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By N. Snyders, I. Mwandawande, S. M. Bradshaw, M. Karimi

"Flotation columns are normally operated at optimal superficial gas velocities to maintain bubbly flow conditions. However, with increasing superficial gas velocity, loss of bubbly flow may occur with adverse effects on column performance. It is therefore important to identify the maximum superficial gas velocity above which loss of bubbly flow occurs. The maximum superficial gas velocity is usually obtained from a gas holdup versus superficial gas velocity plot in which the linear portion of the graph represents bubbly flow while deviation from the linear relationship indicates a change from the bubbly flow to the churn-turbulent regime. However, this method is difficult to use when the transition from bubbly flow to churn-turbulent flow is gradual, as happens in the presence of frothers. We present two alternative methods in which the flow regime in the column is distinguished by means of radial gas holdup profiles and gas holdup versus time graphs obtained from CFD simulations. Bubbly flow was characterized by saddle-shaped profiles with three distinct peaks, or saddle-shaped profiles with two near-wall peaks and a central minimum, or flat profiles with intermediate features between saddle and parabolic gas holdup profiles. The transition regime was gradual and characterized by flat to parabolic gas holdup profiles that become steeper with increasing superficial gas velocity. The churn-turbulent flow was distinguished by steep parabolic radial gas holdup profiles. Gas holdup versus time graphs were also used to define flow regimes with a constant gas holdup indicating bubbly flow, while wide gas holdup variations indicate churn-turbulent flow. IntroductionTwo types of flow can be distinguished in gasliquid flows in bubble columns: bubbly flow and churn-turbulent flow. The bubbly flow regime is characterized by uniform flow of bubbles of uniform size. Churn-turbulent flow, on the other hand, is characterized by a wide variation in bubble sizes with large bubbles rising rapidly and causing liquid circulation.Flotation columns are normally operated in the bubbly flow regime, which is the optimal condition for column flotation (Finch and Dobby, 1990; Yianatos and Finch, 1990; Ityokumbul, 1992). However, it has been generally observed that flotation column performance deteriorates when the superficial gas velocity is increased beyond a certain limit where the flow regime changes from bubbly flow to churn-turbulent flow (Xu, Finch, and Uribe-Salas, 1991). The identification of this critical or maximum superficial gas velocity is therefore important for optimal operation of flotation columns."

Feb 1, 2019

1. Recent books D. K. Hsiao, D. S. Kerr, and S. E. Madnick. Computer security. New York, Academic Press, 1979.276 pp. $18. W. C. J. van Rensburg and S. Bambrick. Economics of the world's mineral industries. Isando, McGrawHill, 1979. R18,95. Soviet metallurgical research 1973-1977. Vo!. 1. Subject index and author index (1963-1972). Vo!. 2. Chronological listing of titles with full bibliographical information (1960-1972). London, Scientific Information Consultants Limited (661 Finchley Road, London NW2 2HN). £24 per set. W. Hoosen. Miners' dictionary. London, Institution of Mining and Metallurgy, 1979. (Reprint.) £11 (£9 for members). G. J. Pitt and G. R. Millward. Coal and modern coalprocessing: an introduction. New York, Academic Press, 1979. 224 pp. $18. D. Stephenson. Rockfill in hydraulic engineering. Amsterdam, Elsevier, 1979. 228 pp. U.S. $45, D.fl.90. 2. NIM reports Report no. 2015 The preparation of synthetic standards for use in instrumental neutron-activation analysis. Report no. 2029 The commissioning of a 5 kW inductively coupled plasma unit for use with a 3,4-metre Ebert spectrograph. Report no. 2032 The Cancer Project: a summary of the computer-aided operation of a 48 MV.A ferrochromium furnace. Report no. 2036 The determination of thallium in ores, concentrates, and metals. Report no. 2040 A solid-state constant-current power unit for the magnetic analyser of the MS702R mass spectrometer. Report no. 2044 The separation and determination of anions by ion chromatography. Computer congress In October 1980, Japan and Australia are hosting the 8th World Computer Congress. This Congress is a triennial event conducted under the sponsorship of the International Federation for Information Processing. INFACON 80 The Second International Ferro-Alloys Congress, organized by IPFEO (Institute of Western European Ferro-alloy Producers), is to be held in Lausanne, Switzerland, on 13th to 16th October, 1980.

