Search Documents

By Brij M. Moudgil, Shoulian Zhu, J. L. Pinault

A new technique, prompt neutron activation probe (PNAP), for analyzing phosphate rock slurry in-situ was evaluated both in the laboratory and at the plant. The technique yielded a high precision in the analysis of Ca, Si and H using 252Cf source. Low accuracy of the direct measurement of P using 241Am/Be in the laboratory tests was attributed to the interference of rare earth elements present in the samples, particularly Gadolinium. No significant effect of variables such as solids loading, particle size distribution, and flotation reagents was observed on the probe performance. The probe can detect the compositional changes of the feed, tailings and the concentrate streams in the plant.

Jan 1, 1993

By M. S. Celik, G. Onal, S. Atak, A. A. Abramov

An oolitic phosphate ore composed of phosphate (mainly francolite) and carbonates as gangue has been tested for the suitability of the reverse flotation process. The samples were first ground autogeneously followed by the reverse flotation process. While the carbonates were floated by sodium oleate the phosphate was depressed by phosphoric acid. The effect of particle size, reagents type and concentration on flotation recoveries have been investigated to determine the optimum conditions. By this process, a run-of-mine ore containing 16.72 % P205 was upgraded to 28.00% P205 with a recovery of 77.0% The mechanism of optimum flotation with phosphoric acid observed at pH 6.3 is explained based on a relationship involving surface potentials and the ratio of required collector concentrations for the respective minerals.

Jan 1, 1993

By George P. Demopoulos, Vladimiros G. Papangelakis, Dimitrios Filippou, A. J. Monhemius, G. W. Warren, E. Peters

A new method developed for the estimation of the activity of Ht in mixed sulfate solutions is described and examples of application of this method to the system H2SO4-ZnSO4-FeSO4-Fe2(SO4)3 from 298 to 473 K are offered. The method makes use of an "extended Debye-Hiickel" type of equation that was originally put forth by Das for pure H2SO4 solutions at ambient temperature. The treatment of mixed sulfate solutions was made possible by combining that equation of Das with a speciation algorithm which calculates the abundance of all species formed. The developed method, which also takes into account ionic strength and temperature effects, was used to generate hydrogen ion activity and speciation data for all possible acid/metal sulfate pairs of the system H2SO4-ZnSO4-FeSO4-Fe2(SO4)3. Finally, under the light of the reported data, specific examples of hydrometallurgical reaction systems are analyzed in terms of thermodynamics or kinetics. In particular, the systems discussed are: hydrometallurgical precipitation of hematite, solvent extraction of Fe(III), acid leaching of zinc ferrite, and oxidation of Fe(II) to Fe(III) by O2(aq).

Jan 1, 1993

By A. S. Malicsi, Vathsala Rajagopal, I. Iwasaki

Corrosion and abrasion properties of a series of chromium-containing, cast-iron balls, with Cr contents ranging from 0% to 29%, were evaluated and compared with austenitic stainless-steel and mild-steel balls. Marked ball wear tests were performed on artificial ore samples consisting of 95% quartzite, with either 5% pyrrhotite or 5% chalcopyrite, under a nitrogen or oxygen atmosphere. The electrochemical mechanism was investigated by correlating the corrosive wear with the corrosion currents obtained from potentiodynantic polarization curves under abrasion. Flotation recoveries were determined on a 95% quartzite + 5% pyrrhotite sample ground with various cast-iron ball materials under an oxygen or nitrogen atmosphere. Electrochemical results are found to be in good agreement with flotation results and with corrosive wear data obtained from marked ball wear tests.

