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"MASSACHUSE'M'S INSTITUTE OF TECHNOLOGYBOLSAITIS, PETERMassachusetts Institute of TechnologyDepartment of Mineral Engineering77 Massachusetts AvenueCambr1dge,MA 02130(614) 253-5069ELLIOIT, JOHN F.Massachusetts Institute of TechnologyDepartment of Mineral Engineering77 Massachusetts AvenueCambridge, MA 02130(617) 253-3305RING, TERRYDepartment of Materials Science and EngineeringMassachu5etts Institute of TechnologyCambridge, MA 02130(6117) 253-4299"

Jan 1, 1988

By James C. Cawley

This report presents results of recent Bureau of Mines research to establish the probability of spark ignition as a function of current (or voltage, for capacitor circuits) for resistive, inductive, and ca-pacitive circuits in 8.3% methane-air atmospheres. The data presented quantify the explosion hazard created when low-power electronic devices catastrophically fail in an explosive mine atmosphere. Previous litera-ture dealt with levels of probability between 10-3 and 10-4. This re-port extends the probability data to levels as low as 10-7. This study has verified that when the probability of ignition, PI, is plotted on a log-log coordinate system versus the current (or voltage), a continuous, straight-line relationship is formed. An interesting result that can be statistically hypothesized is that at some low level of igniting current the ignition process ceases altogether.

Jan 1, 1988

By Kenneth L. Bickel

During an underground mine fire, the importance of controlling the spread of smoke and toxic gases with suitable ventilation structures has been proven. However, under certain conditions, control of the propagation of the fire itself may be even more critical in insuring a safe mine evacuation. Fire doors offer the means for accomplishing both objectives. In 1978, the Bureau of Mines initiated research to evaluate the state of fire-door technology and develop and test a fire door suitable for large openings (10 by 12 ft or larger) in noncoal underground mines. This report discusses current fire-door technology in the context of the underground mine environment and the design, fabrication, lab testing, and in-mine field testing of a mineworthy fire door. This door has a 1.5-h fire resistance rating and limits temperature rise across the door to 2500 F during the first 30 min of fire exposure.

Jan 1, 1987

By A. K. Schellinger

1. In the United States, the industrial application of centrifugal force for separating phase constituents has been confined almost entirely to aqueous systems at room temperature. This paper presents results for experimental tests on the use of centrifugal force for separating the liquid and solid phases in molten nonferrous alloys. 2. The development and use of a small centrifuge for treating molten metals is described. The centrifugal apparatus was, in essence, a 3-inch diameter spinner pot, which revolved, within -a gas -fired furnace, at speeds up to 3,000 r.p.m.

Jan 1, 1953

By R. J. Gajan

As part of its research program on secondary metal refining, the Federal Bureau of Mines has developed a fast method for determining aluminum, iron, copper, cadmium, and lead in zinc-base alloys. The new method is intended for use by trained technicians in laboratories with inexpensive equipment. It can be used either in the analytical laboratories of the many small plants that are characteristic of the secondary metals industry or in laboratories engaged in basic research to improve refining processes. A complete analysis for the foregoing elements can be made in less than 3 hours from a single sample in solution. The method is especially helpful when a small amount of sample is available. Aluminum and iron are determined spectrophotometrically and the other elements polarographically. The new method is now being used for control analysis in metallurgical research, and the results compare favorably with previously used spectrographic methods. Luke and Braun4/ described a photometric method for the determination of aluminum in zinc diecasting alloys in which the aluminum was complexed with Aluminon reagent (ammonium salt of aurintricarboxylic acid), forming a red lake. An adaptation of this method was used for determining aluminum. Beers law is obeyed between 0.01 and 0.06 milligram of aluminum.

