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By J. R. Thoenen

[Before 1914 Germany held virtual monopoly on the world supply of potash for fertilizer purposes. During the world War, potash shipments to the United States ceased, and recourse was had to domestic supplies. High war-time prices stimulated interest n various sources, and domestic production increased rapidly. At the close of the war, resumption of shipments from Germany and other sources reduced prices to below pre-war levels, and, as a result, most of the domestic producers ceased operational.]

Jan 1, 1941

By Steven J. Page

Since 1982 standard calibration materials recommended for respirable crystalline silica analysis by the Mine Safety and Health Administration (MSHA) P7 Infrared Method and the National Institute for Occupational Safety and Health (NIOSH) X-ray Diffraction (XRD) Analytical Method 7500 have undergone minor changes in size distribution. However, a critical assumption has been made that the crystalline silica in ambient mine atmosphere respirable dust samples has also remained essentially unchanged in particle size distribution. The objective of this work, therefore, is to compare recent particle size distributions of underground coal mine dust and the silica component of these dusts with estimated aerodynamic particle size distributions of calibration standard materials MIN-U-SIL 5, Berkeley 5, and SRM 1878 used by two crystalline silica analysis techniques. This work provides resolution to a previously reported discrepancy involving the proper sample dilution for the particle sizing method used. Dust impactor sampling data for various locations in 13 underground coal mines were collected between 1991 and 1998 and analyzed for the respirable mass median aerodynamic diameters. The data suggest that the MSHA P7 Method will underestimate the silica content of the sample by at most 8.5 % in the median size range of 0.9–3.6 µm and that it is unlikely one would obtain any significant error in the MSHA P7 Method analysis when the method uses Berkeley 5, MIN-U-SIL 5, or SRM 1878 as a calibration standard material. The results suggest that the NIOSH Analytical Method 7500 would be more appropriate for a dust sample that is representative of the total (no cyclone classifier) rather than the respirable airborne dust, particularly since the mass fraction in the size range below 4 µm is usually a small percentage of the total airborne dust mass. However, the NIOSH Analytical Method 7500 is likely to underestimate the silica content of an airborne respirable dust sample by only 5–10 %. The results of this study also suggest that any changes that may have occurred in the median respirable size of airborne coal mine dust are not significant enough to cause any appreciable error in the current methods used for respirable crystalline silica analysis.

Aug 3, 2005

By McClelland. John J.

This Bureau of Mines report discusses recent applications of water in-fusion technology to control dust in U.S coal mines and presents recommended guidelines for determining coal seam infusibility. The techniques required to use water infusion are presented in detail. A Bureau case study indicated that water infusion reduced dust levels by 68 pct along a longwall plow face, bringing this section into compliance with the Z.0-mg/m3 Federal dust standard. Similar studies conducted by Occidental Research Corp. under a Bureau contract show water infusion at two longwall double-drum shearer operations produced dust reductions ranging from 38 to 50 pct. Water infusion was found to be cost effective, aver-aging 5 cents per ton.

Jan 1, 1987

[In selecting deposits for exploration projects, tabular deposits or large mineralized masses are favored because they may be explored systematically and because they afford the best opportunity for blocking out reserves in advance of mining whereas irregular, small pipes and scattered]

Jan 1, 1941

By Larry A. Haas

The U.S. Bureau of Mines, in cooperation with Cleveland-Cliffs, Inc. (Hibbing, MN), investigated ways of enhancing the quality (compressive strength, after-tumble and reducibility) of domestic acid and fluxed magnetite pellets by modifying the oxygen content during the preheat and induration periods of the firing operation . Oxidation of magnetite was best accomplished when sufficient oxygen and time were available before the peak induration temperature was reached. The rate of magnetite oxidation increased directly with the gas oxygen content during the preheat period at 7000 C and above. With 30 pct ( or more) O2 and a preheat rate of 2000 C/min, most of the magnetite was oxidized during the preheat period. With laboratory tube and mini-pot furnace tests, oxygen enrichment during the preheat period improved the pellet properties more in the simulated grate-kiln tests than in the simulated straight-grate tests. The longer induration period with the grate-kiln test resulted in more sintering of the residual magnetite and its reaction with the silicon compounds. When flux was present in the pellets, calcium silicates and calcium and magnesium ferrites were formed. More calcium ferrite was formed when the magnetite was oxidized early and less iron was present in the fayalitic calcium silicate slag.

