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By J. E. Scott, L. M. Heaman, R. A. Creaser, G. S. Salazar

"Schaft Creek is a calc-alkaline porphyry Cu-Mo-(Au) deposit located in northwestern British Columbia. The deposit formed in a volcanic arc setting, likely on a back-arc rifted continental fragment. It is hosted by Late Triassic basaltic to andesitic volcanic rocks of the Stuhini Group (Stikine Terrane), and is associated with porphyritic granodiorite dikes emanating from the nearby Hickman batholith. The age of the Hickman batholith is approximately constrained here by a composite U-Pb zircon date of 222.1 ± 9.6 Ma, which is in broad agreement with a well-constrained age for mineralization at Schaft Creek of 222.0 ± 0.8 Ma (Re-Os molybdenite). The deposit is in most respects typical of calc-alkaline porphyry systems, but displays silica-poor sericite-chlorite alteration in mafic country rocks in place of classic phyllic altera¬tion. The deposit comprises three distinct, but related, zones: the northern Paramount zone, the Main zone, and the West Breccia zone. Two phases of mineralization are observed. The first phase occurs as hydro-thermal veins and breccias, and minor disseminations. It consists of bornite, chalcopyrite, molybdenite, and pyrite with potassic and sericite-chlorite alteration. The second phase is minor and consists of veins of molybdenite ± specularite, as well as Cu-Pb-Zn sulfide veins without any significant corresponding alteration. Extensive structural modification has affected the deposit both during and after its formation.Schaft Creek est un gîte porphyrique de Cu-Mo-(Au) calco-alkalin situé dans le nord-ouest de la Colombie Britannique. Ce gîte s’est formé dans environnement d’arc volcanique, probablement situé sur un fragment continental bordé par un bassin d’arrière-arc. Le gîte est encaissé par les roches volcaniques basaltiques à andésitiques du Groupe de Stuhini (Terrane de Stikine) d’âge Triasique tardif, et est associé à des dykes de granodiorite porphyrique provenant du batholithe de Hickman avoisinant. L’âge du batholithe de Hickman est estimé par un âge U-Pb composite sur zircon de 222.1 ± 9.6 Ma, lequel est grossièrement en accord avec l’âge de la minéralisation de Schaft Creek, estimé a 222.0 ± 0.8 Ma (Re-Os sur molybdénite).Ce gisement, bien qu’à plusieurs égards typique des systèmes porphyriques calco-alcalins, présente une altération en séricite-chlorite pauvre en silice dans l’encaissant mafique a la place de l’altération phyllique classique. Ce gîte comprend trois zones distinctes bien que connexes : la zone Paramount au Nord, la zone Principale et la zone West Breccia. Deux phases de minéralisation sont observées. La première phase se présente sous forme de veines et de brèches hydrothermales ainsi qu’en disséminations mineures et consiste en bornite, en chalcopyrite, en molybdénite et en pyrite avec une altération potassique et en séricite-chlorite. La seconde phase est mineure et consiste en veines de molybdénite ± spécularite ainsi qu’en veines de sulfures de Cu-Pb-Zn sans association à une altération particulière. Le gisement a été profondément modifié par la déformation a la fois durant et après sa formation."

Jan 1, 2008

By Kathleen A. Altman

"This paper supplements the information provided annually at the Canadian Mineral Processors Operators Conference regarding the education of Mineral Processors in Canada. The purpose of the paper is to provide information regarding the engineering accreditation process in the United States and the universities that offer programs in Mineral Processing and Extractive Metallurgy in the U.S.There is a critical shortage of trained Mineral Processors and Mining Engineers world wide. The Society for Mining, Metallurgy and Exploration (SME) formed a task force to evaluate the national needs for trained engineers and to track the number of engineers who graduate from U.S. universities each year. The statistical information for Mining Engineers is well-developed. The current effort is to assemble similar information regarding students who graduate with expertise in Extractive Metallurgy and Mineral Processing as well as to explore the limitations of the accreditation system in the United States and its impact on the education of Mineral Processors. The long-term objective is to develop a data base regarding Mineral Processing programs and Mineral Processing graduates that is as complete as the one that has been maintained by the Canadian Mineral Processors.INTRODUCTIONIn the United States engineering curricula are accredited by ABET, which was formerly known as the Accreditation Board for Engineering and Technology. The objective of ABET accreditation is to ensure that educational programs in applied science, computing, engineering and technology meet quality standards set in conjunction with the professional organizations that represent professionals in the industries which hire students graduating from those educational programs. For example, the Society for Mining, Metallurgy and Exploration (SME) is the lead society for accrediting Mining Engineering programs in the U.S. For Materials Science and Metallurgical Engineering programs, the lead society is The Mineral, Metals and Materials Society (TMS). SME is a cooperating society for accrediting Metallurgical Engineering programs. Cooperating societies for the accreditation of Materials Engineering include the National Institute of Ceramic Engineers (NICE), the American Institute of Chemical Engineers (AIChE) and the American Society of Mechanical Engineers (ASME)."

