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By Regis F. Kopac

With the growing dependence on coal as an energy source, finding a means to prevent or reduce the freezing of coal during winter shipment has become increasingly important. Several chemical companies focused on this problem and applied chemical technology to develop suitable solutions. As a result, a number of freeze conditioning agents have been introduced in the past few years, several of which have been highly effective in controlling frozen coal. The efficacy of these chemicals has been well established, however many users have found that only a well defined program will produce acceptable results at a reasonable cost. Positive program results yielding recognizable benefits have caused many power generating and coking plants to consider freeze conditioning agents. A freeze conditioning agent (or FCA) has been defined as a multi-component organic liquid designed to be sprayed on coal particles at bulk shipping points to assure that receiving locations will be able to unload, store and use the treated coal with minimum delay or inconvenience. The chemicals are generally applied at rates of 1 to 2 pints (0.473 to 0.946 liters) per ton and normally function by changing the crystalline structure of water left on the coal during processing. The bond strength of the ice that may subsequently form is markedly reduced. Instead of freezing into solid, unmanageable masses, the coal can be easily unloaded by rotary dumping or the opening of hopper car doors.

Jan 1, 1980

By A. E. Isaacson, D. B. Dreisinger, G. A. Kordosky

The U.S. Bureau of Mines is researching the application of solvent extraction technology to highly acidic (pH < 1) copper leach liquors. As increasingly complex copper ores are mined for leaching, use of highly acidic leach solutions maybe necessary to effectively recover the contained metal values. A mixture of two commercially available extractants, based on aldoximes and substituted 8-hydroxyquinoline, which has a high transfer efficiency has been identified. A synthetic leach liquor, containing 5 g/L Cu at pH 0.9 was processed utilizing the mixed extractant and a laboratory SX circuit. The loaded organic was stripped with a synthetic barren electrolyte compatible with electrowinning technology.

Jan 1, 1993

By Wolfram Schnabel

Recently Lurgi has succesfully commissioned Peru&apos;s first direct reduction rotary kiln at SIDERPERU?s Chimbote works. The order included comprehensive engineering services and supply of special equipment to modify three existing cement kilns according to the SL/RN process. The kilns were cut to 62m length and installed with a slope of 2.5%. A new heating system, including shell burners, was supplied and inlet and outlet ends of the kilns completely renewed. Figure 1 shows the kilns after modification.

Jan 1, 1981

By Roderick G. Eggert, John E. Tilton

During much of the 1970s and 1980s, world metal consumption grew more slowly than during the 19505 and 1960s. The slowdown contributed to surplus capacity and low real prices because actual consumption was consistently less than expected as new mining and mineral processing capacity came on stream. Over the last year or so, however, world metal consumption has picked up noticeably, raising the question, Has metal demand returned to the long-run growth rates more typical of the 1950s and 1960s than of the 1970s and 1980s? This paper examines this possibility and, more generally, assesses the factors that will shape demand for the major metals over the longer term. TRENDS IN METAL CONSUMPTION The extent to which metal consumption has recaptured the brisk growth rates typical of the 1950s, 1960s, and early 1970s is shown in Figure 1. This figure traces the consumption of crude steel, primary aluminum, refined copper, refined lead, and refined zinc between 1960 and 1987 for the western world, consisting of the OECD countries (including the United States), and the developing countries. Consumption increased in 1987 for all five metals, and preliminary data for the first six months of 1988 suggest even more substantial increases, at least for the United States (U.S. Bureau of Mines, 1988). However, Figure 1 also shows that the recent increases in consumption are not untypical of similar surges during earlier periods of economic expansion and thus may reflect only cyclical or temporary factors. In short, the available data are unable to provide a clear indication of whether recent increases in metal consumption reflect the beginning of a new era of faster growth or simply a cyclical and temporary upturn associated with the expansionary phase of the business cycle. Consequently, to pursue this issue, we are forced to examine the underlying forces that will shape metal demand trends over the next decade. The approach we have taken involves two steps. The first examines the prospects for overall economic growth. The expectation is, the faster the economy expands, the faster the production of metal-containing goods grows.2

