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By C. H. Mathewson

COPPER and the copper-base solid solutions readily form twin crystals when plastically deformed at a suitably elevated temperature or annealed after cold deformation. In fact, no feature of the microstructure of these materials is more prominent or characteristic than these straight-sided bands or simple lines of division which sometimes come from groups of thin polysynthetic lamellae, penetrating part way or wholly through the parent grain substance, but often divide the grain into a few or perhaps only two crystallographically related parts. Nearly always the bands as seen in the usual microscopic examination of a specimen come into vivid contrast with the adjacent crystalline material owing to the inherent difference in orientation. Bands which under special conditions of orientation cannot be seen with vertically incident light are often visible under oblique illumination and, when this fails, contrasting effects usually may be obtained by using polarized light. There is no longer any doubt that these synthetic banded structures obtained in the ordinary course of working and annealing are due to twinning of the spinel type which was observed long ago in a number of metals crystallizing in the isometric system.1 It has been customary in metallurgical literature to designate these synthetic twins, which grow into prominence during an annealing process, as "annealing twins" without regard to the actual mode of their formation, which is, indeed, obscure and with scant recognition of the fact that prior deformation is essential, no twins having been observed in metal of known unstrained history. This is questionable; especially in view of. the fact that in a number of metals and minerals, reorientation into the twin configuration is known to occur as a result of a simple shearing mechanism along the recognized twinning planes and the

Jan 1, 1930

By Selma Hermann

For the past century, the so-called aluminum bronzes have been assuming a role of ever-increasing importance in the metallurgical field. The last quarter of that century has marked many efforts to find alloying elements that would alleviate some of the undesirable qualities of the aluminum bronzes-for example, the heterogeneity of the alpha solid solution and the extreme hardness of the beta. Much of this work, however, has been rather haphazard-compositions and heat treatment are usually so much at variance as to make comparison impossible. It is the object of this research to study the effect of certain percentages of common alloying elements on aluminum bronzes of analogous compositions and heat treatments. It is hoped that the material gathered here will at least serve as a basis for further systematic study.

Jan 1, 1930

By C. T. Eddy, R. W. Drier

The conductivity of copper wire is of prime importance to the electrical industry and consequently to the copper refiner and wire manufacturer. Annealed copper wire has a higher conductivity than hard-drawn wire, but, on the other hand, its tensile strength is lower. In an attempt to explain the reasons for these changes in properry. or at least to study the conditions existing in these two types of copper wire, the experiments described here were carried on in the Department of Metallurgy of the Michigan College of Mining and Technology This is only a partial and preliminary report on some of the work done to date on a research program of which the object is an intensive study of copper. It is offered with the hope that, though it is not an exposition of the most rigorous of conclusions, the general trend of inferences which may be drawn will be of value and interest. Effect of Direction of Drawing In 1928 some work was done on hard-drawn copper wires to determine whether wire drawn in a continuous machine (that is, all in one direction) would have a different structure from wire that had a reversal in direction at some stage of the drawing process. The diffraction spectra obtained indicated that as the position of the wire rayed approached the core, a preferential crystal orientation existed, and that the closer to the core the more preferred was the orientation. The data obtained partly corroborated the work done by Schmidt and Wassermanl and by Clark.2 Samples Used in Following Investigation The samples selected for use in both the diffraction work and the resistivity measurements were taken from Nos. 6, 8, 10 and 12 gage

Jan 1, 1930

The problem of surface support in coal mining is naturally divided into three branches: 1. Surface covered with improvements of such value as compared with the value of the underlying coal, or with such elements of danger to mining, that absolute support is essential. 2. Surface with improvements of less value than the underlying coal such that moderate settlement may be permitted, but destructive settlement must be avoided, either by reason of danger to human life or unwarranted property damage. 3. Surface of relatively small value as compared with the underlying coal where destructive settlement may be permitted. First Problem In the first case it is evident that the original support must be maintained either (a) by leaving ample pillars and confining the coal recovery to a very conservative first mining, (b) by so supporting less conservative first mining by filling or flushing that the gradual deterioration of the pillars may be prevented and subsidence avoided, or (c) by incompressible support as masonry either as an adjunct to insufficient pillars or in place of the original coal support. a. From tests made by the Scranton Engineers Club, it appears safe to figure on 2000 Ib. per sq, in. as the safe squeezing strength of coal pillars in place, provided that these are, as usual, not higher than their least horizontal dimension; and from this figure the percentage of pillar to be left for various depths may be easily calculated. For safety in this

