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By P .. F. Ziemkiewicz, T. E. Rymer, J. J. Renton

Prediction and quantification of acid mine drainage (AMD) from a given rock unit is in its infancy. Acid Base Accounting is the current procedure. II is a useful screening procedure and is designed to indicate whether a rock unit will or will not produce acid. In this sense, Acid Base Accounting is qualiwtivc. Researchers at West Virginia University arc developing a prediction method to estimate how much acid will be produced over the life of a rock unit's AMD production. TI1c AMD prediction procedure can also evaluate the required rates and effectiveness of various AMD control amendments. This presentation discusses the WVU AMD prediction procedure in the context of historical approaches and indicates the mechanics and applications of this new technology.

Jan 1, 1991

By Ivan Hunter, Gary Johnson

In many comminution circuits based on SAG mills, an operating cost penalty is incurred in terms of high unit power consumption. By the addition of a crusher to the circuit, to crush part of the so­called critical size fraction extracted from the mill charge, the power efficiency of the circuit can be significantly improved. Dominion Mining has now incorporated pebble crushing into three of its comminution circuits. The improvements in circuit performance have in all cases been significant, and in some cases dramatic.

Jan 1, 1991

By W. P. Staunton, K. Jones

INTRODUCTION The increased activity in the Aus­tralian gold industry over the last decade has resulted in a concomitant increase in the use of sodium cyanide, with a projected consumption of 80,000 tonnes in 1991. Growing environmental awareness by government, industry and the public has generated increased interest in the fate of cyanide near gold mine tailings dams and has highlighted the lack of basic knowledge in the area, particularly for Australian conditions. In 1989 the Chemistry Centre (W.A,) commenced a' project, under the auspices of the Australian Mineral Industries Research Association entitled "Fate of cyanide in the Enviroment Near Mine Tailings" to investigate some of the issues arising from the management of tailings containing cyanide, The project, which has been supported by thirteen companies has three broad aims:

Jan 1, 1991

By David E. Peterson, F. Merz

The Waihi Gold Mining Company Limited, Martha Hill Project was the first major hard rock mining operation following the resurgence of the mining industry in New Zealand. Because of its location adjoining a town and at the southern part of the sensitive Coromandel Peninsula, the operation received a high level of public scrutiny. Very srrict limits for effluent criteria had to be met and led to the necessity for advanced wastewater rreatment technology. The process technology selected was the copper catalysed oxidation of cyanide using hydrogen peroxide, with subsequent removal of heavy metals by precipitation and filrration. This paper discusses the adoption of environment limits together with the detailed description of the plant and design criteria. Data of the one year's operational history is also presented.

Jan 1, 1991

By L. D. Jayaweera, R. G. Robins

The pocessing of gold bearing sulphide minerals wr ich contain arsenopyrite and other complex arsenic sulphide minerals results in arsenic containing emissions and effluents which must be given careful consideration in relation to clean air and clean water standards. The sources of arsenic and the various process options for treating arsenical gold ores and concentrates are briefly reviewed. The problem relating to the removal of arsenic from gaseous emissions from roasting processes is considered. Residues from aqueous processing contain a variety of arsenical materials which have not been characterised, and the long-term stability of these is suspect. 'rhe use of lime to stabilise aqueous residues as either calcium arsenate or calcium arsenite has been shown to be inadequate for long term disposal since both compounds are converted into calcium carbonate due to the influence of carbon dioxide in the atmosphere. Ferric ion solutions have been used to precipitate ferric arsenate or to form ferric hydroxide which binds the arsenic for short term disposal, The long term stability of these ferric materials is poor, but could lead to the acceptance of a slow release option rather than complete containment of residues.

