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By Jesse A. Miller

ALTHOUGH the element titanium was discovered by William Gregor in 1790, over a hundred years passed before it was put to commercial use. The first commercial application of titanium was as an alloy additive to iron and steel, and the first ferroalloys were produced domestically in 1906. Titanium pigments were developed somewhat later and have been produced in the United States since 1918. The use of titaniferous material in welding-rod coatings first gained acceptance ill the mid-30's. The metal titanium has only had commercial importance since 1948; domestic production for that year was 10 tons. The relative importance of these major uses of titanium in various forms may he gaged by the consumption of titanium dioxide (Ti02) for these purposes in 1954. Of a total of 440,000 short tons of Ti02 consumed in 1954, 95 percent of the total was consumed for pigments; 2 percent for welding-rod coatings; 1 percent for non-titanium-base alloys and carbide; and 2 percent for miscellaneous uses. The titanium-metal industry is in its infancy, but it has more than doubled its output every year from 1948 to 1954, reaching 5,370 short tons in 1954.

Jan 1, 1957

By Norman G. Foster

The mass spectra of four tertiary butyl substituted thiophenes are reported. A comparison and contrast with earlier structure correlations made by API-RP48 mass spectroscopists is presented. The fragmentation routes of these types of molecules are discussed and explained in terms of existing theories in mass spectrometry. Low ionization voltage data are presented to support the mechanistic picture developed. Structures are inferred about some of the ions, and these are correlated with existing theories. Metastable peaks in the spectra are used to support the fragmentation paths. The presence of doubly charged ions in the spectra is noted and the possible implications toward mechanisms discussed. The general picture of simple, small fragments leaving the ion moiety upon further fragmentation is developed in detail. Some suggestions are presented for further work utilizing isotopically labeled molecules to establish firmly the general picture of fragmentations of the alkylthiophenes.

Jan 1, 1966

By Richard J. Mainiero, Michael J. Sapko, James H. Rowland III, Marcia L. Harris

All explosive materials produce a cloud of reaction products, the most toxic of which is nitrogen dioxide (NO2). In the study reported here, 4.5-kg (10-lb) charges of blasting agent confined in either thin-wall 10-cm (4-in) diameter galvanized pipe or 10-cm (4-in) schedule 80 seamless steel pipe were detonated in a closed chamber. The detonation gases were analyzed for NO2, nitric oxide (NO), ammonia (NH3), hydrogen (H2), carbon monoxide (CO), carbon dioxide (CO2), nitrogen (N2), oxygen (O2), and methane (CH4). Data were evaluated to determine the kinetics of the oxidation of NO to NO2. Analysis revealed that the only mechanism for NO loss for the conditions existing in the chamber was the reaction 2NO + O2 6 2 NO2. The rate constant was 2.08 @ 10-38 cm6 molecules-2 sec-1 for the rate equation -½d [NO]/dt = K @ [NO]2 @ [O2] for NO concentrations up to 100 ppm. The rate constant is in agreement with that recommended by Baulch, Drysdale, and Horne (1973).

By Curtis H. Elder

In studies conducted by the Bureau of Mines, two test areas were hydraulically stimulated and exposed by mining: One in the Pittsburgh coalbed at the Vesta No. 5 mine, Washington County, Pa.; and one in the Illinois No. 6 coalbed at the Inland mine, Jefferson County, Ill. Induced fractures were contained totally within the coalbed with no adverse effect on the stability of associated rock strata. Induced fractures were vertical and were propagated normal to the direction of least residual tectonic stress. Gas production was increased fivefold to twentyfold by hydraulic stimulation.

Jan 1, 1977

By R. T. Langland

Using a finite-element computer model, we have conducted an analytical study of roof behavior in a room-and-pillar coal mine. With standard engineering property in formation and a computer code developed for the Bureau of Mines to calculate roof sag, convergence, and roof-bolt load change, we have calculated the stability of roof-support systems and compared the computed data with experimental data collected during a field investigation at three test sites, one in a development area and two in production areas of a coal mine.

