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By L. F. Heising

Ten composite samples of Mesabi Range nonmagnetic taconite from the Hibbing, Minn., area were evaluated by flotation and by reduction roasting-magnetic separation to determine their potential as a future source of iron are. Only one of the composites yielded concentrates that could be considered marketable, using as a criterion a 10-to-1 iron-to-silica ratio. Cursory petrographic examinations of all 10 composited samples and a detailed mineralogical study on 1 sample suggest that unfavorable mineralogical associations between iron and gangue minerals are responsible for their poor beneficiation characteristics.

Jan 1, 1967

By B. W. Dunning

The Bureau of Mines investigated the concentration and distribution of precious metals in the various fractions produced from mechanical processing of obsolete military electronic scrap. Whole avionic units, printed circuit cards, and electrical connectors were processed and analyzed. Materials recovered included baghouse lights, wire bundles, mag-netics, and metal concentrates from eddy-current and high-tension sepa-ration. Higher value fractions were processed by a commercial toll refiner for recovery of gold and silver. Lower value fractions were analyzed by the Bureau. Three fractions, the lights, wire bundles, and metallics from high-tension separation, contained most of the precious metals. Depending on the type of scrap feed, these fractions represented 34 to 60 pct of the original sample weight. Collectively, they represented 68 to 97 pct and 75 to 98 pct of the contained gold and silver, respectively.

Jan 1, 1983

By Eric R. Bauer

The ground control aspects of extended depth-of-cut mining are presented in this U.S. Bureau of Mines report. A trend analysis of extended cut approvals was performed. A comparative review of roof fall fatalities for extended and nonextended cut mining is included. Current ground control guidelines for extended cut approval are summarized. The problems and concerns of this extraction system are addressed, and typical extended cutting face operations are described.

Jan 1, 1993

By M. M. Wong

Salt mixtures consisting of KC1, BaC12, and HfCl4 with RbCl or CsCl were investigated as electrolytes for refining hafnium. The presence of RbCI or CsCl in the electrolyte appeared to suppress the volatility of. Best electrorefining was obtained with an electrolyte containing 50.7 percent KCl, 27.l percent BaCl2, 15.7 percent CsCl, and 6.5 percent HfCl4. In this electrolyte, hafnium metal with an average oxygen content of 470 ppm was produced from an anode feed containing l,600 ppm oxygen. All metallic impurities were lowered, except titanium, manganese, and tin.

Jan 1, 1966

By E. T. Bowers

The Accident Analysis (ADA) computer program was developed at the Spokane Research Center (SRC) to provide a rapid broad-based analysis of mining accidents. Because the Bureau of Mines often needs this type of information for the development of viable research programs the ADA program was written to access and analyze accident data available frog the Labor Department's Mine Safety and Health Administration (MSHA). This report describes the ADA program, the data it uses, and the potential value it has for planning mining research.

Jan 1, 1987

By W. T. Culler

"The ""rate-of-preduotion curve"" described in the revised Treasury Manual* was devised by the author in May, 1920, and since that time has been use by the oil and gas valuation section of the Treasury Department in determining the rate of production of wells for purposes of taxation. This curve is most useful for estimating the future production of a well, or group of wells, of known daily settled production, where future-production curves and tables based on yearly production records are available. It also provides a means for determining the past year's production of a well of known daily settled production, or conversely, the estimated production on any day for a well of known yearly production.The rate-of-production curve is auxiliary to the production decline curve and is derived from it in estimating the future production of a tract, a production decline curve formed from the records of the tract itself should be used. If such records are not available, and there is no information which leads to the belief that the average production decline of the wells in this tract differs from the average for the pool or district, an average curve for the pool or district may be used.The accompanying chart illustrates a typical rate-of-production curve, with the yearly production decline curve from which it is derived. The production decline curve shown is for an average well in the Augusta district, Butler County, Kansas, and has been constructed from the tables given on page 128 of the revised Treasury Manual.The ordinate (vertical scale on the chart) of any point on a yearly production decline curve represents the production of the well during the year previous to the date shown by the abscissa (horizontal scale). For example, the chart shows that an average well, which produced 100,000 barrels of oil in 1915. produced 92,000 barrels in the year previous to January 19, 1916, produced 53,300 barrels in the year previous to June 1, 1916; produced 49,000 barrels in the year previous to July 1, 1916, 27,000 barrels in 1916, and 10,000 barrels in 1917."

