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By J. Jankovic

Numerous advantages have been recognized for solid oxide fuel cells (SOFCs) operating at temperatures of 500-700°C. However, there are several issues related to low temperature SOFCs, such as high electrolyte resistance and high electrode polarization. One of the routes to enhance the electrode performance, particularly for the cathode, is to use new materials with optimized microstructure. In this work, the plasma-spraying technique, recognized to have several advantages over presently used deposition techniques, was used to deposit cathode materials onto ceramic and stainless steel substrates to obtain highly porous structures. Cathode materials with composition of Lao 6Sr0.4Co02Fe0 8O3 (LSCF) were employed in the powder form. The LSCF was prepared from powder precursors with different pore formers and binder levels, or from already produced, single-phase LSCF. The (La0.8Sr0.2)0.98MnO3 (LSM) cathode material was also processed for comparison purposes. The deposition process was developed to obtain coatings with good bond strength, porosity, film thickness and residual stresses. The phase and microstructure of deposited materials were characterized using XRD and SEM.

Jan 1, 2005

By R. D. Brown

"AbstractOver the past five years, tax rates in the Canadian mining industry have skyrocketed upward across Canada, as both federal and provincial governments have sought to increase their share of mining revenues.However, the past few years have not only brought high tax rates to the industry, but also a number of important new federal and provincial tax incentives.In large part, these incentives ~ special credits or reduction in tax for carrying out specific exploration, processing or other activities - have helped to moderate the adverse effects of the higher tax rates and have provided inducements for exploration and processing activities which might not otherwise have been undertaken.However, the effectiveness of certain of these incentives can be questioned: our over-all tax structure now consists in large part of punitively high marginal rates with some extraordinarily generous but capricious tax reductions for specific activities and may not be in the best long-term interest of either the industry or the nation.A rational tax structure, with moderate and stable tax rates, together with reasonable incentives confined to activities specifically requiring them, could be a more effective spur to investment than the present tax and incentive jungleIntroductionIN THE YEARS since federal tax reform, the mining industry in Canada has faced a continued escalation in its tax burdens as federal and provincial governments have leapfrogged each other in imposing new and higher taxes on the industry. The result has been that marginal tax rates imposed on mining and processing activities throughout Canada have jumped to hitherto unparalleled levels."

Jan 1, 1977

By W. M. Armstrong, John A. H Lund

The paper describes an investigation of some of the tensile properties of single crystal vanadium, poly-crystalline vanadium and polycrystal-line tantalum, in the range of: W°C to -196°C. Techniques employed in the preparation and testing of specimens are discussed in detail. Some results of determinations of the temperature dependence of yield stress and ductility are given, and discussed in terms of the Cottrell-Bilby Theory of yielding. At subnormal temperatures, all the body-centred cubic transition metals in the Periodic Table exhibit; a) the "yield phenomenon" in tension, b) a strong temperature and strain rate dependence of yield stress, and c) a large decrease or complete loss of ductility. The yield phenomenon (existence of an upper and lower yield point) has been explained by Cottrell and Bilby ( 1) in terms of the dislocation-locking effect

Jan 1, 1961

By Samantha A. Beeson, Colin Poole

"A selective flocculation-floe flotation technique is already in use in the Canadian potash industry for the removal of water-insoluble slimes, but the process is currently limited in its application and reagent consumption is high. The work described in this paper details investigations into the separation of sylvite and halite from water-insoluble slimes by selective flocculation utilising other commercially available polymers.Preliminary flocculation performance tests were undertaken on pure sylvite, halite and water-insoluble minerals to establish the importance of a number of experimental parameters. The data from these single mineral tests was then used to establish optimum parameters for the separation of sylvite and halite from a synthetic mixture similar in composition to a typical potash ore. Under optimum conditions, separation was achieved with high recoveries using dispersant and flocculant dosages significantly lower than those currently used in plant practice.IntroductionAlthough solar evaporation and solution mining are used in some operations, most potash is extracted by conventional underground techniques and is then processed by froth flotation, in order to separate the valuable sylvite (KCI) from halite (NaCl) and water-insoluble gangue minerals. Flotation is usually preceded by a desliming stage to remove water-insoluble fines, but this also results in high potash losses and affects process brine requirements. To overcome these problems, one plant operated by Cominco in Saskatchewan uses a selective flocculation -floe flotation process (Banks, 1979/1980), in which a polyacrylamide flocculant is added to produce floes of water-insoluble material with minimal incorporation of halides. A collector is then added to render the floes hydrophobic and suitable for removal by froth flotation.A number of workers have also investigated the use of selective flocculation in potash processing, but these too have been concerned with developments in the removal of water-insoluble slimes (Williams, 1960; Brogiotti et al, 1974; Chan et al, 1986; Thompson et al, 1979; etc.). This paper provides results of novel investigations into the selective flocculation of sylvite and halite from water-insoluble minerals and discusses the possible mechanisms involved."