Jan 1, 1989

By M. L. Harris

In underground mines, coal dust explosions are prevented by the addition of rock dust sufficient to render the coal dust inert. The National Institute for Occupational Safety and Health (NIOSH) developed a hand-held instrument that uses optical reflectance to measure the explosibility of a rock dust and coal dust mixture. This instrument is called the Coal Dust Explosibility Meter (CDEM). In this study, NIOSH personnel accompanied Mine Safety and Health Administration (MSHA) inspectors on their routine band surveys in five underground coal mines in MSHA District 2 (Pennsylvania) and three underground coal mines in MSHA District 11 (Alabama). While underground, NIOSH personnel and MSHA inspectors used the CDEM to assess the explosibilities of the dust samples. The values of percent incombustible content (percent IC) determined by the CDEM agreed well with those obtained later by low-temperature ashing (LTA) in both MSHA and NIOSH laboratories. Further, the meter identified some samples as potentially explosible that LTA analysis had found to possess sufficient rock dust for inerting. The CDEM provides more information on the hazards in the mine. Rapid identification of areas with explosible dust mixtures using the CDEM allows for immediate intervention rather than a wait of several weeks for laboratory analysis.

Jan 1, 2008

By Odin Wilhelmy

Agriculture in the United States today is becoming more and more a business, rather than a way of life. In the light of this, it behooves the farm-supply industries that provide the American farmer with his tools of production--feed, fertilizer, machinery, and the like--to give even greater attention than they have in the past to meeting the needs of the farmer-businessmen they are serving. Increasing competition among the companies that make up these industries merely accentuates this need for better service. An opportunity for such improved service, not yet fully realized, exists in the fertilizer industry today. That opportunity lies in the increased transportation of fertilizer ingredients by water. However, before the benefits inherent in this increased water movement of fertilizers can be fully realized, certain obstacles must be met and overcome. It is the purpose of this paper to outline the nature and magnitude of this opportunity, to point out some of the roadblocks and the steps that can be, or are being, taken to remove them, and to indicate some of the rewards that would logically stem from success in these efforts.

Jan 1, 1961

By Randy Vranes

Sophisticated information technology, quality management systems and a commitment to the environment has allowed Solutia’s Soda Springs phosphate mine and elemental phosphorus plant to reduce operating costs, improve product quality and contribute to the sustainable development of Idaho’s industrial minerals. Soda Springs background The Soda Springs phosphate mine and plant is a joint venture between Monsanto and its operating partner, Solutia Inc. The operation is based in southeastern Idaho in the Western Phosphate Field. The plant is located about 275 km (170 miles) northeast of Salt Lake City, UT and about 4 km (2.5 miles) north of the town of Soda Springs.

Jan 1, 1999

By M. A. D. Azevedo

The effect of pulping reagents on the flotation de-inking of laser printed wastepaper was investigated with regard to the removal efficiency of toner and mineral filler particles for different pH values. These results show that caustic pulping causes the toner to be released from the fibers at larger particles sizes. On the other hand, acid pulping not only causes the toner to be released at smaller particles sizes but also increases the concurrent flotation removal of mineral filler particles. It was experimentally observed that the froth generation and stability during flotation were improved for acidic pH values.

Jan 1, 1997

By C. W. Matthews

Introduction Screening is defined as a mechanical process which separates particles on the basis of their size and their acceptance or rejection by a screening surface. The key element in this method of particle sizing is obviously the screening surface, the medium that contains the apertures for the passage of the undersize material. This surface must be strong enough to support the weight of the material being screened, flexible enough to yield to the vibrating force applied to it, yet light enough to provide a reasonable ratio of open area to attain a practical through- put. To balance all of these factors is difficult enough. The problem is compounded, however, because screening media are made in a great variety of types, shapes, sizes, and materials of

Jan 1, 1985

By R. F. Harig

Designing an underground nuclear waste repository is a complex process. Although many decisions are involved before the design is complete, the first three--what the target horizon is, what the underground boundary is, and where the entry point will be located--are important because they establish the basis for the entire repository design. Even more important than these decisions, however, is the data on which the decisions are based. Because the current data are limited, an aggressive data gathering program is needed during the next design phase to augment information about the intricate interplay among all facets of the repository design and the geologic medium in which the proposed repository is to be developed. Although unique to modern engineering enterprises, the challenges involved in designing a repository in the unsaturated zone are within current technology and engineering practices.

