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By K. S. Eric Forssberg, Lennart Ryk

The paper discusses coal utilisation in Sweden. All hard coals have to be imported from other countries. Peat from domestic sources is used as a complement. Environmental legislation and taxation on fuel and emissions are severe. This situation affects the procurement, preparation, handling and use of coal. The paper presents: • R&D projects concerning deep cleaning of thermal coal. • Handling and treatment of coal used in PFBC boilers and for blast furnace injection • Dust prevention for coal and peat briquettes. Procurement of coal emphasising quality and environmental issues.

Jan 1, 1995

By Gerd Oberheuser, Hans Kellerwessel

Comminution with high compression roller mills finds rising interst in ore and minerals industry. Energy saving and upgrading of existing grinding facilities is one of the main reasons. Beside these possibilities other positive effects on the downstream units operations require also intense testwork. Basic interdependencies of the operational parameters gained at the testwork and their influence on the upscaling procedure are described.

Jan 1, 1995

By Mark J. Schultz, William J. Francart, Gary J. Wirth

Atmospheric Monitoring Systems (AMS) utilizing carbon monoxide sensors have demonstrated their superiority over thermal type fire sensors for early fire detection in underground coal mines. After proving their capability and dependability throughout the 1980's, systems are now evolving and applying new technologies to enhance their effectiveness and reliability. The use of AMS in coal mines which utilize diesel equipment presents unique obstacles. Exhaust gases from diesel equipment not only raise mine ambient CO readings, but also cause numerous nuisance alarms. Both of these conditions reduce the effectiveness of the AMS. New technologies, such as discriminating devices, smoke detectors, and time delays, as well as administrative controls, have been developed and are being utilized to help reduce nuisance alarms produced by the diesel exhaust. This paper will discuss these technologies and administrative controls which are being utilized in coal mines to enhance the effectiveness of the Atmospheric Monitoring Systems. Reference to specific products does not imply endorsement by the Mine Safety and Health Administration.

Jan 1, 1995

By J. Drelich

The wetting behavior of liquid polymers at solid surfaces and the adhesion forces involved at polymer-filler interfaces should always be considered in the fabrication of high quality polymer composites, including those made with mineral fillers. Spontaneous polymer spreading over the filler surface is a basic condition in the fabrication of the polymer-mineral composites. In this regard, the wetting and adhesion characteristics of polymer-mineral systems are reviewed in this contribution. It appears that several aspects of wetting phenomena at mineral filler surfaces are not well described in the literature and require further systematic study. Specifically, it is clear from this review that efforts should be made to determine the effects of mineral surface contamination (including surface hydration) on wetting and adhesion phenomena, and to determine the wetting characteristics of molten polymers at mineral filler surfaces. It is expected that any improved fundamental understanding of wetting and adhesion phenomena for the polymer-mineral composites will provide the basis for further technological development.

Jan 1, 1995

By W. Lorenz

The responsible treatment of natural resources, including mineral raw materials, contributes to the protection of the environment. The management of resources and the environment encompasses reduction of emission through application of environmentally friendly processes, economical use of resources, recycling and substitution, application of energy saving processes, land reclamation and recultivation, as well as a well balanced regional and land use planning. A variety of materials are needed for measures to protect the environment. Many of these materials are, or to a large percentage consist of, mineral raw materials, which become effective either directly or indirectly in their natural state or after an appropriate industrial treatment. We call them environmental minerals. Although extraction and processing of these mineral raw materials destined for use in the protection of the environment, may have a negative impact on the environment on one hand, preventive or curing measures to protect the environment on the other would not be possible without them. We have to accept certain smaller burdens of the environment, which naturally will have to be kept at the lowest possible level, in order to avoid or minimize greater damages to nature. In the broad group of industrial minerals and rocks there is a wide variety of mineral raw materials, which lend themselves for countermeasures in favor of the environment. To hamper their production and processing through excessive environmental regulations would make the protection of the very environment more difficult or even impossible.