Jan 1, 1995

By Erol Yilmaz

This poster presents results obtained from an experimental test set-up called CUAPS (curing under applied pressure system) allowing to assess the performance and quality of cemented paste backfill (CPB) materials. CUAPS can be used for carrying out a series of tests: one-dimensional consolidation, saturated hydraulic conductivity, pore-water pressure dissipation, and curing under uniaxial stress. The poster presents CUAPS testing preliminary results including uniaxial compression tests (UCS) and mercury intrusion porosimetry (MIP). It was demonstrated that CUAPS-consolidated CPB materials cured under time-dependent stresses provide higher UCS values than standard mould (undrained and unconsolidated) CPB samples. This may be explained by the release of excess pore water within backfill that gives rise to a significant reduction in the total porosity of fresh CPB materials prior to hardening and thus, to higher mechanical strength (UCS) gain. The results obtained from MIP highlighted a good correlation between CUAPSconsolidated and mould-unconsolidated CPB samples. MIP results were also related to UCS values in order to predict the final CPB mechanical strength.

Nov 1, 2008

By B. Galy, L. Giraud

"This paper compares Canadian provincial mining safety regulations addressing hoist safety, automatic hoisting, and shaft obstruction. The regulations are quite similar among provinces, with only slight differences. Risk-mitigation strategies used in other industries are discussed, including their applicability to mine hoists. The specific case of software safety is introduced through examples. The mitigation of software failure is based on the use of the software lifecycle as recommended by the International Electrotechnical Commission (IEC) 61508 standard. Finally, ways to improve hoist safety are proposed.RÉSUMÉ Le présent article compare entre elles les diverses réglementations provinciales canadiennes concernant la sécurité des machines d'extraction, le levage automatisé et les obstructions dans les puits. Les réglementations sont assez semblables entre les provinces, mais elles comportent de légères différences. Les stratégies d’atténuation des risques utilisées dans d’autres industries sont abordées, incluant la possibilité de les appliquer aux treuils de mines. Le cas spécifique de sûreté des logiciels est abordé par des exemples. L’atténuation de la défaillance des logiciels est basée sur l’utilisation du cycle de vie du logiciel, comme cela est recommandé par la norme 61508 de la Commission électrotechnique internationale (CEI). Des moyens d’améliorer la sécurité des treuils sont également proposés."

Jan 1, 2016

By R. Clarkson

"Free gold particles occur in many base metal and precious metal mines throughout the world. Due to the high density and malleability of gold, large circulating loads of free gold particles can build up over time in grinding circuits. This gold is often deposited in unintended traps throughout the mineral processing system.These unidentified free gold deposits represent a serious security risk as well as an inaccessible inventory of gold. Deposits of free gold particles often remain undetected by mine management until they are accidentally discovered while repairing mill equipment.Nuclear tracers have been used to determine the free gold recovery efficiency of gravity recovery equipment, drills, and sampling equipment (Clarkson, 1994, 1995; Walsh and Rao, 1986; Walsh and Kelly, 1992). In November, 1993, the author inspected the grinding circuit at La Mine Doyon in Rouyn-Noranda, Quebec and made recommendations to recover coarse gold and to eliminate gold traps from the circuit. In 1995, the author salted mineral processing circuits with radioactive gold particles. The gamma and X-ray radiation from gold’s nuclear isotope (Au198) were detected through steel, in pipes, and in moving equipment using scintillometers. The radiotracers proved to be a safe, rapid and accurate method of identifying gold traps and improving security.Nuclear TracersWhen particles of gold are placed in a nuclear reactor, some of the gold atoms (Au197) absorb another neutron in their nucleus to form gold’s radioactive isotope (Au198). In the process of radioactive decay, this isotope emits high energy gamma rays and X-rays which are easily detected (even through steel) with scintillometers.Radioactive gold (Au198) has a very short halflife of 2.7 days. At the relatively low activity levels used for tracing, the particles remain detectable with a small hand-held scintillometer for about 10 to 14 days. After 14 days the irradiated gold is close to background levels and within two months it is essentially non-radioactive. The radiation has no effect on the recovery characteristics of the gold particles. The gold radiotracers are very safe due to their very low level of radiation, short half-life, and their inherent physical and chemical stability. However, the use and possession of even mildly irradiated gold is strictly licensed and regulated."