Oct 1, 1921

By S. C. Termes

To help develop the basis for new fine-particle separation methods, the Bureau of Mines has investigated the use of cross-linked starches containing four chelating groups--carboxylate, iminodiacetate, dietha-nolamine, and xanthate--as flocculants for selected metal oxide and hydroxide mineral fines. It was found that those starches capable of interacting with the mineral surface by a chemisorpti,on mechanism (as indicated by zeta potential measurements) produced the highest recover-ies and'grades of the metal oxide or hydroxide when flocculated from a binary mixture with quartz. The effects of pH, dispersing agent, stirring rate, stirring time, and starch dosage on selective flocculation were studied for binary mixtures of hematite and chromite with quartz. Floc strength becomes important in achieving maximum recoveries by mechanical postflocculation separations.

Jan 1, 1985

By N. S. Dalal, Xiaoya Sun, Xianglin Shi

"The in vivo toxicity of vanadium(V) has been found to correlate with the depletion of cellular glutathione and related non-protein thiols. With a view to understanding the mechanism for this observation, we have investigated the oxidation of glutathione, cysteine N·acetylcystcinc and pcnicil· lamine by vanadium(V), using electron spin resonance (ESR) and ESR spin trapping methodology. The spin trap used was 5,5-dimethyl-l-pyrroline I-oxide (DMPO). It is found that the oxidation of these thiols by vanadium(V) generates the corresponding thiyl radicals and vanadilim- (IV) complexes. The results suggest that free radical reactions play a significant role in the depletion of cellular thiols by vanadium(V) and hence in vanadium(V) toxicity. 1. INTRODUCTIONThis communication reports on the identification of thiyl radicals formed as intermediates in the reaction of vanadium(V) with glutathione (GSH) and related nonprotein thiols. This study was undertaken because the biochemical mechanism of vanadium toxicity is still not fully understood,. despite being a topic of current research activity [1-20). As to possible clues, it is known that vanadium is most toxic when administered in its pentavaient state [21), and that vanadium(V) administration into laboratory mice reduces cellular levels of NAD(P)H and GSH [22). While the oxidation of NAD(P)H by vanadium has been studied extensively [16-20), that of glutathione and related non-protein thiols has been paid less attention. On the other hand, GSH and related thiols are important cellular antioxidants [23). Their functions include decomposing lipid peroxides and protecting cell membranes [23-25). Thus any reduction in the cellular contents of such nonprotein thiols after vanadium exposure may result in the accumulation of lipid peroxides which might ultimately lead to tissue injury. With a view of finding the mechanism for this thiol depletion process, we have investigated reactions of non-protein thiols with vanadium(V). Particular attention has been paid to the detection of thiyl radicals, since it has been postulated [l] (but not experimentally proven) that the glutathionyl radical (GS·) might be an intermediate in the reaction between vanadium(V), NADH and GSH. We have used electron spin resonance (ESR) and ESR spin trapping methodology for investigating the reactions of GSH, cysteine, N-acetylcysteine and penicillamine with vanadium(V). The results show that the corresponding thiyl radicals are indeed formed in the one-electron reduction of vanadium(V) by all of the above mentioned thiols."

Jan 1, 1990

By F. N. Kissell, C. H. Elder, C. M. McCulloch

The applicability of the "direct method" for determining the methane content of virgin coalbeds was tested. Preliminary results indicate that the direct method, when applied to exploration cores, can be successfully used to estimate coalbed gas content and also approximately predict the total gas emission from a prospective mine located in the coalbed at the exploration site.

Jan 1, 1973

By Joseph B. Cummings

The Twin Buttes camp embraces eight mines in the Pima mining district. The first mining claims in the camp are said to have been located in 1876, but little mining was done until 1905. Intermittent operation of five of the mi.nes to 1928 yielded 388,231 tons of ore averaging 6.19 percent copper and 8 small tonnage of high-grade oxidized zinc ore. While the Bureau was investigating the area, one mine was active, and it started to produce in 1944. The mines of the Twin Buttes camp are at or near contacts of intrusive granite with Paleozoic limestones and quartzite. The ore shoots lie in metamorphosed sediments adjacent to a zone of garnet rock that separates the ore from the footwall granite. Small fissures that originate at the contact and cut the sedimentaries appear to have been controlling factors in ore deposition. No important ore bodies are exposed at the surface, and those developed wore discovered by sinking on the fissure veins to the contact zone. Most of the area overlying the favorable ore zone is covered by alluvium ranging in thickness from 5 to more than 20 feet.

Jan 1, 1950

By Rustu S. Kalyoncu

A major goal of the Bureau of Mines is to conserve the Nation's mineral resources by developing improved performance materials. In support of this mission, a survey of the state of the art of chemically bonded refractories has been made, covering the scientific literature, government reports, and patents. This review includes research and development results for phosphate, silicate, oxychloride, oxysulfate, and other bonding agents used in refractories manufacture. A significant finding of the review was that references on bonding mechanisms, bond formation kinetics, and other important process parameters and conditions were few and universally vague. As a result, recommendations are made to expand research efforts to investigate the kinetics and mechanisms of reactions in chemically bonded refractories.

