sb.

Jan 1, 1980

By Jochen Petersen, Jean-Paul Franzidis, Allan Nesbitt

This study presents a method for the determination of intra-particle diffusivities in ion-exchange resins for the purposes of evaluating the state of resin degradation during service. The method uses a zero length column (ZLC) in a closed circuit with variable speed pump and reservoir. The intra-particle diffusion is determined from absorption data by using the Nernst-Plank approximation along with the ‘mass transfer factor’ - which is a product of the mass transfer coefficient (kf )and the concentration of the adsorbing ion in the liquid at the surface of the resin - in a computer algorithm fitting simulated curves to experimental data.. Through this approach the changed intra-particle diffusivity, of a gel-type acid resin, over a 1000 loading and elution cycles, is shown.

Jan 1, 2014

By B. McFadzean, M. Tadie, T. Dzingai, M. Becker

Ores from a single deposit may exhibit extensive variability in their mineralogy and texture. The ability to quantify this variability and link it to mineral processing performance is one of the primary goals of process mineralogy. This study focuses on the effect of alteration in three platinum group element ore samples from the Great Dyke in Zimbabwe – two of which were more pristine compared to the third, which was locally classified as ‘oxidized’ ore. These ores are known to be characterized by varying degrees of alteration, resulting in numerous challenges in flotation and affecting both grade and recovery. Alteration, by near-surface oxidation, of the valuable base metal sulphides and platinum group minerals resulted in lower flotation recoveries of Cu, Ni, Pt, and Pd. Evidence of incipient oxidation was more readily observed in the base metal sulphide assemblage than the platinum group mineral assemblage, even though the loss in recovery (because of oxidation) was most significant for Pd. Alteration through hydration resulted in a significant increase in mass pull and dilution of concentrate grade through the inadvertent recovery of naturally floating gangue comprising composite orthopyroxene and talc particles. In this study, the amount of naturally floating gangue was more strongly correlated with the talc grain size distribution than the grade of talc in the flotation feed. The oxidation and hydration alteration reactions are not necessarily mutually exclusive, although one may be more dominant than the other, giving rise to ore variability.

Sep 1, 2021

By P. Harris

"Comparison of the two most commonly used classes of depressant in the South African platinum industry is complicated by the fact that these polymers induce different effects on the surfaces onto which they adsorb. The use of carboxymethyl cellulose (CMC), which is ionically charged in solution, can lead to increased particle dispersion in addition to the effect of reduced surface hydrophobicity (depression). Guar is typically only slightly charged in solution. Comparison of these two depressants is complicated since it is uncertain whether differences in their action is a result of either depression of dispersion effects.This work investigates the role of dispersion independently to that of depression in the batch flotation of a platinum bearing ore. An inorganic dispersant, sodium hexametaphosphate (NaHMP) was added in parallel to the uncharged guar depressant to simulate the action of depressants with varying degrees of dispersion. By distinguishing between the material recovered by entrainment and the floatable gangue and by including the effects of froth stability it was possible to decouple the effects of dispersion and depression.The results show that both dispersion and depression led to increased grade of the sulphide minerals. Depression leads to a decreased recovery of floatable gangue minerals. Dispersion leads to an increased recovery rate of these minerals and an accompanying decrease in froth stability."

Jan 1, 2003

By P. Harris, D Bradshaw

"Comparison of the two most commonly used classes of depressant in the South African platinum industry is complicated by the fact that these polymers induce different effects on the surfaces onto which they adsorb. The use of carboxymethyl cellulose (CMC), which is ionically charged in solution, can lead to increased particle dispersion in addition to the effect of reduced surface hydrophobicity (depression). Guar is typically only slightly charged in solution. Comparison of these two depressants is complicated since it is uncertain whether differences in their action is a result of either depression of dispersion effects.This work investigates the role of dispersion independently to that of depression in the batch flotation of a platinum bearing ore. An inorganic dispersant, sodium hexametaphosphate (NaHMP) was added in parallel to the uncharged guar depressant to simulate the action of depressants with varying degrees of dispersion. By distinguishing between the material recovered by entrainment and the floatable gangue and by including the effects of froth stability it was possible to decouple the effects of dispersion and depression.The results show that both dispersion and depression led to increased grade of the sulphide minerals. Depression leads to a decreased recovery of floatable gangue minerals. Dispersion leads to an increased recovery rate of these minerals and an accompanying decrease in froth stability."

