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By Pol Duwez, Paul Pietrokowsky

The crystal structure of the compound TisGeS has been determined from X-ray powder diffraction data. Related silicon and tin compounds have been found to be isomorphous. Unit cell dimensions, axial ratios, and parameters for equivalent atomic positions are given. THERE is, at present, only meager information pertaining to the solid state reactions of titanium with the elements in group 4B of the periodic table (silicon, germanium, tin, and lead). The only two compounds whose crystal structure has been established are TiSi² and TiGe² (references 1 and 2 respectively). These two compounds are isomor-phous and have an orthorhombic symmetry D242h— Fddd. The titanium-rich regions of the constitution diagrams of titanium-silicon, titanium-tin, and titanium-lead have been investigated by Craighead et al.³ While valuable information concerning the alpha solid solubility of these three elements in titanium was obtained, no light was shed on the existence or nature of the titanium-rich compound in these systems. The present study is concerned with the crystal structure of the intermediate phases Ti5Si ?, Ti³Ge³, and Ti5Sn³, which were found to be isostructural. The alloys were prepared by mixing the pure metal powders in the desired proportions, pressing the mixture into pellets, and melting them in an electric arc furnace in the presence of a helium atmosphere.& After melting, the specimens, weighing approximately 5 g, were sealed in evacuated quartz vials, homogenized at 1038°C for three days, and quenched from that temperature. Powder diffraction patterns were made with a 143.2 mm diam Debye-Scherrer X-ray camera in which the Ievins and Straumanis film arrangement was utilized. Filtered copper radiation was used throughout the entire investigation. A study of the powder patterns of a series of alloys of various compositions indicated the presence of a compound around a composition corresponding approximately to a ratio of 3 titanium to 2 silicon, germanium, or tin. From a visual examination of the diffraction patterns, it was evident that the silicon and germanium alloys were iso- morphous. For small angle reflections, the powder pattern of the tin compound was analogous to that of the silicon and germanium compounds, but after the first ten reflections, the similarity was no longer clear. The powder pattern of the germanium compound was selected for indexing, since it exhibited a weak small angle reflection and clearly resolved doublets in the back-reflection range. Good agreement between observed and calculated values of (1/d)² was found by indexing the pattern on the basis of hexagonal symmetry. For the hexagonal system:

Jan 1, 1952

By R. P. Carreker, R. L. Fullman, J. C. Fisher

THE existence of the phase TiAg has not been reported previously. Other investigators have denied the existence of compounds in the Ti-Ag system.13' However, phases of equi-atomic proportion have been reported by Raub, et al.' in the (similar) systems of titanium with gold and copper and zir- conium with silver. Raub's work indicated that titanium and silver are immiscible in the liquid state. No evidence of this was found although a very wide melting range exists which makes the preparation of homogeneous alloys difficult. TiAg is apparently formed by a peritectic reaction between /3

Jan 1, 1954

By V. B. Tare, H. Schmalzried

The use of solid electrolytes for determining kinetic paraneters at elevated tevnperatures is pointed out. The reaction rate constant k1 of the phase-boundary reaction during oxidution of iron to wiistite by CO2-CO gas mixtures has been deternined between 850 nnd 975C, using ZrOz(+CaO) as an electrolyte. Values are between 1.4 x 10-a and 5.2 x 10 ole per sq ctn atm. The tzain difficulty is due to mixed potentials arising from side reactions at the electrolyte inteyface. In a number of papers the calcium-doped zirconia electrolyte has been used for the determination of thermodynamic data from measured differences in oxygen activities (or potentials) between two electrodes. The purpose of this note is to suggest the use of this solid electrolyte for kinetic measurements as well. The principle can be seen from Fig. 1. A thin and compact phase II (electron conductor) is fixed on a plate of gas-tight, polished ZrO2(+CaO) (I), which separates two compartments with different oxygen potential. p, is a constant reference pressure of oxygen (1 atm). The electromotive force of this galvanic cell is given by E = RT5 In pep, and pe is the oxygen partial pressure at the interface electrolytephase 11. If phase I1 is in equilibrium with the surrounding gas phase, p, = DR. If pg changes sud- denly to a value pi, p, and therefore the electromotive force, E, change as a function of time according to the phase-boundary reaction rate at the gas phase I1 interface and the transport processes inside phase 11. It is assumed that local equilibrium is established at the boundary electrolytephase 11, that the gas phase shows no concentration gradients, and that the con-

Jan 1, 1967

[NORTH AMERICA UNITED STATES ALABAMA Bessemer Coston, Otis D., Jr. Birmingham Cord, Richard M. Dismukes, Edward B. Pagel, Herbert E. Citronelle Mason, Seeber William Mize, Frank W. Perrin, Huey P. Fairhope Ruffles, William R., Ill Huntsville Waggoner, J. B. Mobile Hankins, James D. Petroutson, Peter C. Montgomery Crenwelge, Joe Ed Tuscaloosa Mason, William L. University Jones, Walter B. *Ricnards, Edward F.]