Jan 1, 1982

By R. D. Leitch

The work of the United States Bureau of Mines on stream pollution by coal-mine drainage has included a study of seasonal variations in acidity and volume of several streams in Pennsylvania. The acidity of these streams has been determined during the two or three years prior to 1930 and the results may be considered to represent "normal" low water conditions. The summer of 1330, however, was unusually dry and represents what may be termed "extreme low water conditions on these streams. This report is a comparison of the results obtained for extreme low water of 1930 and for other years. The streams investigated were Buffalo Creek in Somerset County, Indian Creek (lower 5 miles) in Westmoreland County, Little Toby Creek in Elk and Jefferson Counties, Daguscohonda Run in Elk County and West Creek in Elk and Cameron Counties. These will be treated separately in the order given. Most of the descriptive matter and physical data pertinent to the streams and drainage basins are taken from published reports of the Pennsylvania State Water Supply Commission, 1917.

Jan 1, 1931

By Maria I. De Rosa

Table 46 and figure 16 show the number of fires and fire injuries for metal/nonmetal mills by state during 1990-2001. Table 46 also shows the injury risk rates, employees' working hours, and lost workdays. In all, 77 fires occurred in 26 states. Thirty-seven of the fires caused 41 injuries and 1 fatality (including 5 fires and 3 injuries involving contractors). The yearly average was 6.4 fires and 3.4 injuries. Fifty-four fires with 26 injuries and 1 fatality occurred at metal mills; 23 fires with 15 injuries occurred at nonmetal mills. The Ewhr value was 845 x 106 hr (Irr = 0.01), and the LWD value was 6,681. Minnesota had the most fires (16 fires and 5 injuries), followed by Arizona (9 fires and 3 injuries), Wyoming (8 fires and 3 injuries), Nevada (7 fires, 4 injuries, and 1 fatality), and Texas (4 fires and 7 injuries). Of these states, Texas had the highest injury risk rate value (Irr = 0.033). Table 47, partly illustrated in figure 17, shows the number of fires, fire injuries, fire fatalities, risk rates, employees' working hours, and lost workdays by time period. The number of fires increased slightly during the second period, then decreased during the remaining periods. The number of fire injuries show a decrease during most of the periods (an increase is seen during the third period), accompanied by a decline in employees' working hours during most of the periods. The Irr values follow patterns similar to those shown by the injury values. Tables 48-53 show the number of fires by ignition source, method of detection and suppression, equipment involved, location, and burning material by time period. Figure 18 shows the major variables related to fires for 1990-2001. Table 54 shows the number of fire injuries per number of fires causing injuries and total fires by year, ignition source, equipment involved, and location.

Jan 1, 2004

By A. W. Fahrenwald

[In studying coarse sand flotation3/ the question of the relation between fineness of grinding and mill capacity logically arose. Everyone familiar with present fine-grinding practice knows that the capacity of a ball mill or similar mill is determined, among other things, by the fineness of the finished product. Undoubtedly a great many mining companies must have a good deal of data directly bearing on this point, yet no quantitative relationship between ball-will capacity and fineness of finished product has been established. The experimental study presented here is an effort to establish this relationship in a semiquantitative way. The subject is a tremendously large one and grows in complexity as the study becomes more searching. In this work the power consumed by the mill in the various experiments was not determined end neither vas the steel consumption measured; mill capacity only was considered.]

Jan 1, 1930

By D. A. Elkins

This report is the second of a series of three that will evaluate, in order, the metallothermic, carbothermic, and electrolytic methods of magnesium production. The historical development of the carbothermic process is outlined. Production costs varying from 38.9 to 21.8 cents per pound of magnesium are estimated for different versions of the process. Additional suggested process modifications are listed. The technical and economic potential of the different versions are compared. Areas deemed most promising for future research on the process are delineated.

Jan 1, 1967

By Ted A. Lewtas

The effectiveness of induction fans in ventilating dead headings was studied in the laboratory and underground. The following fan attachments were evaluated: a. Aerodynamic nozzle b. Various lengths of vent tube c. Honeycomb airflow straightener. Various fan locations were also tested. The following conclusions were reached: a. A nozzle on a fan located against the drift wall gives the greatest jet penetration distance. b. Air straighteners are ineffective in increasing jet penetration. c. Induction fans are ineffective in removing contaminants from dead headings without sufficient main ventilation flow.