Jan 1, 2003

By B McFadzean, N P. Lima, D A. Deglon

The reverse flotation of Itabirite iron ore is typically performed after a desliming step in which most of the sub-10 µm particles are removed. This is done to limit processing problems such as poor flotation recovery of SiO2 due to slime coatings and increased slurry viscosities, unmanageable froths and increased losses of hematite particles due to entrainment. However, the rejection of ultrafine particles contributes to large losses in iron recovery and may contribute to the instability of tailings dams. The aim of this study is to decouple the effects of ultrafine particles in the pulp and froth phases to better understand the processing capabilities of the fines fraction. The flotation test work was performed in a special-purpose continuously operated laboratory flotation cell that has a deep froth section to simulate plant-scale froth conditions. Five conditions of fines addition were investigated at three different froth heights and a solids concentration of 50 per cent. The behaviour of the pulp and the froth were decoupled using froth stability and froth recovery tests. This showed that, even though there is an exponential increase in froth stability at increasing fines quantities, the performance of the pulp has the overriding effect on the overall SiO2 recovery. Pulp zone, froth zone and overall SiO2 recoveries showed that overall recoveries increased by about 3.6 per cent for every 1 per cent decrease in fines content. This meant a large increase of 20 per cent in SiO2 recovery when going from undeslimed to deslimed feed. This was driven largely by increases in the pulp zone recoveries, which were about 4 per cent for every 1 per cent decrease in fines content. The froth recoveries, on the other hand, decreased by between 0.75 per cent and 2.5 per cent for every 1 per cent decrease in fines content, depending on froth height. This paper explores further insights into iron ore flotation processing at different slimes concentrations.

Aug 24, 2022

Growing concerns of climate change and its potential association with the release of greenhouse gasses to the atmosphere have prompted possible legislation which would require minimization of greenhouse gas emissions. Carbon dioxide and methane, both of which largely contribute to the greenhouse effect, have direct links to the fossil energy industry sector. Specifically, the combustion of one ton of coal produces between one and three tons of carbon dioxide, dependent upon the carbon content and heating value of the combusted coal. Additionally, coal mine methane (CMM) released through a mine?s ventilation system has a radiative trapping impact approximately 20 times greater than that of an equivalent mass of carbon dioxide. The capture of coalbed methane (CBM) prior to the mining process and its utilization as an alternative energy source provides the possibility of a decreased carbon footprint. Domestically, the past 25 years have seen a significant expansion of the CBM industry. Internationally, in developing countries such as China, the need for western coal degasification technology is growing. A collaborative, international effort will be required to initiate a recognizable decrease in global greenhouse gas emissions. This paper identifies the potential decrease in equivalent carbon dioxide emissions through effective degasification at a hypothetical longwall mine located in China. Advanced, three-dimensional gas reservoir simulation software will be utilized to determine the maximum feasible CBM recovery in a low permeability, high gas content reservoir prior to the mining process.

Jan 1, 2010

By Hassan El-Shall, El-Sayed A. Abdel Aal

The major goal of this study is to decrease iron content in wet-process phosphoric acid. Reducing the amount of post-precipitated sludge in the acid is another important objective in this investigation. In order to achieve these goals, research efforts have focused on bench scale testing of an iron-chelating reagent to remove iron from phosphoric acid produced from South Florida high-iron and -magnesium phosphate concentrate, and plant testing using freshly produced concentrated acids for reducing the post- precipitated sludge. The data obtained in the above studies suggest that the addition point of the precipitating reagent is very important, as the precipitated iron compound has higher solubility at higher P2O5 concentrations. Up to 60% Fe2O3 removal efficiency is achieved depending on the amount of the reagent, concentration of acid used, and operating conditions. The addition of precipitating reagents to freshly concentrated phosphoric acid leads to a decrease of up to 84% in sludge volume percentage depending on acid type and clarification conditions. Decreasing the volume percentage of the sludge facilitates acid handling as well as decreases the adherent water- soluble P205 leading to lower total P2O losses.

Jan 1, 2002

By A Nisbett

The largest single operating loss in many hydrometallurgical plants is the poor recovery of leached product in the solids sent to tailings. Any reduction in the concentration of the valuable species in this stream will improve the project economics. Conventional design, to reduce the soluble loss, is to increase the number of wash stages or the wash/water ratio. This approach is limited in effectiveness as it can only reduce the soluble loss to that dictated by the concentration in the returning solution. For copper plants this concentration is set by the recovery in the solvent extraction (SX) plant. When using a single grade of SX feed a single grade of SX raffinate is produced generally with five to seven per cent of the copper still remaining in solution. An alternative approach has been developed by Cognis Corporation and implemented on a number of recent projects using engineering input from Miller Metallurgical Services. The SX plant feed is æsplitÆ into two different streams: a high-grade stream containing up to 75 per cent of the copper and a low-grade stream with the remaining copper. This Split-CircuitÖ concept has significant benefits in terms of both copper recovery and reduction in acid costs. The high-grade stream has the bulk of the copper removed and the raffinate sent directly back to the leach; to fully re-use the acid that has been generated during extraction in the SX process. The recycling of this higher concentrated acid stream considerably reduces the acid in the raffinate sent to washing steps. It represents a significant saving in acid consumed via the tails stream. The low-grade stream has a significantly lower SX feed grade and hence produces a lower raffinate acid and copper concentration. This lowers the economic species in the wash solution and hence reduces the soluble loss accordingly. Other operating improvements are realised with lower neutralisation costs (with the lower acid in the wash stream) and from a decreased need for in-circuit neutralisation to improve SX performance. The SX plant itself is also split into a high-grade extraction and a low-grade extraction stream to enable the low-grade raffinate to be produced. A number of circuit alternatives have been utilised that have provided a range of benefits. The circuit concept has been included into both new and existing plant operation. As a result of this experience other methods of incorporating the concept into a circuit have been developed.