Jan 1, 1978

By R. H. Lien

The Bureau of Mines has conducted research on a flue gas desulfurization (FGD) process as part of its goal of minimizing the undesirable environmental impacts associated with sulfur dioxide (S02)-bearing waste gases. This FGD process, referred to as the modified citrate process, involves absorption of S02 in a buffered citric acid solution. The absorbed S02 is subsequently stripped from the solution using steam, which regenerates the solution and produces a wet S02 product. This product can be further processed to make sulfuric acid or liquid S02. Economic evaluations showed the process to be expensive when the stripper was operated at or near ambient pressures because of the large amounts of steam required for solution regeneration. Research was directed at reducing steam consumption in the stripper. The effect of stripper pressure on steam consumption was investigated. A process research unit (PRU) was operated with the stripper pressurized in the range of 5 to 150 psig. Test results showed that steam consumption decreased with increased stripper pressure. For example, when operating the PRU stripper at 150 psig, 4.1 grams of steam per gram of S02 was required to remove 90 pct of the S02 from a 1.0-vol-pct-S02 gas. This compares to 7.1 grams of steam per gram of S02 required for 90-pct S02 recovery at 5 psig.

Jan 1, 1982

By G. S. Scott

Mine fires have occurred since the mining of coal was begun, and they are still occurring. The resulting economic waste may become considerable (219),3 especially if a fire is allowed to assume major proportions or to get beyond control temporarily. It is important, therefore, to act promptly whenever a fire is suspected and to have every action count. To do this effectively, it is necessary to know at the earliest possible moment and thereafter what is happening in a remote or inaccessible area. It is equally important to know before¬hand what may be expected as a result of any proposed combative measure. The logical method of combatting a fire demands the cooperation of both mining engineer and chemist. They should decide the course of action to be taken, drawing upon the mining engineer's intimate knowledge of the physical structure of the fire area, the cost and time required for proposed operations, and the probable efficiency with which they could be carried out, and upon the chemist's knowledge of the results to be expected therefrom.

Jan 1, 1944

By R. V. Ramani

One area of study in the Coal Mine Injury Analysis project was to illustrate and enhance the ability of mine safety management personnel to apply analytical techniques to injury experience data and to justify requests for funds for safety enhancement actions on a cost/benefit and other quantitative basis. Four volumes of this final project report detail (1) the objectives and scope of the mine safety management research, (2) the results of literature review, and case studies, and (3) models developed for mine safety management. The four volumes are titled as Volume III: Mine Safety Management, Volume IV: Analytical Techniques for Mine Safety Management; Volume V: Mine Safety Management Case Studies and Volume IX: Training Cost Model. This volume deals with the development of a microcomputer based training cost model (TCM) which can be used to analyze training cost implications of various types of training. The model has been developed using Aston Tate's dBASE III plus language. The computer program and a test run of the model are presented in this report.

Jan 1, 1993

The condition of the domestic mining industry is obviously affected by the cycles in general business conditions. This study, the results of which are presented in a series of 78 charts, attempts to examine the interrelationships between the general business indicators and the major statistical measures for the base-metals industries during the cycles in the United States economy following World War II. For these industries the cyclical problem is perhaps less acute than the secular-trend problem. However, short-run fluctuations in production and employment do have very important impacts upon the welfare of the regions which derive a significant portion of their income from base-metals mining and processing industries. Any information concerning the normal patterns of development as the industries enter into a cyclical recession will permit better forecasts and perhaps help promote measures to alleviate the distress that occurs. Also, a systematic study of the comparative movements among the statistical measures during a series of cycles can bring to the fore the economic causation involved, and perhaps, after intensive study, can lead to a better method of short-range forecasting for these industries. This study has not fully achieved these aims. However, observations which significantly aid the interpretation of the current monthly statistics on these commodities are made, and some very general conclusions are drawn. The charts are presented so the interested people can examine them and draw additional conclusions. The charts refer specifically to cyclical analysis. The technique of indexing each cycle to its turning point effectively subordinates the longer term trend movements of the data. Thus, certain general conclusions flowing from this study and from the continuing economic research of the Office of Chief Economist will aid the reader by clarifying the frame of reference within which the charts should be examined.