Jan 1, 1993

By Joseph J. Wallace, William H. Tavenner, D. A. Reynolds, John M. Provost, James J. Dowd, R. F. Abemethy

"CONCLUSIONSThe investigation shows that there are 5 coal beds of major importance in Wyoming County from the standpoint of present production - Pocahontas No. 3, No. 2 Gas, Sewell, Beckley, and Eagle - and 5 beds of minor importance - Pocahontas No. 6, Cedar Grove, Winifrede, Douglas, and Chilton. The Pocahontas No. 3 bed contains the largest remaining known reserves.Known measured and indicated reserves in all beds, based on a minimum thick¬ness of 14 inches and on 1,800 tons per acre-foot of coal in place, are estimated at 2,665 million short tons as of January 1, 1951. Of this total, 2,121 million short tons is in beds 28 inches and more thick. Areas in each bed were omitted from the estimate because available data relative to the bed characteristics are too meager to make an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.Recoverable reserves of coal have been estimated in beds 28 inches and more thick. This thickness is about the minimum now being mined by hand loading onto conveyors in the Appalachian region. The weighted average recovery for all beds in Wyoming County, as determined by this investigation, is 55.0 percent. This percent¬age is based on the total thickness of coal (less partings 3/8 inch or more thick) in the bed rather than on the thickness of the coal mined. The known recoverable reserves are estimated to be 1,167 million tons as of January 1, 1951.4. Since most of the Wyoming coals are medium- and low-volatile bituminous in rank and expand during carbonization in modern ovens, they are blended with high-volatile contracting coals."

Apr 1, 1953

By Frank L. Hess

In 1876 cassiterite was identified in the placer gold from the northern Black Hills, and such a mixture could have come only from Nigger Hill or one of the streams draining the hill, because in no other part of the northern hills have cassiterite and gold been found together. Nigger Hill is in western Lawrence County, South Dakota, and on it is the little camp of Tinton. The Wyoming line runs along the west side of the hill and crosses the ridge which is the hill's continuation about miles north-northwest of Tinton.

Jan 1, 1938

By Donald W. Fausett

This Bureau of Mines publication presents a system of thermal decompositions providing an adequate description of the mechanism of oil shale pyrolysis. Specific rate constants for systems of thermal decompositions studied are estimated via a least-squares procedure. The estimates thus obtained provide a mathematical model of the corresponding thermal decomposition system. A model that generates a good fit to published Bureau of Mines experimental data, in comparison with other models studied, is based on a thermal decomposition system consisting of two first-order reactions and three second-order reactions. Values computed for the specific rate constants corresponding to this system are shown to exhibit a temperature dependence that is in good agreement with the Arrhenius equation.

Jan 1, 1974

Relatively few longwall mines in the U.S. operate under multiple seam conditions where the two seams are less than 200 ft apart. This paper describes the experience of six that do. These operations are located in PA, WV and UT, and include examples of both undermining and overmining. Some operate above or beneath their own workings, others are in historic mining districts and must contend with abandoned mines that are decades old. The lessons that these mines have learned cover a broad range of topics, including: • Whether to stack gateroads or place them under old gob areas; • How to size pillars and select artificial support to cross longwall stop lines; • How to use yield pillars to minimize multiple seam stresses and coal bump potential, and; • When to anticipate the creation of pathways for gas, water, or oxygen between current and abandoned gobs.

By C. M. McCulloch

As part of the Bureau of Mines methane control program, the Pittsburgh coalbed was studied in Washington and Green Counties, Pa., and in Marion and Monongalia Counties, W. Va., where this coalbed is now being mined at its greatest depth. The coalbed thickness appeared to be structurally controlled; the bed was generally thinner near the axes of anticlines and thicker near the axes of synclines. The overburden isopach shows a similar relationship. Most of the clay veins in coal occur in the synclinal troughs, generally under sandstone roof. Cleat orientations measured in 18 underground mines showed that face cleats are perpendicular to the axial trends of the folds, and the butt cleats are parallel to the axial trends, indicating structural control of the cleat. Measurement and analysis of surface joint orientations provide a method for predicting the cleat orientations of the coalbed, but linears measured from infrared photographs and photoindex sheets helped only to determine regional trends. The results of these investigations provide a geologic framework for rational planning for underground mine development to use the best available technology to cope with methane emissions, coalbed discontinuities, and related ground support problems.

