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By Wei Ye, Lei Li, Xianjian Guo, Feng He

The purpose of the paper is to study the smelting process of copper concentrate with high Cu/S ratio produced in Africa or other areas around the world and theoretically analyze the influence of slag type on the smelting process. The paper has compared the processes used successfully in smelters, including CAPEX and OPEX and other factors, to provide reference for the industry to select the best process under specific conditions. INTRODUCTION At present, a great amount of copper concentrates with high Cu/S ratio, with chalcocite being the major source of copper, have been produced or are about to be produced in the Copperbelt in Africa and other countries in the world. The copper concentrate is usually high in copper (~30–55wt.%) and low in sulfur (~10–15wt.%). The conventional processes of smelting-converting and roasting-leaching-electro-winning for treating this type of concentrate is high energy and materials consumption such as electric power\fuels\flux et al. The direct-to-blister (one-step) smelting process can be considered favorable due to a reduction in processing steps. Up to now, there are four copper smelters in the world operating with the direct-to-blister smelting process. There certainly are problems in the process such as high copper content in the slag, strict operation requirement of slag cleaning electric furnace, etc. Except technical issues, the impact of factors on economical aspect such as power and material cost needs to be considered comprehensively in process selection. In this paper the technical issues of direct-to-blister smelting process, including slag treatment process, were analyzed and the comparison to the conventional processes and economic analysis of direct- to-blister smelting process to treat high Cu/S ratio concentrate were done.

Jan 1, 2019

By Robert A. Bosschart, Harold O. Seigel

"Most electromagnetic methods presently used in mining exploration are of the moving source type; i.e., the primary field source is moved simultaneously and in a fixed configuration with the receiver. Of the fixed-source methods, which employ a stationary primary field and a moving receiver, the Turam method is the most effective and has marked advantages over alternative electromagnetic methods. The results are little affected by topographic relief, and a high degree of resolution can be obtained because of the constant relation between source field and investigation area. Another inherent advantage of the Turam configuration is that it provides more favourable dimensional relations. Thus, the primary field attenuates at a much lower rate than in moving-source configurations and, secondly, the method is size sensitive; i.e., conductor size affects the strength of the response, which is not the case with moving-source methods. These factors result in a considerably better potential depth penetration."

Jan 1, 1966

By H. Lorenzen, D. Buyze

"Magnesium-bearing salts occur in the Zechstein Basin in the north eastern part of the Netherlands at a depth of 1500m to 2500 m.Exploration results justified the exploitation of these salts by means of solution mining for the production of refractory grade magnesium- oxide. This paper discusses design criteria, operation parameters, and methods used for magnesium chloride solution mining by Noordelijke Zoutwinning B. V. (NOZO), an operating company of Billiton International Metals B. V.A unique variation of widely used solution mining techniques has been developed for mining the complex Veendam salt deposit. NOZO extracts salt through deviated wells with a set of parallel, suspended tubings. Cavern fluid pressure is maintained close to that of overburden rock. These special design features provide an answer for the complex characteristics of the minerals, halite, carnallite, bischofite and kieserite, from which a solution rich in magnesium is generated. Dissolution chemistry and rock mechanical behaviour of these salts are unlike those of rock salt. Throughout a few years, NOZO demonstrated adequate process control while they continue improving the operation.IntroductionBilliton, a wholly owned company of the Royal Dutch /Shell Group of Companies, is active in metal exploration, mining, processing, and trading, mainly in the non-ferrous sector.Since 1972 Billiton has been active with solution mining magnesium salts in the northeastern part of the Netherlands, in the Province of Groningen, near the city of Veendam . Solution mining techniques were developed in conjunction with the ""Koninklijke/Shell Laboratorium Amsterdam"" (KSLA) and the ""Koninklijke/Shell Exploration and Production Laboratorium"" (KSEPL), Rijswijk. The company's objective is to produce magnesia sinter (MgO) from magnesium-chloride brine (MgClz) and de-carbonated dolomite (CaO.MgO). The magnesia produced serves as base material for the manufacturing of refractory bricks, used for furnace linings in the steel industry."