Jan 1, 2008

By F. Habashi

Lead is an ancient metal, has been produced to-date from its ores exclusively by pyrometallurgical route. The process suffers from high operating cost and excessive pollution problems. Extensive research has been going on since the beginning of the twentieth century to find a non-polluting process for its production and a solution for its complex refining scheme. It has been assumed correctly that the hydrometallurgical route should be the most promising. Pilot plants have been constructed and operated for a reasonable periods, but no process has proved to be satisfactory. As a result, a number of smelters and refineries have been shut down. The present review analyses the situation and suggests that the best route to treat lead sulfide concentrates is by leaching with fluoroboric acid, HBF4, containing ferric fluoroborate, Fe(BF4)3, and electrolyzing the solution in a diaphragm cell - - a process recently invented by Italian metallurgists. In this process, any silver present in the concentrate remains in the residue together with elemental sulfur and can be recovered by known methods.

Jan 1, 2008

By John Starkey

"During the period June 2007 to March 2007, John Starkey of Starkey & Associates (Starkey) worked in Russia for High River Gold, supervising the engineering design work that was being done at the IRGIREDMET Research Institute, in Irkutsk Russia. The work entailed moving the Newmont No. 4 mill from Elko, Nevada to Berezitovy, a mine site north and west of the city of Skovorodino, in the Amur Region of Siberia. This was a grass roots project and required construction of all phases of the infrastructure and process facilities that are associated with a 5000 t/d open pit mine and CIP mill.During the course of this engineering design exercise, many aspects of doing business in Russia were encountered, with regard to laws, norms, and business practices. This paper discusses many of these findings. Also by living in Irkutsk, many observations on Russian life and social customs were made and these merit discussion from a general interest point of view.Prior to going to Russia, another engineering and ore testing firm (TOMS) had approached Starkey to find out if Starkey could assist them in upgrading their SAG ore testing procedures to Western standards in order to offer their clients turnkey projects, that included reliable SAG and AG grinding. TOMS was aware that Starkey had invented the SPI test but did not know that the SAGDesign test had by then been fully developed and was being offered commercially as the most accurate way in the world to design new grinding mills. They were also unaware that this new testing method had been patented by Outokumpu (now Outotec) and that this method allowed them access to a design method, through Starkey, that would lead to a manufacturer’s guarantee (by Outotec) of throughput and grind for any new semi-autogenous or autogenous grinding circuit, with or without ball mills.When Starkey started working at IRGIREDMET in June 2005, they also made a request to add a design method for SAG mills that would be considered acceptable to Western clients. From these requests, presentations were made in Russian to both institutes and each decided to join the SAGDesign Consulting Group as satellite members and buy a SAGDesign test mill to use with their Bond Ball Mill Work Index mills, to provide SAGDesign testing services. To complete the service, contracts have been put in place for Starkey to use these results to design new grinding equipment and to train engineers at TOMS and IRGIREDMET how to do this work.Starkey also undertook to train engineers at both labs to go into the field and to take the samples for SAGDesign testing programs. It is here where the SAGDesign testing service upgrades other grinding test programs because the samples to be used for design are professionally chosen, and the results will be much more likely to produce a satisfactory design. Starkey is a mining engineer and is uniquely qualified to do this task. This and the SAGDesign test are the key components that lead Outotec to offer a performance guarantee for mills designed by Starkey."

Jan 1, 2008

By Burrows. A.