Jan 1, 1961

PRODUCTION of nonmetallic mineral raw materials used by the fertilizer, ceramic, chemical, and construction industries and many others, was greater during 1953 than in any previous year. Production of fertilizer minerals was the highest in history despite somewhat decreased consumption in the second half of the year. Marketable phosphate rock production increased 10 pct to an estimated total of 13.1 million LT, valued at $78.5 million, and potash production was estimated at 1.8 million tons of K2O equivalent, valued at over $60 million. Crude gypsum output exceeded the 1952 total and approached the record of 8.66 million tons mined in 1951, with indications that 1953 will show a new all-time high. Gains and losses among gypsum products were irregular, with major gains in plate- glass and terra-cotta plasters, sanded building plasters and miscellaneous building plasters, and principal declines in base-coat plasters, prepared finishes and tile. Lath and wallboard outputs were each about 20 pct higher than in 1952.

Jan 2, 1954

By E. Northcott, I. M. LeBaron

Before describing the electrostatic processing of feldspar, it might be well to review some of the basic definitions and terminology of feldspars. The feldspar minerals constitute a group of alumino-silicates of potassium, sodium, and calcium. Barium feldspar sometimes occurs naturally but is very rare. Hardness varies between 6 and 6.5 and specific gravity between 2.5 and 2.8. Color is generally white or pale shades of red, yellow, or green. The approximate chemical composition of the principal feldspars is given in Table I. The albite (sodium aluminum silicate) and an-

Jan 1, 1959

By Paul Weir

During the past decade, methods of producing bituminous coal in the state of Illinois, which ranks third in production among the states in which bituminous coal is mined, have undergone great changes. From less than one million tons in 1923, the strip-mine production has gradually increased to a high of 11,725,870 tons in 1937. From a negligible amount prior to 1927, the amount of coal mechanically loaded underground had increased to a high of 28,374,362 tons in 1937. The amount manually loaded in 1937 reached a low of 12,332,023 tons. In this same year, this state ranked first in strip-mine production, also in mechanically loaded production. For this reason a study of the influence of mechanization on location of production in Illinois may be helpful in anticipating what may happen in other producing states. The reason for the changes in methods lies in the differences in costs of production. The Bureau of Research and Statistics of the National Bituminous Coal Commission has made public the following costs of production by various methods in the state of Illinois (district 10) for the last nine months of 1937: all mines, $1.7602 per ton; strip mines, $1.4319; mechanical loading mines, $1.7457; hand loading mines, $2.1793; all underground mines, $1.8703. These are weighted averages for the entire district. Inasmuch as production in 1937 was reported from 58 counties scattered over two-thirds of the area of the state and from five different seams varying in thickness from less than 3 ft. to as much as 12 ft., it is apparent that the location of production must be influenced by the extent of mechanization possible in the various producing counties. SHIFT in Production The term "mechanization" is commonly used to designate the coal-loading operation. However, in a broader sense it embraces the use of any and all mechanical and electrical equipment on the surface and underground. Strip mining is an intensive form of mechanization. The mechanical cleaning of coal is a form of mechanization. Cutting machines and motor haulage likewise are forms of mechanization, hence