Jan 1, 1986

By K. Mayhew, A. Lossin, H. Salomon-de-Friedberg

"The proportion of arsenic-bearing copper concentrates that supply the copper industry is on the increase. The current strategy of miners and smelters to blend feeds to reduce average arsenic levels is rapidly becoming unsustainable as more concentrates with even higher arsenic levels enter the marketplace. In addition, the capability of smelters to manage increasing arsenic levels to more stringent and restrictive environmental standards is limited by available process technologies.CESL Cu-As Technology is a viable technical and economic alternative to traditional smelting. It offers the advantage of simultaneous leaching and precipitation of the arsenic in a single processing step while achieving high copper extractions. The process has been piloted in six separate, fully-integrated pilot campaigns for feeds ranging from ~1% to 12% arsenic in concentration. This paper will focus on the behaviour of arsenic in CESL’s leaching/precipitation step and operational factors that influence it, and on the chemical and physical characteristics of the subsequent iron-arsenic residue that represents today’s best available technology from a long-term sustainable (capital/operating costs, metal recovery, safety, environmental) perspective.The examples provided will demonstrate copper extractions approaching 99% and arsenic deportment to residue of 99%. Instantaneous settling rates of the residue were measured at 15+ m/hr. Data from subsequent short and long-term stability testing of the residue confidently support the view that the scorodite-bearing residues from the process will be stable and provide an acceptable arsenic management practice. The technology offers increased revenue and environmental certainty for miners, smelters & refiners to support the development of metallurgically challenged copper-arsenic deposits. Furthermore, results will be presented demonstrating the technology’s ability to successfully incorporate hazardous arsenic containing smelter by-products such as dust into the process feed and simultaneously extract copper value while fixing the arsenic in a stable residue."

Jan 1, 2016

By A. E. Wraith, R. Harris, J. Qiu, R. Parra

Small pilot scale experiments have shown that it is possible to almost fully eliminate the minor elements (ME), namely As, Sb, Bi and Pb contained in smelter dusts by vacuum calcination of mixtures of the dust with sulphidizing agents such as dirty copper concentrate or elemental sulphur at 900 °C and 80 +/- 30 Pa for 90 minutes. The products of this calcination are a residue comprising a purified mixture of copper containing compounds along with the gangue constituents and a high sulphur condensate comprising a mixture of the minor element compounds. In particular, the Cu:ME ratios of the concentrate and dust were increased from 250 and 50, from 28 and 12 and from 36 and 8 to roughly 3000, 3000 and 100 for the calcine, for Bi, As and Sb, respectively. It has also been calculated that (i) the copper content of the vacuum calcine may be recovered by feeding it into a Peirce-Smith converter during its slag blow, and (ii) the resulting recycling could increase the minor element treatment capacity of a smelter by 100 % while also reducing the blister As content by a factor of three. The experimental results are briefly discussed and a treated dust recycling option is examined. Example operating conditions are presented and available commercial technology for the vacuum calcination of the mixtures is reviewed.

Jan 1, 2007

By D. M. Richards

"IntroductionThe Highland Valley Copper partnership was formed in July 1986 as a logical result of a mine with a large ore reserve but a small mill, and a mine with a large, modern mill but dwindling ore reserves. The original partnership of Cominco and Rio Algom was expanded in January 1988 to include Highmont Mining Company. During 1988/89 the Highmont mill was moved 7.5 km to adjoin the Lornex mill, becoming the Highland mill in the process, with a nominal capacity of 130 000 tonnes per day.The mine is located near the town of Logan Lake, 220 km northeast of Vancouver, British Columbia and 55 km southwest of Kamloops. The map in Figure 1 shows the general area. Kamloops is a major service centre and is served by two railways, two major roads and a regional airport. The mine site is situated between 1200 m and 1600 m above sea level on the Thompson Plateau. Principle activities in the area, in addition to mining, are cattle ranching and forestry. Ore reserves at the beginning of 1996 totaled 533 million tonnes at a grade of 0.42% copper and 0.008% molybdenum. Ore is mined from two pits — Valley, 3 km northwest of the mill; and Lornex, 1 km southwest of the mill. With 78% of the reserves, the Valley pit is the focus of activity.In order for Highland Valley Copper to remain competitive with a very low grade ore reserve, it has been necessary throughout the mine’s life for new technologies to be embraced as they become available. These have included such diverse technologies as in-pit crushing and conveying, large mechanical drive trucks, computerized truck dispatch and oneman survey instruments. During the next few years, it is planned to introduce two further technologies that are relatively new to both the world at large and the mining industry in particular. These are namely Global Positioning Systems (GPS) and Geographical Information Systems (GIS), both of which are expected to have a major impact on the way mining is carried out in the years to come."