Jan 1, 1980

By R. L. Montgomery

Heats of solution of yttrium chloride and oxide in hydrochloric acid were measured by Bureau of Mines researchers. Using the heat of combustion of yttrium mentioned in the literature, the Bureau calculated the heat of formation of yttrium chloride to be -239.16 + 0.50 kcal./mole. The Bureau experiments gave evidence that the heats of solution of yttrium chloride from the literature are mostly too low because of water and/or oxychloride impurities. Heat of combustion of yttrium (8)3/ and its heat of solution in hydrochloric acid (2, 14) have been measured. The earlier heat of solution measurement (2) is unreliable because of possible potassium contamination (4). Heat of solution of yttrium chloride has been measured by three researchers (3, 9, 15), who obtained widely different results. Spedding and Flynn (14) report the heat of formation of yttrium chloride as -232.69 kcal./mole from their solution studies. The present work was designed to check the reported heats of solution of yttrium chloride and to determine the heat of solution of yttrium oxide. The latter measurement would allow the results of solution and combustion data for yttrium to be intercompared.

Jan 1, 1960

By William W. Odell

Certain gas-making processes are in use in Europe, particularly in Germany, which differ radically from those in common use in America. A number of them are of particular interest because they are different. The questions naturally arise: Are any of them applicable to the making of gas in this country and, if so, with what particular type of solid fuel? It is a fact that some of them were developed with consideration of a particular set of conditions and for the utilization of solid fuels available in Germany. The latter fuels, in certain characteristics, are unlike the high-rank fuels commonly used for making gas in the United States; therefore, in attempting to evaluate the various foreign- developed processes with regard to usefulness here, one must give attention to the particular conditions that will prevail in any specified case and also the characteristics and requirements of the process and generator under considera- tion. Three of the processes that were developed and put into commercial operation in Germany, and which have some characteristics in common, are con- sidered in particular in this publication; they are: 1. Lurgi pressure gasification process. 2. Winkler process. 3. The Leuna slagging-type producer-gas process. Each of these processes requires steam and oxygen as gas-maiding fluids. For a number of years, oxygen, has been used in a relatively pure state,. along with steam, in making gas in Germany, and many of the difficulties initi-. ally encountered have been overcome. Although it appears that oxygen recovered from air was first used in this manner as a method of utilizing a byproduct in a plant that used the nitrogen complement in the manufacture of ammonia; more recently, the oxygen was made particularly for the purpose. The fuels - brown coal or lignite used in processes 1 and 2 were not suitable for use in the older and commonly used intermittent-type water-gas generators, and it was necessary, therefore, to devise a different process for gasifying them. A gas of higher heating value than producer gas, was desired, and the use of oxygen (not air) along with steam made possible the production of the desired gas without nitrogen dilution, which characterizes producer gas. Operating data presented herein are based upon observations by, members of the Technical Oil Mission at plants in Germany, on records, and on information vocally given to members of the lässion, including the author, while visiting those plants, and they are believed to be reasonably correct; however, certain hasic observations, comparisons, and conclusions are. made by the author.

Nov 1, 1947

By Timothy J. Rohrbacher

This report presents results from an ongoing U.S. Bureau of Mines study defining domestic coal reserves. Examinations of five 7 ½ -minute central Appalachian quadrangles have been completed to date. Only 26.4%, 5.0%, 6.5%, 8.2%, and 4.2% at the coal resources remaining in the Matewan, Boltsfork, and Hoskinston, KY; Vansant, VA; and Beckley, WV quadrangles, respectively, constitute economically recoverable reserves. An evaluation of the coal mining industry's impact on the economy of Pike County, KY, wherein the Matewan quadrangle is located, was also completed in order to provide a basic understanding of the influence of coal mining on the local economy. Results show that coal mining is the only major income producing industry in Pike County, accounting for about 46% of the county's income, and 21% of the total available employment, in the base year 1990. If similar results are found in subsequent investigations, a strong argument can be made that traditional coal producing regions may soon be experiencing resource depletion problems far greater and much sooner than previously thought. This will affect not only the coal industry but, given the obvious dependence of Pike County's economy on its coal mining industry, the entire social and economic infrastructure of large areas.

Jan 1, 1994

By R. V. Ramani

In this the available information friction factors and leakage report, on characteristics are reviewed and summarized. The use of Penn State Mine Ventilation Simulator (Volumes II and III of the Final Report) to analyze the sensitivity of the ventilation system to the changes in leakage and friction factors is discussed with examples. In simple ventilation systems, the results of changes in leakage and friction factors can be easily solved and explained by the laws of air-flow. In complex systems, with fixed quantity branches and multiple sections, the effect of changes in leakage and friction factors cannot be generalized. This study points out the importance of good input data for obtaining reliable information from computer analyses and demonstrates the application of simulators to analyze the effectiveness of ventilation systems. An extensive bibliography on friction factors, leakage characteristics and ventilation economics is included.

Jan 1, 1977