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By J. Dong

"Xanthate is a sulfide collector that has been widely used in flotation for almost a century. It is inexpensive, easy to synthesize and apply, and produces good metallurgy in the right applications. However, a major drawback of xanthate is that it decomposes easily and generates CS2 gas in transportation, storage and operation, which can be harmful to human health. Also, excessive xanthate in tailings pond leads to toxicity of the process water and potential damages to aqua-life systems. New regulations in Ontario require that the TWA (time-weighted-average) value of CS2 in the work place is below 1 ppm, which is 1/10 of the previous limit. The stringent regulation may eventually sweep other regions of Canada with the increased awareness of healthy working conditions and environment protection. Therefore, it becomes very important to find xanthate replacements which will be “green”, i.e., environmentally friendly.In this research work, a systematic procedure is used for collector evaluation using the Sudbury nickel sulfide ores from Vale’s Ontario operations, starting with the collector properties (MSDS) evaluation, followed by batch flotation tests, miniplant tests, plant trials and economic evaluation. It is found that the most promising xanthate replacement is dithiocarbamate.INTRODUCTIONSulfide mineral flotation has been practiced since the early 20th century. Its industrial importance is well recognized as mineral concentrates from flotation can be economically smelted and refined to provide primary metals. Collectors play a vital role in froth flotation. There are reagents possessing both a polar group that binds them to the mineral surface and a nonpolar group that is oriented away from the surface to attach air bubbles. The introduction of xanthate as a sulfide collector in 1925 was a remarkable development in froth flotation (Keller, 1925). It is low cost, easy to synthesize, water soluble, simple to control in application. Most importantly, it has strong capability and usually good selectivity for sulfide mineral flotation, which have been keeping its application prominent for almost a century."

Jan 1, 2011

Gold recovery from refractory ores can be very difficult and complicated depending on the causes of the refractoriness. Typically, a fine wind and/or the oxidation of the gold-bearing sulfide minerals are required to liberate gold from the host rock matrix. Mineral separation techniques, particularly surface¬wettability based separation (i.e., flotation) and magnetic separation, can be used to pre-concentrate the gold and sulfide minerals, or to remove mineral species that are harmful either to the oxidation of the gold-bearing sulfides or to the cyanidation following the oxidation. In this paper, several processes are described, including oil-agglomeration flotation recovery of fine-grained gold and sulfide, reverse flotation of carbonate minerals prior to pressure or bio oxidation, reverse flotation of elemental sulfur after pressure or bio oxidation but prior to cyanide leaching, and magnetic concentration of gold-bearing iron oxides. The integration of these techniques with gold hydrometallurgical processes may make the economic recovery of gold from an otherwise uneconomic refractory ore possible.

Jan 1, 2011

By S. Mathieu, R. Mennillod-Blondin, P. Cousin, N. Valle, H. Bouzahzah, P. Marion

The gold deposit of the Lapa mine has a complex mineralogical gold state with coarse and fine native gold, aurostibite and submicroscopic gold within arsenopyrite. A specific mineralogical characterization of the refractory fraction was conducted combining various techniques such as optical microscopy, electron microscopy, electron microprobe and secondary ion mass spectrometry. In parallel, the mineral processing behaviour and the recovery of the refractory gold were studied by pressure oxidation and cyanide leaching. This paper presents the mineralogical methodology developed to characterize the refractory gold distribution within arsenopyrite. These results are presented and interpreted in order to plot gold recovery versus sulphide oxidation. The comparison of the metallurgical behaviour yields predicted from the mineralogical data and the one calculated from leaching tests shows a good agreement and allows mineralogical explanations of the gold metallurgical behaviour.

Jan 1, 2011

By J. Mirza, E. Nicol, J. Lipkowski

Gold passivation in thiosulfate leaching media is a major barrier to its implementation. Addition of Cu (II) into the leaching solution has shown to aid in gold dissolution, but the mechanism by which it acts, and its role in the passive layer, remains unknown. Surface Enhanced Raman Spectroscopy (SERS), in tandem with linear sweep voltammetry, were employed to determine the dependence of leaching currents on mass transport and for fingerprint identification of sulfur species on the surface of gold. SERS leaching experiments were performed using gold nanorod electrodes that showed increased stability compared to other SERS active surfaces.