Jan 1, 1997

By K. Ihara, R. Akiyoshi, Y. Takaki, S. Kang, H. Shishido

"Tensile tests and scanning electron microscopy-electron backscattered diffraction (SEM-EBSD) analysis were performed in an Al-Mg-Si alloy to clarify the effect of annealing and cold-rolling reduction on the texture formation. The hot-rolled specimens were cold-rolled with the reduction of 58-75%(CR1), followed by annealing at 773 K for 5 min(IA). The secondary cold-rolling(CR2)for the IA specimens with the reduction of 33–66%, followed by the solution heat treatment(ST), were performed. Focusing on the CR1 and CR2 specimens, the average r-values increased with higher primary and lower secondary cold-rolling reduction, respectively. This was considered to be due to the increase of r-values measured in the direction of 45 degree with respect to rolling direction, caused by the formation of the ß-fiber components (Brass {011}<211>, Copper {112}<111> and S {123}<634>) with high density. Based on the texture analysis of annealed specimens it was suggested that the high density of the ß-fiber components after IA and the small amount of stored strain energy of CR2 introduced by the lower cold-rolling reduction remained the ?-fiber components even after solution treatment.INTRODUCTION Al-Mg-Si alloys have been applied to automobile body applications, due to their excellent paint-bake hardening (age-hardening) and corrosion resistance compared to other aluminum alloy. On the other hand, the mechanical properties and deep drawability of Al-Mg-Si alloys are inferior to those of steels. Thus, it is important to improve the mechanical properties and deep drawability in order to expand the application components. One of the best methods to improve the deep drawability is to increase the Lankford coefficient (r-value). Previous studies reported that the increase of the average r-value ( ) improves the deep drawability. The relationship between the r-value and texture of the alloy is also well known. Inoue et al. reported that the ß-fiber components, such as Brass ({011}<211>), Copper ({112}<111>) and S ({123}<634>), increase the r-value measured in the direction of 45o with respect to the rolling direction. r"

Jan 1, 2018

By William James Kempson

This paper discusses ore handling systems in shafts. These are considered from the loading facility at shaft bottom all the way through to the discharge mechanism in the headframe. These systems will be discussed from the following perspective: i. Intrinsic safety of the systems ii. The efficacy of the systems to perform consistently iii. The maintainability of the systems iv. Overall system cycle times Particular emphasis is placed on the following specific areas: 1. The Shaft Bottom Loading Facilities The various shaft loading systems currently in use are discussed, the selection parameters surrounding these are quantified and the specific selection criteria are outlined. 2. The Various Skip Configurations In this section the various skip configurations in use around the world will be described and the specific design details associated with these will be highlighted. The advantages and disadvantages of these systems will be compared and the overall efficacy of these will be discussed. 3. The effect of the loading and skip configurations on the Load Cycle Times. The overall cycle time which can be achieved by a shaft system is strongly dependant by the speed and efficiency with which the ore can be loaded and transported out of the mine. The potential of the various systems to be optimized will be discussed. The emphasis of this paper is to highlight the lessons which have been learned with respect to ore transport system design and provide a common basis against which these can be compared in future applications.

May 1, 2013

By I. Colquhoun

Current practice tends towards "integrity as an afterthought". That is, integrity is treated as an isolated aspect of operations and maintenance. In fact, this works quite well. But it would work so much better and with less uncertainty if integrity management measures were introduced at the design phase and addressed the entire life-cycle of the pipeline asset. The talk will address the measures and metrics that can be implemented on a new pipeline during design to optimize integrity and deliver a comprehensive operating manual and integrity management program for the pipeline system. This deliverable should describe the risks to be assessed and monitored, and the actions to be taken to control these risk adequately. Properly executed, integrity by design will provide a good working estimate of the life-cycle integrity management costs and maximize system reliability.

