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By DING TANG, JINGHE CHEN, Shuiping Zhong, CHEN KUANG

The Zijinshan gold-copper mine, in spite of the low-grade nature of the ore, has become one of the largest production-scale and most profitable non-ferrous metal mines in China. The successful application of hydrometallurgy as well as proper engineering design are the key factors for large-scale development of the Zijinshan gold-copper mine. In this contribution, the practical experience acquired in the development of the Zijinshan gold and copper mines is summarized. This covers most aspects of the production process including mining, beneficiation, ore stacking, heap (bio)leaching, carbon-in-leach, solvent extraction, electrowinning, wastewater and tailing treatments. The authors believe that this practical experience will not only help to promote the development of hydrometallurgy, but can also serve as a model for other gold and/or copper plants around the world.

Jun 3, 2020

By Jack S. Watson, Rasika Nimkar, Robert M. Counce, BRADLEY BENNETT, Patrick Zhang

This study level process design represents an economically viable method for extracting thorium dioxide and other rare earth elements from monazite ore. This paper incorporates results from the 2019 capstone project from the honors Design Internship in Green Engineering in Chemical and Biomolecular Engineering. In this activity, senior students in Chemical Engineering at the University of Tennessee (UT) focused on the development and study of a process for the recovery of thorium dioxide and P2O5 from monazite. While not mandated, the process offers rare earth oxides as attractive byproducts. The project focused on recovery of byproducts rather than the creation or addition to waste streams. Additionally, (1) the process economics relied heavily on recovery of rare earth byproducts, (2) thoriumhandling portions of the process could be effectively segregated from rare earth and phosphate handling portions of the process, and (3) thorium and uranium content of waste streams should be carefully managed and eliminated where possible.

May 29, 2020

By Snehamoy Chatterjee, Sanjay Kumar Palei, Smarak Das

Machine manufacturers’ recommendations on maintenance strategies of capital-intensive draglines are not always based on real data and therefore lead to losses from downtime. This paper proposes a preventive maintenance strategy for a dragline deployed in an opencast coal mine based on reliability-centered maintenance and failure-mode-effects analysis using real operational data. Reliability-centered maintenance replaced a cluster of critical failure components of the dragline while satisfying two specific conditions: (i) the components should be replaced at the earliest mean time to failure (MTTF) within the group and (ii) the time taken to replace all the parts should be equivalent to the maximum downtime within the group. Estimated threshold weightage factor identified twenty-six critical failure components for the preventive maintenance strategy, and clustering of components divided them into nine groups. In a group, the loss that is expected to occur by replacing some of the components before their failure, and the gain by reducing the overall maintenance downtime, has been explained through a cost-benefit analysis. The total net profit generated is calculated as US$200,178. This clustering activity also led to a reduction of annual downtime by 231 h, whose approximate market price as equivalent coal production costs $295,365.

May 28, 2020

By V. Aghazadeh, E. Bidari, M. Aazami

In this study, mineralogical and microanalysis characterization, as well as diagnostic leaching and cyanidation tests, were performed to gain a better understanding of the refractory nature of the arsenical zone of a Carlin-type gold deposit and also to evaluate possible treatment routes to maximize gold recovery. The results obtained showed that only 56% of the ore’s gold content is amenable to direct cyanidation. The majority of the remaining gold was found as submicroscopic gold and in association with sulfide minerals, such as orpiment, pyrite, and sphalerite. It was also found that despite the abundance of silicate and carbonate minerals in the arsenical zone, they do not play a key role in the refractory nature of the ore, and gold can be liberated from such minerals by appropriate grinding. The analyses further revealed that orpiment dissolves readily during cyanidation, and this dissolution retards the kinetics of gold extraction. Pyrite and sphalerite were generally found to occur in fine network texture and in association with quartz. Flotation of such auriferous sulfides may be difficult due to their oxidized surface. Fine grinding (−20 μm) was found to be partially effective in improving gold extraction.