Jan 1, 1930

By Cyril Stanley Smith

Although alloys of copper and silicon were examined several years ago,' and their excellent mechanical properties were shown, it was not until C. B. Jacobs 2 introduced manganese in small quantities to the alloys that they became of commercial importance. A few years ago The American Brass Company took over the patents and commenced to manufacture the alloy under the name "Everdur." The present study of the constitution of the ternary system was undertaken in order to reach a fuller understanding of the behavior of the alloy. Review of Previous WORK on the BinaRy Systems There have been no papers published dealing with the constitution of the ternary system, although some tests of the mechanical properties have been described," which indicate that there is a change in solubility with temperature. Copper-silicon System The copper-silicon system has been studied in detail by the author and is described in two papers published in 1928.V he portion of the diagram up to 8 per cent. silicon, as determined by this research, is reproduced in Fig. 1. The author's previous papers include a complete review of the work of other investigators and it is not necessary to deal further with this system here. Copper-manganese System The copper-manganese system has been investigated by several workers, notably Lewis,5 Wologdine,6 Sahmen7 and Schemtschuschny,

Jan 1, 1930

By J. M. Gaines, C. H. Herty, M. W. Lightner, H. Freeman

Few subjects have attracted the attention of metallurgists more than oxygen in steel. From the days of Mushet and Ledebur interest in this subject has been increasing, and as additional knowledge has become available, the problem has naturally grown more complex. Instead of using the simple term "oxygen" we now distinguish between iron oxide, silicates of various kinds, oxysulfides, oxygen as gas and oxygen in solid solution in steel. There are five general methods for determining oxides in steel: hydrogen reduction; vacuum fusion; various wet-extraction methods, including electrolytic methods; methods depending on volatilization of the iron away from the oxides; and metallographic methods. For oxygen in solid steel each of these methods has both advantages and disadvantages. The hydrogen-reduction method is of no use on steels above about 0.20 per cent. carbon;' furthermore, it gives only FeO and possibly some MnO. The vacuum-fusion method2 is expensive and gives total oxygen, with the exception of some A12O3, and does not differentiate between the various oxides in which the oxygen exists. Most of the wet extraction methods3 give only the more insoluble oxides SiO2 and A12O3, though the iodine method gives MnO to an uncertain degree (information that may be more misleading than no information

Jan 1, 1930

By N. A. Ziegler

IN every research it is desirable to eliminate as many variables as possible and to leave only a few to be investigated one at a time. Metallurgical problems are no exception. Some of the variables that are difficult to control are the size, the distribution, and the orientation of the grains in a metallic test piece. It is therefore very desirable to obtain isolated metallic grains (single crystals, as they are commonly called) large enough to enable one to study their mechanical and physical properties. The present investigation is a part of magnetic research work on iron and iron alloys, undertaken to obtain, if possible, the magnetic properties of pure iron (Fe). This paper will deal primarily with the preparation of single crystals of iron and their mechanical properties, while another paper, by T. D. Yensen, now in preparation, will deal specifically with their magnetic properties. The work with "single crystals" is attracting more attention every year among the investigators in metallurgy. Van Liempt1 gives an interesting summary of the work done and the different methods used in the preparation of metallic single crystals. Briefly stated, the four principal methods used are the following: 1. The cooling of a liquid metal in such a way that the crystallization would start at one point only, causing the entire liquid to solidify as one crystalline unit. This method can be successfully applied to the majority of the metals that do not have any allotropic transformations in the solid state. It has been used and described by a number of investigators,2 but it has never been successfully applied to iron on account of allotropic transformations.