Jan 1, 1961

By D. E. Wolfson

Twenty-two samples of West Virginia coals were carbonized at 9000 C by the Bureau of Mines-American Gas Association (BM-AGA) method, and yields of products and physical properties of cokes were determined. Eighteen samples represented the Coa1burg, No. 2 Gas, No. 2 Gas and Peerless, Powellton, Eagle, Big Eagle, Lower Eagle, Sewell, Fire Creek, and Pocahontas No.6 beds in Fayette County, and four samples represented the Sewell and Fire Creek beds in Greenbrier County. Expansion characteristics of the majority of samples were determined in the Bureau of Mines sole-heated oven. Chemical analyses were determined for all coals. The coals in Fayette County are high-volatile A, medium-volatile, and low-volatile in rank, and the Greenbrier coals are medium-volatile in rank. Most of the coals are chemically suitable for metallurgical coking. All coke strength indices are within acceptable limits for metallurgical coking coals. All the high-volatile A coals contracted and the medium-and low-volatile coals expanded in the sole-heated oven expansion test.

Jan 1, 1966

By W. M. Myers

"The continued expansion of modern industry broadens the markets for minerals and their product. With these increasing demands new uses are being found for minerals that heretofore were considered as possessing no commercial possibilities. This tendency is reflected in the nonmetallic field in a constantly increasing demand for minerals formerly considered to be of scientific interest only, Furthermore, nonmetallic minerals of established commercial importance are used in new ways in various products, and this tends to expand the markets for these minerals. Some recent outstanding developments in applications of minerals are given in the following pages.The Andalusite GroupAmong the minerals that until recently were considered of scientific interest only, may be listed those of the andalusite group. This group is composed of the three minerals, andalusite, cyanite (or kyunite), and sillmanite, which are all forms of the compound Al2SiO5 (A1203, S1O2), and are therefore identical in chemical composition, but differ in physical properties,"

Mar 1, 1924

By Edward D. Thimons

The Bureau of Mines developed a stopping design that allows the stopping to be blown down by strong blast forces without incurring any permanent damage. Trials with the new stopping, dubbed the quick-fix blowout stopping, have been conducted in the Bureau's Safety Research Coal Mine at Bruceton, Pa., and in two New Mexico uranium mines. Results have been favorable in all cases. Compared with conventional brattice stoppings or wood bulkheads, the quick-fix blowout stopping is easier and less time consuming to install, is easier to maintain, and in most cases is just as efficient an air barrier. There is same indication that the shape of the stopping makes it more resistant to blast fore s than the fabric stoppings now in use.

Jan 1, 1976

By Bernard J. Steblay

Two instruments have been constructed that extend microseismic data collection and processing capability for Bureau of Mines research in rock burst, coal bounce and outburst, and roof fall monitoring. The first instrument is a 13-channel tape-triggering system. This system allows better utilization of instrumentation tape recorders by collecting data digitally, turning the tape on only when valid data are present, and increasing the dynamic range of the recorder by using digital data. A digital-to-analog converter is used to provide analog output of the recorded digital data. The instrument records a much larger time slice of transient events than do current commercial devices. The second instrument is a microseismic energy measurement device. This device uses recent developments In integrated circuits to overcome the dynamic range and accuracy limitations of previous instruments. The analog signal is converted to a digital one, and then high-speed multiplication techniques are used to square the amplitude value in real time and integrate it.

Jan 1, 1983

By C. M. Frost

The hydrodesulfurization characteristics of a residual fuel prepared from Wilmington, Calif., crude oil were determined at temperatures from 600° to 900° F, pressures of 200 to 800 pSig, and space velocities from 0.2 to 2.0 Vo/Vc/hr, using cobalt molybdate type catalysts. A prediction equation, developed from the experimental data, satisfactorily predicts the fraction of total sulfur that can be removed under any combination of operating conditions within the ranges investigated. Yields and properties of the low sulfur product are correlated with the fraction of total sulfur removed. Kinetic calculations show that the apparent reaction order and activation energy change with space velocity and temperature.