Jan 1, 1991

By J. A. Organiscak

The National Institute for Occupational Safety and Health (NIOSH) has investigated various factor effects on cab air filtration system performance. Factors experimentally investigated were intake filter efficiency, intake air leakage, intake filter loading (filter flow resistance), recirculation filter use, and wind penetration. Adding an intake pressurizer fan to the filtration system was also investigated. Results indicate that the intake filter efficiency and recirculation filter were the two most influential factors on cab protection performance. Use of a recirculation filter significantly reduced cab penetration over the intake air filter by itself due to the multiplicable filtration of the cab interior air. Cab penetration was also affected to a lesser extent by intake filter loading and air leakage. Adding an intake pressurizer fan notably increased intake airflow and cab pressure while providing only minor changes to cab penetration.

Jan 1, 2008

By X. Xie

The dissolution behavior of palladium powder in thiourea solutions has been studied. The variables studied included temperature, stirring speed, and concentrations of thiourea, acid and ferric ion. Palladium was found to be soluble in thiourea solutions in the presence of an oxidant such as ferric ion. The dissolution of palladium in thiourea solutions was found to be chemical reaction controlled with an apparent activation energy of about 2S.3 kJ/mol.

Jan 1, 1995

By William S. Gilmer

INTRODUCTION As man moved through the ages into the era of metals, he became increas¬ingly dependent on the extraction and beneficiation of various ore types. His progression has required more material, new sources, and inevitably, a need to extract the values from ores of much lower yield. Inherently welded to this need to extract has been the attendant requisite of power and water to carry out these tasks. With the richness of these deposits diminished, and the in¬crease of demand, mining has become so intimately tied with the needs of these auxiliary systems that the modern day milling operation can ill afford to ignore them. In the times of Agricola 16th century methods of milling required little thought for power or water consumption. Reduction was accomplished by hand¬sorting and hammer and grinding done with stamps and millstones. Medieval concentration was carried out by the "Jigging sieve" with agitation supplied by the sleeveless arm of the operator (The Mines Magazine,_ March 1933). Little consideration was likely given to the power source unless it became apparent that he had insufficient means to meet the demands of a dawn to dusk operation. Fuel for power production was also probably of little consequence unless sustained drought or warring neighbors burned the miners fields. Water was available from any adjacent stream with recycle, potable, tailings and mill consumption all going and coming from the same source. By the end of the 18th century and the early 19th century the requirements of larger throughputs and better re¬covery were forcing the miner to the need for greater sources of power and water. Arrastras, capable of accepting several hundred pounds of charge, con¬sisted of a clay bottom, a "liner of rocks harder than the substance to be crushed" and a revolving center post in which the ore was ground and amalga¬mated. Used in conjunction with a slucing system, this formed the primary recovery method of the time. Power was supplied by horse or oxen or, if terrain was amenable, by use of a horizontal or overshot water wheel. A typical system required 4.5 kw (6 hp) and needed to run in the vicinity of 15 rpm (Pre¬ston, 1895).

Jan 1, 1986

By Peter L. Comanor

At Getchell, Nevada a thousand tons per day mill for extracting gold from an ore containing orpiment and realgar was operated several years until early 1967. A cyanide process with a roaster was used in the processing of the ore. Mill wastes were contained in tailings ponds, in which the concentration of arsenic, currently, is one per cent or higher, Studies were conducted determining the effect of the tailing wastes on the Upper Sonoran vegetation of the area. Grid and line-intercept techniques were employed to obtain botanical informatics of the area surrounding the tailings ponds. Data of the per cent ground cover, species frequency, and plant vitality as a function of distance from the tailings ponds was collected. The data was compared to other botanical data collected from a control site outside the influence of the tailings ponds. In an attempt to isolate naturally occurring factors for varying plant communities from hose induced by factors derived from the close proximity of the tailings, soil cores were taken along the line-intercepts at intervals of 30 meters. The cores were analyzed for several compounds and elements needed for growth, or known to inhibit growth. Specific physical parameters of the soil samples were also taken. The paper describes the impact made by mill wastes containing large amounts of arsenic on the Upper Sonoran vegetation of the Getchell region. Described in detail are the techniques used to make the correlations between the plant communities and the influences of mill wastes.