Jan 1, 1993

By J. Hanna, R. Kalathur

Over the years, Alabama's coal industry has generated, during mining and cleaning operations, about 150 million st of fine waste coal, with this total increasing at a rate of 2 million stpy. Reclamation of the fine-size wastes (containing 20% - 60% clean coal by weight) provides, free of charge, mined and crushed feed stocks for coal recovery. Also, the removal or recovery of pyrite from the tailings should eliminate a major source of acid-water pollution. Tests were made on the impounded wastes and current plant discharges to recover the coal fraction by sizing, gravity and flotation techniques. Gravity separation of the +100-mesh material produced commercial-grade coal averaging 7.6% ash, 0.8% sulfur and 13,471 Btu/lb. However, the coal yield, at about 31 % - 56%, was relatively low. Froth flotation, using mechanical and froth column methods, gave similar coal products at much higher coal recovery rates of 87% - 93%. This coal analyzed 10% ash and 1.1% sulfur.

Jan 1, 1993

By Thomas J. Feeley

The US Department of Energy (DOE) is supporting the engineering development of three advanced physical coal cleaning technologies: selective agglomeration, advanced flotation and advanced cycloning. Each is capable of significantly reducing the pyritic-sulfur content of US coals. The objective is to provide the coal and electric-utility industries with a cost-effective option for addressing the SO, emission reductions required by the 1990 Clean Air Act Amendments (CAA). A secondary objective is to evaluate the potential of advanced coal cleaning for removing trace elements that are precursors to the formation of hazardous air pollutants (HAS). The proposed National Energy Strategy (NEE) and the 1990 CAA lay a foundation for a more efficient and environmentally sustainable energy future (1991). The need to use energy resources in an environmentally sound manner presents critical challenges and opportunities for coal preparation during the next decade, particularly regarding the control of SOS and HAY emissions. The principal challenge is the development of cost-effective coal preparation approaches for sulfur and HAY precursor removal.

Jan 1, 1993

By M. J. Richards, T. X. Ren

Determination of the state of an underground fire plays an important role in fire fighting, rescue and reopening operations. This is normally achieved by the analysis and interpretation of fire gases taken from the fire zone. However, drawing conclusions from gas analysis is not an easy task and needs specialist skills, expertise and experience that are usually beyond the knowledge of the officials in a mine. The complexities of a mine fire and the uncertainties of available information often make effective fire fighting decisions difficult if not impossible. This paper describes a knowledge based expert system that can aid in the diagnosis of sealed coal mine fires. Using a commercially available shell, the expert system has been designed to accommodate a series of diagnostic rules replicating the reasoning logic that would be used by human experts. The system allows the diagnosis of explosibility of the fire zone and trends of various fire ratios to be easily visualised for decision making. By continuously analysing the incoming information, the system is able to provide a rapid assessment of the situation of a sealed mine fire prevailing under specific mining and geological conditions. In addition, short term trends in fire behaviour can be predicted and possible fire control actions recommended. An example is given and shows how this system can be used as an analytical tool in various ways to assist the combating of coal mine fires. Further development of the system is discussed.

Jan 1, 1993

By S. Todd Mickleborough

The geostatistical technique of conditional simulation is applied to measure the uncertainty in factor of safety predictions for soil slopes where there is incomplete knowledge of the spatial distribution of soil properties. A case study considers a natural clay slope in Canada. The sequential indicator simulation technique is used as a means for generating a series of spatial maps of soil properties for this site. These maps approximate random draws from the conditional probability density function that characterizes existing uncertainty in the spatial distribution. Factor of safety determinations are then made for each simulated map using the simplified-Janbu approach, where the computations are performed with a new computer program that can operate on irregular spatial profiles of soil properties specified on a discrete grid. A unique capability of this approach is the ability to generate the distribution of factor of safety conditional to the type, position, and value of existing site characterization measurements. This capability should reduce uncertainty in FS predictions.

Jan 1, 1993

By III Feeley

The U.S. Department of Energy is supporting the engineering development of three advanced physical coal cleaning technologies--selective agglomeration, advanced flotation, and advanced cycloning--capable of significantly reducing the pyritic-sulfur content of U. S. coals. The objective of this activity is to provide the coal production and electric-utility industries with a cost-effective option for addressing the SO2 emission reductions required by the 1990 Clean Air Act Amendments. A secondary objective is to evaluate the potential of advanced coal cleaning for removing trace elements that are precursors to the formation of hazardous air pollutants. This paper will summarize the status of the three advanced physical coal cleaning engineering development projects.