Jan 1, 1997

By Carl Lausen

Within recent years several mining companies have sent expeditions co the east end of Great Slave lake co determine the mineral possibilities of that area. Little was known of the geography of the region, and even less of the geology; and, not until Blancher's survey was made and the results published, was an accurate map of the lake available. Early explorers followed the Inconnu channel and the north shore of McLeod bay to Port Reliance, and, just prior to Blancher's survey, Hornby showed that the southern passage was feasible. Apparently, but few geologists have ? travelled through the country, for geological information is meager. In 1900, Robert Bell, of the Geological Survey, made a trip to Fort Reliance by way of the north shore of McLeod bay, and he gives a brief description of the geology. The present paper is the result of an expedition into this little-known region by Mr. Geo. M. Douglas and the writer in the summer of 1928. The south shore of Great Slave lake was followed to the east end of Tochatwi bay, and an extensive exploration was made of Kahochella and Pethei peninsulas. The prime object of the expedition was co determine the presence or absence of the copper-bearing Keweenawan basalts.

Jan 1, 1929

By G. Scamans, J. Lazaro-Nebreda, Z. Fan, J. B. Patel

"Melt quality is crucial for both continuous and shape casting of light alloys and in order to improve it, removal of excessive inclusions, accumulated impurities and unwanted gases becomes necessary. To address this problem, a new multi-purpose high shear liquid metal treatment technology, based on intensive melt shearing by a rotor/stator unit, has been developed. The device ensures achieving uniform temperature and chemical composition and an efficient dispersion of gas and solid phases in the melt with minimal disturbance of melt surface, and can be used, among other things, for de-gassing and de-ironing of Al-alloy melts. Efficient degassing is achieved by dispersing each argon bubble into many small ones, which significantly increases the overall surface area of the bubbles and the time they remain in the melt capturing hydrogen before reaching the surface. This allows using much lower inert gas flow and mixing times than conventional rotary degassing. When applied to Al-alloy scrap, with accumulated iron, the high shear melt treatment speeds up the nucleation and growth of primary Fe-rich intermetallic particles, allowing a faster removal rate. Therefore it reduces processing times, increasing recycling productivity, and facilitates full metal circulation of secondary Al-alloys.INTRODUCTION Aluminium and magnesium alloys are widely considered in various industrial sectors for the purpose of weight saving (Polmear, 1995). In particular, they are used in the automotive sector, where components are mostly manufactured by high pressure die casting (HPDC) because of its simplicity and relatively low cost, but efficiency and mechanical properties are quite low compared with other processes. To date, the main focus to overcome this problem has been for improving the HPDC machinery (Dahle, 2001) but little attention has been paid to the opportunities of controlling the nature and quality of the molten metal supplied to the die. In this way, liquid metal treatment, which involves a variety of physical and/or chemical processing methods to improve melt quality prior casting, is crucial for both continuous and shape casting products."

Jan 1, 2018

Train on Different Equipment - * Immersive?s interchangeable cabin controls technology - ?clip on & off? * Change Simulator from one machine to another in minutes * No technical expertise required to swap * Real, functioning, controls and displays are used to aid rapid learning Immersive has produced a range of Conversion Kits to suit most equipment. Modular design - Easy to convert from one machine model to another with a Conversion Kit. Caterpillar Models Trucks - 769D, 773D, 777D Trucks - 785B, 789B, 793B Trucks - 785C, 789C, 793C, 797 Excavator/Shovel - 5130, 5230 Front end loader ? 992, 994 Dozer ? D10, D11 Komatsu Models Trucks - HD325, 785-5, 985-5 Trucks - 730E, 830E, 930E Dozers - D375A-3, D475A-3 Shovel - PC8000 P&H Shovels - 4100A, 4100XPB, 4100BOSS Hitachi Shovels - EX2500, EX5500 O&K Shovel - RH200 Bell Articulated Truck - B40C