Jan 1, 2005

By S. C. Libby

The amount of fine material (minus 60 Tyler mesh) generated during calcination and/or handling of calcined abrasive grade bauxite from Alcoa's operations at Moengo, Suriname, has recently increased relative to past production experience. Bulk samples of raw abrasive grade bauxite from three deposits in the Moengo area have been studied in order to determine the factors controlling the generation of fine material samples from the Jones IC and Tapira deposits, which generate excessive amounts of fine material, have been compared with reference samples from the Begi Gado deposit, which does not generate excessive fine material. Additional type samples of abrasive grade and marginal abrasive grade bauxite from deposits in the Moengo area which represent different bauxite textures found in the Jones IC, Jones I, and Begi Gado deposits have also been studied. Field observations in the Moengo area have indicated that abrasive grade bauxites with a dull, earthy appearance generally do not generate excessive fines. On the other hand, excessive fines are generally associated with coarsely crystalline bauxite in which the gibbsite crystals appear to sparkle in sunlight.

Jan 1, 1980

By S. C. Libby

Physical degradation of calcined bauxite is related to the presence of goethite in the raw bauxite and to the development of secondary gibbsite. Goethite in the bauxite matrix will shrink and decrepitate during calcining, leaving a friable matrix and allowing disaggregation of the calcined bauxite during transport and handling. A matrix consisting of cryptocrystalline gibbsite alone or mixed with hematite will not shrink during calcination, yielding a calcine with high abrasion resistance. The development of secondary gibbsite between coarse gibbsite crystals also reduces degradation of the calcine by reducing the amount of disruption between grains resulting from differential thermal expansion.

Jan 1, 1981

By S Hapugoda, M Kilburn, M Adam, L Lu

Lump ore is one of the key ferrous materials used in the blast furnace ironmaking process, typically accounting for 5–25 per cent of the blast furnace ferrous burden. Like other ferrous materials, the characteristics of lump ore have an important impact on stable operation and productivity of a blast furnace. As the cold burden lands on the top of the hot burden in the furnace and descends, it is inevitably subjected to thermal shock, which will likely lead to breakdown of the lump particles, or decrepitation and affect the gas permeability inside the blast furnace adversely. An ISO decrepitation test has therefore been developed to assess this behaviour of lump ore. However, the results obtained according to the existing standard decrepitation test method vary considerably between laboratories even for the same lump ore. To improve the test procedure of the existing decrepitation test, this paper first discusses the mechanisms leading to decrepitation and then studies the factors affecting lump ore decrepitation. Understanding the key factors affecting lump ore decrepitation is particularly important to improve the existing test procedure that enables researchers to achieve a higher degree of precision when conducting the decrepitation test.CITATION:Lu, L, Adam, M, Hapugoda, S and Kilburn. M, 2017. Decrepitation of lump iron ores, in Proceedings Iron Ore 2017, pp 91–96 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

Jan 1, 1902

Jan 1, 1908

The Bureau of Mines extends. a cordial invitation to all members of the Institute to visit Pittsburgh, Sept. 29 to Oct. 1, to participate in the dedication of the Mines Experiment Station. Accompanying this will be a nation-wide participation in a First-aid and Mine Rescue Contest. The Pittsburgh Chamber of Commerce will cooperate. The Institute will be represented by a special delegate appointed by the President. MONDAY 8:30. A. M. Bureau Building open for inspection. 10:30 A. M. Dedicatory Ceremonies in rear of Main Building, .4800 Forbes St. 2:00 P. M.. Special Train and Automobiles to Experimental Mine near Bruceton, Pa. 3 to 6 P. M. Mine Explosion and Inspection of Experimental Mine . and of Explosives Testing Plant near Bruceton, Pa. 6:00. P. M. Return by Special Train and Automobiles to B. & 0. Station, Pittsburgh. 8:00 P. M. Informal Reception and Organ Recital Carnegie Music Hall. Arranged by Carnegie Institute of Technology.