Temperature profiles in the lead smelter sinter bed at Xstrata Zinc Mount Isa sinter plant have been measured using a wireless temperature probe. Corresponding sinter samples have been collected for characterization. The sinter peak bed temperatures were found to be in the range of 1000 - 1200 °C. Microstructures and softening temperatures of these sinters have been characterised. Strong correlations have been observed between peak bed temperature and peak hood temperature, and between mean sinter softening temperature and peak bed temperature. It was found that higher peak bed temperature results in higher sinter softening temperature. For the feed material used in the trials, to obtain sinters with mean softening temperatures above 1050 °C, peak bed temperatures above 1130 °C are required. There appears to be a direct correlation between granule size distribution in the feed and peak bed temperature attained. High peak bed temperatures are observed in sinters with narrow granule size distribution.

Jan 1, 2008

By F. Hassani, R. Mikaeil, B. Ferdowsi

Two analytical solutions for estimating the ovaling deformation and forces in circular tunnels are widely used in engineering practice, due to soil-structure interaction under seismic loading. This paper discusses the discrepancy between the two analytical and finite difference methods. A comparison of the two analytical methods shows that the calculated forces and displacements are identical for the condition of full-slip between the tunnel lining and ground. However, the calculated lining thrusts differ by an order of magnitude when considering no-slip between the tunnel lining and the ground. The analytical solutions are compared to numerical analyses of the no-slip condition using the finite difference method to validate which of the two methods provide the correct method. To achieve the goal, numerical modelling, field data of the Kuhin railway tunnel and Manjil earthquake characteristics are used. Numerical analysis results agree with one of the analytical solutions that provides a higher estimate of the thrust on the tunnel lining, thus highlighting the limitation of the other analytical solution.

Jan 1, 2008

By Z. Yang, M. J. Collins, N. E. Tuffrey, R. J. Kalanchey, I. M. Masters

The high elevation of China Western Mining Company (WMC)' s Ganhe refinery, and the high iron content of concentrates produced by the WMC mines, were key factors in the selection of pressure leaching by WMC for their new zinc refinery. This paper describes the results of pressure leaching test work conducted by Sherritt in Fort Saskatchewan with a sample of WMC concentrate from Qinghai Province in China. Results from batch pressure leach tests and a four-day pilot plant campaign are reported. The pilot plant campaign included continuous operation of a two-stage pressure leach circuit, as well as neutralization and iron removal steps, resulting in the production of iron-free zinc sulphate solution. Greater than 98% zinc extraction was achieved in pressure leaching, while producing solution containing about 9 g/L H2SO4 and 2 g/L Fe. Following neutralization and iron removal, the solution contained about 170 g/L Zn and less than 10 mg/L Fe. Overall recovery of sulphur in the zinc concentrate feed to elemental sulphur byproduct was about 85%, while 75 to 80% of the indium in the feed was recoverable from the neutralization residue. The test results highlighted the technical and economic advantages offered by the Sherritt Zinc Pressure Leach Process and provided the required data for the engineering design.

Jan 1, 2008

By W. Haibei, Lei. Z., Z. Bangsheng, W. Yufang, J. Kaixi

In 2007 output of zinc was more than 3.71 million tons in China. Some new projects have finished FS and several new zinc plants are building now. In recent ten years it happened great changes in zinc industry. For zinc concentrates one pressure leaching plant was built with capacity 10,000t/a and at least four companies are carrying out FS or engineering design now. Direct atmospheric leaching will put into used in China in 2008 with capacity 100,000t/a. It is estimated that until 2010 the output of direct leaching will be 400,000t/a.

Jan 1, 2008

By M. K. Mishra, U. M. R. Karanam

Relative to slender pillars, larger size pillars exhibit improved strata control. Fly ash, though traditionally treated as a waste product, is emerging as an alternate engineering material. This paper deals with the development of a strong fly ash composite material with additives. The geotechnical properties of this fly ash composite were determined and used to trap model core pillars, which resemble squat pillars. The trapped samples were tested under uni-axial loading in the laboratory and the results showed higher load-bearing capacity of the model core pillars. The reinforced fly ash composites provide lateral confinement and exhibit improved post- failure behaviour of the model cores.