Jan 1, 1980

By D. Moses, J. A. Onyango

Carbonatites are generally competent rock masses with rock mass rating class II rating 60–74. In spite of their competency, they tend to be affected by weak features like manganese-iron veins and/or in situ rock damage due to brecciation associated with carbonatite complexes. Rock slope failure in such hard rocks is complex since such structures within the rock mass form weak links that could potentially control slope instability. In this contribution, a numerical simulation using phase2 v 7.0 was carried out to investigate the influence of in situ rock damage on the stability of mine pit walls. The outcome reveals that, the existence of breccia in the competent rock mass has the capability to reduce the slope stability performance particularly at gentle dipping angles of emplacement in close range to the slope toe. However, as the emplacement position of breccia moves away from the pit wall, the stability performance increases at gentle dipping angle <50º. On the contrary, at the dipping angle of 50° the performance of slope reduced, and at steeper angles >50° the impact becomes negligible. Thus, from a series of analyses, mine design in brecciated rock masses, the ratio of 1:5 between the breccia distance from slope toe and pit depth should be implemented to counter its impact, and if the breccia is within or close to the pit limit, a deliberate effort must be made to mine it out.

Sep 1, 2025

By A. Ennen, R. Wagner, B. Orberger, J. -M. Milazzo, N. Uhlmann, J. Banchet, J. Lucic, N. Wörlein, M. Firsching, J. L. Dubos, C. Bauer

The residues from mining and processing ores can often be considered as secondary raw materials. However, the material is only available in the form of fine particles (< 3 mm). In order to recycle these wastes, it is necessary to agglomerate it for transportation prior to reprocessing. The resulting agglomerates need to mechanically resist the stress of transportation and loading into the furnace. X-ray computed tomography (CT) is an established method for characterisation of internal structures in material science. This non-destructive technique can provide information on size and distribution of particles and grains. However, the information is not limited to the size, but also can yield structural features like orientation and position of cracks and fractures, which are important features indicating potential for deteriorating the agglomerates. Furthermore, deduced features such as contact conditions of inclusions or boundary surfaces can also be calculated. We studied binder-free tablets of manganese-oxyhydroxide, bentonite, kaolinite and slag powder using micro-CT. Inclusions of highly absorbing particles were identified using a watershed transformation with automatic segmentation by Otsu thresholding. Subsequently, the resulting data was analysed regarding their volume percentage, distribution in size and location within the sample. For the slag agglomerates, the volume fraction of iron could be determined. Furthermore, visible cracks were investigated with the goal to determine the long-term durability. It was shown that the data provided by micro-CT is reliable and helpful for the characterisation of industrial waste agglomerates. Keywords: X-ray, computed tomography, micro-CT, agglomerates, manganese fines, slags, kaolinite, bentonite

Jan 1, 2020

By I. Mitov, A. Stoilova, D. Krastev, B. Yordanov

We present three technological scenarios for the recovery of valuable components from gangue, stored in the tailings dam at Kremikovtzi metallurgical plant in Bulgaria, into marketable iron-containing pellets. In the first approach the iron concentrate was recovered through a two-stage flotation process, desliming, and magnetic separation. In the second proposed process, the iron concentrate was subjected to four sequential stages of magnetic separation coupled with selective magnetic flocculation. The third route entails the not very common practice of magnetizing roasting, followed by selective magnetic flocculation, desliming, and magnetic separation. The iron concentrate was pelletized in a laboratoryscale pelletizer. Each technology has been assessed with regard to the mass yield of iron concentrate, the iron recovery. and the iron, lead, and zinc content in order to identify the most effective route.