Jan 1, 2011

By A. Warczok, C. M. Diaz, A. Bergman, T. Utigard, M. Barati

The world wide consumption of energy is steadily increasing and by 2030 it is forecasted to grow by another 50%, leading to mounting political and economic pressures. For any pyrometallurgical operation, it is therefore paramount to investigate and implement methods to decrease the use of energy. In the pyrometallurgical processing of steel, copper, nickel and other high temperature metals, a large amount of energy is lost in hot off-gases, molten slags, mattes and molten metals. Most of this energy is generally lost during the cooling and solidification steps with very little focus on energy recovery or reuse. In this paper we will quantify how much energy is contained in the various slag streams, then review previous attempts and methods employed to recover some of this energy, and finally evaluate some novel technologies that could potentially be employed.

Jan 1, 2011

By T Nakamura, M. Itoh

Most of the used cathode ray tube (CRT) glass in Japan, which contains lead oxide, was exported and recycled in overseas factories of new CRTs. However, domestic treatment and recycling of waste CRT glass has become necessary because overseas CRT factories have shut down and exports of CRT glass have stopped. Some of the waste CRT glass recycled domestically is charged in lead blast furnaces instead of silica flux, because there is no local reproduction route for glass that contains lead. However, the mass of CRT glass that can be treated in this manner is limited because of its high silica content. Consequently, additional treatment methods for waste CRT glass are required so that more can be used as a lead smelting material. In this study, waste CRT glass was treated with hydrofluoric acid to dissolve the silica contained in the glass, and the dissolved lead was recovered by precipitation. Lead metal was recovered by electrodeposition from the prepared hexafluorosilicic acid solution.

Jan 1, 2011

By \/eena Sahajwalla, Alexander Blagus

This paper reports the effect of using High Density Poly-Ethylene (HDPE)/coke blends on the reduction behaviour of Mn3O4 to MnO at 1000°C. The results suggest that CH4 release increases with increasing HDPE addition. The results show that the rapid release of methane, over only the initial five minutes, limited the interaction of Mn3O4/MnO with CH4. With the devolatilisation of HDPE there was increased porosity in samples containing HDPE, assumed to be the major factor in differences of reduction rates.

Jan 1, 2011

By J. G. Peacey, G. Csicsovszki

The target of this study was to clarify the role of lead on the dissolution of gold in the (NH4)2S2O3-Cu leaching system via chronopotentiometry, linear sweep voltammetry and chronoamperometry. It was found that the dissolution of gold was significantly increased with lead concentration up to 10 mg/1 Pb in the system of 0.1 M (NH4)2S2O3 and 50 mg/1 Cu. \/oltammograms suggested that the anodic dissolution of gold was virtually independent of lead concentration in the range of 1-10 mg/1 in 0.1 M (NH4)2S2O3 solution while in solutions containing copper as well, addition of lead increased the anodic dissolution of gold.

Jan 1, 2011

By P. Leo

Al-Mg-Si alloys are widely used as medium-strength structural materials; extrusion is the most common processing route. In the present hot deformation investigation of a 6060 alloy, the microstructure of the alloy has been analyzed in the as-cast state, after homogenization heat treatment and after hot deformation by tensile tests in the range 400-490°C and 10-4 to 10-2s-1 on both as cast and homogenized alloys. After deformation the microstructure of the as-cast alloy exhibited cavitation. The flow curves at the lowest test temperature T show a gradual softening after a stress peak, being more evident for the alloy deformed in the homogenized state in association with a high yield stress; at higher T a plateau is attained which is lower as T rises and strain rates decrease. For each fixed T, the ductility decreases as strain rate increases for the homogenized alloy whereas, for the as cast alloy, it rises with strain rate. Constitutive analysis gives Q = 240kJ1mol for the homogenized alloy in agreement with published values; this indicates a more rapid strength decline with rising T than Al, suitable for good hot workability along with the lack of cavitation.

Jan 1, 2011

In-Situ Leaching (ISL) process plants are low cost producers for uranium deposits where the geology is suitable. In the 1970s, a three-year pilot ISL program occurred on gold ore from the Ajax Mine, Cripple Creek District, Colorado, using a chloride and iodide solution [1]. The test was halted due to poor results. With gold and silver the international ISL progress has been slow; however the potential for low capital expenditure (CAPEX) and operating expenditure (OPEX) with large low grade deposits is real. Unless the metallurgy has been demonstrated there are significant risks which could be fatal flaws to an ISL gold or silver project. The metallurgy of gold ISL projects is far from simple and it is early days with project development.