Jan 1, 2008

By J. E. Dutrizac

The dissolution of low-iron sphalerite, (Zn,Fe)S containing 0.08% Fe, in ferric sulphate-sulphuric acid media was investigated using closely sized fractions of crushed sphalerite crystals and sintered disks made from the crushed crystals. Linear kinetics are observed, and the predominant reaction products are ZnSO4, FeSO4 and elemental sulphur. The leaching rate increases systematically with increasing temperature, and the calculated apparent activation energy is 56 kJ/mol for the sized sphalerite and 54 kJ/mol for the sintered disks. The relatively high apparent activation energy suggests that the rate is chemically controlled, a conclusion supported by the insensitivity of the rate to the disk rotation speed. The rate increases as the 0.22 power of the Fe(SO4)1.5 concentration, and as the 0.22 power of the H2SO4 concentration. However, in the absence of ferric ions, the rate increases more significantly with increasing H2SO4 concentrations, and relatively rapid rates are observed in solutions containing >0.5 M H2SO4. In 0.1 M Fe(SO4)1.5-0.3 M H2SO4 media, the measured rate decreases with increasing sulphate concentrations, added as Li2SO4. The rate of dissolution of low-iron sphalerite is promoted by dissolved copper concentrations as high as 800 mg/L. In contrast, dissolved silver, even in the 0-2 mg/L concentration range, significantly retards the dissolution of the low-iron sphalerite.

Jan 1, 2008

By Champoux. G., E. Ghali, W. Zhang, G. Monteith, A. -M. Lafront, G. Houlachi

The efficiency of the electrowinning process of zinc depends on the performance of oxygen evolution reaction, anode quality and corrosion resistance of lead anodes. Original surfaces of rolled commercial lead-silver anodes were examined using conventional polarisation methods in acid zinc sulfate electrolyte with manganese sulphate at 38 °C. The self-discharge method (potential decay) following 5 h polarisation at 50 mA cm-2 was considered to evaluate electrochemical activity, oxygen overpotential and anode stability. The influence of silver content is compared to that of the microstructure, the fabrication process and the composition of the corrosion products. Polished anode samples have also been examined for microstructural and corrosion performance studies. The experiments show that the duration of the plateau at 1600 mV versus SHE, the potential level (active corrosion state/stationary state) and the rate AEco/At during the decay could be a good indicator to compare the corrosion rates of the anodes in industrial zinc electrolytes.

Jan 1, 2008

By E. Pribonic

Failure of a mine material hoist can cause injuries, fatalities and significant infrastructure damage, along with an associated loss of production. Principal causes of hoist accidents are overwind and underwind. Past and present means of arresting hoisting equipment are marginally effective and utilize destructive systems that are not reusable following an arrest. The use of permanent magnet eddy current arrestor technology is proposed; the history and fundamental science of the technology are presented, followed by real world examples and calculations of performance for failsafe, friction-free, instantly reusable eddy current arrestors as applied to stopping a 30-ton ore skip traveling at 16 metres per second. A comparison of existing arrestor types with the eddy current arrestor is included and limitations of the ECA are also discussed.

Jan 1, 2008

By Dave Bulled, Khiratt Husain

"The use of High Pressure Grinding Rolls is gaining significant interest as a replacement for SAG milling in the comminution of hard rock ores because of the potential for reduced costs in terms of energy and grinding ball consumption. Estimation of expected energy consumption for fullscale operations has conventionally involved the testing of a few fairly large samples in pilot scale HPGRs. This paper describes the development of a small-scale batch test method for determining a work index for HPGR of a large number of samples that can be used to show the variability of the ore as an integral part of a geometallurgical approach to circuit design and production forecasting.The test equipment that was developed comprises a hydraulic press with adjustable pressure operating on small batches of ore in a locked cycle test procedure. A work index measurement was determined that links the specific energy consumed in the test to the breakage achieved such that the index can be used to predict comminution energy requirements.The measurements were calibrated against laboratory scale HPGR equipment to develop a model for design and forecasting that includes crushers, HPGRs and ball mills in a complete comminution circuit.INTRODUCTIONEstimation of the expected energy consumption for full-scale HPGR operations has conventionally involved the testing of a few fairly large samples in laboratory and pilot scale machines (Danilkewich, 2006). With the financial input of five mining corporations, SGS Lakefield Research has developed a small scale test capable of providing relevant information on the variability of energy consumption and size reduction from drill core samples. It is our intention that the values measured in the test will be scaled up, through benchmark comparison with pilot sized and full sized HPGR units, to allow plant design and throughput forecast on a block by block basis of the mine plan using a new CEET program. CEET® (an acronym for Comminution Economic Evaluation Tool) is an advanced grinding design and performance predicting tool that uses energy relationships to model the performance of SAG / Ball mill circuits."