Jan 1, 1930

By Howard Scott

INVAR is the preeminent low-expansion metal by virtue of the fact that it can be prepared with a zero coefficient of expansion at atmospheric temperature. This fact suggests that there is little room for improvement in the expansion properties of the low-expansion nickel steels. The inference is true, however, only so far as the expansion at and near atmospheric temperature is concerned, because the expansivity of invar starts to increase rapidly on heating above 100° C. and soon reaches the value of copper. Guillaume1 met this situation by increasing the nickel content above that of invar. By that expedient, alloys having low expansivity under higher temperatures were obtained, but not without a large increase in minimum expansivity. The increase in minimum expansivity with increasing nickel content severely limits the technical applications of these alloys at high temperatures. Prospects of improving the expansion characteristics of the nickel steels is offered by alloying. Search for an advantageous alloying addition by analogy with other alloy systems, however, is not productive because the low-expansion characteristic is unique with that system. The rule of mixtures usually gives a fair value of the expansivity of other solid-solution alloys, but in the iron-nickel systems gives a value of 18 X 10-6 per deg. C. whereas the actual value is 1 X 10-6 per deg. C. Apparently suitable additions are not to be deduced from such ingenuous considerations. Recognition of the fact that the temperature range of low expansivity in nickel steels is terminated with loss of magnetism affords a more promising basis for the selection of an advantageous element. One may expect from that fact that additions of nonmagnetic elements to the iron-nickel alloys are detrimental to the low-expansion characteristic. Indeed, carbon, manganese, silicon, copper and chromium are detri-mental to the expansion properties and no nonmagnetic element is reported to be beneficial. From the same viewpoint, the addition of a magnetic metal offers prospects of improvement. As two of the three ferromagnetic elements are already present in the

Jan 1, 1930

By A. M. Guadin

Direct quantitative comparison of the results of concentrating operations on different ores is frequently desired but almost impossible to obtain if comparison has to be made by means of two quantities for each ore, as must be done at present. This paper represents the outgrowth of attempts to arrive at a single-number quantitative measure of the segregation between minerals or metals as the result of concentrating operations. The usual practice in estimating the effectiveness of concentrating operations, particularly those of ore dressing, has been to determine the recovery of the metal or mineral of interest and the grade of the concentrate. The difficulty in quantifying the effectiveness of concentration by the usual criteria may be illustrated by a few examples. Consider, for instance, two lead ores which yield by flotation the same recovery of lead, say 92 per cent., and the same grade of concentrate, say 60 per cent. Pb. If a substantial difference in the grade of the feed had existed, say if one ore contained 5 per cent. Pb and the other 10 per cent., it is clear that the concentrating operation was more effective in the case of the lower grade ore. It is difficult, however, in the light of these data to state how much more effective was the concentration of the lower grade ore. Consider again two lead ores containing 5 and 10 per cent. Pb and yielding concentrates containing 60 and 72 per cent. Pb respectively, with recoveries of 93 and 92 per cent. respectively; it is well-nigh impossiblc to tell from these figures which results represent the best separation of the minerals. It may be noted that in the usual method of estimating the effectiveness of the segregation of mineral values, no consideration is given to the rejection of the unwanted substances from the concentrate, except in the very indirect manner in which it enters into the grade of the concentrate. Consideration of the rejection of gangue from the concentrate, adequately weighted with recovery of the desired mineral in the concentrate, should supply an adequate criterion of concentration effectiveness.

Jan 1, 1930

By Walter Remmers

THE fact that gray iron increases in volume, cracks and distorts upon repeated heating and cooling is rather common knowledge. In ingot molds, Diesel engine pistons, carburizing boxes, continuous furnace parts, grate bars, stoker parts, and all castings that are subjected repeatedly to high and low temperatures, the phenomenon of growth presents a vital problem. Ingot molds distort and produce cracks which result in seams or laps and later appear as defects in the finished product. The heads of Diesel pistons frequently fail by cracking in a stellar shape. This is attributed usually to the result of permanent growth. Distortion and change of dimension of furnace parts frequently renders them entirely unusuable. In chain grate stokers, mechanical difficulties frequently are caused by the growth of the links. In proper operation these links should never attain a temperature sufficiently high to start growth; nevertheless, some have grown 1/8 in. on an 8-in. length when improperly operated. Even though the phenomenon is generally known there still exists a deficiency in the explanation of the mechanism of this growth. The field of investigators of this subject has a decided variation in opinion concerning the causes. The problem is of sufficient importance therefore to warrant further consideration.