May 28, 2020

By George Saratsis, George Exadaktylos

In the marbel industry, ore reserves refer to the produced tonnage of orthogonal prismatic, defect-free blocks of commercial sizes and of marketable aesthetical quality. On the contrary, in the mining sector, ore reserves refer to the tonnage of ore with grade above some cut-off value. While in the mining sector ore reserves are reported according to existing standard guidelines, the marble industry has no standardmethod. The purpose of this paper is to present a method to estimate white marble reserves using drill coring or borehole wall logging and limited joint mapping on exposed marble surfaces. Data pertaining to fracture orientation, fracture frequency, size, and whiteness were collected. The primary phase of marble characterization is followed by the discretization of the orebody into a three-dimensional array of orthogonal prismatic blocks, where the marble whiteness and fracture intensity are attribute values. Both these variables are considered to obey continuous and not discrete probability distributions. The discretization is performed using computer aided design and the Block Kriging techniques. An outline to improve the description of a given marble ore deposit at the exploration stage is presented for the prediction of marble block size distribution from joint count measurements along diamond drill cores. An example case of a white dolomitic marble quarry is used to demonstrate these methods.

May 27, 2020

By Herry Poernomo, Agus Prasetya, Iga Trisnawati, Himawan Tri Bayu Murti Petrus, Gyan Prameswara, Panut Mulyono

We studied yttrium extraction from untreated zircon sand processing waste tailings. Xenotime mineral as the rare earth element source with an abundance of yttrium (REY) was detected in sufficient grade for extraction. As much as 9.03% yttrium exists in zircon tailings (analysed by X-ray fluorescence spectrometry). The presence of yttrium was confirmed by X-ray diffractometry in xenotime minerals, which are yttrium carriers (Y-PO4). The purpose of this research was to determine the effect of leaching conditions on yttrium recovery from zircon sand after alkaline fusion treatment. Alkaline fusion was chosen to decompose phosphate into hydroxide in the xenotimemineral,which will reduce further required hydrometallurgical processing.Alkaline fusionwas carried out for 3 h at 450 °C, with a ratio of sodium hydroxide to zircon tailings sand of ~ 1:1. The alkaline fusion product was leached with water, followed by hydrochloric acid treatment to leach the yttrium. Yttrium recovery reached 87% under optimum conditions (60 °C, 1MHCl, and solid-to-liquid ratio = 1/10 for 7.5 min). A suitable model for yttrium dissolution with hydrochloric acid was diffusion through a solid particle ash layer. The calculated activation energy (EA) for this model was 20.21 kJ/mol.

May 26, 2020

By Thomas Novak, Sampurna Arya, Joseph Sottile

Dust generation and its dispersion in a longwall mine pose significant health and safety issues. The concern is prominent at both the working face, where coal excavation exposes workers to high dust concentrations, and also in the return, where float dust accumulates. To address this issue, researchers at theUniversity of Kentucky designed and fabricated a flooded-bed dust scrubber integrated into a full-scale physical model of a longwall shearer. This mock-up was installed in the longwall test gallery at the Pittsburgh Research Laboratory (PRL) of the National Institute for Occupational Safety and Health (NIOSH). A full-factorial experiment was designed to measure the effectiveness of the scrubber on dust capture. Test results indicated dust reduction of up to 57% in the return airways. This paper presents the development of a computational fluid dynamics (CFD) model and its validation by comparing the simulation results against the experimental results. The CFD simulations show good agreement with experimental results with differences between + 6.9 and − 9.7%. The validated CFD model was used further to predict the scrubber performance under additional operating conditions, resulting in a dust reduction of up to 66.5%. With this level of success, the scrubber concept can be a game changer for the mining industry, and it can be utilized to improve health and safety in longwall mines.

May 26, 2020

By Ana Chiquini, Clayton V. Deutsch

The most common approach used in the mining industry for mineral resources modeling is to estimate the grades using ordinary kriging and report the recoverable resources based on this deterministic estimated model. Mineral resources calculated with kriging are a smooth representation of the actual distribution of grades and do not provide an assessment of uncertainty. Unlike kriging, simulation reproduces the variability of the grades in the mineral deposit and provides an assessment of uncertainty. Reporting mineral resources directly on high-resolution simulation results would assume perfect knowledge of the grade at the time of mining and selectivity at the scale of the data. There will always be uncertainty left at the time of mining, so assuming perfect knowledge of the grade in the future is incorrect. There are two concerns when geostatistical simulation is used for resources modeling: the information and the mining selectivity effects. A new framework for resource estimation is proposed with two separate modules to address those concerns. The information effect is accounted for by anticipating the additional production data that will be available at the time mining to guide the destination for the mined material. The mining selectivity effect is addressed by mimicking the grade control procedure to get mineable dig limits at a chosen selectivity, represented by a minimum mineable unit size. In addition to a prediction of recoverable resources that will be closer to the material mined in the future, the framework proposed provides an assessment of local and global uncertainty for risk management.