Jan 1, 1991

By W. Hopkin

INTRODUCTION Necessary science and technology are not well established for the design of responsible treatment and disposal of arsenical residues from refractory gold ores. Specifically, there is uncertainty about the precise composition and behaviour of oxidised arsenic species in these wastes, and an analysis of possible chemical behaviour suggests that potentially difficult control and disposal problems remain to be so 1 ved. In tackling these the undoubted toxicity of arsenic in excess and its bad press should not blind one to the realities of actual behaviour in the environment, and that some adverse behaviour inevitably has to be to 1 erated as a cost in return for the recovery of an operation's gold for society. The problem is to minimise any such cost. Each refractory ore will be different. Many will contain so little arsenic that it will cause only trivial problems in disposal, but there remain others with significant arsenic content, say in the order of 1% or more, to cause concern. As already implied, concern can be over emphasised but equally underestimated. The balance which must be struck in the design of responsible disposal in the widest sense requires objective and practical assessment of a complex range of chemical, biochemical, engineering and economic design factors, all of which should involve the process design team in constructive dialogue with the 1 oca l regulatory authorities. In British terms, the general objective should be the Best Practicable Environmental Option. Arsenic is ubiquitous in waters, rocks and soils and all living things. Its compounds undergo natural geochemical and bi ochemi cal cycles including powerful adsorption and precipitation processes which return to nature all leakage from the inevitable disturbance of mining and extraction operations. Within limits, all life is tolerant to its presence, and adaptation and detoxication processes occur to deal with local excesses.

Jan 1, 1991

By Richard E. Deery, Reginald E. Reid

A large portion of the public lands in the United States is managed by the U.S. Department of the Interior, Bureau of Land Management (BLM). Public lands administered by the BLM comprise about 39 per cent (270 million acres) of the entire Federal surface estate or about 1/8 of the surface of the United States. Most of this land, located in the 11 Western States, including Alaska, is available for mineral exploration and development. The BLM is a multiple-use land management agency responsible for the balanced management of the public lands and their resources. The BLM's task is to ensure the balanced and sustainable development of the public lands and resources. This task translates into the management of people and their use of the public resources. As a result, the BLM manages a diverse group of programs including recreation, range lands, timber lands, fish and wildlife habitat, watershed, wilderness, scientific, cultural, and historic properties, and most importantly for this paper, energy and mineral resources. The BLM has developed several new policies with respect to mining, including policies on inspection and enforcement, financial guarantees for reclamation, and the use of cyanide. The goal of these policies is to demonstrate to the American public that mineral exploration and development can be an integral part of sustainable development on public lands in an environmentally sound manner.

Jan 1, 1991

By Alan G. Fricker

Cyprus Gold NZ Ltd will be recovering residual free cyanide in barren gold pulp by air stripping. Laboratory investigations by DSIR have indicated additional advantages by recovering the cyanide from pregnant pulp. These are a lower leach pH, a greater cyanide recovery and less carbon consumption. They have a net economic advantage of $1.20/tonne over recovery from barren pulp. The realisation of these advantages is dependent on three crucial technical aspects -optimum pH for dissolution, the absolute loss of cyanide and the stability of the aurocyanide ion. The laboratory investigations described herein address these aspects. Earlier work had indicated that the rate of dissolution of freely revolving gold discs at constant cyanide ion concentration increased with decreasing pH from 11 to 8. Attempts to repeat the work in a more controlled manner by measuring the corrosion potential and current density have, to date, not been reproducible, but do not contradict the earlier observations. Cyanide recoveries and balances were obtained on leaches at pH 10.5 and 9 at the same cyanide ion concentration -the lower pH requiring three times as much total cyanide. Unaccounted-for losses, unfortunately, exceed the accounted-for losses, making interpretation of the balances difficult. Nevertheless, it appears that the additional amount of cyanide at the lower pH of 9 may not be fully recoverable. It may not, however, prove necessary in practice to use more cyanide at a lower pH. Both the gold and silver cyanide complexes remain available for carbon adsorption, as do mercury, copper and iron. Zinc, and probably cadmium, nickel and lead, may precipitate during stripping, which is an environmental advantage.