Jan 1, 1930

By R. Thiessen

The question whether the kind, rank and grade of coal is in any way determined by the kind or type of plant from which it originated has been a problem since coal was first studied. Some investigators claim that the kind of plants has contributed none of the attributes that characterize the differences found in the various coals; others claim that all differences are caused by the contributing plant; and others hold that only a few characteristics are inherited from the kind of plant from which the coal originated. Most coalologists, however, give this matter no thought. It can easily be shown that the kind of plant which contributed to a coal had a marked influence on its kind and type. A number of factors enter into this problem, and all unrelated ones must be carefully eliminated, including metamorphism caused by the pressure of the cover, earth movements, mountain building and higher temperature. Only the fundamental substance—the plants out of which coal was formed—• and the causative conditions that gave rise to a peat swamp and the conditions imposed upon the plant and the plant substances during the formation of the peat swamp can be considered. Everything else being equal, the question then is, how far do different classes and types of coal owe their differences to different kinds or types of plants? Geologic Age of Coal Coal has been laid down in almost every geological period since the Devonian era. Even as early as the middle Devonian some coal was formed; although of no value it has great scientific significance. The most valuable coal was deposited during the Carboniferous. The coals of England were formed during the Mississippian, and most of the valuable coals of America, Europe and China during the Mississippian and chiefly the Pennsylvanian. From the Permian come the coals of France, Saxony, Thuringia and Schwarzwald in Germany and of Bohemia and of the Ural districts of Russia. From the Mesozoic come the coals

Jan 1, 1930

By M. MacFarland, E. McAuliffe

Our North American railway system, including the lines serving the United States, Canada and Mexico, with a total operating mileage of 303,040, employing 71,818 locomotives, represents not only the greatest industrial user of fuel coal, but in the variety of coals used, ranging from anthracite down through the several gradations of bitumirlous coals, as well as lignites, covers about all there is in American-mined coals. Necessarily the wide range of fuel coal embraces not only extremes of calorific value but also every possible gradation shown in size and preparation, from run of mine to washed nut and slack. Approximately 8 per cent. of the fuel used by the railroads is consumed in shop power plants, shop buildings, pumping stations, station buildings, etc. The principal class of coal (as designated) used by the railroads is bituminous, such, however, including a substantial tonnage of subbituminous and lignite coal; all United States railroads using in 1923 for locomotive, shop, station buildings and miscellaneous uses, a total of 4,578,000 tons of anthracite, 155,795,000 tons of bituminous, subbituminous and lignite coal and 58,005,000 bbl. (42 gal.) of fuel oil. The Class 1 railroads of the United States (those whose gross annual earnings equal or exceed $1,000,000) used in 1926: Bituminous, subbituminous and lignite coal, net tons..... 140,083,885 Anthracite, net tons................................ 3,667,505 Fuel oil, gal........................................ 3,058,915,511 Railroad fuel-purchasing agents rarely attempt to classify coal for locomotive use on the basis of chemical analysis; although this is very generally used as a guide in the initial selection of a fuel supply. The extraordinarily high rate of combustion developed in the modern locomotive, generating as high as 2500 b.hp., with limited facilities for cleaning fires en route, suggests the importance of a fuel supply containing a reasonably low percentage of ash-making material, and while the percentage of locomotive coal handled through automatic stokers is growing, the principal tonnage is yet fired by hand.