Jan 1, 1995

By C. Abbruzzese, L. Piga, P. Fornari, S. Ubaldini, R. Massidda

The effects of certain variables on the extraction of gold by thioureation have been investigated on a quartzose gold-bearing ore using a statistical multifactorial strategy. The factors taken into consideration were milling time (which corresponds to a given grain size), oxidant concentration, thiourea concentration and liquid/solid ratio. The influence of these four variables was ascertained first by a full factorial design at two levels for each variable (16 runs). This permitted the estimation of first-order effects of the factors affecting the process. Then 9 runs were added whose levels were both in the centre of and outside the axes of the previous plan thus originating a central composite design. This permitted estimation both of second-order effects of the factors involved and of parameters of a second-order polynomial model. The results show that extraction of gold depends only on milling time and oxidant concentration, at least in the experimental range considered. The equation fitting experimental data, as calculated by the least squares method, allows a response surface to be drawn. Due to the low gold grade of the ore (6 ppm) statistical analysis could lead to contradictory results, hence strict observance of Gy's rules for sampling and very accurate and precise chemical analyses were required.

Jan 1, 1995

By Heinz Hoberg, Fred Ulrich Schneider, Rudolf Diegel

The risk of contamination of dumped tailings and ground water by coal flotation reagents has been investigated by using the 14C-radiotracer method for adsorption and desorption measurements. The results indicate, that a high amount of the reagent components adsorbed on the tailings if there was no coal in the pulp. In coal flotation however a competitive adsorption behaviour could be observed, with the effect that only a low quantity of reagents adsorbed on the tailings. Mobilization tests showed, that only small quantities of reagents could be desorbed by rinsing water. Therefore the contamination of ground water should be low.

Jan 1, 1995

By Chien D. Ngo, Andre Bachmann, Rainer Bunge

The remediation of contaminated sites has gained great importance in many industrialized countries. One method for cleaning the polluted soils from such sites is "soil washing," the scope of which is the separation of the contaminants from the soil. Soil washing is an outstanding example for a successful transfer of technology from Mineral Processing to Environmental Engineering. This presentation intends to introduce the Mineral Processing Engineer to soil washing through a short review of the fundamentals, and the discussion of an example for a successful soil cleaning operation in Switzerland.

Jan 1, 1995

By N. Edmonson

Frasch sulfur production/pricing decisions are based on market demand, less nondiscretionary sulfur supply. Price covers the cost of Frasch production and byproduct sellers accept the Frasch price structure. Large stocks have led Canadian byproduct producers to price aggressively at times, but their near-term drawdown suggests more passive price policies in the 1990s. Expanding continental nondiscretionary supply is combining with sizable Frasch supply increments to weaken prices. Simulations using a market model embodying these structural characteristics indicate that expanding demand may not result in substantial recovery from 1992 price lows before 1996.

Jan 1, 1995

By Y. Wang, E. Forssberg

Wet magnetic separation methods for the recovery of hematite and chromite fines and ultrafines were investigated. These methods included wet high-intensity and high-gradient magnetic separation, carrier or "piggy-hack" magnetic separation, magnetic field-induced aggregation and magnetic seeding. This investigation indicated that wet magnetic separation is more efficient for fines and ultrafines. This investigation also indicated that other methods can be used to enhance the particle aggregation and/or the magnetic response. The magnetic behavior of these minerals with respect to the magnetizing field, temperature and particle size is also presented.

Jan 1, 1995

By Robert S. Setren, Jeffrey L. Ambs

The disposable diesel exhaust filter (DDEF) system developed by the U.S. Bureau of Mines and Industry cooperators for heavy-duty permissible, diesel-powered haulage vehicles, effectively reduces in-mine diesel particulate matter concentrations up to 95%. However, there are concerns about the hazards that exist when the filter is used in situations for which it was not designed. This work investigates the exhaust gas temperature limits to which the filter elements can be exposed without posing a safety or health hazard, such as 6re or off-gassing toxic compounds. A filter approved by the Mine Safety and Health administration and after-market filters were evaluated under varying engine exhaust conditions to determine if after-market filters pose an unacceptable hazard when used in a DDEF system. Filters were laboratory tested at engine exhaust temperatures ranging from 77°C to 290°C. Of the seven filter types tested, six appeared suitable for use on water scrubber-based cooling systems and two appeared suitable for use on dry heat exchanger type exhaust cooling systems with exhaust temperatures up to 150°C. Any filter elements used as exhaust filters on permissible diesel machines must be approved by MSHA for that application. Mine operators who wish to use an after-market filter element should request an MSHA field modification. MSHA will work with the mine and filter manufacturer to ensure its use in this exhaust system application does not pose a health or safety hazard.