Jan 1, 1975

By T. W. Smelser

This Bureau of Mines report presents a review of underground testing, test results, and design guidelines of steel-fiber-reinforced concrete (SFC) mine support (cribbing) developed at the Spokane Research Center. The objective of the work was to verify, in field applications, the performance, economics, and acceptance by the mining industry of the SFC supports and establish design guidelines for their use underground. Results indicate superior performance, favorable economics, and enthusiastic acceptance by the mining industry.

Jan 1, 1983

Engineering controls for overburden drilling include dry dust collection systems, wet dust suppression systems, and enclosed cabs [Zimmer and Lueck 1986; Volkwein et al. 1979]. Proper maintenance of the dust suppression system is critically important for drills using dry dust suppression methods. Failure to rigorously maintain these systems will result in inadequate dust control. Acute silicosis has been reported in miners operating equipment that relies on dry dust suppression [NOSH 1992].

Jan 1, 1997

By H. E. Hilliard

A method was investigated for detecting and counting filamentous iron bacteria in open recirculating cooling systems. It is simple and fast and does not require trained microbiologists. Samples from 26 systems were examined. Cells were cultivated on commercially prepared ready-to-use media. Cultures grew well on this medium and were identified as filamentous iron bacteria by microscopic examination and by their ability to deposit iron using the prussian blue reaction.

Jan 1, 1976

By Michael Schmitz, Eugene Ahrenholtz, William A. Heitbrink, Jeanne A. Zimmer, Andrew B. Cecala, Ernest S. Moyer, Earle H. Andrews, Chris C. Coppock, John A. Organiscak

Many different types of surface mining equipment use enclosed cabs to protect equipment operators from health and safety hazards. The overburden removal and mining process can be extremely dusty and can cause excessive dust exposure. To study this issue, a cooperative research effort was established between the National Institute for Occupational Safety and Health, U.S. Silica Co., Clean Air Filter Co., and Red Dot Corp. in an effort to lower respirable dust levels in an enclosed cab on an older surface drill at a silica sand operation. Throughout this research effort, a number of modifications were incorporated into the drill's filtration and pressurization system, as well as in other areas, to improve its design and performance. An average cab efficiency of 93.4% was determined with gravimetric sampling instruments when comparing the outside with the inside cab dust levels on the final design. Although this study considered just one operation, the goal was to identify cost-effective improvements that could be implemented on all types of enclosed cabs to lower respirable dust concentrations. Two critical components for an effective enclosed cab system are having a properly designed, installed, and maintained filtration and pressurization system, along with a method for maintaining structural cab integrity, which allows the cab to be positively pressurized. Another important component is maintaining cab cleanliness. Although this research was originally directed toward the mining industry, it is also applicable to agricultural or construction equipment.

By Edward J. Chuhta, Joseph E. Chilton, Robert J. Timko

in underground mines to measure worker exposure to various gases such as methane, carbon monoxide, and nitrogen dioxide (NO2). Even in relatively small concentrations, NO2 can produce harmful side effects in underground workers. Mines using equipment powered by diesel engines, carrying out explosive blasting operations, and performing extensive arc welding and/or cutting work will have measurable quantities of NO2 released by these processes. Workers in these areas often use gas monitors to warn of excessive gas concentrations and to help them determine when to increase ventilation air that will dilute these gases, thus minimizing exposures to this gas. Portable gas monitors, used to measure NO2 levels, must be calibrated before each use. Calibration is typically performed using a small portable pressurized cylinder containing a certified gas mixture. The certified NO2 standard mixture, usually 10 ppm NO2 concentration, is diluted with either air or nitrogen gas. To determine the stability of commercially available portable gas standards, two different cylinders containing NO2 in nominal 10-ppm concentrations were examined. One cylinder was diluted in air, the other, in nitrogen. Baseline NO2 mixtures were generated using a standard liquid NO2 permeation tube operated at a constant temperature. Final dilutions of the test gas mixtures were made with air or with nitrogen using a mass flow-controlled gas dilution system. This study showed that, when a permeation-type NO2 generator is used, the electrochemical sensors in portable NO2 monitors provide identical results for gas mixtures whether they are diluted with air or with nitrogen. Two different gas monitors, one with a two-electrode sensor and one with a three-electrode sensor, were used to measure gas concentrations in the two commercially available cylinders. One month after the cylinders were delivered, the NO2-in-nitrogen cylinder, stated to contain 10 ppm NO2, measured 8.13 ppm. The NO2-in-air cylinder, also stated to hold 10 ppm NO2, measured 6.88 ppm. Therefore, before using NO2 gas cylinders to calibrate monitors, it is recommended that their concentrations be verified either by manufacturer recertification or by comparing the stated cylinder gas concentrations to a laboratory-based permeation tube-generated standard.