May 26, 2020

By QINGXIANG CAI, Lin Li, PENG LIU, IZHAR MITHAL JISKANI, XIANG LU, Wei Zhou, YONGLI ZHOU

The concept of green mining is to improve the mining industry in a holistic way so that it is safe, efficient, and environmentally sustainable. The purpose of this study was to develop an evaluation index system of green surface mining based on the theory of green grades. The evaluation model is comprised of three attributes (safety, efficiency, and environment), nine criteria, and 35 indicators. The fuzzy comprehensive evaluation method was used to determine the weights of indicators by taking into consideration degree centrality, closeness centrality, and betweenness centrality. Findings indicate that the environment is the most critical aspect of green surface mining, followed by efficiency and safety. The top five ranked green mining success indicators were the application of new technology, starting-off-rate of equipment, science and technology input to total investment, the number of accidents (decreased), and the production (increased). It was observed that more improvements are needed to overcome water, air, waste, and sound pollution. Attention should also be paid to land reclamation and post-mining land uses, which are key factors in green mining. The proposed model can be applied to evaluate and improve the level of green surface mining in other regions. This study provides a tool for decision-makers that can offer technical assistance to green mining.

May 26, 2020

By Marcelo de Oliveira, Antoine Allanore, Dennis P. Chen, Davide Ciceri

Potassium fertilizers (potash) are mined in a handful of countries in the Northern Hemisphere. Potash is either expensive or unavailable to the farmers of the Southern Hemisphere. Alkaline alteration of K-feldspar rock (ultrapotassic syenite) in autoclave in the presence of Ca2+ generates a mixture of K-bearing calcium-aluminum-silicate-hydrate (C-A-S-H) minerals that potentially can be used as an alternative local fertilizer. This work investigates the effect of processing temperature (200 °C, 220 °C, and 230 °C) and time (from 0.5 to 3.0 h) on pH, mineralogy, and elemental availability of the C-A-S-H mineral mixture. Increasing temperature results in an increased conversion of K-feldspar and increased content of both the mineral tobermorite (Ca5Si6O16(OH)2·4H2O) and amorphous phase in the resulting C-A-S-H mixture; increasing time results in an increased conversion of α-dicalcium silicate hydrate into tobermorite. The amount of K leached from the mixture is relatively constant across all processing conditions. Hydrothermal alteration in autoclave of K-feldspar-bearing rocks such as ultrapotassic syenite permits the synthesis of a potential potassium fertilizer which alkalinity and mineralogy can be tailored according to soil requirements.

May 22, 2020

By Feridon Ghadimi, Saeed Mojeddifar, Massume Khavari

Separation of geochemical anomalies from background is an important and essential issue in the exploration of mineral deposits. Statistical methods are used to separation of anomaly from background. Fractal/multifractal and singularity methods are very suitable for the separation of weak anomalies. For interpolation, various methods could be used such as most distance-weighting methods, kriging, spline interpolation, interpolating polynomials, and finite difference methods. This paper addressed application of multifractal techniques together with finite difference procedure to detect the anomalous regions. Fractal models such as concentration–area, spectrum–area, and singularity index model were selected to identify Pb–Zn anomalies. In this research, 170 samples from 33 boreholes were taken in the Haft-Savaran area and analyzed for determination of Pb–Zn anomaly. Singularity method was a suitable method for separating Pb and Zn anomalies. Also, the results showed that the geochemical anomaly has occurred along NE–SW trend and is consistent with the sulfide mineralization process and the faults of the region.

May 18, 2020

By Kwangmin Kim, Junnhyeok Park

In the hard-rock mining industry, the generation of fines during blasting is an important issue because it has a significant effect on production processes. Although various approaches have been used to estimate fines generation in recent decades, as a practical matter, measuring the amount of fines is nearly impossible given the technical limitations and the scale of mine blasts. In this study, a dynamic PPV damagemodel was developed and applied to predict fines generation as a result of blasting. This modified version of the crushed zone model (CZM) considers dynamic rock properties and peak particle velocity (PPV), which represents the induced stress in blasting. Dynamic rock-fracturing tests were conducted using a split Hopkinson pressure bar (SHPB) to determine the parameters that represent the relationships between rock strength and strain rate as well as the relationships between fines amount and strain rate in the model. A case study was conducted that entailed determining the radius of the crushed zone for given blast designs and rock properties and then measuring the fines amount within this crushed zone. This case study indicated that the dynamic PPV model can provide a rough estimate of fines generation for given dynamic rock properties and blast design parameters and that this method has the potential to be a useful indicator, or index, of fines generation.