Jan 1, 1930

By Stewart Coleman, Thomas W. Moore, H. D. Wilde

It is recognized that in the early days of the petroleum industry oil was produced with practically no scientific or fundamental knowledge of the laws and principles governing its extraction from the ground. Only a few, if any, of those exploiting the oil resources made any effort to collect accurate scientific information. There was little need for it, for as is frequently the case where the supply of a natural resource appears inexhaustible and is greater than the demand, large profits were possible from merely skimming the surface with little regard to the efficiency or thoroughness with which the oil was obtained. With this policy in force, great quantities of gas were wasted and when the reservoirs ceased producing by natural means they still contained a large fraetion of the oil originally in them. The present tendency in the industry is toward conserving existing oil reserves. In order that greater percentages of the oil present in the ground may be recovered, efforts are being made to improve production methods and to rework depleted fields. If the production methods are to be improved intelligently it is essential that the fundamental laws be known and understood, consequently large amounts of money and effort are being spent in gathering data that will serve to define and interpret these laws. A great deal of attention is being focussed on the study of the motion of oil through an oil-bearing sand, the forces that cause it to move and the factors that affect its motion. It is recognized that one of the important factors is pressure, but its quantitative effect is not known. In a given field the rate of production declines with time and so does the rock pressure. Furthermore, a comparison of different fields shows, as a

Jan 1, 1930

By W. H. Blauvelt

The only way in which the difficult problems of classification of coal for the manufacture of by-product coke can be solved is to analyze them by the use of scientific data. It is very easy to adopt classifications for coal for the manufacture of by-product coke along certain lines; we can easily say that for a certain class of metallurgical operation coke made from bituminous coal must not contain more than so much sulfur or more than so much ash and should yield certain returns in the by-products, tar, ammonia, benzol, gas, etc. Those points we are fairly clear on and I think it is hardly worth while to discuss them because I presume that they are familiar to most of us who have any occasion either to make coke or to use it. But there is a field in the manufacture of coke which we know very little about. For example, we are operating a plant on a certain mixture of coal. Suddenly our blast-furnace man or the user of the coke tells us the coke is not as good as it was before. The coke is analyzed and the coal is analyzed. Everything seems to be about the same as it was— the ash is the same, there is no more sulfur, and so on—but the coke, for the use to which it is put, particularly in the blast furnace, is wrong. What happens? The management decide to try a slightly different coal mixture. They do not necessarily raise the total hydrocarbons, the volatile matter in the mixture, nor change the sulfur or the ash, but they do make a change which improves the value of the coke for metallurgical use. The reason for this difficulty, as I see it, is the " combustibility " of the coke—I hesitate to use the word, but it is the best one I have available. Combustibility of Coke We know now that the combustibility of coke is a very vital point in many metallurgical processes and I think one of the most notable instances of the proof of this is the experience of the Carnegie Steel Co. in the production of coke at its Clairton plant. The history of that

Jan 1, 1930

By George H. Ashley

At the beginning of the war, about 13 years ago, a conference was called in Washington to lay plans for pooling the coals of the United States. A careful review of the various systems of classification then extant showed none well adapted to the needs of coal pooling. The system of Tidewater pools then adopted, using numbers to distinguish one pool from another, was based on typical coals of different localities. At that time, the writer undertook the preparation of such a practical classification. Aside from drawing on his experience of over 20 years in the coal fields of the United States, reaching from the Pacific Coast and the Rio Grande to Rhode Island, he first examined and carded all of the large collection of coals in glass jars made by and for M. R. Campbell. Next, he carded all of the descriptions of coals he could find in the U. S. Geological Survey bulletins and elsewhere, as well as practical tests of coals by the Navy and other organizations and then took account of every published coal analysis of the U. S. Geological Survey and U. S. Bureau of Mines. A study of this information, involving thousands of recomputations, led to the presentation of a paper on "A Use Classification of Coal" before this Institute at the Chicago meeting, September, 1919. That classification was unique (1) in a classification based on "standard coal" which included moisture, but used standardized ash, sulfur and nitrogen, (2) in using physical properties to distinguish the major classes or orders, (3) in recognizing British thermal unit values in the minor subdivision, (4) in the large number of classes recognized (thirty-six), (5) in proposing mineral names for all classes, (6) in proposing a letter code for the several classes for practical use, (7) in proposing a code for expressing what has commonly been called "grade" of the coal, the grade code to be combined with the rank code to designate and describe a coal. The writer still thinks that the principles then offered, though not necessarily the exact proposals, are valid and desirable in any practical classification. The actual classification of coal by rank was based on the ratio of fixed carbon to volatile matter for the high-rank coals—the well-known