Jan 1, 1995

By E. Valdiviezo, J. F. Oliveira

Adsorption of residual flotation reagents onto equilibrium fluid cracking catalysts is a promising method of purification of flotation process water. In the present paper, adsorption of sodium dodecyl sulphate (SDS), dodecyl ammonium chloride (DAC) and sodium oleate onto a spent catalyst from petroleum industry was studied by analysing the residual concentration of the surfactant after contact with the zeolite catalyst. The adsorption of the DAC was rather low but SDS and sodium oleate presented a high affinity for the catalyst surface. The loading capacity was 4.2 kg/ton for SDS and 5.5 kg/ton for oleic acid. After the treatment of the loaded catalyst with a HCI 1 N solution these surfactants are desorbed and the catalyst may thus be regenerated. This would be an additional advantage to its low cost, not to mention its condition as a discarded product and its availability in large tonnages.

Jan 1, 1995

By Richard Jr. Ray, Richard Druesedow

The Virginia Operations of Consolidation Coal Co. include a diversity of mine fan configurations which have been tested to quantify pressure losses through the inlet ductwork. Airflow and pressure measurements were taken at four shaft sites to calculate losses for the 90-degree bend at the top of the shaft and the self-closing dampers or closing doors located between the shaft and fan. Velocity contours were then developed from the test data to determine flow patterns in each fan system component. In addition, yaw and pitch angles of airflow through the fan annulus were measured to evaluate turbulence levels created by various inlet ductwork designs. The test results indicate that proper design of the shaft collar and ductwork arrangement for main mine fans can substantially reduce system pressure losses and air turbulence. BY minimizing the pressure drop experienced on the surface, these design improvements enable the bulk of the total pressure developed by the fan(s) to be utilized in the mine.

Jan 1, 1995

By E. Suoninen, K. Laajalehto, L. Kartio

Efficient separation of pyrite from other sulfides is of great importance for the metallurgical performance of flotation processes. In this work Fourier Transform Infrared Spectroscopy (FTIR) and X-ray Photoelectron Spectroscopy (XPS) were used to study the surface chemistry of pyrite in depression, activation and xanthate adsorption under conditions of controlled potential. Modifications of pyrite surfaces after treatment with depressants (lime, sulfur dioxide, sodium cyanide) and after activation with metal ions (Cu, Pb) were studied. The principal adsorption product identified on pyrite was dixanthogen whose formation started at about +0.15 V and +0.25 V (vs, SHE) in ethyl and amyl xanthate solutions, respectively. Copper xanthate was formed on copper(II) activated pyrite. Activation mechanism of pyrite by copper(II) salts is likely to be electrochemical where copper occurs as copper(I) on the surface of pyrite. Effective depression is achieved by sulfur dioxide and sodium cyanide. Depression at high pH is due to formation of iron(III) hydroxides. Calcium ions do not affect the electrochemistry but adsorb on pyrite and reduce the surface sites for dixanthogen adsorption.

Jan 1, 1995

By F. K. Letowski

Leaching of zinc sulphide concentrate by nitric acid which is simultaneously regenerated by oxygen in the reactive froth has been investigated. The reactive froth was formed by a recycled zinc sulphate electrolyte containing nitric acid, a mixture of gaseous 02 and NOx, entrapped in the foam and particles of the zinc concentrate suspended in the foam. In the reactive froth the multiple regeneration of nitric acid proceeded owing to the encapsulated oxygen and amount of nitric acid used can be considerably lower than in the continuous liquid phase. 93 to 97% of zinc was extracted to a solution containing 30 to 409/1 HNO, during 40 to 60 min of leaching in a batch reactor without regeneration of nitric acid. 50 to 100% of the consumed nitric acid was regenerated during continuous leaching in froth carried out in the ‘flotation column’-type reactor at 80 to 90°C and under pressure of 100 to 200kPa. The rate of HNO, regeneration in the froth was proportional to oxygen pressure and inversely proportional to nitric acid concentration in the froth. A two-stage process flowsheet is proposed. In the first, the reduction stage, removal of nitric acid from the leach solution directed to standard purification and electrolysis is carried out by its reduction to nitric oxide using fresh concentrate in the froth. In the second, the oxidation stage, nitric acid is continuously regenerated by oxygen in the froth.