May 16, 2020

By Nikhil Dhawan, Sanjay Pindar

The limited lifespan, ever-growing demand, and significant lithium and cobalt content are responsible factors for the immediate recycling of discarded lithium-ion batteries. Discharged batteries were dismantled, segregated, and size reduced to recover cathode and anode material. The active cathode material comprises LiCoO2 (65.8%) and LiMn2O4 (34.2%) and was carbothermal reduced with recovered graphite in a microwave furnace followed by water leaching and magnetic separation. A Box Behnken statistical experimental design is used for process optimization. Both cobalt and manganese report to magnetic fraction, whereas graphite and lithium carbonate report to non-magnetic fraction and solution crystal respectively. The final product comprises of cobalt 73% and manganese of 14% with process yield of 36% and saturation magnetization of 76 emu/g.

May 16, 2020

By MAHESH SHRIWAS, CHRISTOPHER PRITCHARD

Ventilation monitoring and control in mines are becoming an integral part of day-to-day activity for maintaining health and safety of miners. The authors evaluate potential real-time monitoring solutions for detecting and reducing diesel particulatematter, mine fires, and dust in situ, and examined the state-of-the-art use of ventilation monitoring and control in underground mines for detecting and reducing air contaminants to acceptable regulatory limit. Authors review relevant documents, including research papers, trade publications, and manufacturers’ website-based information, to identify research gaps. The authors also evaluate contemporary sensors (airflow, gas, dust, silica), control system and software technologies, data transport systems, Industrial Internet of Things, ventilation network simulators, and control devices to identify potential health and safety research gaps. In this study, examples of some mines from Canada, Australia, and the USA are included where ventilation monitoring and controls have been applied. Overall, this review identifies multiple challenges and research gaps in applying mine monitoring and control systems that could be the focus of future research, offering potential improvements to miner safety and health and financial benefits.

May 12, 2020

By Muhammad Zia-ur Rehman, Sajjad Ahmad Baig, Gao Lei Fu, Muhammad Mohsin, Sobia Naseem

The environmental sustainability is linked back to human sustainability; the sustainability development comprises the environment, society, and economics. This study mainly focused on mining sustainability and its impact on the environment of Pakistan. For measuring the level and environmental mining sustainability nature to Environmental Impact Assessment (EIA) of the world’s second largest salt mine “Khewra,” Folchi and Phillips environmental sustainability mathematics (PESM) models are applied. The results indicated that Khewra was deemed to be potentially sustainable for the environment and quality of salt. The results suggest the delicate balance of maintaining sustainability successfully, regarding the mining process in Pakistan which has been affecting the local environment and community so badly. The paper lays emphasis on the potential significance of the model’s application for the attainment of sustainable mining goal. This study is essential for researchers,

May 11, 2020

By K. Muralidharan, P. R. Rao, M. Momayez, K. A. Runge

The evolution of trapped geothermal heat in hot underground mine along with emission of toxic gases and dust during mine activity makes the mine environment unfavorable is hazardous to worker’s health. This imposes significant demand on cooling and ventilation systems. As a result, substantial costs are incurred while implementing environmental regulation processes to dissipate the heat and provide comfortable working conditions. Thus, as an alternative, the development of cost effective materials to act as efficient thermal insulators is on the rise. Thermal conductivity is an important property that is a direct measure of a material’s ability to facilitate/deter heat flow. In addition to their superior chemical resistance, adequate mechanical strength, abrasion and fire retardant as well as environmental benefits in comparison to existing building materials such as ordinary Portland cement, aluminosilicate based geopolymers are now gaining widespread interest as promising thermally insulating and sustainable materials. This paper begins with an overview of geopolymers, transitioning into a discussion of recent developments in the field of geopolymer development as a thermally insulating material broadly classified into: filled geopolymers and porous geopolymers resulting in structures with enhanced ability to impede heat flow.