Jan 1, 1974

By J. A. Siekmeier

The thickness of the laminated beam modeled in this study is based on bridging potential and TDR measurements. The laminated beam stiffness is based on the effective stiffness of an equivalent transformed section. The maximum deflection of this near-surface laminated beam is compared with the maximum measured surface subsidence. The spreadsheet provides a rational technique to graphically display the character of the overburden and potentially allows prediction of a subsidence factor based on boring logs and the proposed mine plan. The U.S. Department of the Interior, Bureau of Mines (Bureau), utilizes a commercially available computer spreadsheet program in combination with a modified version of Bieniawski&apos;s Rock Mass Rating (RMR) system to characterize the geology overlying high extraction coal mines. The spreadsheet program calculates a RMR for each bed based on the lithology, thickness, and engineering properties, which are determined from boring logs and laboratory tests. Once the RMR is calculated the spreadsheet has two major functions. First, the spreadsheet calculates values used to graphically represent the character of each individual bed in the overburden. It calculates an in situ deformation modulus using an empirical rela¬tionship between the modulus and the RMR and then uses this effective modulus along with additional parameters that are based on mine geometry to calculate the bending stiffness and bridging potential for each bed. Second, the spreadsheet creates a transformed section that allows groups of beds to be modeled as an elastic beam. It then calculates a bridging potential for the entire rock mass. The bridging potential of the rock mass is a single value that takes into account both the geology of the overburden and the geometry of the mine. It seems reasonable that there would be a strong correlation between the bridging potential, the overburden response to high extraction mining, and the subsidence ratio. The results presented in this paper focus on the relationship between the bridging potential of individual beds and the deformation measured using Time Domain Reflectometry (TOR). Subsurface displacements measured over seven high extraction coal mines in southern Illinois were correlated with the bed stiffness and bridging potential profiles. Based on these correlations it was evident that the process of caving and subsidence over these high extraction mines involved momentary bridging by individual beds or groups of beds and the ultimate development of a laminated beam near the surface.