May 1, 2021

By J. S. Contreras, E. Córdova, I. Gottreux, A. Anani, A. Ferrada

Cave mining is an underground mass mining technique. The largest projects, which are known as ‘super caves’, produce hundreds of thousands of tons of ore per day, which involves large footprints with considerable column height, and have a life of mine of over 20-40 years. These operations are typically located deep, under high stresses and in competent rock masses, making initiation and propagation of the caving process harder to manage. These challenges must be confronted by optimizing the fragmentation of the orebody to achieve smaller size blocks that will result in consistent caving and improved flow of the ore from the drawpoints. To achieve better performance from the drawpoints, preconditioning is applied to fragment and damage the material required to cave. We present a proposed design for preconditioning in underground mines, considering the challenges that these large-scale mines are already facing, based on a comprehensive analysis of current design parameters, case studies, and sensitivity analyses using numerical models.

Feb 2, 2021

By A. R. Javadi

Pyrite (FeS2), chalcopyrite (CuFeS2), sphalerite (ZnS) and galena (PbS) generate hydrogen peroxide (H2O2) when placed in water, with pyrite generating the most amount of H2O2. The order of these minerals for generating H2O2 in water is: pyrite > chalcopyrite > sphalerite > galena. In previous research, the methods of generation of H2O2 in the grinding mill were studied. In this study, data from experiments were included by using MODDE 9 software for six parameters composed of water, grinding media, particle size; adding collector to the grinding, and adding depressant and pH. Finally the optimal condition was achieved. According to the results, most of the recovery is related to the particle 75 μ size and when using processed water, adding 100% collector and without depressant and pH 10. The most recovery of lead in the case of the use of fresh water is in the case of 100% collector, without depressant, pH 10 and 150 μ particle size. Maximum recovery in fraction size 45 μ in the case of water process is 100% collector, without depressant and pH 10. Maximum depressant of pyrite will be the fraction size 75 μ, distilled water, without collector, 100 depressant. Keywords: Sulfide mineral, hydrogen peroxide, flotation, oxidation

Jan 1, 2020

By R. W. O. Kersten

"The aim was to investigate stable pillar design procedures currently in use on chrome and platinum mines, subject them to a critical appraisal, and review some of the alternatives proposed in the literature. It is concluded that these pillar design methodologies suffer from drawbacks that can be detrimental to the mining industry and that an improvement is essential.It was decided that the increased availability of analytical models and failure criteria could be exploited to update the empirical to an analytical/empirical method. The proposed methodology adopted FLAC2D simulations using the Hoek-Brown failure criterion to calculate full stress-deformation curves for typical pillars. The mine stiffness concept was introduced to determine the pillar load, integrating the influence of the pillar and strata stiffness and mining geometry.The proposed methodology was calibrated by comparing experimental and predicted deformations and failure depth of pillars in one hard-rock mine. The conclusion was that the methodology is an improvement over the one currently in use. An improved factor of safety is given by the intersection point of curves for the stiffness of the system and the pillar strength. IntroductionThe paper describes part of the findings of a PhD thesis (Kersten, 2016) on an alternative stable pillar design methodology. This publication contains sufficient information to implement the method for further interpretation and testing. A detailed comparison of measured and predicted data is dealt with in the thesis, and the results show that there is promise in the methodology.The design of stable pillars in mining is of fundamental importance, not only in the Bushveld Complex mines but throughout the mining industry. Wherever mining occurs, pillars are formed at some stage and it is essential to predict their behaviour, i.e. whether they will burst, yield, or remain stable. Although of crucial importance, pillar design still suffers from major shortcomings and weaknesses."