Jan 1, 2008

By E. M. Shemang, C. E. Suh, L. Mbinkar, University of Yaounde

"Two iron deposits within the Precambrian mineral belt of Cameroon are described in detail for the first time: the Archean Metzimevin replacement iron deposit enclosed in Fe-enriched itabirite, and the Proterozoic granite-hosted, shear zone-related Mayo Binka magnetite deposit. In the Metzimevin de¬posit, quartz is corroded and microplaty hematite overprints martite-textured hematite. The Mayo Binka massive magnetite veins show evidence of deformation in magnetite (fracturing and microbrecciation) and in overgrowths of specular hematite (mechanical twinning and undulating extinction). The magnetite is partially replaced by hematite (martitization) and goethite. Ores from both deposits have >88% total Fe2O3 and low contents of contaminants such as SiO2, Al2O3, MgO, CaO, P2O5, and TiO2. They are also poor in Cu, Pb, Zn, V, Cr, and Ni. The Metzimevin massive hematite is characterized by an accentuated light rare earth element depletion relative to the Fe-enriched itabirite. It is suggested that the Metzimevin iron deposit is the result of hypogene leaching of gangue minerals from, and further hematitization of, an itabirite protore. Although the genesis of the Mayo Binka massive magnetite is unclear, it is spatially related to Neoproterozoic granitic rocks. The data allow some comparison of these little known, but pot¬entially economic iron deposits, with some of the world’s better investigated deposits, and are useful to the exploration efforts for iron ore currently underway in Cameroon and the Central African subregion.Deux gisements de fer de la ceinture minérale Précambrienne du Cameroun sont ici décrits en détail pour la première fois : le gisement de fer Archéen de Metzimevin formé par remplacement et encaissé par des itabirites enrichies en Fe, et le gisement de magnétite Protérozoïque de Mayo Binka as¬socié au cisaillement dans un granite. Au gisement de Metzimevin, le quartz est corrodé et de l’hématite en microplaquettes se développe au dépends de l’hématite a texture martitique. Les veines de magné¬tite massive de Mayo Binka présentent des évidences de déformation dans la magnétite (fracturation et microbréchification) et dans les surcroissances d’hématite spéculaire (Macles tectoniques et extinction ondulante). La magnétite est partiellement remplacée par l’hématite (martitisation) et par la goethite. Le minerai des deux gisements contient >88% de Fe2O3 total et un faible contenu en contaminants tels que SiO2, Al2O3, MgO, CaO, P2O5, et TiO2. Il est également pauvre en Cu, en Pb, en Zn, en V, en Cr et en Ni. L’hématite massive de Metzimevin est caractérisée par un appauvrissement relatif en terres rares légères relativement à l’itabirite enrichie en Fe. Il est suggéré que le gisement de fer de Metzimevin résulte du les¬sivage hypogène des minéraux de la gangue ainsi que de l’hématitisation poussée d’une préconcentration de fer dans l’itabirite. Bien que la genèse de la magnétite massive de Mayo Binka demeure obscure, elle est spatialement associée aux roches granitiques Néoprotérozoiques. Ces données permettent de comparer ces gisements de fer peu connus et potentiellement économiques avec certains des gisements mondiale¬ment mieux connus, aidant ainsi les efforts d’exploration présentement en cours en Afrique de l’ouest et au Cameroun."

Jan 1, 2008

By Paul Staples, Paul Messenger, Greg Lane

"Every project is different. While “conventional” SAG and ball mill circuits will suit many projects, for others there are alternatives, which may produce improved outcomes. This paper examines particular examples of recent front end designs which either went against conventional thinking or which employed “out of the box” thinking to realize the desired results.One such example is the design strategy employed for a small capacity gold plant in Victoria, Australia. The selection of HPGR technology for small capacity projects is not generally favoured, given the relatively high cost of small HPGR machines. However, the unusual size distribution of the gold and its liberation characteristics were expected to lead to improved gold recovery offsetting the higher capital cost.Another example is the first large scale application of milling in acid for copper recovery, at a project in south east Asia. The stainless steel, single stage SAG mill using ceramic grinding media was more expensive than a mill constructed of conventional materials. However, the steps of scrubbing, slurrying, grinding and leaching could all be achieved in a single unit operation and the need for thickening and repulping with acid after milling was eliminated.Rod mills were selected for both primary and secondary milling duties for another south east Asian project despite their somewhat outdated reputation. A review of previous industry experience confirmed that rod mills could outperform conventional rod/ball or SAG/ball circuits in cases where the size distribution of the ground product is critical to downstream recovery.These examples are discussed with particular focus on the key drivers in each case."