May 1, 2003

By R. Luchese de Moraes, J. A. Matthews, C. Feliciano Bruzual

The role of biomass char in blast furnaces has been re-examined by scientists worldwide, as a feasible option to reduce the carbon intensity of ironmaking. This contribution makes a technical and economic analysis of the ferro gusa industry in Brazil, with the last 172 charcoal-Blast Furnaces operating in the world. A key strategic question is presented: what is the current status and future prospects of biomass use in Blast Furnaces? Findings provide significant implications to metallurgists: while ferro gusa from charcoal is regarded as carbon neutral iron with low impurities, there are limiting factors that hinder the further proliferation of charcoal-BFs: biomass generation requires vast extensions of arable land and aggregates have low production capacity. Additionally, most of the charcoal is presently generated in beehive kilns with low yields. These elements combined make charcoal-hot metal expensive in price. With respect to the future prospects of biomass, the injection of small biochar particles through the PCI rigs in BFs (here coined Bio-PCI) and iron ore sintering may offer a practical alternative to significantly reduce the CO2 emissions in the ironmaking process.

Jan 1, 2015

By Karen I. McMaster

"Abstract - The mining industry has endorsed the concept of sustainable development in principle. We now need to ensure that it is "lived" throughout the workplace. Frequently, sustainable development is viewed as just a policy and, more often than not, it is regarded as something that is applicable only to the areas of health and safety, environment, or community philanthropy. However, sustainability requires the collective action of an entire organization on a regular basis, a corporate culture where values are transformed into action.This paper reviews two of the many functional areas through which sustainable development can be pursued. Law and internal auditing are powerful means of instilling values, driving behavioral change, and improving performance. The development and role of each tool vis-a-vis sustainability is reviewed. Suggestions are offered regarding option and joint venture agreements, contract management programs, and various auditing programs based upon international standards and processes, market indices, and codes of conduct.The goal of this paper is to provide a general overview of these functional areas and to encourage further dialogue between employees and management in the workplace. It is hoped that others in the industry will examine the values of their companies, and review the ways in which individuals in all functional areas work, or want to work, on a daily basis. If we can harness collective commitment, creative thinking, and action in sustainable development, then the desired acceptance by stakeholders and improved financial performance will follow."

Jan 1, 2003

By R. K. Kandasami

"Naturally occurring geomaterials such as sandstone, limestone and other soft rocks, residual soils are composed of a particulates held together through a cohesive matrix, usually composed of argillaceous or siliceous cementing agents. Geo-materials such as these have been reconstituted in the laboratory using ordinary Portland cement in lieu of the naturally occurring cohesive matrix, in addition to using sand particulates. This cohesive frictional granular ensemble is an ideal model material for understanding the mechanical behaviour of transitional geomaterials such as soft rocks. An important consequence of this cohesion that pervades the inter particulate system is the enhanced tensile strength when compared to a purely granular ensemble. The assessment of strength of these soft rocks and cemented sands is often understood in the framework of continuum mechanics, i.e. considering the cemented sand to be a continuum, and performing simple elemental tests such as uniaxial compression or tension tests. A simple model to describe the behaviour of these cemented sands has been to use elements such as springs, sliders, and dashpots in parallel to describe the existence of a cohesive and frictional component of strength (Jiang et al. 2007). In the framework of continuum mechanics, the mechanical response of these cemented sands have been modeled using traditional plasticity theory, for example utilizing variants of the traditional Mohr Coulomb model, Modified cam clay (Sun and Matsuoka 1999) etc. The typical sand models are amended to include the effects of cohesion, as proposed by Lagoia and Nova (1995).The mechanical response of cemented sands is understood to be transitional to the behaviour of a typical particulate assemblage and a quasi-brittle material. However, the effect of length scale in these material systems has not been investigated. This paper presents a series of uniaxial compression experiments conducted on weakly cemented sand specimens of various sizes. The effect of length scale in these weakly cemented sands is investigated through unconfined compression tests."