Jan 1, 1995

By G. Machiavelli, P. Bevilacqua, G. Ferrara, T. P. Meloy

During several years of operation in Europe, South Africa and other locations, the Tri-Flo process has demonstrated substantial improvements in dense-medium dynamic-separation systems. The reasons for this improvement are: • a high-sharpness separation due to the multistage system and the application of new concepts in the design of the regeneration circuit and in the control of the medium Theology, and • the possibility of performing two cuts at different densities using a single separation device and a single regeneration circuit. This paper discusses the above points in detail with particular reference to the multistage technology (based on the circuit analysis theory) and to the control of the medium rheology (based on recent work in the modeling and simulation of the rheological behavior of dense suspensions). Concerning the multidensity separation, information is given on the new three-stage separator where the high-density separation is performed by the first stage and the low-density separation is performed by the second and third stages. This configuration (already realized in two operating plants) was selected because no particular sharpness was required at the high-density separation, while high sharpness was required at the low-density separation. However, the configuration can be inverted or a fourth stage can be added (at very low additional cost) to provide two stages for each separating density. The importance of achieving a high sharpness separation is related to minerals (industrial minerals in particular) where the density difference of the phases to be separated is very low (as in processing of lithium ores, feldspar- and others). Information is provided on plants operating in South Africa and Canada, for the beneficiation of lithium minerals and on a plant under construction in Italy for the beneficiation of feldspar. Finally, the importance of making the separation at two densities is emphasized with particular reference to coal; i.e., producing a low-ash premium coal and recovering, in the middling, a by-product without losing heating value. Also, very important for some minerals is the production of a high-grade concentrate (at the first stage) suitable for sending directly to metallurgy (e.g., chromite ores) and the production of a low-grade concentrate that can be further treated. In this way, a higher overall recovery of the valuable mineral can be achieved, and, at the same time, a reduction of the treatment costs can be obtained. All of the above applications were once considered impossible.

Jan 1, 1995

By Hang Yang, Linneas W. Laage

A major concern of mine fires is the heat generated ventilation disturbances which can move products of combustion (POC) through unexpected passageways. Fire emergency planning requires simulation of the interaction of the fire and ventilation system to predict the state of the ventilation system and the subsequent distribution of temperatures and POC. Several computer models were developed by the U.S. Bureau of Mines (USBM) to perform this simulation. The most recent, MFIRE, simulates a mine's ventilation system and its response to altered ventilation parameters such as the development of new mine workings or changes in ventilation control structures, external influence such as varying outside temperatures, and internal influences such as fires. Extensive output allows quantitative analysis of the effects of the proposed alteration to the ventilation system. This paper describes recent USBM research to validate MFIRE's calculation of temperature distribution in an airway due to a mine fire, as temperatures are the most significant source of ventilation disturbances. Fire tests were conducted at the Waldo Mine near Magdalena, NM. From these experiments, temperature profiles were developed as functions of time and distance from the fire and compared with simulations from MFIRE.

Jan 1, 1995

By Pertti Koivistoinen

There are many grinding schools in the mining world, which claim their grinding method to be the best possible - and still the methods concerned vary a great deal. Some of them have multi- stage crushing and only single stage grinding while in others crushing may be nominal, but grinding can be very complicated. - In this presentation firstly the nine most common comminution circuits will be analyzed. Then results from a pilot scale test series will be reviewed, in which nickel ore ground by four different comminution methods was fed to a common flotation treatment.

Jan 1, 1995

By T. Knuutinen, M. Klemetti, P. Mörsky

This paper presents a comparison study done at VTT's new pilot plant facilities in Outokumpu, Finland, for chromite ore. The ore was ground in a rod mill -, a ball mill - and high pressure roller mill - ball mill circuit in the capacity range of 0.5 - 3.0 t / h. The main grinding characteristics are discussed and the quality of the products are compared from the mineralogical point of view. The benefits of high pressure roller mill comminution for further mineral processing of chromite is also discussed.

Jan 1, 1995

By Sylvain Duchesne, Claude Bazin, Robert Grant

Grinding simulators are now widely available to assist in the selection of circuit operating conditions or flowsheet designs that yield a given product size distribution. These simulators do not inform of the impact of the grinding product size distribution on subsequent flotation stages. This paper presents a method to predict the effect of fineness of grind on a flotation bank operation. Application of the method is illustrated with data from two Canadian concentrators.

Jan 1, 1995