Jan 1, 1991

By H. N. McLeod, M. J. Thom

The use of cyanide in gold mining requires the careful handling and storage of cyanide rich tailings. Cyanide in groundwater can frequently be both persistent and mobile, so that tailings basins need to be designed to limit and collect seepage. Assessment of the potential environmental impact requires an understanding of the hydrogeologic regime, both before, during and after mining. Groundwater monitoring wells provide a basis for monitoring tailings pond behaviour and for assessing the impact of mitigative measures to reduce or control seepage. A case example of Cheni Gold Mines Lawyers Project in Canada is presented to illustrate the use of groundwater monitoring to determine the amount of cyanide degradation and attenuation between the tailings pond and the receiving environment.

Jan 1, 1991

By Des B. Bolton, Neil P. Boland

Typically, environmental work on mine sites in Northern Australia involves addressing an individual problem as it arises. However, individual mining companies are moving toward a more holistic approach to managing the interactions between the environment and the mining process and are thus pre-empting environmental problems. This paper presents a broad overview of this holistic approach and provides a few examples, drawn from our own experience, which illustrate some of the tangible benefits to be gained from Environmental Planning.

Jan 1, 1991

By Jacob D. Baker

Sulphur dioxide is a versatile gas which has many uses throughout Pulp & Paper, Chemical, specialty Chemical, Mining and other industries. During recent years, S0 2 consumption and distribution patterns have resulted in renewed interests for liquid S0 2 and on site gaseous S02 manufacturing facilities. one relatively new use for S0 2 in the Mining Industry is its use for cyanide detoxification. Our purpose in this paper is to describe the process steps, economics and general technical features of so 2 gas generation using a Jet Type sulphur Burning System.

Jan 1, 1991

By E. A. Devuyst, G. Robbins

A unique process for removing cyanide and base metal complexes from industrial waste streams was patented by G.J. Borberly et al. (1984). The process uses SO2 (liquid or gas, or solutions of sulfite salts, or from burning elemental sulfur), plus air that is dispersed in the effluent using a well agitated vessel. Acid produced in the oxidation reactions is neutralized with lime at a controlled pH generally in the range 7 to 10. The reaction requires the presence of soluble copper as a catalyst which can be supplemented by copper sulfate if necessary. The process can be applied to the detoxification of gold and silver mining waste streams, such as carbon-in-pulp (CIP) tailing pulps, barren solution bleeds, pond waters and heap leach rinse solutions and also to plating shops wastewaters. The SO.jAir process has substantial advantages over two of the main alternative methods of cyanide destruction, namely alkaline chlorination and hydrogen peroxide. Alkaline chlorination is highly penalized in terms of reagent consumption. Chlorine is a strong oxidant reacting with species other than cyanide present in the effluent such as thiocyanate and sulfides. Furthermore alkaline chlorination is an incomplete detoxification process. Iron cyanide is not removed and the potential for harmful by-products species exist. Consequently final effluents may be subject to additional treatment in order to comply with regulatory demands.

Jan 1, 1991

By Byron K. nelson, David Mathieson

Until quite recently concentration of free gold in gravity circuits ahead of froth flotation and/or chemical treatment was considered an uneconomical pursuit in many gold pi.ants in Australia. Over the past 10 yenrs since initial introduction of the Knelson Gold Concentrator, over 600 hnvc been surpl led world wide and they have been developed to the stage that Lhey can now be utilised in almost all instances where free gold appears in significant quantltles ln grinding circuits. They out perform and displace more conventional gravity sepnration equipment such as spirals, tables, sluices, jigs, drum separators etc.

Jan 1, 1991

By A. Bruynesteyn

Most ores and coals contain sulphide minerals such as pyrite, FeS2, the sulphur portion of which is a ready substrate for a variety of sulphur oxidizing bacteria. Although there are several bacteria capable of oxidizing sulphide minerals, the most often discussed culprit is Thiobacillus ferrooxidans.. Oxygen from the air slowly oxidizes pyrite into sulphuric acid, but T- ferrooxidans can increase this reaction rate several 100,000 times.