Jan 1, 1961

By Linneas W. Laage

The purpose of this report is to document the fire experiments conducted at the Waldo Mine, NM during March 1990. The U.S. Bureau of Mines is concerned with improving and validating the predictive capability of the mine ventilation and fire simulator, MFJRE. To accomplish this, fire experiments were conducted at the Waldo Mine and temperature profiles were developed as functions of time and distance from the fire. These tests then provided data for verifying the heat transfer model in the MFIRE mine ventilation and fire simulator. An initial analysis of this data indicates that it will serve this purpose well. This report summarizes the data obtained during six fire tests at the Waldo Mine.

Jan 1, 1994

By L. A. Morely

The overall objective of the subject contract was to investigate the application, economic, and safety considerations of electrical-shock prevention techniques applied to surface and underground mines. Volume I of the four-volume final report starts by summarizing all research performed, and synopses of the three other report volumes are included. The balance of this volume concerns one major task of the contract, the protection of maintenance personnel. After specifying the scope of work for the task, electrical is defined, and needed ground-fault relay characteristics to prevent ventricular fibrillation are established. This is followed by an analysis of alternating-current systems, a comparison of these systems with respect to body currents, and the advantages and disadvantages of the various ground-fault protection techniques. An analysis of direct-current systems for off-track vehicles is then covered. These analyses form the basis for the research recommendations which along with suggestions for future research, conclude the report volume.

Jan 1, 1982

By M. M. Tilman

In a Bureau of Mines investigation to develop lead alloys with improved tensile strength and creep resistance, lead-base alloys containing cadmium and antimony in nominal 1-to-1 atomic ratios were melted in air, cast, and rolled into sheet to 90 percent reduction at temperatures varying from room temperature to 175° C. Tensile testing at room temperature and stress-rupture testing at 900±3° F were conducted on the as-rolled alloys. The best tensile properties were observed in an alloy of Pb-4.2 wt pct Cd-4.5 wt pct Sb which exhibited an average tensile strength of 7,270 psi with 36 percent elongation in 2 inches. An alloy of Pb-5.5 wt pct Cd-6.0 wt pct Sb had 100-hour stress-rupture values of approximately 2,100 psi and 1,000-hour values of approximately 1,700 psi.

Jan 1, 1969

By R. V. Ramani

This report is volume 3 of an eleven-volume final report for a Grant completed by The Pennsylvania State University for the Bureau of Mines to develop a dynamic general purpose computer simulation model for underground coal mining. The simulator developed under the Grant has a wide range of possible applications in the design and evaluation of underground coal mining systems from the standpoints of health and safety, productivity, and mine environment. The Master Design Simulator consists of nine free-standing function-oriented subsystem models linked together into an integrated, comprehensive model of an entire mining system. The subsystems comprising the Master Design Simulator include geology and reserves, methane generation, roof support, subsidence, production, rail haulage, cost, water generation,' and ventilation. This volume of the final report describes the Methane Generator subsystem of the Master Design Simulator. This subsystem is used to determine methane emission rates into the mine environment. These flow rates are then used by the simulator in planning primary and secondary ventilation systems, planning a methane drainage system, and analyzing complex ventilation networks. Both steady state and unsteady state gas flows are included, and have been modeled as second order nonlinear partial differential equations. Finite difference equations are used to obtain numerical solutions to the models using a central differencing scheme. An application of the model is presented. The appendices include derivation of the gas flow equations used in the model as well as a users manual for the computer program.

Jan 1, 1974

By Daniel G. DiCanio

This report describes a computer-based model for estimating the tangible costs of injuries and deaths from work-related accidents in underground coal mines. The study undertook to identify and quantify the elements of accident costs, including field visits to coal mines, insurance carriers, and public agencies. The mathematical models developed for each tangible element of accident cost are presented in Volume I of the report. A listing of the computer programs which comprise the model and instructions for using the programs are presented in Volume II. Statistical distributions of mining family characteristics, data on 95 miners killed in underground accidents, and other basic data used to develop the model are presented in Volume III. Application of the model to a data base of 9,286 accidents which occured in underground bituminous coal mines during 1974 yielded a total of $56,900,000 in tangible costs to industry, mining families, and public agencies. Loss of income to the families of miners injured or killed in these accidents accounted for 47 percent of the total.