Jan 1, 1986

By John J. Gillis

There is an ongoing battle to gain general acceptance of fossil fuel byproducts as safe, economical and useful agro-industrial materials. Despite that, the US ash industry is witnessing a steady growth in the volume of coal burned, along with the production of greatly refined, higher-quality ash particulates. There are two principal reasons for this. Economics have caused an increasing number of US electric utilities to convert from oil-burning to coal-burning. And the Federal government has tightened specifications on fly/bottom ash production quality. Hence, it must be noted that new and more stringent Federal regulations were implemented in 1980. The resultant ash particulates are finer, more compact, and less heavy than in previous years. Additionally, the first shift from oil to coal in the US was initiated in December, 1979 by the New England Power Co. in Massachusetts. Coal is the most widely-distributed fuel in the US. And it is found in 38 states. The wide availability of this fossil fuel and its general cost-efficiency, coupled with the undaunted move of US electric utilities toward nuclear power, are major factors affecting the current statistics on ash generation (65.4 x 106 million tons). Interest in the use of coal in power plants is creating a unique ash disposal and use situation for ash producers as well as the Federal government. There are growing quantities of fly/bottom ash residue. Ash producers must decide how this byproduct can be dealt with effectively and profitably. At the same time, government agencies such as the US Environmental Protection Agency (EPA), are commissioned by Congress to assure that solid, liquid, or gaseous material released into the environment is not harmful or offensive to human health and the environment. Additionally, the Federal government is often responsible for establishing and enforcing guidelines and standards governing the use of recycled materials. Several standards and guidelines governing the properties and use of ash in the US have been established by governmental agencies as well as by the ash industry itself. Of these, some have been developed for ash use by a specific federal agency. Others apply to the entire industry. The following is a brief identification of the major specifications for fossil fuel ash: • US Corps of Engineers - These specifications were first established in 1957. They delineate the physical and chemical requirement for pozzolans used in mass concrete. These specifications applied only to Corps of Engineers&apos; concrete construction projects for locks, dams, and other mass concrete projects until 1977. At that time, a joint effort between the American Society for Testing and Materials and the Federal government produced a modified specification that is now generally applied. The Corps of Engineers&apos; ash, however, retained certain aspects of its specifications for its own use, particularly in the area of handling and shipping fly ash to its own projects. Prior to transporting the fly ash to the corps, all potential sources for the ash must be inspected and approved as a supply source. All silos must be filled, sealed, and tested before the ash is released for shipment. The normal test period for the ash is seven days, although several testings may require up to 28 days. Once the fly ash has been released, it can only be shipped to US Corps of Engineers&apos; projects. All shipments are made with a government inspector present during loading. After a truck or railcar is loaded, the silo is resealed until the next shipment. This procedure requires three silos, and a minimum of 454 t (500 st) each should be considered for each storage unit. All silos are strictly committed to Corps of Engineers&apos; use and are not available for other commercial shipments. • US Bureau of Standards - This Federal agency maintains a standard testing sample of nearly every product used in the US. The accuracy of the fly ash chemical analysis is measured by a regular cement and concrete reference laboratory (CCRL) inspection and based on test results from a standard sample of cement. • US Bureau of Reclamation - This agency pioneered several projects using fly ash and required Federal Standard Certification for pozzolans. • American Society for Testing and Materials (ASTM) - This nongovernmental organization began preparing standards for fly ash sold and used in the cement and concrete industry in 1947, at the urging of ash marketing firms. Current standards define chemical and physical requirements and is entitled, "Fly Ash and Raw or Calcined Natural Pozzolan for Use as a Mineral Admixture in Portland Cement Concrete (C 618-80)." • State Highway Specifications - Led by Alabama, many states are moving toward permitting - and in some cases requiring-the use of fly ash in portland cement concrete and with lime for base stabilization projects for roads and highways. • Federal Aviation Administration (FAA) - The FAA acts in an advisory capacity. It has final approval on design specifications for airport construction projects. The agency has established a set of guidelines permitting the use of fly ash, and has approved several fly-ash-specific designs. The most current FAA fly ash projects

Jan 8, 1984

By L. M. English

A basic model has been developed to help assess methane control needs for longwall mining of coal in gassy areas. Rather than depending upon reservoir and rock mechanic theory, it uses an empirically-determined gas emission rate as an input and operates on the assumption that, within a specific region and zone, gas emissions will be relatively equivalent for uniform incremental volumes of gob created by mining. The computer program divides longwall panels into segments, keeps track of the face advance, and generates emission rates and volumes for both the entire panel and for individual zones within the panel by summing values for all undermined segments. This model can aid the determination of the number, size, and location of vertical wells or other methane control applications that are needed for gob gas control.

Jan 1, 1998

By Chi M. Phan, Anh V. Nguyen, Geoffrey M. Evans, Graeme J. Jameson

Surfactants are used to control the interfacial properties of the gas-liquid and liquid-solid inter- faces inflotation. This paper investigates the dynamic adsorption of surfactants at the gas-liquid intelface. The dynamic adsorption process was modeled by considering the surfactant mass transfer to the gas-liquid interface by dimion and the Langmuir and Frumkin adsorption isotherms. The numerical computation was applied to solve the non-linear governing equations. The dynamic adsorption was measured in tenns of the dynamic surface tension using the pen- dant drop method. The theoretical modek were compared against the experimental data obtained with non-ionic (Dowfroth 250) and ionic (sodium dodecylbenzene sulfate, SDBS) surfactants. The theoretical results agreed well with the erperimental data for SDBS, but not for Dowfrother 250, especially for the initial stage. Reasons for the variation in results are given in the paper.