Jan 1, 2008

By D. Komljenovic, E. Lafontaine, J. Paraszczak

Availability of the production equipment used in underground mines has a substantial impact on production costs and, thus, on mine profitability. Appropriate collection of pertinent data and information, as well as use of adequate performance measures and their analyses, can help mine operators identify cost-effective opportunities to improve equipment availability. This paper presents study results aimed at reviewing and analyzing means and measures used to quantify equipment availability and its contributing factors (reliability, maintainability and maintenance support) in several Canadian underground mines. It overviews sources, as well as quality and quantity of relevant data and information, and examines performance measures and their definitions, as applied to surveyed mines. Problems concerning data acquisition and meaningfulness of the performance measures are discussed. The paper concludes with some suggestions and recommendations concerning several aspects of equipment availability assessment. Evidence suggests that the latter may become a more useful tool for mine operators in their efforts to reduce production cost.

Jan 1, 2008

By Joseph Poplawski, Christian O’Keefe, Robert Maron

"Unique and difficult minerals processing measurement situations will be described and the application of passive array-based technology for performing these measurements will be illustrated. Examples of these situations include volume flow measurements in froth lines and flotation feed lines with entrained air, slurry lines with magnetite and other magnetic ore, slurry lines with abrasive or corrosive materials, high pressure lines, and slurry and non-slurry lines exhibiting scale buildup. Other situations include measurement of entrained air levels in pipes and in flotation columns. These measurements are achieved through CiDRA’s patented passive sonar array-based technology. This technology performs two independent measurements – flow rate and entrained air amounts. Two hardware implementations of this technology have resulted in a non-intrusive flow and entrained air meter which easily is installed on the outside of the pipe, and a submersible version for entrained air or gas holdup measurements which is used in flotation processes. Recent developments in extending this technology to solve other unique measurement problems such as valve movement confirmation will be covered.INTRODUCTIONThe minerals processing industry faces many unique and challenging process control conditions and environments. In terms of flow measurements, many of these situations are not being properly served by traditional flowmeters such as ultrasonic meters, magmeters, turbine meters, orifice plate meters, vortex flow meters, Coriolis flow meters, and venturi meters. A new class of flowmeters has been developed that solves these unique situations and flow measurement problems. This new class of flowmeter technology utilizes sonar-based processing algorithms and an array of passive sensors to measure not only flow, but also fluid composition. It does so accurately, reliably and without making contact with the fluid. These measurements are performed on practically any type of fluid within virtually any type of pipe.PRINCIPLE OF OPERATIONSonar array-based flowmeters are ideal for tracking and measuring the mean velocities of disturbances traveling in the axial direction of a pipe. These disturbances generally will convect with the flow, propagate in the pipe walls, or propagate in the fluid or slurry. First let us focus on the disturbances that convect with the flow. The disturbances that convect with the flow can be density variations, temperature variations or turbulent eddies. The overwhelming majority of industrial flows will have turbulent eddies convecting with the flow, thus providing an excellent means of measuring the flow rate as described below."