May 1, 2019

By H. Cevizci

In this study, a newly developed plaster stemming method is studied and compared with the usual dry drill cuttings stemming method for surface blasting in mines and quarries. Drill cuttings are generally used in open pits and quarries as the most common stemming material since these are most readily available at blast sites. However, dry drill cuttings eject very easily from blastholes without offering much resistance to blast energy. The plaster stemming method has been found to be better than the drill cuttings stemming method due to increased confinement inside the hole and better utilization of blast explosive energy in the rock. The main advantage of the new stemming method is the reduction in the cost of blasting. In one series of blast tests, blasting costs per unit volume of rock were reduced to 16 per cent by increasing burden and spacing distances. Also, better fragmentation was obtained by using the plaster stemming method. Blast trials showed that plaster stemming produced finer material. In the same blast tests, +30 cm size fragments reduced to 5.4 per cent of the total, compared to 37.7 per cent in the conventional method of drill cuttings stemming. With this method of stemming, vibration and air shock values increased slightly due to more blast energy being available for rock breakage, but these increased values were small and under the permitted limit for blast damage criteria.

Jan 1, 2012

By M. Mabuza

Two Rivers Platinum Mine (TRP) is a 55:45 joint venture between African Rainbow Minerals and Impala Platinum, respectively. TRP is situated on the farm Dwarsrivier 372KT, in the southernsector of the eastern limb of the Bushveld Complex. Dwarsrivier is underlain by rock formations of the Critical Zone (Winterveld norite-anorthosite) and the Main Zone (Winnarshoek norite-anorthosite). Two economically significant PGE-bearing layers namely the Merensky Reef and the UG2chromitite are found within the upper Critical Zone. These are approximately 140 m vertically apart, separated by a series of barren norites and anorthosites. At Two Rivers Platinum, only theUG2 chromitite layer is currently being mined for PGEs. The UG2 sub-outcrops north/south along the Klein Dwarsrivier river valley with a very gentle dip to the west of 7º?10º. At Two Rivers the UG2 averages about 120 cm in thickness, overlain by a waste pyroxenite parting about 20 cm thick, above which is a leader seam about 20 cm in thickness. The mineable cut consists of the leader seam, the waste pyroxenite parting, the UG2chromitite layer including 25 cm of pegmatoidal pyroxenite footwall, below the UG2 reef to a minimum of 185 cm trackless mining cut. The mining method is a mechanized bord and pillar layout, which will yield a total of 185 000tons at full run of mine production from the underground UG2 mine.

Jan 1, 2006

By V. V. Getman, V. A. Chanturiya, T. N. Matveeva

Most of the Au and PGM ores in Russia are characterised by a thin mineral impregnation of noble metals in sulfide minerals, and a large variety of mineral forms that lead to high loss of precious metals with fine fractions during flotation. In modern flotation technology, the rational choice of reagents is one of the main trends for selective separation of minerals and effective metals recovery. New data on the selectivity of the thermo-sensitive polymer with specific functional groups (TMPPh) as a flocculant and collector of Au and Pt fine fractions are available. The selective modified collector (DEDTCm) for the recovery of Au and Pt from complex ores is discussed in this paper. Scanning electronic microscopy (SEAM), laser SIM and AFM microscopy, UV and IR spectroscopy were applied to study the adsorbed layer of new reagents on the mineral surface. Flotation tests of TMPPh on the gold-bearing ore of the Olimpiada deposit showed an increase in Au extraction and Au content in the concentrate of the rougher flotation. Using a combination of reagents TMPPh and ButX, the quality of the Au and Pt concentrates increased in 1.7 time with an increase in recovery up to 15 % compared with the traditional reagent mode. Testing of TMPPh polymers in flotation of Pt-Cu-Ni ore at Norilsk Nickel has shown the ability to obtain a concentrate with a higher Pt content. Recovery of platinum is 17% higher than recovery in an experiment without polymer. Application of DEDTCm helped to achieve higher technological parameters in flotation of lowgrade Rt-Cu-Ni ore. Compared to the basic mode Pt recovery was plus 13%, Pd recovery was plus 9% and the content of precious metals in the rougher flotation concentrate increased in 2,5 - 4 times. The studies have been supported by Grants of the President of RF “Scientific School of Academician V.A. Chanturiya” NSh-220.2012.5, NSh-748.2014.5. Keywords: Au and Pt complex ores, flotation, flocculation, thermo-sensitive polymer TMPPh, modified collector