Jan 1, 2005

By A. K. Debnath

Coal is the mainstay of Indian energy supplies. The many-fold increase in demand for coal puts a huge pressure on augmenting production, primarily from opencast mines. The increase in production necessitates heavy blasting in overburden and coal benches of opencast mines, which poses numerous challenges in carrying out blasting operations techno-economically. Presently, the consumption of industrial explosives and accessories in Coal India Limited (CIL) has touched a whopping figure of $350 million USD per annum and CIL will be spending approximately $1 billion USD between 2012?2013 to 2014?2015 for procuring explosives and accessories. This paper discusses some of key challenges faced in various mines of CIL during blasting, where blast instrumentation at the mine level will prove to a harbinger for practicing blasting engineers. Presently, the problem of scattering in surface detonators and down-the-hole detonators affects the blast performance significantly by increased blast induced ground vibration and reduced fragmentation. The paper discusses a case study carried out at Umrer opencast project of CIL to investigate the effect of scattering by using blast simulation techniques (i.e., JKSimblast) and observing the actual blast results with the help of a high-speed camera and multi-channel high frequency data acquisition systems. The fragmentation assessment was carried out by adopting Digital Image Analysis techniques and using the granularity software viz. Wipfrag. The blast instrumentation in the case study mine resulted in improvement in fragmentation of 12.76% and a direct savings in explosives cost of 28%. Geophysical techniques such as the seismic survey method have been used at Umrer Project, CIL to characterize the rock mass using the Multi Channel Analysis of Surface Waves system for selecting the explosives technoeconomically. The minimum deck thickness for mines of CIL using drill cuttings as decking materials should be 10 D, where D is the drill diameter. The estimation of blast performance on the basis of prescribed Powder Factor (i.e., kg of explosives per m3 of rock) is technically unscientific as the criterion of a good blast depends on many factors (i.e., good heave, loose muck, muck profile angle, ease of digging, uniform fragmentation). The present paper proposes a new methodology for techno-economic evaluation of blast performance. The new methodology involves four significant factors viz. specific energy consumed by the loading equipment, charge factor, productive yield and diggability index for assessing blast performance. The use of user-friendly, accurate, reliable, rugged and handy instruments in blasting will significantly improve mine productivity, equipment efficiency and economics. The improvement in blast performance, even by 1%, will provide a significant savings of $3.5 million USD per annum to CIL. It may be concluded with high degree of confidence that blast instrumentation at the mine level will influence the mine productivity and economics.

Aug 1, 2013

By E. Latorre, T. S. Golosinski

ABSTRACT; his paper proposes new methodology to define the pit limits that yield the maximum net present value (NPV) for a deposit, under a given economic scenario and for a given discount rate. The method uses an algorithm that combines dynamic programming and heuristics. It was tested for evaluating deposits with different sizes and various grade distributions. For the discount rate of zero, the results confirm that the economic pit limits are the same as that defined using Lerchs Grossman method. However, when discount rates higher than zero are used, the pit limits differ, yielding a higher NPV.

Jan 1, 2011

By F. Kapeller, G. Herget

"The need for monitoring the effect of changes in ground stresses due to mining in hard rock has existed for many years. The Mining Research Laboratories of CANMET, EMR have developed a new tool which monitors with high precision the radial deformation in boreholes. The result is the Mining Research Laboratories strain monitoring system (MSMS) which uses the highly stable and very sensitive vibrating wire principle to monitor deformations in relatively large boreholes, e.g. 76 mm to 153 mm diameter.The vibrating wire is strung across a relatively large proving ring and operates at a frequency between 600 to 1800 Hz. The read-out system is based on continuous vibration.The ring is installed with a hydraulic tool and brought into contact with the surrounding rock through precisely machined and guided wedges. The resolution of the system is in the neighbourhood of 4 x 10-4 min/ Hz. The data collection can be carried out with a portable read-out unit and provisions are available for automatic data collection. Stresses may be calculated from strain readings.The system was tested in cooperation with the Centre de recherches minérales at the Niobec Mine in Quebec for the purpose of monitoring the effects of drill drift development and slope mining on surrounding ground stresses.After access was available to the site, 153 mm diameter holes were drilled for the determination of in situ ground stresses. These holes were then used to install the strain monitoring system. The effect of drill drift development and production blasting in stopes C-203-13 and C-203-15 on ground stress distribution could be observed clearly.The horizontal relaxation in the core of a pillar which occurred during mining of adjacent rooms was between 0.082 mm to 0.111 mm. Calculations of stresses from these deformations indicate that the rock material is still in an elastic condition.Roctest of Montreal has obtained a license on the manufacturing and distribution rights. A patent has been registered and CANMET will assist in installation of the MRL strain monitoring system and the interpretation of records."