Jan 1, 1930

5. The medal committee may invite nominations from the membership of the Institute, such nominations to be accompanied by an argument in favor of the award and details sufficient for a proper citation to be drawn. This medal has been awarded as follows: 1927—David William Brunton. 1929—John Hays Hammond. 1928—Herbert Hoover. 1930-Daniel C. Jackling. Miscellaneous Prizes Many of the Local Sections have established or administer prizes for the best paper presented within the year by any junior member. Annual Lectures Howe Memorial Lecture The Howe Memorial Lecture, in memory of Henry Marion Howe, Past President of the Institute, was authorized in April, 1923, as an annual address to be delivered by invitation under the auspices of the Institute by an individual of recognized and outstanding attainment in the science and practice of iron and steel metallurgy or metallography, chosen by the Board of Directors upon recommendation of the Iron and Steel Division. The following were the Howe lectures and lecturers for the years indicated: 1924 What is Steel? By Albert Sauveur. 1925 Austenite and Austenitic Steels. By John A. Mathews. 1926 Twenty-Eve Years of Metallography. By William Campbell. 1927 Alloy Steels. By Bradley Stoughton. 1928 Significance of the Simple Steel Analysis. By Harry D. Hibbard. 1929 Studies of Hadfield's Manganese Steel with the High-power Microscope. By John Howe Hall. 1930 The Future of the American Iron and Steel Industry. By Zay Jeffries. Institute of Metals Lecture An annual lectureship was established in 1921 by the Institute of Metals and it has come to be one of the important functions of the Annual Meeting. A number of distinguished men from this country and abroad have served in this lectureship. The roll is quoted below: 1922 Colloid Chemistry and Metallurgy. By Wider D. Bancroft. 1923 Solid Solution. By Walter Rosenhain. 1924 The Trend in the Science of Metals. By Zay Jeffries. 1925 Action of Hot Wall: a Factor of Fundamental Influence on the Rapid Corrosion of Water Tubes and Related to the Segregation in Hot Metals. By Carl Benedicks. 1926 The Relation between Metallurgy and Atomic Structure. By Paul D. Foote. 1927 Growth of Metallic Crystals. By Cecil H. Desch. 1928 Twining in Metals. By C. H. Mathewson. 1929 The Passivity of Metals, and Its Relation to Problems of Corrosion. By Ulick R. Evans. 1930 Hard Metal Carbides and Cemented Tungsten Carbide. By 8. L. Hopt.

Jan 1, 1930

By A. W. Fahrenwald

The function of the c1assifier in modern fine-grinding practice is to remove a finished product from the grinding-mill discharge, leaving material that needs further comminution. The classifier, therefore, makes two products: (1) "finished" product, which overflows the rim of the classifier tank, sometimes referred to as "slimes" or as "classifier overflow," and (2) "unfinished" product, which settles to the sloping bottom of the classifier tank and is removed by dragging or raking. This product is generally referred to as "sands" or "oversize." One of the outstanding features of the closed-circuit classifier is its ability automatically to return the unfinished product of the ball-mill discharge to the feed end or scoop box of the ball mill. This is a distinct advantage because it avoids dilution of the ball-mill feed, and, furthermore, the particu1ar method of removing the settled sand, by raking it up the inclined bottom of the classifier, gives a classifier discharge containing a minimum of water. This leads to maximum classifier efficiency, in this type of classifier, because the maximum volume of water is displaced upward by the settling sands. The closed-circuit classifier is required to deliver a finished pulp of closely specified density requirements, therefore added hydraulic water generally is not permitted. Relation of Classifier Efficiency to Grinding Efficiency The energy of crushing, and therefore the cost, according to Rittinger's Law,l is proportional to the new surface exposed in crushing. Since the new surface produced in crushing is nearly proportional to the reciprocals of the diameters crushed to, it is obvious that the cost of crushing in the finer sizes is tremendously greater than in the coarser sizes for equal ratios of reduction. High circulating load of finished sand in the circuit of the classifier and grinding mill is therefore obviously expensive practice. It is the classifier's function to reduce this to a miniMum.