Jan 1, 1993

By G. L. Simmons

Aqueous pressure oxidation at low temperature, although desirable from a process engineering and operations point of view, presents unique problems when temperatures approach 160°C (320°F). In developing the pressure oxidation process for the Lone Tree Mine, elemental sulfur formation and agglomeration with pyrite proved to be a problem. This paper discusses some of the unique features of the Lone Tree sulfide deposit and its amenability to low temperature oxidation. Problems encountered during pilot plant operation and their solutions are discussed.

Jan 1, 1993

By J. R. Sturgul

Computer simulation models of working mines can be of great benefit to the mining engineer. Such models have been used in mine planning (how many trucks/shovels to have, when to add new equipment, etc.), mine design (should a dispatch system be purchased, where is the optimum location for mine equipment, etc.). A simulation model can be thought of as a dynamic representation of the mine and can easily be changed to reflect a wide variety of different situation. Often a major problem for the engineer is how to present the results of the simulation study. Using PROOF(R) animation it is now possible to interface the results of the simulation and project them onto a computer screen in cartoon fashion.

Jan 1, 1993

By R. H. Weiland

The dewatering of flocculated clay suspensions by compression in a centrifugal field has been investigated. The results are evaluated with regard to both direct applicability to centrifugal dewatering, in solid-bowl centrifuges for example, and indirect applications to gravity sedimentation systems. It is well known that sediment consolidation under gravity depends on structural characteristics such as permeability and on the "self-weight" of overlying sediment layers. An important objective of the study has been to evaluate the self-weight effect using centrifugal forces to simulate consolidation in deep sediments. In this way, small-scale laboratory tests can be used to predict the rates and limits of sediment compression in industrial systems such as thickeners and settling ponds. Experiments have been conducted in which the sediment mass and initial structure were maintained constant while the effective sediment weight was varied by centrifuging at different speeds. The effects of initial structure have also been studied using controlled variations in flocculation conditions.

Jan 1, 1993

By K. Dagdelen

The definition and shortcomings of traditional cutoff grades are discussed. The concept of optimum cutoff grade policy which maximizes the Net Present Value (NPV) of annual cash flows coming from a mining project is introduced within the basic framework outlined by K. F. Lane. Several examples are used to demonstrate the shortfalls of cutoff grade policies obtained by various heuristic optimization techniques. An algorithm to obtain an optimum cutoff grade policy which maximizes the NPV of a project is given and described in detail.

Jan 1, 1993

By A. B. Cecala

The Bureau of Mines performed a study to determine optimal locations for longwall face methane monitoring equipment. Longwall face ignitions continue to be a concern to the U.S. coal mining industry. Gains in ignition control technology have been somewhat negated by advances in longwall productivity. More reliable, heavy-duty longwall face systems generate higher production rates and increase methane liberation rates. These rates will likely continue to rise in the future as further coal production increases occur. Efforts will continue in the areas of methane drainage, methane containment, and methane dilution. In addition, more effective face methane monitoring is needed. As technology continues toward automated longwall panels, the importance of monitoring for methane at the shearer becomes even more significant. Since the primary face ignition source is the shearer mining machine, the Bureau ran tests to determine the best location to take methane readings on the shearer. This information, in conjunction with data obtained from field studies, provides a knowledge base for selecting optimum face methane monitoring locations.

Jan 1, 1993

If a fire occurs outby an underground coal mine section, the immediate safe evacuation of miners from the working section should always be the first action during the rescue operation. Unfortunately, in many cases, the escape-ways (escape routes) dedicated for miners' evacuation are contaminated with fire byproducts from adjacent entries. The purpose of this paper is to present the ventilation control process that will maintain the escape-way free from contaminants and available for travel. Several scenarios in a different section on ventilation system arrangements are analyzed, discussed and presented. To perform these studies, the author used a mine-fire simulator, which provides a dynamic (in real time) representation of the fire's progress and also gives a display, a color-graphic visualization, of the spread of combustion products throughout the ventilation system. Presented and discussed in this paper, also, are ways in which the mine-fire simulator can be used as a training and teaching tool for miners and, particularly, for ventilation and safety personnel.