Jan 1, 2020

By J. O. Claassen

"Homogeneous populations are required to perform descriptive, probabilistic, and inference statistics and to support stable, predictable mining operations. The geological and downstream processing environments are, however, highly heterogeneous. The complex nature of mining environments requires means to identify and define multipopulation environments that could affect the performance of mining value chains. A study performed at several operating mines suggests that the impact of heterogeneous or variable geological, mining, and plant processing environments on overall mining value chain performance may not be a key focus area at these operations. This was illustrated through the use of basic and spatial statistics, which included the log-probability plot, a modified range equation, and chronovariography. The findings reflect high relative variability in the geological and processing environments studied and mining operators’ inability to effectively deal with the sources and consequences of variability. The study suggests that a focus on heterogeneity in complex mining operations may significantly enhance overall mining performance. IntroductionHeterogeneity and why it mattersHeterogeneity refers to a state or quality of being variable/diverse and comprising different non-compatible elements or parts. In statistical terms a heterogeneous population can refer to a population comprising different non-compatible sub-populations or a multipopulation environment. The latter is commonly found in natural environments such as geological environments (Bardossy and Fodor, 2001). The inherent heterogeneity of complex geological environments is also referred to as spatial heterogeneity. Heterogeneity or variability, however, also occurs over time at mining operations. A case in point is variable ore composition on a conveyance system feeding a processing plant or product stockpile.Heterogeneity associated with the mining environment can significantly influence key aspects of day-to-day mining operations such as sampling, the use of descriptive, probabilistic, and inference calculations, and an operation’s ability to manage and control the mining value chain as a whole."

Jan 1, 2016

By J. Engelbrecht

Understanding the deportment of minerals in size fractions has already led to improvements in the flow sheets for platinum minerals beneficiation. There are, however, more potential changes in the flow sheets that may improve the recovery of platinum group metals or reduce the costs of beneficiation before refining. Based on known technology of pre-concentration, milling, gravity concentration, flotation, and magnetic separation a number of potential alterations or additions can be considered and motivated based on the mineral deportment in size fractions.

Jan 1, 2012

By O. T. Konina, V. A. Masloboev, A. V. Svetlov, E. A. Krasavtseva, D. V. Makarov, A. A. Goryachev

Dusting phenomena have been examined at the tailings storage facility of Apatit JSC Kirovsk, a mining operation located in the far north of the Russian Federation. The material composition of the tailings was identified. Existing dust suppression methods were examined. Field observations were undertaken and official data was obtained from the Murmansk Administration for Hydrometeorology and Environmental Monitoring, and analysed. A database was built for forecasting dusting according to critical scenarios in order to estimate the peak MPCs of suspended solids in the atmospheric air. Mitigation measures were formulated and recommended to the mining operation. Keywords: Mineral dust particles, apatite-nepheline ore concentration tailings, suspended solids MPC, climate change