Jan 1, 1989

By G. Banini

Prior to installation of High Pressure Grinding Rolls (HPGR) at PT Freeport Indonesia (PT-FI) a series of laboratory tests were carried out to determine the design parameters and also determine key performance indicators (KPIs) for the industrial unit. The design parameters derived from the lab test work were then scaled up to estimate the industrial capacity of the HPGRs to be installed. These parameters include specific power draw, specific throughput, and specific force, rolls speed, product size distribution and wear rate of the rolls. This paper compares the performance of the scale-up procedure against the installed industrial size HPGR. Overall, the specific throughput of the industrial size HPGR is higher by a minimum of 30% compared to the expected scale-up value. As a result of the high specific throughput, the specific power draw and grind sizes are below the scale-up expectations in the commercial application. The impact of these factors also contribute to a lower than expected wear rate on the industrial rolls. Installed rolls achieved a service life in excess of 18,500 hours relative to the target of 6,850 hours predicted from the laboratory testing.

Jan 1, 2012

By Fred V. Seibert

The Functions and the Responsibilities of the Institute The Canadian Institute of Mining and Metallurgy is unique. ln addition to the welfare of its members, it has a real interest in the welfare and promotion of one of Canada&apos;s largest and most important basic industries. It is because of this that the membership is composed of both individual and corporate members. The individual members are both technical and non-technical (Members and Associates). Both Members and Associates have the same status in the Institute and all are interested in the welfare of the mineral industry. The aims and objects of the Institute 11re twofold. The education and welfare of its individual members and the sound promotion and welfare of the mineral industry. Perhaps it might be well if we reviewed these aims and objects as stated in our Constitution: "First - To promote the arts and sciences connected with the economical production of valuable minerals and metals, by means of meetings for the reading and discu11ion of technical papers, and the subsequent distribution of such information as may be gained throo.gh the medium of publications". It cannot be denied that we have do ne a good job in this particular phase of our work. Nevertheless, there is still room for improvement. It has been suggested that we might have more discussion and, on occasions, more criticism of our papers and programmes. This can best be done if the authors will have their papers prepared in sufficient time to permit of preprints being made availa1ble before the meeting at which they are to be presented.

Jan 1, 1950

By N. Bakhshizadeh

In this investigation, the aging effect on creep behavior of A12024-10%SiC composite fabricated by powder metallurgy was studied. P/M bars were manufactured by hot powder extrusion method at 450°C with a ratio of 16 to 1. Creep specimens were over-aged at 187 ºC for 43 h. It was found that almost full density composite with relatively homogenous distribution of reinforcing particles throughout the aluminum alloy matrix could be attained by direct powder extrusion process. Creep tests were conducted at temperatures from 275 to 325°C under stresses from 25 to 60 MPa. The analysis of the creep mechanism determined that dislocation glide was the predominant mechanism of plastic deformation. The activation energy of the creep process was found to be higher than that of lattice self-diffusion in pure aluminum.

Jan 1, 2007

By A. Bendada, P. Servais, X. P. Maldague, C. Ibarra-Castanedo, C. Mohr

Infrared (IR) thermography is a nondestructive, non-contact and non-intrusive technique that allows the fast inspection of large and complex structures with limited accessibility. Pulsed thermography is particularly interesting for the inspection of aerospace materials such as composites given that, after submitting the specimen surface to a thermal front, the most common types of subsurface discontinuities (e.g. porosity, de laminations, dis bonds, fiber breakage and inclusions) can be detected with an IR camera as regions showing abnormal temperature patterns. We present first the case of an aircraft door with water ingress and surface repairs on its honey comb structure. We also highlight the advantages and limitations of thermography for the inspection of aircraft composite parts, such as edge flaps, rotor blades and speed breaks. Finally, we expose some results from a Kevlar® non-planar specimen with Teflon® inclusions at different depths and locations.