Jan 1, 1940

Jan 1, 1892

By H. D. Pearsall

It is well that the usual system for supplying water at high pressure purposes of hydraulic mining possesses serious disadvantageense, delay and large annual repairs. Where plough work possible, the first expense of the ditch is moderate; but it is verynree years before the work is solid and the ditch water-tight, lxPenditure for repairs being needed during this time and greaf water occurring. Moreover, in the course of a long ditch, it happens that part of it has to traverse a diffi cult country fluming, masonry, or other expensive construc tion is necessich makes even the first cost high. The life of flumes is also) The ad visa if pumping water instead of supplying by gravity has therefore been suggested, when sufficient water-power for the purpose oping happens to be available. But the expense of the requiuchinery and its complication, which involves skilled attend expensive wear and tear, has hitherto pre vented. The author ever, having been called upon to make plans and estimates for Lulic works for an extensive placer-mine in Colo rado, has such in devising pumping arrangements which are free from these sections, and are in fact estimated to cost less than half what a din the usual plan would cost. Several incidental advantages in plan also accrue, which will be referred to more particularly be The works placer-mine have not yet been carried out, on account of final arrangements, but in the meanwhile an hy draulic 'engineilar to that designed for the mine, has been con structed and so work for other purposes in England; and in order to explane plan which I have recommended for working the placer-mine will' describe this, which is actually at work, in preference to cibing the one which is not yet constructed. The engine machine acts on the principle of the hydraulic ram

Jan 1, 1888

By Ralph E. Davis, Lyon F. Terry

The rapid expansion of the natural gas industry in this country during the past three or four years has necessitated the construction of a number of long and comparatively large diameter high-pressure pipe lines This period of expansion and construction is still at high tide, and the current year will doubtless surpass all prior years in mileage and capacity of gas line installation. The fundamental economics of the business of long-distsrier transportation of natural gas may be briefly and simply stated, although most careful consideration must be given the actual determination and integration of the several more important factors which determine the ultimate success or failure of such a project. Reduced to its simplest form, a sound natural gas transportation project requires: 1. A competent source of gas, where the combination of quantity of gas available, cost of production, and longevity meet the given requirements. 2. A market, reasonably certain to endure in the face of any probable competition, of satisfactory size and price, and having a sufficiently favorable load factor. 3. A cost of installation of pipe line systen and an operating cost such as will, with honest and reasonably efficient management, afford a net operating return sufficient to attract the necessary capital required. In a11 new projects of this kind it is necessary that thehe three cssentials to ultimate success be assured. Hence the necessity of competent surveys of gas supply, and of market, both industrial and domestic. The prudent engineer will allow for "factors of safety" in reaching his conclusions just as he would in the design of a bridge. This paper deals primarily with but one of the major considerations enumerated above, I. e, the economic design of the pipe line system. The "pipe line system" will be considered to include (1) the pipe Iine, and (2) a series of compressor plants along the pipe line for maintaining

Jan 1, 1929

By M. Dubrovsky, J. W. Evans

A laboratory scale cell (approximately 50 amps current) equipped with a fluidized bed cathode was used in a study of the electrodeposition of cobalt from acidified aqueous sulfate solutions The effect of current density (in the range 0.1 to 1 amp/cm2 of diaphragm), cobalt concentration (4 8 to 100 glliter) and catholyte pH (1 35 to 6 2) on current efficiency and energy consumption were determined. Generally the current efficiency increased with increasing current density and cobalt concentration Current efficiencies were comparable to those reported in the literature for conventional electrowinning

Jan 1, 1981

By R. S. Goodrich, G. S. Ansell

The microstructure of three Al-Al2O3 SAP-Type alloys (containing 2.0, 3.0, and 5.7 wt pct alumina, respectively) was studied utilizing transmission electron microscopy. These alloys were fabricated from aluminum powders by powder-metallurgical techniques, cold-rolled into thin strips, and recrys -tallized. Thin foils suitable for an electron-transmission study were then prepared from the strip material by electropolishing. The microstructure of these alloys is shown to consist of small (0.1 mean diameter) plate -shaped alumina particles finely distributed in an aluminum matrix. In the higher-oxide content alloys the platelets are somewhat larger and more irregular in shape. The distribution of oxide particles is not uniform and there is an increasing tendency toward clumping SINCE the discovery by Irmann1 that aluminum alloys produced by compacting, hot pressing, and extruding fine aluminum powders possess remarkable high-temperature mechanical properties, the Al-A12O3 SAP-Type alloys have been utilized extensively as model dispersion-strengthened alloys in both experimental and theoretical invest igations.2-8 The use of the SAP-Type alloys as model dispersion-strengthened alloys implicitly assumes that their microstructure has been completely delineated. This is, however, not the case. with increasing oxide content. In all the alloys studied, the mean center-to-center spacing of particles was quite small (0.2 u) due to the very fine oxide debris present. Selected-area diffraction of the specimen identified the oxide as either y Al2O3 or y' Al2o3. The re crystallized MD-5100 alloy exhibited a mean grain diameter of only 0.7u, while the grain size of the other alloys was several hundred microns. Severe pinning of the grain boundaries by oxide particles was rarely observed, and the grain boundary triple points in the small-grained MD-5100 alloy were often particle -free. Diffraction contrasts visible around the particles are attributed to elastic strain fields set up by differential thermal contraction during cooling from the recrystallization anneal. Early investigation demonstrated that optical metallography did not possess sufficient resolution to observe the microstructure of the SAP-Type alloys.' Later, extensive use was made of replication techniques to study the microstructure by means of electron microscopy.7-9 These studies indicated that the SAP-Type alloys consist of a dispertion of irregular Al2O3 platelets, approximately 150A thick 9 and a micron or so on edge,9 distributed in a matrix of commercial-purity aluminum. These oxide platelets tend to be oriented in the aluminum matrix, with their largest dimension parallel to the extrusion direction. 8,9 A study employing polarized-light techniques1' indicated that the grain size of a series of as-extruded SAP-Type alloys was several microns in diameter, while the grain size after re-crystallization was several millimeters in diameter. A more recent study 12 utilizing surface-replication techniques examined the particle morphology,