Jan 1, 2020

By J. Bal, V. D. Dao, W. Li

"SynopsisThis study proposes a methodology for evaluating the risk of coal bumps in multiple-seam longwall mining. Both the stress field and the total energy release (TER) during retreat were evaluated in the specified case involving multiple-seam mining using the LaModel program. The results of numerical simulations indicated that both the peak vertical stresses on the panel edges and the peak TERs in the outby longwalls increased significantly as the horizontal offsets were reduced from 60 m to zero. With the comprehensive consideration of the stress field and TERs, a conservative offset of 60 m was ultimately adopted when developing the gateroads of the lower panel in the field. The field measurements indicated that coal bumps were avoided completely by employing the proposed design, and the maximum roof-to-floor and rib-to-rib convergences of the tailgate during retreat were only 360 mm and 576 mm, respectively.IntroductionCoal bumps – sudden, violent bursts of coal – pose a serious threat to the safe excavation of coal. Their occurrence depends on the properties of the surrounding rocks, stress field, and dynamic disturbance. The complexity of the mechanism of coal bumps is further enhanced in multiple-seam mining due to seam interaction. Multiple-seam mining is most frequently found in the coalfields in eastern China, such as Xuzhou, Xinwen, Zaozhuang, and Huainan. In the past, due to issues of availability, economics, and ignorance of the potential risk in multipleseam mining, coal seams in such conditions were mined without proper planning to account for seam interaction. Fortunately, studies published over the past three decades have raised awareness of the problems associated with multiple-seam mining, and indicated that the ground control issues induced by multiple-seam mining can be avoided and/or minimized with proper planning.A number of technical studies pertaining to the design of multiple-seam mines have been published. These studies can be divided into two groups based on their methodologies of design: empirical (Chekan and Listak, 1993; Haycocks and Zhou, 1990, Matetic et al.; 1987a, 1987b) and numerical approaches (Li et al., 2000; Maleki, 2007; Mark, 2007; Peng, 2007; Zipf, 2005). The majority of the extant studies on the interaction mechanisms in multiple-seam mining have focused on the load transfer during operation, resulting in the proposal of the pressure bulb theory (Forrest et al., 1987; Haycocks and Karmis, 1983; Peng, 2008; Peng and Chandra, 1980) and pressure arch theory (Holland, 1973; Oram and Ponder, 1997) to guide multiple-seam mine design. However, neither, of these theories can be used to evaluate the potential for coal bumps."

Jan 1, 2015

By T. Szendrei and S. Tose

Historical approaches to the problem of flyrock based on correlation studies and regression analysis, including artificial neural networks and similar techniques, are inherently incapable of addressing two core issues – root causes of flyrock and projection velocity. A further shortcoming of correlation techniques is that they give no information on the influence of rock size and shape on the flight distance. The scaled depth of burial model for crater blasting in the collar zone and bench face does not specifically address the question of flyrock velocity. A third approach, based on flight trajectory calculations, often neglects the very significant effects of air resistance on the trajectory. Some trajectory models incorporate air resistance but use an implausible fragment velocity model that cannot propel sizeable rocks to distances much beyond 150 m. Nonetheless, trajectory calculation incorporating the effects of air drag affords the most promising approach to the prediction of flyrock range. A unique and insightful feature of the proposed realistic flight modelling is that it collapses all suspected causes of flyrock, many of which are not well understood, to just a single parameter – the launch velocity. This indicates that the root causes of flyrock lie in the mechanisms of momentum transfer to broken rock and suggests new avenues of study.

Dec 13, 2022

By E. Garab, M. Pillalamarry, E. Develo

"Recent geological exploration at Rosh Pinah mine revealed that the mine’s major production is shifting towards the western orefield, which will increase the demand for air flow to be supplied to this area. A snapshot of the ventilation survey carried out in December 2014 at the western orefield drill drive B (WOF-DDRB) showed that the air flow was well below the required standards. In order to improve the existing conditions, possible options were considered and simulated using Ventsim™ software.The best option found was to replace the existing western orefield fans with the larger fans from the inactive southern orefield workings, to increase the air flow in the DDRB district. Simulation showed that as much as 20 m3/s of air can be received at the working faces of WOF 30, compared to the previously received amount of 1.37 m3/s. The economic analysis indicated that the above option can reduce the ventilation cost by N$1.9 million annually. It was also noticed that after implementing this option together with other projects, the ventilation conditions in the mine were greatly improved and currently give no cause for concern. IntroductionA good mine ventilation system should be capable of providing adequate quantity and quality of air to all working faces, and is critical to the occupational health, safety, and comfort of underground employees (Luxbacher and Ramani, 1977; Exikis and Kapageridis, 2006). No ventilation system can remain adequate indefinitely; as the mine workings are extended, the ventilation characteristics such as system pressures, air volumes, leakages, and airway resistances change considerably. Continuous improvement of the ventilation system is needed to ensure compliance with health and safety regulations (Lovejoy, 2010). It also ensures that the right quality and quantity of air is delivered to all the necessary areas at the lowest possible cost. This can be achieved by identifying inefficient airways and poorly ventilated areas in the mine and planning how best to upgrade them.The latest geological exploration shows that the focus of production at Rosh Pinah mine is shifting towards the western orefield (WOF). As mining progressed, the working areas have advanced away from the main fans, which increased the resistance to air flow drastically and resulted in increasing demands being imposed on the main fan in order to supply an adequate air flow. This process also created more leakage paths between the fan and the working areas, which has caused the air to short-circuit before it can reach the faces. Consequently, a much larger quantity of air has to be circulated by the fan so that the stipulated quantity reaches the face, which increases operating costs (Singh et al., 2004)."