Jan 1, 2006

By Ron Davidson

"The Utility Mine in southeast Saskatchewan is owned by Saskatchewan Power Corporation and operated by Mana/ta Coal Ltd. Up to 3.3 million tonnes of lignite is supplied annually to Saskatchewan Power's Boundary Dam Generating Station. The coal occurs in two predominant seams which are covered by up to 37 metres of saturated fine-grained overburden. Overburden is removed by two draglines working in two pits. Coal is hauled to the mine mouth power station. Comprehensive drainage and reclamation programs are integral parts of the operation. IntroductionThe Utility Mine is owned by Saskatchewan Power Corporation and operated by Manalta Coal Ltd. It is located in southeastern Saskatchewan, approximately 200 km southeast of Regina and 8.5 km southwest of Estevan (Fig. 1). The climate of the Estevan area is semi-arid with long, cool winters and short, hot summers. The mean annual precipitation is 42 cm and the mean summer temperature is 20°C; mean winter temperature is -10°C. The Utility Mine supplies coal to the adjacent Boundary Dam Generating Station. Increases in the station's generating capacity during the past decade have resulted in an extensive expansion program for the Utility Mine. This expansion program, the geological conditions present in the area, and the mining/reclamation operations will be highlighted in the following sections<1.2). History The Estevan area has a long history of coal mining. In the early years, coal was mined via entries into coal seam outcrops along the slopes of the Souris River valley. Surface strip mining was introduced in the late 1920s and progressed to the point where it totally replaced underground mining by the 1950s. Surface mining methods are currently used exclusively by all of the Estevan area operators."

Jan 1, 1985

By Tom Gaines, G. S. Brant, J. G. Debanne

"AbstractThe Bonnie Glen oil field, one of Canada's largest, lies about fifty miles southwest of Edmonton, Alberta. One hundred and thirty-eight wells have been completed in this field since its discovery in January, 1952. Five different procedures have been used in completing the producing wells.The reservoir is an Upper Devonian biohermal reef with good porosity and uniformly high permeability. The top of the reef is quite flat but the flanks slope at angles approaching 20 degrees from the horizontal. The reservoir has a gas cap with a maximum thickness of 400 feet, an oil column of 300 feet, and a :porcus aquifer of over 300 feet. The reservoir pressure is now 2,400 pounds per square inch gauge at datum ( -4100 M.S.L.).Because of the high permeability and the high •pressure, lost circulation and resultant blowouts are a particular hazard in drilling at Bonnie :Glen field. To reduce the dangers of blowouts, it is general practice to run casing to the top of the reef. If the reef is encountered 'high' it was usual practice to run a liner and perforate for completion. Wells penetrating the •reef below the gas/oil interface were either completed in open hole or through casing perforated opposite the oil pay, with the former method more frequently used. Eight wells were completed by the Humble-Otis permanent-type completion, and recently five high wells were completed open hole with the gas •cap exposed. This latter completion, 'tubing submergence', has proved highly satisfactory thus far.The open-hole type of completion is cheaper than the liner perforation method and results in better well performance. More experimentation and data are needed before the tubing submergence method can be recommended unqualifiedly. but all evidence thus far favours its use in reef reservoirs."

Jan 1, 1955

By J. Baumbach, H. Bombach, M. Stelter

"Today technical electro-refining processes for copper exclusively use sulfuric acid, for silver refining nitric acid electrolytes are used. Sulfuric acid is characterized by very good chemical and electrochemical stability, good conductivity and low cost. The disadvantages of sulfuric acid are the precipitation of fine-grained cathodes with smooth surfaces only by using additives like glue, thiourea and chloride. In case of silver the electrolyte is electrochemical unstable and bears the risk of the formation of toxic NOx when pH is too low. A second disadvantage is the form of electrodeposition of silver as dendrites with their removal from the bottom of the Möbius cells.This paper reports the results concerning the application of an alternative electrolyte in copper and silver electro-refining. At first the electrolyte was characterized by the determination of current density potential curves. Electrolysis experiments were performed in laboratory scale using technical anodes for copper and synthetic anodes for silver. During the copper tests the solubility of contaminations from the anodes and the amount and chemical composition of the anode slimes were determined. Moreover the influence of current density, electrolyte temperature and the effect of several additives on the precipitation and chemical purity of the cathodes were investigated. In all experiments cell voltage as well as anodic and cathodic polarization was measured and current efficiency and specific energy consumption were calculated. A comparison with the results with those of tests using conventional sulfuric acid electrolyte shows the advantages and disadvantages of both systems, additionally the technical application chances and limitations for the new electrolyte. This electrolyte enables the precipitation of smooth copper cathodes with low silver and sulfur concentrations even at lower temperatures without any additive. For silver refining the electrodeposition of compact silver sheets is possible, that can be stripped comparable to those in copper electro-refining."

Jan 1, 2016