Jan 1, 2011

By Y. Zedan

In this study, the statistical design of experiments (DOE) was applied to study and regulate the properties of near-eutectic Al-11%Si alloys. Develop regression equations for such response variables as hardness, yield stress, ultimate tensile stress, percent elongation, total cutting force, cutting power, and tool life together with other factors which, include the percentage composition of the alloying elements, and the requisite modification (Sr) level. These equations may be analyzed quantitatively to acquire an understating of the effects which the main variables and their interactions may have on the mechanical behaviour and the machinability of the alloy under investigation. The results reveal that increasing the levels of Cu and Fe content results in an increase in hardness, yield stress, and ultimate tensile strength in both modified and non-modified alloys. On the other hand, both Cu and Fe appear to affect the percentage elongation adversely, whereas the Sr-level has a positive effect on this parameter. It was found that Sr-levels have the most significant effect on the cutting forces and cutting power followed by the content in Fe and Cu. The results also reveal that the interaction coefficients of these variables have a significant effect on tool life compared to the main independent variables. This fact may be attributed to the formation of complex insoluble phases between Cu, Fe, Si, and Al as investigated using Scanning Electron Microscopy (SEM) attached to an EDX analysis system. The accuracy of the regression equations in predicting the expected properties has been verified by carrying out random experiments in the range of variation of these variables.

Jan 1, 2011

By Catalin Florin Petre, Elahe Ghasemian Langeroudi, Abdelaaziz Azizi, Éric Proulx, Caroline Olsen, Paul Blatter, Faïçal Larachi, Claude Gagnon

"The recovery of gold from ores is often accompanied by the release of other species in the leach solution. This state of affairs leads to depleted free cyanide levels in the slurry. Therefore, separation and quantification of these cyanicides and free cyanide at different stages of the cyanidation process as well as in waste solutions is crucial to provide mitigation tools by preventing leaching of deleterious metals for environmental considerations.COREM and the research group of Prof. Larachi have been working together on the control of gold passivation and cyanicides during cyanidation for several years. Previously, a first capillary electrophoresis (CE) protocol for the speciation of sulfur and cyanicides (SCN-, Cu, Fe) during cyanidation of gold complex sulfide ores was developed and validated for assessing industrial process water.The separation of zinc cyanide complexes used to be confronted with a number of difficulties due to the weak and/or undetectable cyanocomplexes in formally available CE protocols. Moreover, according to our knowledge, no direct CE protocol exists to separate free cyanide. Therefore, a new study aimed at developing a second CE protocol for the detection and quantification of cyanide complexes of zinc and nickel as well as of free cyanide in the cyanidation process water.To achieve this goal, six common carrier electrolytes such as pyridine, trimellitic acid, 4-methylbenzylamine, sodium chromate, phthalic acid and tris base were studied, using an indirect UV detection method. The best results were obtained using sodium chromate for which all ions were successfully separated and quantified. In addition, the effect of electric field strength, injection volume, electro-osmotic flow (EOF) modifier and background electrolyte (BGE) concentration were examined, while peak height, peak area and noise were considered for optimization.As a result, the new protocol is expected to complete the initial CE protocol by detecting cyanide complexes of zinc and nickel as well as free cyanide. Moreover, analytical determination of free cyanide in the presence of weak cyanide complexes achieved by the new protocol was also compared to conventional titration using silver nitrate solution. This new CE protocol will contribute to applied research and help plants to better understand and eventually control the behaviour of cyanidation circuits."

Jan 1, 2011

By G. Van Weert

In the spring of 2010 double refractory ores from historical stockpiles were processed through Barrick's Goldstrike pressure oxidation facility, thereby providing preg robbing feeds for a variety of metallurgical testwork. This paper describes the effects of amount, type, place and time of addition of activated carbons on CIL gold recovery and shows that native carbon in plant PDX'ed discharge solids can still preg rob gold loaded activated carbon.

Jan 1, 2011

To determine the optimal circuit configuration for gravity gold recovery consideration should be given to a range of factors in addition to the efficiency of the gravity circuit, including capital costs, ease of operation and impact on comminution. The most common gravity gold circuits utilise a centrifugal concentrator treating a portion of the hydrocyclone underflow. This paper will examine this option and alternative circuit configurations to illustrate the effect of various gravity circuit feed and tailings configurations on the equipment sizing, capital costs, operating costs, water balance, comminution efficiency and gravity gold recovery. The optimum circuit configuration can provide reduced capital and operating costs, maximise gravity gold recovery and improve comminution efficiency.