Jan 1, 2016

By S. T. L. Harrison, A. Kotsiopoulos, M. D. Maluleke, E. Govender-Opitz

In the extraction of base metals from printed circuit boards (PCBs) using bioleaching, the accumulation of metal ion stress in solution has been shown to inhibit the microbial regeneration of ferric iron. This poses a challenge for the development of this technology for e-waste treatment. The paper explores the application of a microbial immobilisation system in a two-stage bioleaching system consisting of a chemical leaching reactor in series with a microbial ferric iron regenerating reactor to mitigate microbial inhibition and to enhance base metal extraction. A mixed microbial culture dominated by L. ferriphilum, L. ferrooxidans and At. Caldus was maintained over a period of two months in the presence of polyurethane foam which acted as the biomass support particle. Microbial metabolic activity of immobilised cells and their tolerance to inhibitory Cu ions was investigated. Results showed that immobilised microbial cells maintained higher ferrous iron oxidation activity compared to planktonic cells in the presence of increasing Cu2+ concentrations up to 6 g/L. This presents an opportunity for microbial immobilised systems to be adopted in two-stage bioleaching system. Keywords: Bioleaching, microbial immobilisation systems, microbial inhibition and ferrous iron oxidation

Jan 1, 2020

By A. Muller

The magnesia-carbon refractories used in the ConArc process experience severe wear as a result of the varying slag composition during the blowing phase. This work determines the basicity range in which minimum as well as maximum refractory wear was experienced by the magnesia-carbon refractories during service. In order to determine an optimum slag composition, the crucible test in an induction furnace was used. The magnesia-carbon refractory bricks were cut into cylindrical crucibles to which a synthetic slag in the form of pellets was added. The basicity (B2) of the slag was varied from 0.5 to 3. Tests were done at 1 600°C for one hour. Apart from the crucible test in an induction furnace, visual inspection and SEM analysis were also done to investigate the corrosion mechanism. FACTSage® predictions about the interaction between refractories and slag were also done. These predictions were compared to the actual results attained. It was found that the extent of corrosion by slag attack decreases as the basicity increases. The most severe corrosion of the MgO-C refractories occurred at a basicity of 0.5 whereas the optimum basicity is above 2.0. SEM analysis indicated severe slag attack at the lower basicities with no visible refractory-slag interaction at higher basicities. TheFACTSage® predictions supported most of the actual findings. Keywords Magnesia-carbon, ConArc, blowing phase, slag resistance, induction furnace, crucibles.

Jan 1, 2011

By E. Marè, D. R. Groot, R. Engelbrecht, T. Coetsee

Hydrogen peroxide is often used as an oxidising agent in experimental waste electronic equipment (WEE) leaching work. However, the high cost of peroxide is a negative factor in its consideration in further process development. A few studies have reported on the efficient application of peroxide addition schedules to ensure optimum reagent consumption. Large quantities of unleached substrate material contained in WEE feed material result in a large dead volume of material in the leaching reactor. This factor necessitates fast reaction rates to enable the use of a high feed material throughput reactor to enhance overall project viability via hydrometallurgical processing. In this study the effects of hydrogen peroxide addition schedules on base metal leaching efficiency and solution temperatures were tested at laboratory scale. The results showed that overall peroxide consumption can be optimised to lower levels by matching peroxide additions to the particular feed material’s leaching behaviour. A simplified integrated model for peroxide decomposition is used to explain its effect on solution temperatures and leaching rates. Keywords: Peroxide consumption, waste electronic equipment, copper leaching, integrated model

Jan 1, 2020