Jan 1, 1964

Jan 1, 1961

By O. W. Walvoord

Mill design of the past will not necessarily dictate mill design of the future. There have been many advances and changes in the last few decades, many of which have been extensive and remarkable. Almost certainly, there will be still greater changes in the near future. Minerals beneficiation, for example, as it relates to future mill design, is likely to experience the greatest progress. Gravity separation, though one of the older arts, is in a continuous state of refinement. Flotation, having celebrated its 50th anniversary in 1961, has yet to be surpassed in its contribution to the art of mineral dressing. Ion-exchange, too, will flourish.

Jan 1, 1971

By Arthur Phillips, Carl H. Samans

The study of anisotropy in metals has been greatly stimulated in recent years by the rapid development of X-ray methods for determining the crystallographic relationships of wrought and annealed materials. Prior to this time the knowledge regarding the directional properties of commercial alloys consisted almost exclusively of observations of a practical nature made during the fabrication of metal objects, supplemented by a limited number of mechanical tests on specimens cut at various angles to the direction of working. Such observations clearly indicate that the common methods of cold-working metals cause both a crystallographic and a mechanical fibering varying in character and degree according to the nature and extent of the deforming process. Even after annealing, following certain not too well known combinations of reductions and anneals, a preferred orientation may exist,, thereby constituting a residual fiber effect sufficiently pronounced to manifest directional properties. With the application of the X-ray the experimental horizon was extended chiefly because the study of anisotropic metals promised to offer direct and quantitative evidence regarding the involved mechanism of fragmentation and plastic flow. As a natural consequence the intensive studies in this direction have yielded a vast accumulation of data of ultimate potential value. Unfortunately, however, as is commonly the case in entering a virgin field of experimentation, many of the data cannot be molded into complete and coherent form because of the many unrelated conditions of the experimental projects. Again, the results of the study of single crystals have been rather naturally but at times indiscriminately applied to poly crystalline metals. Furthermore, sweeping statements have been made regarding the behavior during working and annealing of metals and alloys, entirely on the basis of similarity in lattice arrangement. There is abundant reason for believing that relatively small concentration variables, differences in magnitude and distribution of applied stresses, and the character of associated annealing treatments may in some cases greatly influence the mechanics of flow

Jan 1, 1933

By George Burgess

NOTE BY THE EDITOR.-This resume of a Technologic Paper which is published in full by the U. S. Bureau of Standards, is brought before the membership of the Institute with the object of affording an opportunity for the open discussion of results of an investigation by the authors named above, of some phases of the manufacture of steel rails which are of great importance to manufacturer and consumer alike. This resume will be presented at the Pittsburg Meeting of the Institute. Discussion is invited, by either members or non-members of the Institute. The discussion may be sent in writing to the Editor, in advance of the meeting, or should preferably be presented in person at the meeting. To those who desire to discuss, copy of the full Technologic Paper (No. 38), as published by the Bureau of Stanaards, will be sent upon request addressed either to the Bureau of Standards, Washington, D. C., or to the Editor, American Institute of Mining Engineers, 29 West 39th Street, New York, N. Y. Summary of Researches and Conclusions The main objects of this investigation were to determine, from measurements taken at representative rail mills, the present American practice regarding the temperatures at which rails are rolled; to demonstrate the ease and accuracy with which such temperatures may be measured, without interfering in any way with the manufacture of the product; to find out what the "shrinkage clause" in rail specifications really means; and, finally, to determine some of the physical properties of rail steels, particularly those of interest in manufacture, some of which seem to be insufficiently known as yet. 1. Ingot Temperatures.-Measurements made in four mills show that ingots for rails are rolled at temperatures ranging from 1,075° to 1,150° C. (1,965° to 2,100° F.), and that, in a series of 20 to 40 ingots, the variation in temperature from one ingot to another is only 10° to 20° C. 2. Finishing Temperatures.-Rails are finished at temperatures ranging broadly from 880° to-1,050° C. (1,615 to 1,922° F.), but usually ranging within 50° C. of 935° C., and occasionally above 1,100° C.