Jan 1, 2011

By S. Kelebek, E. Yalcin

This paper reports bulk flotation characteristics of a pyritic gold ore sample from the Barry District, Quebec using isopropyl and amyl xanthates. The ore sample was highly floatable with particles showing tendencies for self-aggregation that was most apparent in the first stage of flotation. A possible reason for this is discussed. The gold concentrate grade-recovery performance with respect to the particle size is presented for the rougher-scavengers as well as for the cleaners. The effects of copper sulphate as an activator, fuel oil and NaSH as a sulphidising agent are discussed along with the recovery by size behaviour.

Jan 1, 2011

By F. Nava-Alonso, A. Uribe-Salas, C. Rodriguez-Rodriguez

Ozone has been proposed to pretreat refractory ores before the cyanidation process for precious metals extraction. As pyrargyrite is one of the silver species most common in Mexican refractory ores, the ozonization of this silver sulfide was studied. The effect of pH and ozone concentration on silver dissolution was evaluated by means of a factorial experimental design. Two levels of sulfuric acid concentration and ozone in gas concentration were evaluated: 0.18 and 0.72 mol/L of acid and 0.054 and 0.077 gO3/L, respectively. The highest silver dissolution was obtained when using the higher acid and ozone concentration.

Jan 1, 2011

By J. Kouam

Al-Si-Cu and Al-Si-Mg alloys are widely used in several applications. Although they can be produced near-net-shapes, products made of these alloys very often require some machining. The purpose of this study is to evaluate the machinability of A319 and A356 under TO and T6 conditions. The machinability was assessed using during dry drilling machining process and the machinability indexes used are the chip form, the chip breakability and the cutting forces. It is found that 319 and 356 exhibit different machinability behaviors, especially in the T6-condition in terms of forces requirements, chip breakability and chip segmentation. It is also found that both the microstructure of the workpiece materials and the machining conditions significantly affect the chip formation mechanism, and therefore, the machining parameters could be selected to promote a chip form that is easily manageable in production.

Jan 1, 2011

By P. J. Sylvester, S. J. Piercey, S. Maloney, S. M. Brueckner, L. Pilgrim, D. Hyde, G. Ogilvie

The 1806 zone is part of a Au-rich volcanogenic massive sulfide deposit at the Rambler Camp on the Baie \/erte Peninsula, northwestern Newfoundland, and is characterized by high Au grades (3.97 g/t), relatively low Cu and Zn grades (0.60 wt% Cu, 1.17 wt% Zn), and moderate Ag grades (27.83 g/t) at ca. 0.37 Mt ore. Gold and Ag occur as electrum and different Ag varieties including Ag-Hg ± Au alloys, miargyrite, and pyrargyrite that occur often in close proximity to electrum. Additionally, Ag-, As-, Sb-, and Sn-bearing sulfosalts are frequently observed and usually close to electrum. These textural relations strongly favor a syngenetic/magmatic origin for the 1806 zone, despite having a metamorphic overprint.

Jan 1, 2011

By K. Hawboldt, J. E. Halfyard, C. Bottaro

The removal of sulfur from leach residues has been practised in the zinc industry using a combination of flotation and hot melt filtration. The process is highly dependent on the nature of the concentrate and the subsequent residue. When the mineral constituency of the residue alters, the process can encounter significant operational challenges. An alternate method of converting elemental sulfur to water-soluble polysulfides was applied to leach residue from Vale's nickel demonstration plant in Argentia, Newfoundland. Reaction parameters, sulfur purity and other key indicators are discussed as is the potential commercial application.

Jan 1, 2011

By J. Pepin

When using alternating current submerged arc welding (SAW) to produce pipes from microalloyed linepipe steels, it is critical to balance penetration depth and deposition rates, in order to minimize the number of weld passes while still maintaining good heat affected zone (HAZ) microstructures and properties. A series of bead-on-plate (BOP) submerged arc welds were performed on X70 steel, using different waveform variable settings (i.e., balance, offset and frequency). Weld bead cross-section profile deposition and penetration areas were measured, and both Vickers hardness and Charpy V-notch impact testing were performed. Both single electrode and tandem electrode welds were evaluated.

Jan 1, 2011