Jan 1, 1993

By S. S. Peng

A well designed mining plan is one which minimizes the cost and the mining induced problems and maximizes the recovery of the coal reserve. In order to minimize the negative effects on surface structures caused by ground subsidence process due to underground mining activities, two kinds of practices are commonly employed by the mine operators. One is the support techniques which leaves an area of coal un-mined or partially mined beneath the structure to be supported. The other is the protection techniques which protect the structure when it is subsiding with ground taking advantage of the ground subsidence process (Luo et al., 1992). In designing the supporting techniques, the only currently available method in the U.S. is the one stated in the Pennsylvania Underground Coal Mining Rules (1985). However; The size of the support area designed by this method will be excessively large resulting in wasteful use of coal reserve when the overburden depth is more than 350 ft. A more scientific method is proposed in this paper for de-signing the support area. This method is based on a large amount of subsidence data collected throughout a number of major U.S. coal fields and the authors' experience with monitoring and protecting surface structures undermined by longwall panels. It considers the critical deformation in-dices that a structure can tolerate, and depth and height of underground extraction. The support area designed by this new method will not only assure the safety of the structure to be supported but also maximize the extraction of the coal reserve.

Jan 1, 1993

By A. W. Khair

This paper presents an analysis of the dynamics of bit wear on the productivity of the continuous miners. Two field surveys have been carried out. The first survey was to assess the impact of bit wear on productivity and production cost. The second survey was to study the wear characteristics of the cutting tool (i.e. magnitude, forms, and mechanisms of bit wear). Primary factors affecting bit wear is identified and laboratory experiments were carried out to study the effects of some of these primary factors on wear in detail. Results indicate that bit wear has a significant effect on the productivity of the continuous miners. Furthermore under the severe geologic conditions (i.e. cutting rock partings and roof and floor rocks) bit wear not only hampers the productivity, but also increases the production cost due to a higher number of bit consumption. This study also indicated that bit wear accelerates beyond 20% of the conical height loss which corresponds to 7% of the weight loss. This increase rate of wear is an indicative of higher abrasion between bit body and cutting material, resulting in a dustier environment.

Jan 1, 1993

By Y. Guan

The adsorption of zinc species onto silica in ammonical solutions has been studied. Adsorption isotherms reveal that increasing adsorption occurs as the solution pH is made more alkaline. Fr-IR spectroscopy revealed that the adsorbed species is a zinc ammine complex.

Jan 1, 1993

By M. L. Smith

SAG mill throughput is often a bottleneck in increasing metal productivity. Improved size distribution control in the mill feed can be used to increase mill production. This can be accomplished by controlling blast fragmentation as a function of energy input and rock characteristics. Such an approach requires the integration of rock fragmentation and comminution modeling. The optimal mill feed size distribution is determined by adapting a population balance comminution model to a measure of rock hardness or fragility which is also relevant to the rock fragmentation that is achieved by blasting. The relation between the size distribution and fragility of the feed and of the mill's product and the critical size in a SAG mill is examined.

Jan 1, 1993

By X. P. Zheng

Barium fluorphlogopites were synthesized in the laboratory in order to investigate the effects of composition and crystal parameters on surface properties and floatability. The negative surface charge of mica is determined by the barium content, the crystal cell volume, the distance between layer structure and the Ba-O bond length. The higher barium content, the larger the cell volume and distance between the layer structure and the longer the Ba-O bond, the more negatively charged the surface is and hence the more easily adsorbed to cationic collectors. When an anionic collector (sodium oleate) is used, barium oleate forms on the mica surface and hence chemical adsorption occurs.

Jan 1, 1993