Jan 1, 2005

By G. Brooks, J. T. Ellington, M. Yensco, G. E. Mcquien, M. T. Ityokumbul

Coarse silica flotation from intermediate pebble (IP) product has been carried out a pilot plant Dual Extraction Column (DEC) at an operational phosphate mine in Central Florida. The solids feed rate ranged from 4.16 – 5.3 TPH while the amine dosages ranged from 0.32 – 0.93 lb/T. The optimum amine dosage when using recycled process water was deter-mined to be 0.6 lb/T. With a feed containing 40-45 BPL and 38-45% insol, the results show that the IP can be upgraded to 56-61 BPL and insol of 16-22% at 85-90% BPL recovery. The results show that the DEC is an effective device for flotation of coarse silica from the IP. The advantages of upgrading the IP prior blending with the pebble are presented and discussed.

Jan 1, 2004

By V. R. Degner

Comments Summary It is very interesting to review the technical changes which have occurred in the industrial practice of minerals flotation over the past two decades. In 1972, worldwide industrial flotation was dominated by &apos;mechanical&apos; flotation machines having an individual cell volume less than 500 cu.ft. Manufactures, such as DENVER Eqpt. Co., OUTOKUMPU, WEMCO, GALIGHER (AGITAIR), AKKER, and later DORR-OLIVER, produced flotation machines featuring a mechanical rotating impeller which served to mix pulp and air, prior to flotation, and to keep the solid ore particles in suspension. While sharing this common mechanical impeller feature, the machine design of the various manufactures differed in detail; particularly in regard to the vertical location of the impeller in the cell and the means by which flotation air was brought into contact with the pulp within the rotor mechanism. A review of the existing technical literature in 1972 would identify academic research studies, particularly at Columbia University (N. Arbiter, C, Harris ...) aimed at comparing flotation cell design concepts, of the various machine manufactures, on a hydrodynamic basis. These research studies were confined to very small, laboratory bench size, flotation machines, and the benefits of incorporating hydrodynamic considerations in the scale-up of the existing 300 cu.ft. mechanical flotation technology to larger cells was not commonly practiced industrially. Technological advances in minerals flotation, over the past two decades, have been influenced by a variety of economic factors including the increasing development of lower grade ore bodies, the attractions of producing a higher grade final concentrate, and the economy of tails retreatment to improve overall plant recovery performance, and flotation system “optimization" became increasingly important through the 1970-80 time period. The trend toward processing lower grade ores led to higher tonnage mill operations, and stimulated the development of the very large capacity mechanical flotation machine for roughing and scavenging duty. In 1972, the 500 cu.ft. size flotation machine was being pilot tested and introduced to the industrial market. Today, 1993, individual cell volumes of 1500-3000 cu.ft. are operating successfully throughout the world, and well planned plant test programs have concluded that the very large flotation machine can achieve the same metallurgical performance level of its smaller predecessor. The large flotation machine development record clearly credits the incorporation of internal cell hydrodynamic considerations in guiding the scale-up of the mechanical flotation machine to large sizes. This guidance eliminated, or reduced significantly, costly in-plant prototype machine changes which increase Dramatically with increasing flotation machine size. Early in the 1980&apos;s, at approximately the time that flotation machines in the 1500 cu.ft. class were being introduced into the market, it became evident that the availability of the very large mechanical flotation machine brought with it the need for a systematic means to "optimize" the flotation system by relating flotation cell size, row length (i.e. number of cells per row), and flotation rougher, scavenger, and cleaner system configuration to the economic objectives of the concentrators&apos; operating management. Flotation system optimization consists of quantifying the flotation process performance using a suitable model which relates the kinetic response of the trace specie and the gangue material to the cell overflow, and produces a numerical relationship between product grade and value recovery. The computer analysis technique has proven to be an invaluable tool in determining the kinetic model coefficients which characterize a given application, and is also used to apply the resulting model to a proposed minerals beneficiation situation seeking to "optimize" the flotation system by relating metallurgical grade-recovery performance, flotation cell size, and circuit arrangement, to plant space, installation, and operating costs. It is interesting to note that these same computer based kinetic flotation analysis techniques can be easily applied to quantitatively evaluate the effect of different chemical reagent strategies, and flotation air transfer, on process performance for a variety of candidate feed ore types.

Jan 1, 1993