Dec 1, 2005

By Nicholas Kyriazi

A joint effort by the U.S. Bureau of Mines (USBM) and the U.S. Mine Safety and Health Administration (MSHA) was undertaken to determine how well self-contained self-rescuers (SCSR's), deployed in accordance with Federal regulations (30 CPR 75.1714), held up in the underground environment with regard to both physical damage and aging. This report presents findings regarding laboratory-tested SCSR's in the fourth phase of testing from 1989 to 1993. The SCSR's were tested on human subjects and on a breathing and metabolic simulator (BMS). These results indicate that most of the apparatus, if they pass their inspection criteria, perform as expected except units with manufacturing defects. However, when the apparatus are carried in and out of the mine daily and stored at the working section, they may suffer abuse. Physical signs of abuse, unless extremely obvious, are frequently not detected by the miners or mine operators. In addition, some apparatus collected for this study had not been returned to the manufacturer in a recall effort for correction of a manufacturing defect. In both cases, the apparatus would have presented problems in emergency use. Recommendations include improved training in inspection procedures and better enforcement of recall notices.

Jan 1, 2010

By T. G. Mayhew, A. A. Bergeron, R. J. Mahany

This report describes an operational communications system which provides remote intra-terrestrial wireless transmission of environmental information. Design and modification specifications of requisite equipment are included along with a detailed description of system operation

Jan 9, 1976

By R. Unger, L. Mallett

The use of virtual reality (VR) technologies to train miners is an evolving area in research and development. In July 2006, representatives of 14 international organizations met to discuss current VR-related efforts and explore ways to employ VR in the future. This paper gives an overview of the various approaches presented at the meeting and discusses directions for future implementation. An example of a training package that teaches mine map-reading skills is presented. The meeting was the first step to building collaborations for furthering VR applications for mining. Planning has begun for a 2008 meeting open to broader participation. Disclaimer: The findings and conclusions in this report are those of the authors and do not necessarily represent the views of the National Institute for Occupational Safety and Health.

By Kenneth H. Johnston

Information on oil and water production, volume of water injected, core analyses, and well completion data was collected on 28 Red Fork sand water-flood projects for comparison and evaluation of results. An average water injection efficiency of 35 percent, an average water-injected to oil-produced ratio of 16.8:1, and an average loss outside the flood pattern of approximately 45 percent of the injected fluid resulted in an oil recovery to January 1, 1969, of only 5.6 percent of the pore volume, or 9.1 percent of the initial stock-tank oil in place. The principal causes of poor oil recovery from these projects are the losses of large quantities of injection water from the flood patterns through oriented, natural fracture systems or zones of high permeability and excessive channeling of injection fluids from input wells to oil wells. For more efficient operation and a higher percentage of oil recovery from the Red Fork sand and other low-permeability-sand waterflood projects, directional orientation of both induced-and natural-fracture systems should be determined during early development. The success of a low-permeability-sand waterflood project depends to a large extent upon the orientation of the injection wells with the fracture system.

Jan 1, 1970

By G. T. Fisher

The U.S. Bureau of Mines conducted research on calcium ferrite slags to determine the distribution of Pb and minor elements (Ag, Cd, Zn, and Co) between Pb bullion and slag. These fundamental data are required to evaluate nonferrous smelting with calcium ferrite slags as a substitute for conventional iron silicate slags. Determinations were made in 25-cm3-capacity MgO crucibles at 1,250° C for 2 h in a CO-CO2 atmosphere with an O2 potential that would retard the formation of magnetite. Calcium ferrite slag composition variables studied were from 16 to 32 wt pct CaO in 2-pct increments and Si02 ranging from 1 to 5 wt pct in 1-pct increments with equal additions of MgO. For all compositions studied, the retention of Pb in the calcium ferrite slag was less than 1 wt pct, which compares favorably to about 6 wt pct Pb in conventional iron silicate slags used in smelting of Pb concentrates. Minor element distribution was insensitive to changes in slag composition in the range studied. However, slag composition had significant impact on the melting and fluidity of the slag.

Jan 1, 2010