Jan 1, 1930

By R. S. Archer

THE binary aluminum-silicon alloys have certain characteristic advantages which are now well known, and these alloys have come into considerable use during the past several years.1 Their field of application has been limited to a certain extent, however, by their low yield point and hardness, low endurance limit, and relatively poor machining characteristics. These properties are improved by the addition of copper, and the ternary aluminum-silicon-copper alloys constitute an important class. The addition of copper decreases the corrosion resistance of the aluminum-silicon alloys and increases specific gravity. Magnesium is a hardening addition which seems to have relatively little effect on corrosion resistance, and which, of course, reduces specific gravity. The object of the work described in this paper was the development of alloys and heat treatments for the production of sand castings and permanent-mold castings having substantially all the advantages of the binary aluminum-silicon alloys together with mechanical properties improved to a degree permitting wider application.

Jan 1, 1930

By W. E. Mitchell

The ore that is being treated by the present plant lies between the leached zone, or capping, and the mixed sulfide and oxide zone. The principal copper minerals are chalcanthite (CuS04.5H20), brochantite (CuSO4.3Cu (OH)2 and atacamite, (CuC12.3Cu (OH)2). There are, in addition, some other minerals such as cuprite and kröhnkite (CuS04. Na2S04.2H20). These minerals, with many others, occur in a greatly crushed granodiorite rock. most of the copper-bearing minerals occur in the cracks and veinlets, but there are disseminated values and it is probably the relative proportion of these that accounts for some otherwise unexplainable variations in extraction. The entire mineralization of the ore is complex and varies with depth. This variation, the problems presented thereby, and the effect of various constituents of the ore will be taken up in detail. An analysis of :in unweighted composite of the ore treated during 1927 follows: I'Lr Cent. Per Cent. Per Cent. Cu............... 1.58 S................. 2.10 Mo............ 0.01 SiO? ............. 66.10 HNO3 ........0.03 As............ 0.005 Fe.......... 1.41 C1 .............. 0.05 Sb............. 0.005 CnO ..... 0.20 Na................ 0.80 Ba............ 0.01 A1203 .......... 17.70 KI.............. 4.80 H20............ 0.70 mgO.............. 0.68 Mn............... 0.07 0 in sulfates. . . . 3.94 Total..... 100.19 The most important constituents of the ore, as indicated by experience to date, are: (1) The total copper content; (2) the acid-insoluble copper; (3) the acid-making copper mineral, mainly the chalcanthite; (4) the chlorine; (5) the nitrates; (6) the soluble iron; (7) the soluble molybdenum. The total copper content needs no discussion. In Table 1, the values are weighted averages calculated from individual charge analyses. The acid-insoluble copper directly affects the extraction, as the present leach recovers practically no acid-insoluble copper. In Table 1 the values are unweighted averages of the analyses of monthly composite samples. The acid-making copper mineral affects the amount of copper that can be dissolved from the ore without neutralizing acid in the solution. The

Jan 1, 1930

By Alfred H. Bell, Paul F. Simpson

The year 1929 was one of continued activity in the petroleum industry of Indiana and Illinois but the new production obtained has not been sufficient to offset the decline in the production of the old wells. (Table 1). Drilling costs have not changed materially during the year and the prices of crude oil have increased slightly so that the prospects for further testing are good. The total number of completions in Illinois in 1929 (Table 2) was greater than for any year since 1917. More than half of these were in the Dupo field, St. Clair County, and the development of this field was largely responsible for the increased ratio of producers to dry holes in the state as a whole. In the southeastern Illinois field which has produced about 97 per cent. of the state's petroleum the number of completions was greater than in 1928 and the percentage of producers was a little higher. Although a number of scattered wildcat tests were drilled most of them were not located on favorable structure and the only noteworthy discovery was that of a shale-gas horizon at shallow depth in Morgan County in western Illinois where gas has been produced for a number of years from sandstone and limestone. In Indiana the number of completions (Table 2) was only slightly less than in 1928. Most of the new wells were drilled in the southwestern part of the state, which now produces more than 90 per cent. of Indiana's petroleum.

Jan 1, 1930