Jan 1, 2015

By J B. Maughan

Gas and oil seeps have been known in Quebec for more than one hundred years. These occur in three main areas which contain sedimentary rocks with a total thickness estimated to vary from 6,000 to 20,000 feet. The strata in these areas are similar in many respects to those in producing areas of southwestern Ontario and the Appalachian basin, and the prospects for finding and developing commercial reserves of oil and gas in Quebec would therefore also appear to be favourable. Little of the exploratory drilling to date has been con-ducted in a systematic manner, and most of the drilling has utilized improper or inadequate equipment. Many wells have also failed to adequately test and fully evaluate the principal zones of interest. Relatively high drilling costs have hindered systematic exploration; however, with improved portable equipment, it is expected that future wells can be drilled with greater efficiency and at less cost. Most of the mineral rights in Quebec are held by the Provincial Government, and acreage can still be leased in large blocks on favourable terms.

Jan 1, 1964

By A. Zorkovská, S. Castro, P. Baláž, Z. Bujnáková

Enargite (Cu3AsS4) belongs among refractory copper minerals with very low hydrometallurgical extractability of copper. An application of enargite leaching in acid solutions leads to simultaneous dissolution of copper and arsenic and the final leach solutions have to be treated for the separation of both elements. However, the alkaline leaching of enargite is selective. Arsenic passes into leach while produced copper sulphide represents the raw material suitable for pyrometallurgy. The hydrometallurgical processing of mineral can be influenced positively by mechanochemical route. We have shown that more than 80 % of arsenic can be extracted from enargite concentrate by atmospheric alkaline leaching at 95 °C when mechanical activation in an attritor is applied. The produced Cu2S can be further treated with elemental iron where mechanochemical intervention is applied in the second stage of enargite processing. The final product forms Cu/FeS nanocomposite from which copper nanoparticles can be easily separated. The illustrated concept of copper obtaining from copper sulphide is an example of so-called “dry” processing, as reactions in gas and liquid phases are excluded. This concept of environmentally friendly metallurgical processing can be classified as an impetus for novel technology to produce copper from enargite concentrates.

Jan 1, 2012

By Raymond Dallaire

The Humphrey's spiral is a static gravity separation device which cannot be adjusted to match short-term variations that occur in the feed. Any disturbance in the feed grade, per cent solids or flow rate affects substantially the recovery and grade of concentrate. Such variations must be minimized in order to maintain the desired rate of production and quality of the product for which the installation has been designed. A study has been performed in which the foregoing assertions were quantified. The feed grade, per cent solids, flow rate and particle size were varied independently. Ore from Carol Lake, Nfld., was used throughout the experiments. This consisted of specular hematite and magnetite in a silica gangue.

Jan 1, 1978

By K. A. Hildebrant, J. R. Norgate

"Synthetic lubricants have for many years documented extended service life and provided superior performance in temperature extremes. Increasing interest in synthetics' ability to reduce energy costs has resulted in laboratory and industry application evaluations. These tests have documented savings in functions such as worm gear drives, spur gears and in compressors. Energy savings data are presented as well as payback calculations as low as thirty days.The National Research Council of Canada has estimated that the Canadian economy loses over five billion dollars per year in friction and wear. Figures quoted were for 1986 during which it was estimated that nine hundred and forty million dollars were lost in the mining industry alone"" It has been further estimated that about 115 million dollars can be immediately recovered through improved tribology practices (Table I).The purpose of this paper is to present results and savings opportunities through the use of synthetic lubricants in various but common applications. Many other areas exist with the opportunity for energy savings such as in the use of more efficient drive equipment, reduced contact seals, spray mist lubrication systems and reduced friction coatings on rotating equipment such as pump impellers"

Jan 1, 1994

By Maria D. Mastalerz, Wei Wang, Maria E. Holuszko, Amit Kumar

In this study, the micro-FTIR analysis was used to investigate in-situ surface properties of coal and its components (macerals) and these were directly correlated to the coal hydrophobicity as measured by the contact angle before and after reagent addition to understand the suitability of the reagent for flotation. The micro-FTIR technique can provide a semi-quantitative analysis of the chemical functional groups on coal surface, exactly where the contact angle is being measured. Selected functional groups and their ratios that provide information about aromaticity, the contribution of oxygenated groups, and aliphaticity are used to evaluate the reactivity between reagents and various coal components. The observations made in relation to the susceptibility of some reagents towards certain coal components should lead the way to a smarter way of using process design in terms of reagents selection for coal flotation.