Jan 1, 1970

By John Ward Smith

Detailed oil yield, lithologic, and mineral distribution data are presented for core and drill-cutting samples from the Western Oil Shale Corp. Project Utah EX-1 Corehole (WOSCO EX-I), drilled to sample a deeply buried oil-shale sequence in the Green River Formation of Utah's Uinta Basin. Drilling of this corehole was part of the evaluation of this site for possible oil-shale development by nuclear explosion. Sections sufficiently thick for nuclear development average 15 gallons per ton or less and consist predominantly of low-grade shales. Some properties of low-grade shales may be advantageous to a nuclear experiment by facilitating breakage, fracture development, and in situ retorting. The formation correlates precisely with the well-studied oil shales 25 miles east near the Colorado border. A 235-foot mineralized section containing nahcolite, shortite, and searlesite whose bottom lies 300 feet above the Mahogany zone is described.

Jan 1, 1972

By Hillary W. St. Clair

Reaction rate coefficients were determined from analyses of the effluent gas for the reduction of granular ferrous oxide to metallic iron by passing carbon monoxide through a packed bed of oxide at a controlled rate in the temperature range 1,000° to 1,300° C. Coefficients were determined by the comparison of observed analyses and calculated analyses using a mathematical model that takes into account the nonuniform composition of both the solid oxide and the gas. A method is also given for finding the value of the rate coefficient that best fits the observed data.

Jan 1, 1968

By J. G. Donaldson

Cobalt-tungsten binary deposits were formed in laboratory experiments by hydrogen reduction of the anhydrous mixed vapors of cobaltous chloride and tungsten hexachloride. The materials were sublimed in seperately heated zones of reaction tube and were transported in a stream of purified helium into the deposition section of the tube where the chloride gases were reduced to metal by a countercurrent flow of hydrogen. Heattreating of the near stoichiometric binary metallic deposits converted nearly all to the intermetallic compound Co3W, however, small quantities of both cobalt and tungsten remained. Mechanical tests showed that the tensile strength of heat-treated 75 percent cobalt-25 percent tungsten deposits was twice as high as that of similarly treated deposits of cobalt.

Jan 1, 1965

By W. H. Pomroy

This report describes research by the U.S. Bureau of Mines to design and in-mine test a rapid response pneumatic fire detection system for multilevel metal mines. The relative merits of pneumatic detection are discussed in the context of typical multilevel mine layouts and environments. The Bureau's prototype system is described, with emphasis on design features that counter commonly experienced and/or perceived operating problems with pneumatic detection systems. Finally, the results of a 3-year in-mine performance evaluation of the prototype system are discussed.

Jan 1, 1990

By Ludwig Schmidt

The petroleum industry has recently shown sucks great interest in the evaporation of crude oil and of gasoline, and in the prevention of evaporation losses that almost daily there is being developed and placed on the market equipment designed especially to reduce these losses. Among the recent developments is a new type of tank roof known as the "floating roof," which practically eliminates the vapor space over the surface of the oil, thus removing one of the chief causes of evaporation. There are at the present writing at least two types of floating roofs which, while similar in fundamental principle, differ mainly in the method of making contact with the inside shell of the tank. One type of floating roof is known as a floating tank deck, and has on its circumference flexible metal baskets containing gravel that .rest against the inside shell of the tank. In the other type of floating roof contact with the tank shell is made by the use of movable buffers or shoes. These are attached to the outer ring of the roof and are pressed against the tank shell by means of springs.

Jan 1, 1923

By Roy E. Peterson

The Bureau of Mines conducted an investigation to produce metallized pellets from domestic iron ore superconcentrates using lignite and subbituminous coal as reductants. Feed materials for the metallizing process consisted of commercially indurated iron oxide pellets and green pellets prepared from upgraded domestic concentrates with graphite or limestone as internal additives. Durability of the green pellets during metallization was investigated in tests conducted in a 7-inch-ID rotating drum furnace. Test results indicated that the major cause of pellet disintegration with the concentrates used was the tumbling action during reduction rather than forces generated within the pellets. In larger scale tests made in a 34-inch-ID by 35-foot-long kiln, the previously indurated pellets were metallized with lignite at 1,030° C with little disintegration. A 96-percent level of metallization was obtained in pellets having an average compressive strength of 420 lb. In subsequent, similar tests using green pellets containing graphite or limestone, pellet disintegration was more severe, with 10 to 40 percent of the feed being lost as dust. The surviving pellets had metallizations ranging from 88.3 to 94.4 percent and compressive strengths ranging from 60 to 68 lb.