Jan 1, 2008

By Balakrishnan Nanthakumar, Marek Pawlik, Dennis Grimm

"The anionic flotation of a high-iron phosphate ore from Agrium - Kapuskasing Phosphate Operations was investigated through batch flotation tests in the presence of soda ash. The flotation data were supplemented by titration of the flotation pulp with soda ash, analysis of process water chemistry, and determination of the mineralogical composition of the ore. The results of lab tests were applied to the flotation circuit design allowing the flotation plant to efficiently process problematic ores. Process control measures (pH, conductivity) were also developed.Calcium cations and sulfate anions were identified as the dominant ions present in the process water when the difficult-to-process ores are beneficiated in the flotation plant. The concentrations of calcium and sulfate ions were consistent with the presence of a small amount of a calcium sulfate mineral in the ore although an oxidation/weathering process of iron sulfide minerals present in the ore could also be responsible for the observed water chemistry and subsequent flotation problems with the ores. The latter possibility suggests that the long-term stockpiling of such ores may have a highly negative impact on the flotation process.The role of soda ash in the flotation circuit is to precipitate metal cations from the pulp thus allowing the tall oil-based collector to selectively interact with the phosphate components.INTRODUCTIONPhosphorus minerals are the main source of this element for the production of fertilizers, and the froth flotation process is the most important technology for beneficiating phosphate ores. The flotation concentrate from Agrium-Kapuskasing Phosphate Operations (KPO) is transported to Redwater Fertilizer Operations in Alberta (also operated by Agrium) where the phosphate concentrate is converted into a phosphate fertilizer and other important chemical products. The KPO phosphate ores differ widely in mineralogy and phosphate grades, and are broadly divided on-site into three classes. The easy-to-float A-type ores do not pose any major flotation problems, but the B-type and “marginal” ores, which are quite common in the KPO igneous phosphate deposit, are not always readily-floatable using the current reagent suites and process parameters (pulp density, feed particle size, pH). In fact, marginal ores are presently considered impossible to process by flotation. A-type ores contain normally more than 15% P2O5 and less than 8% ferric oxide equivalent (Fe2O3). B-type ores are approximately of the same P2O5 grades as A-type ores but their iron content may reach 30% Fe2O3. Any material containing less than 15% P2O5 is rejected as waste rock."

Jan 1, 2008

By H. B. Sahu, N. M. Mishra, D. C. Panigrahi

The paper presents the development of a spontaneous heating liability index (SHLI) of coal based on a mathematical approach. The parameters for the calculation of this index have been determined by differential scanning calorimetric studies. Thirty-one coal samples representing both fiery and non-fiery coal seams of different ranks have been collected from different Indian coalfields and their SHLI values have been determined. In addition, the susceptibility of these samples to spontaneous combustion has been ascertained by standard crossing-point temperature measurement. The moisture percentage of all the samples has been obtained by proximate analysis. A comparative study between SHLI and crossing-point temperature, along with moisture percentage, indicates that SHLI predicts the proneness of coal to spontaneous heating more accurately.

Jan 1, 2008

By L. Nichols, H. Keele, K. Czajewski

"The oil sands industry in northern Alberta disposes of the by-products of bitumen extraction into tailings ponds. The mix of tailings sand and mature fines, with gypsum added as a flocculent, constitute a waste stream called consolidated tailings or composite tails (CT). The two main challenges of the tailings disposal process are a chronic shortage of economical containment and the potential mobility of CT deposits in the event of breaching by, for example, long-term erosion, which makes abandonment of tailings ponds more complicated. Thick deposits of CT do not consolidate in adequate time to provide reassurance for abandonment of the CT containment facilities and that is why the containment must be adequately robust or the properties of CT improved for long-term stability. This paper addresses potential solutions to these problems by applying the gravity drainage of CT and quasi-homogeneous construction for containment facilities.Gravity drainage is suggested as a mechanism to facilitate the consolidation of CT in critical areas of the ponds by inserting internal sand layers within the body of the deposit. Critical CT areas are defined as areas around the perimeter of containment. The advantages of this solution are longterm stability of the disposal area by creation of stiff deposits around its perimeter and facilitation of reclamation efforts on its surface.The present solution for containment of CT deposits is not favourable from a materials balance point of view. In general, sand has become a valuable resource as it both forms the primary component of the CT matrix and becomes the containment building material. If sand is required for CT, less is available for dyke construction. This puts additional pressure on the industry as a whole to maximize the use of overburden and interburden for construction of tailings containment structures. Typically, only 50 percent of dry mine waste (overburden + interburden) is incorporated into dyke construction. The remainder of dry waste is stored either in waste dumps or in tailings ponds, consuming valuable in-pond space originally allocated to CT material. Quasi-homogeneous dykes are proposed to contain CT deposits rather than traditional minimum cross-section dykes built of overburden and/or cell sand. The quasi-homogeneous dyke may change the unfavourable material balance and lessen the construction constraints that are presently imposed on the mine/waste disposal process."

Jan 1, 2008