Jan 9, 1914

Jan 1, 1936

By Jack F. Havard, John S. Lagarias

When ore bodies are faulted or mill feed turns refractory, mining managers and engineers act vigorously to convert imminent failure into eventual success. The recent proliferation of onerous environmental regulations and restraints is likewise a threat to successful mining enterprise, in some ways more insidious and dangerous than the problems presented by natural obstacles. The regulatory burden has become so heavy that a pall of pessimism covers much of the mining industry. In this paper we frankly recommend an approach that does not just "make the best of it" but rather directs the whole environmental process: first, to improve planning, engineering, and operating procedures; and, second, to demonstrate the need for modification of laws and regulations which are intolerably burdensome to both the mining industry and the public.

Jan 1, 1979

By J. Pinto, F. Galasso

THE current emphasis in preparing boron fibers by reduction of gaseous boron compounds on a resistively heated metal wire substrate has renewed interest in the borides of those metals which have relatively high melting points and are available as fine wires. A knowledge of the structures and properties of the borides, which are formed when boron diffuses into the metal core during boron deposition, can be of assistance in the understanding of the boron fiber formation process and the fiber properties. Many of these borides are well-known and their properties have been measured. However, when an unidentified boride is found in the core, it may be difficult to establish its composition because of the small amount of material available, the preferred orientation effects on the reflections in its X-ray pattern, and the possible overlap of X-ray reflections if several borides are present in the core. For example. the proper indexing of the X-ray pattern of WB4, which was formed in the tungsten substrate core during boron fiber formation, was accomplished only after small single crystals of this boride were grown and X-ray precession investigations were conducted.' This note presents the results of a study of the phases formed in the core when tungsten, tantalum, and molybdenum metal wires were used as substrates in the boron fiber preparation process with particular emphasis on the identification and characterization of a higher boride of molybdenum analogous to WB,. Boron was deposited on resistively heated stationary 0.0012-in.-diam tantalum, tungsten, and molybdenum wires at 1050°C for various times up to 60 sec using boron trichloride and hydrogen as the reactant gases. After 60 sec of boron deposition the fibers were approximately 0.006 in. in diam. Examination of photomicrographs of fiber cross sections showed that the boron had diffused nearly to the center of the tungsten and molybdenum cores in 15 and 30 sec, respectively, and only halfway to the center of the tantalum core in 60 sec. X-ray diffraction photographs of the fibers indicated that it was also after 15 and 30 sec deposition times that the tungsten and molybdenum metal reflections, respectively, had disappeared from the X-ray patterns of the fibers. The patterns of the boron fibers produced using tantalum wire as a substrate showed that amorphous boron, TaB2, and tantalum metal were present after a few seconds deposition time and remained even after deposition times of 60 sec. Until a deposition time of 15 sec was reached, the tungsten substrate fibers contained amorphous boron,273 6WB, W2B5, and WB4 as well as tungsten metal, while the molybdenum substrate fibers contained amorphous boron, MoBa, Mo2B5, and molybdenum metal for deposition times up to 30 sec. Just before the molybdenum metal pattern disappeared, a pattern similar to that of WB, appeared, suggesting that a phase, MOB,, isomorphous with WB,, was present in the fiber. This same pattern was obtained from the product formed by heating a mixture of molybdenum metal and excess boron powder in a boron nitride crucible at 1960°C in an argon atmosphere. As was the case with the WBn pattern, this pattern could best be indexed on the basis of a hexagonal unit cell rather than the tetragonal unit cell Chrktien and Helgorsky reported for ~0~4,~ see Table I. The unit cell parameters for MoB4 were calculated to be a, = 5.214A, co = 6.358A. Assuming the space group P63/mmc and positions5 2M01 in 2b and 2MoII in 2c found for tungsten in WB~,' a logical structure for MOB, was determined using geometrical considerations to place the boron

Jan 1, 1969

Jan 1, 1923