Jan 1, 1976

By Frank M. Vodoklys

This is the final report on Contract H0220049 covering the period from 27 April 1972 to 30 April 1974. The objective of the contract was to develop and evaluate materials and methods to achieve post explosion identification of explosives reliably and economically through the use of phosphor coded grains incorporated into the explosive during its manufacture. A coding system of two spotting phosphors and seven coding phosphors was successfully developed during the execution of the contract. The ability of the coded grains to survive detonation in many different types of explosives was demonstrated and the complete code was extracted from a single 100 micron post-explosion fragment. A method was established for testing grain strength to correlate with field test results and an optical system was designed for extracting the code from the grains. Also in fulfillment of the contract requirements a laboratory method for manufacturing the coded grains was established and ten one-pound samples, each with a different code, were fabricated. Finally, a method was developed for applying a coating of polyethylene to the grains to prevent sensitization of the tagged explosives and the ten one-pound samples were coated and delivered to the Bureau of Mines.

Jan 1, 1974

By J. M. Kurtz

Ten Methane Monitoring Systems and Machine Control Circuits were examined and tested per the requirements in CFR Title 30, Parts 18 and 27, the Standard UL 913 and the document "Test Requirements For Instruments or Apparatus to be Considered for M.E.S.A. Intrinsically Safe Certification (Tentative)". The test results indicate that none of the products complied with all parts of all requirements as interpreted by Underwriters Laboratories Inc.

Jan 1, 1980

By J. J. Taber

This is the final report on Grant No. G0144067. The report presents the results of a number of laboratory studies carried cut in several different ways to determine the effectiveness of foam for blocking the flow of gas in coal. The effectiveness; (of foam for retarding or blocking the flow gas in various porous media has been observed by many investigators1-4 but we are not aware of similar detailed studies in coal. Because of the diversity of our experiments, the key findings and general conclusions are presented very briefly in Section II. As a convenience to the reader a complete table of cements is included to enable the reader to find those experiments and studies of greatest interest.

Jan 1, 1976

By R. E. Simpson

Beginning in 1972, fully grouted resin bolts were used in underground mines. An estimated 20 million resin bolts will be installed in 1980 owing to their apparent support improvement in most roof-bolt applications. Inorganic cements were tested to replace the resin at a lower cost while retaining the advantages of a grouted bolt. Although other inorganic materials were considered, all but portland and gypsum cements were rejected for reasons of availability, performance, or cost. Portland and gypsum-type cements were tested by the Bureau of Mines to select a fast-hardening, low-cost material that would anchor a roof bolt adequately to meet safety standards. An alpha-gypsum cement, accelerated with potassium sulfate, was selected as the best material because it had adequate pull strength at a desired set time of less than 5 minutes and was readily available.

Jan 1, 1980

By Juh W. Chen

A process for recovery of energy from waste coal fines was investigated. The process, which was developed through laboratory, bench, and pilot plant scale experiments, consists of mechanical cleaning followed by high temperature oil agglomeration and pelletization. The process can produce a quality product under an economically and environmentally acceptable condition. Waste coal fines with ash less than 35: and HHV greater than 6,000 BTU/1b have been upgraded to a product with less than 15% ash and HHV Greater than 11,500 BTU/lb. A computer model has been developed to optimize the processing costs and to perform economic evaluation of specific sites. Ultimately tine model can be utilized to establish a priority listing for a region in assisting the determination of reclamation strategy.

Jan 1, 1983

By L. C. IlsLey

"This paper is intended for State mining inspectors, safety engineers of mining companies, and others interested in electrical safety inspection in mines, It presents the important points that should be watched by inspectors, and briefly reviews the work of the Bureau of Mines in the testing of electrical apparatus or equipment to determine their permissibility for use in gaseous coal mines.Important Points in Inspecting Mine Electrical Installations or Equipment.The following questions are intended as suggestions to a safety inspector who may not have been specially trained in looking for defects in installations or in the maintenance of electrical equipment:1.,Is there someone in charge of electrical equipment who is fitted for this position by ability, training and experience?2.,Is a systematic recorded inspection of electrical equipment made at least once each month?3.,Is a plan map of the mine kept showing all permanently installed electrical machinery and apparatus, including cables, conductors light etc.?4.,Are there instructions for resuscitation from electric shock posted in each surface and underground electrical station, also at the entrance of the mine and in the first aid station and are employees working on electrical equipment trained to apply these instructions in case of accident?"

Nov 1, 1923