Jan 9, 1919

Many of those who attended the meeting at Chicago spent the first part of the following week in Pittsburgh, when the Experiment Station of the Bureau of Mines was dedicated and the fourth annual First Aid and Mine Rescue Contests were, held. The Bureau buildings were open for inspection during the three days, Monday, Tuesday, and Wednesday. The dedicatory ceremonies were held in the Bureau of Mines main building, Monday morning, Sept. 29, Mr. T. J. Gillespie, representing the Pittsburgh Chamber of Commerce, presiding. In his address of welcome, Hon. E. V. Babcock, Mayor of Pittsburgh, said: "The reclamation work already done stands out conspicuously beneficial to industry and populace alike all over the United States. It has demonstrated methods of preservation of life and reclaiming of injured persons which are new and greatly beneficial to modern civiliza-tion. The establishment of this institution in Pittsburgh was greatly desired, and now it is here it is greatly appreciated." The response was given by First-Assistant Secretary of the Interior Vogelsang, who represented Secretary Franklin K. Lane. He said that the Bureau of Mines did more during the war for the triumph of American arms than any other institution.

Jan 11, 1919

The new Ceramic Engineering Building of the University of Illinois is to be formally dedicated on Nov. 20 and 21. The occasion will be made one of great interest to the clay-workers of the country. It is expected that the exercises will be attended by many representatives of the architectural, structural, mining, geological, chemical, and manufacturing interests. In connection with the dedication exercises, an industrial conference will be -held, in which a number of topics of current interest to the ceramic engineer, the clay-worker and the manufacturer will be discussed by well-known experts. : The number of students registered in the College of Engineering of the University of Illinois eleven days after the beginning of registration - for the new year, is as follows: Architecture, 116; Architectural Engineering, 167; Ceramic Engineering, 46; Civil Engineering, 190; Electrical Engineering, 266; Mechanical Engineering, 273; Mining Engineering, 25; Municipal and Sanitary Engineering, 26; Railway Engineering, 34; total, 1,143. The enrollment of students in the whole University, not including the College of Medicine, the College of Dentistry and the School of Pharmacy, which are located in Chicago, is 5,21.4.

Jan 10, 1916

Jan 1, 1892

By R. D. Brown

In view of the many changes which have taken place since 1950 in the rules of the Income Tax Act concerning the deduction of exploration and development expenses, many corporate taxpayers each year face the tedious task of determining which particular rules their unclaimed exploration and development expenses are subject to and in what sequence these expenses are to be claimed. Recent amendments to the Act have cleared up some of the mystery of the "ordering" of these deductions. This article examines the sequence in which various categories of exploration and development expenses are to be deducted in accordance with the terms of the Act as amended by Bill C-11.

Jan 1, 1978

By Thomas L. Garwood, F. C. Menk

IT is generally, accepted that no method of coal cleaning except froth flotation is effective in cleaning dust. In the majority of coals mined in the United States the dust sizes contain a high percentage of impurities, hence the removal of the dust from the coarse sizes lowers the impurity content of these sizes. Dedusted coal is desired as a means of providing a better feed to cleaning plants because of increased efficiency in both dry and wet plants. In dry-cleaning plants, a dedusted feed makes for a pervious and uniform bed. With a dusty feed the fines tend to segr6gate in the feed stream and pass en masse over the air separators, causing a lack of uniform aeration and fluidity of the bed necessary to efficient cleaning. In wet-cleaning plants dedusting of the feed often decreases the sludge problem to the point of eliminating the necessity of wasting wash water. It may be advantageous to eliminate sludge-settling equipment in favor of dedusting equipment, to provide the advantages of a dedusted feed to the wet-washing process. Dedusting advantages may include: (1) the removal of fusain, especially advantageous in plants washing coal intended for metallurgical coke; (2) prevention of the gradual build-up of solids in the wash water, with a consequent variation in the washing ability of the system; (3) prevention of the loss of dust to the sludge ponds, providing instead a fuel for local consumption or special markets. DEDUSTING The practice of dedusting, sometimes called aspirating, has presented a problem in disposing of the dust and intermediate small sizes recovered in the process. It has been found that no difficulty is experienced in disposing of the intermediate sizes, since they are free of fine dust and burn freely on grates built for small coal. They handle well, flowing freely from bins and hoppers and into conveyors, and pulverize easily. They have a low angle of repose. In tests made on this size as a feed to coke ovens, the results have been excellent, in that the natural breakdown of .coal in handling and shooting in the mine gives this small-size coal good

Jan 1, 1943