Jan 1, 1991

By Jim V. Rouse

The decision to hold parallel conferences dealing with hazardous waste and mining waste grew out of the conviction that there were advantages to having personnel serving the two groups talk to each other, as both groups develop cost-effective and environmentally-protective solutions to present and future waste-disposal problems. There has been a certain amount of "reinventing the wheel" which could have been avoided by a better dialog between the two groups. The intent of holding the two parallel conferences is to allow for networking, to minimize future needless redundant effort. The opening session panel speakers represent expertise from both industries; I feel honored to speak as one with a history of serving both groups as a specialist in the subsurface behavior of heavy metals.

Jan 1, 1991

By Stephen D. Hill, C. R. Ferguson, T. H. Jeffers, P. G. Bennett

The U.S. Bureau of Mines' Salt Lake City Research Center has developed porous polymeric beads containing immobilized non-living biological materials for extracting metal contaminants from waste waters. Immobilized biological materials include peat moss, algae, biological polymers, and other materials that demonstrate high affinities for heavy metals. The beads, designated as BIO-FIX beads, have distinct advantages over traditional methods of utilizing biological materials in that they have excellent handling characteristics and can be used in conventional processing equipment or low-maintenance systems. Toxic metals such as copper, cadmium, zinc, lead, and mercury are several of the many heavy metals effectively removed from mine waste waters using BIO-FIX beads, Continuous cyclic testing indicated that the beads continued to produce treated effluents which met National Drinking Water Standards (NOWS) after 150 loading-elution cycles. Adsorbed metals were removed from the beads using dilute mineral acids. In many cases, the extracted metals were further concentrated to enable processors to reclaim the metals, thus minimizing the generation of a hazardous sludge, Tests indicated that use of the beads in a low­maintenance system was particularly effective for treating remote acid mine drainage waters and small toxic seeps from hard-rock mining districts.

Jan 1, 1991

By N/A

finally, but not least, the staff of Vaal Reefs Chemical Laboratory for their assistance and patience with the introduction of a new technology,

Jan 1, 1991

By Kurt O'Bryan

WaterFlush Technology has recently been implemented at a gold milling operation in the United states. This new technology offers maximum comminution performance bene­fits over today's more common comminution methods. These benefits will be presented via the discussion of performance results from existing installations, and the proj­ected performance gains for circuits sched­uled to begin operation in late 1991.

Jan 1, 1991

By Chris Joyce, Peter Ryan, Graeme Mcllveen

This paper briefly summarizes regulatory procedures and government agency roles and jurisdictions in each Australian State and Territory. The role of the Commonwealth of Australia and selected current trends in environmental regulation are also discussed. While the Commonwealth has played an active role in regulating specific commodities or mines through its powers over export licences, international heritage agreements and the Territories, such cases have largely been a result of response to specific public issues. This may change; the Commonwealth has established the Resources Assessment Commission and is canvassing the establishment of an Environmental Protection Act, aimed at the standardization of environmental standards through the creation of an Environmental Protection Authority. While the States, the Northern Territory and the Commonwealth lwve nominally different resource planning, environmental project approval and operational regulatory authoritit:s, the fundamental principles hinge on mining lease, planning and pollution control approvals.

Jan 1, 1991

By R. L. Murray-Smith, M. E. A. Robertson, M. J. Prosser

The AZTEC is an automated instrument, for the non-destructive analysis of gold ore samples, which uses energy dispersive X-ray fluorescence (XRF), This is achieved by X­ray tube excitation of gold K X-rays. The first production instrument was commissioned at Vaal Reefs Chemical Laboratory (VRCL) in November 1987, followed by two second generation instruments in 1989. AZTECs have also been installed at Western Deep Levels and at Anglo American Research Laboratories (AARL). A further unit is being assembled at Ashanti mine, Ghana. At VRCL the AZTECs are used primarily for the evaluation of mine (stope) samples. Each of the production instruments can routinely analyse 650-700 samples per day, with the aid of a robotic sample transfer system. Various techniques have been evaluated for increasing sample throughput. For example, higher value samples can be counted for a shorter time to obtain the necessary relative precision.

Jan 1, 1991