May 9, 2020

By Martín A. Encinas-Romero, GUILLERMO TIBURCIO-MUNIVE, María M. Salazar-Campoy, Patricia Guerrero-Germán, José R. Parga-Torres, Luis S. Quiróz-Castillo, JESÚS L. VALENZUELA-GARCÍA

Pressure oxidation is a hydrometallurgical oxidative pretreatment for refractory ores, such as sulfide ores. Here, simultaneous alkaline pressure oxidation and sodium cyanide leaching treatments were carried out on a pyritic ore from the Mulatos Mine located in Sahuaripa, Sonora, Mexico. Mineral characterization, agitation leaching, hot cyanidation under atmospheric pressure conditions, simultaneous moderated pressure oxidation and leaching, and kinetic testing results are shown. The modified variables were temperature, pressure, and cyanide concentration. Characterization indicated that pyrite was the main mineral. Simultaneous pressure oxidation and leaching experiments were conducted at a temperature range of 40–80 °C, oxygen pressure of 87.5–200 psi, and cyanide concentration of 0.8–1.2 wt% in a 2-L Parr pressure reactor. A dissolution rate of 81–86% was achieved under the following conditions: 87.5 psi, 80 °C, 0.8 wt% NaCN, for 1 h.

May 7, 2020

By Göksel Hızlı, Selim Ertürk, Ayşegül Bilen, Raşit Sezer, Cüneyt Arslan

The carbothermic reduction of celestite is the first step in producing many strontium products. The way materials move in the rotary kiln has an essential effect on the carbothermic reduction efficiency as well as the temperature. In this study, the reduction of celestite ore and excess carbon blend in a laboratory-scale rotary kiln was investigated. In the experiments carried out at three different temperatures, the rotational speed and slope of the furnace tube were altered, and their effects on the reaction efficiency were examined. The leachability of the reduced powders and the content of the unburned coke indicated the optimal parameters for the reaction.When the speed was increased to 10 rpm, the powders weremoremobile in the stack and could react more easily with the furnace atmosphere. According to the results, celestite can be reduced by carbon at temperatures of 1000–1200 °C, at rates of between 5% and 75%. The maximumreaction yield (75%) was obtained with a slope of 2° and a rotational speed of 6 rpm at 1100 °C.

May 7, 2020

By Li Zhang, Jing Zhao, Chuanwei Zang, Shuanlin Wang

The application of gob-side entry retaining (GER) in steeply pitching seam longwall mining with a hard roof has always been a difficult problem. Based on the simplified roof beam mechanical model, the traditional gob-side entry retaining by packing (GERP) roof structure evolution process and its problems with use in steeply pitching seams are analyzed. Therefore, based on the unique characteristics of the gangue rolling and accumulating in the steeply pitching seam, this contribution proposes an innovative method of gob-side entry retaining by roof cutting (GERRC) in steeply pitching seam and details its technical process. The roof structures of the GERRC and the GERP are compared. Taking the Chang Gouyu Coal Mine as a case study, field experiments were carried out. This research finds that the GERRC can both overcome the impact of rolling gangue on roadside support and make the rolling and stacking gangue become a roadside support. The roof structure of the GERRC is in a one-time statically indeterminate state, which is conducive to the stability of the roadway. In the field test, the total displacement of the roadway roof and floor is 97 mm, the supporting pressure of the serried single props is less than 28 MPa, and the props have no obvious bending phenomenon.

May 6, 2020

By A. M. Anthony, A. Y. Atta, S. S. Magaji, U. Abubakar-Zaria

There are two major gold recovery methods: the hydrometallurgical technique, which employs cyanide solutions, and amalgamation method, which involves mercury (Hg). These methods present considerable health, safety, and environmental concerns. Past applications of alpha-cyclodextrin (α-CD) on gold scraps show that α-CD is not only inexpensive, but is also environmentally friendly. This research work used α-CD to recover gold from gold ores instead of gold scraps. The gold ore was sourced from Shanono gold deposit site Kano State,Nigeria. The gold ore was characterized by fire assay (FA) for the precious metal. The concentrate was digested with aqua regia (AR) for 24 h. Modified AR, where hydrochloric acid was replaced with hydrobromic acid, was used for the gold digestion due to the good match in molecular recognition between gold bromide ion (AuBr)− and α- CD in a second sphere coordination complex. The digestate was characterized using atomic absorption spectroscopy (AAS). Gold recovery using this technique is pH sensitive, and five pH values (2.0, 3.6, 4.0, 5.4, and 6.0) were investigated. FA analysis showed the Shanono gold ore deposit contains an average of 4.71 ppm of gold, AAS analysis showed highest gold recovery of 69% at pH 4.0, which is lower than recoveries from the metal scraps. This could be due to the presence of other gangue minerals closely associated with the ore. However, gold recovery using α-CD on Shanono gold ore has shown to have a higher yield of 69% compared to 35.5% yield obtainable by Artisan Small Scale Miners using mercury.

May 5, 2020