Jan 1, 1976

By Raymond B. Ladoo

"The increasing realization of the fire hazards involved in the use of wooden shingles caused the National Lumber Manufacturers' Association to beginsome five years ago a search for a suitable fire-resistant paint. The problem was submitted to the Educational Bureau of the Paint Manufacturers' Association of the United States and work was started by Mr. Henry L. Gardner at the Institute of Industrial Research, Washington D.C. in collaboration with Dr. Herman von Schrenk, a timber expert of St. Louis.The results of this,work have been described by Heckel, in ""Asbestos"", (Heckel G.B., Asbestos in the Paint Industry, Asbestos, Vol. 2, July, 1920,pp.- 5-10).,,who gives the following formula for one of the colors as typical: It will be noted from this formula that ""asbestine"" forms 33% of the total liquid pigment by weight or 31.8% of the solid constituents. Hockel in the article referred to describes this paint,as ""asbestiform"" and assumes since ""asbestine"" is magnesium silicate it must be the chrysetile variety of ""Asbestine"", however, is not asbestos but is a trade name for a fibrous variety of talc mined in the Gouverneur district, St. Lawrence County, New York. This rather natural error persists through the article and credits asbestos with many desirable properties which are characteristics of talc."

Aug 1, 1920

By S. L. May

The Bureau of Mines has developed several methods for extracting tantalum and columbium (niobium) and the rare-earth compounds from ores and concentrates. A cooperative agreement was made by the Bureau with Porter Bros. Corporation of Idaho to process 200 pounds of its euxenite concentrate by methods that had been developed at the Albany, Oreg., Metallurgy Research Center. The euxenite concentrate was processed to extract and purify the valuable metals by chlorination, solvent extraction, and hydrometallurgical techniques. Chlorination was used to convert the valuable constituents into chlorides and to partly separate them. Solvent extraction techniques were used to separate the tantalum from the columbium. The rare-earth and uranium compounds were purified by hydrometallurgical methods.

Jan 1, 1959

By Paul Hatmaker

This paper covers briefly the particular field of dolomite and magnesium limestone; certain uses of high-calcium limestone are mentioned only to show more clearly the limita¬ tions of the magnesian rocks. Such a comparison is helpful because magnesium carbonate is essential for some uses; for others it is immaterial; and for many its presence in an appreciable amount is objectionable. Magnesium carbonate, occurring as a rock resembling limestone or dolomite, is described in United States Bureau of Mines Information Circular 6437, Magnesite. Other com¬ pounds of magnesium are described in United States Bureau of Mines Information Circular 6406, Magnesium Compounds (Other Than Magnesite). Limestone, geologically, is a rock composed essentially of calcium carbonate; commercially, however, the term may include dolomite and magnesium limestone.

Sep 1, 1931

By Albert W. Deurbrouck

This report describes the preparation characteristics of 23 coal samples collected from nine of the more significant coalbeds of Fayette County, W. Va. In 1963 almost 5.4 million tons of medium to high volatile B coals of excellent quality for metallurgical and steam markets were produced in Fayette County. Of the 23 coal samples collected 11 would require some upgrading to pro-vide metallurgical quality products, 11 were acceptable as received, and 1 was a noncaking coal. Cleaning these coals to metallurgical standards would require only the removal of the sink 1.58 specific gravity material which would be quite easy as very little near-separating-gravity material was present at this gravity.

Jan 1, 1965