Jan 1, 2017

By R. D. Lindsay

"Pamour Porcupine Mines, Limited is involved in the mining, milling and primary refining of various gold, gold - copper and refractory gold ores. Pamour operates five mines in the Porcupine Mining District of Ontario, and two 2,550 t/d milling facilities.Both metallurgical facilities use conventional cyanidation technology including zinc cementation for precipitation of gold and silver from solution. The precipitation process, as applied to clarified leach solutions (less than 1 ppm suspended solids) at Pamour is called the Merrill - Crowe process. Precipitates from both milling operations are treated at Pamour's Area Refinery. Schumacher precipitates, unlike Pamour No. 1, require an ''Acid Treatment Stage"" prior to refining to remove the high contained copper. This is accomplished by leaching the precipitates initiallv with sulphuric acid to remove zinc and then with sulphuric acid and manganese dioxide to dissolve copper. Refining procedures after ''Acid Treatment"" are essentially the same for both precipitates.The following considerations highlight the basic principals applied to refining cyanidation precipitates at Pamour, including:"

Jan 1, 1986

"Previous studies on the effect of polytetrafluoroethylene addition during chalcopyrite leaching under conditions similar to those of the CESL process have reportedly resulted in complete leaching of the copper without the need for grinding of the flotation concentrate. However, these studies employed a pulp density of only 1% and finely sized PTFE particle that required the use of high impeller rotation rates that are not sustainable at an industrial scale. This paper explores the performance of 1/8” diameter balls of PTFE, that readily sink in the leach solution, on leaching performance at impeller rotation rates and ore pulp densities more typical of industrial practice. Possible routes for separation of the PTFE from the leach residues and their regeneration for recycling back to the leaching stage are also discussed.INTRODUCTIONChalcopyrite, CuFeS2, is the most important primary sulfide source of copper. While pyrometallurgical smelting of chalcopyrite remains the only widely accepted route for treating chalcopyrite concentrates, several medium temperature pressure oxidation processes are claimed to be economically feasible (Muir & McDonald, 2007). Among these, the CESL process has been extensively piloted and demonstrated at the prototype scale. The overall process chemistry of the CESL process may be summarized as follows (Marsden & Wilmot, 2007):4CuFeS2 + 5O2 + 4H2SO4 ? 4Cu2+ + 4SO4 2- + 2Fe2O3 + 8S0 + 4H2O (1)4CuFeS2 + 17O2 + 2H2SO4 ? 4Cu2+ + 10SO4 2- + 4Fe3+ + 2H2O (2)Though copper extractions of over 95 % are achieved, the CESL process requires extra grinding of the concentrate (Muir & McDonald, 2007). This is because leaching is conducted at temperatures around 150 °C, where the elemental sulfur produced is molten and grows thicker on the mineral’s surfaces as oxidation progresses, creating an increasingly large barrier for mass transport. In addition, the sulfur is sticky and tends to cause the mineral particles to agglomerate, effectively halting further oxidation of the particles that end up embedded within the agglomerates. Consumable surfactants, such as ligin sulfonate, have been shown to be effective at avoiding agglomeration, but they are not effective at removing sulfur from the minerals. Hence, their use does not obviate the need for fine grinding."

Jan 1, 2012

By V. L. Gravitis

Radioisotope X -ray techniques of analysis for nickel have been tested in laboratory and plant trials. In the laboratory tests. a comparison was made of radioisotope and conventional analyses for nickel in solid s samples taken from streams of a nickel concentrator. Coefficients of variation of 1.7% for feed and concentrate samples , and equal to 10% for final tailing samples, were obtained. Continuous determination of nickel in final tailing slurries was demonstrated in a trial lasting 20 days at a nickel concentrator (Western Mining Corporation), nickel being determined with a standard error of 0.036% Ni in the slurry solids within the range of 0.24 to 0.68% Ni. This error, obtained by comparison of on-stream probe analyses with assays of samples taken from the stream, includes errors in sampling and assay by conventional techniques.

Jan 1, 1977