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By Alexis M. Herman

It?s school vacation time again, and kid?s thoughts turn from textbooks and term papers to fun and play, includ­ing outdoor adventures. Old quarries can become swimming holes on hot summer days; sand and gravel piles look like interesting playgrounds; aban­doned mine shafts beckon explorers. But, for the unaware, all three mean danger. Already this year we have seen two stark reminders that mines and minors don?t mix. In Oklahoma, a 13-year-old girl drowned while swimming with friends in an inactive strip mine. In Maryland, a six-year-old boy playing on a quarry site, plunged more than 100 feet to the bottom of the quarry. Playing at such sites may seem like harmless fun, but every year dozens of children and adults are seriously hurt or fatally injured while playing on active and abandoned mine property. These accidents sometimes happen in traditional mining areas like the coal fields of Appalachia and the remote areas of the west. But the threat is anywhere there are active or abandoned quarries, sand and gravel pits, underground mines, or other mining operations.

Aug 1, 1999

By D. E. Hirsch

A systematic procedure for separation, characterization, and semiquantitative analysis of high-boiling petroleum distillates was developed by the Bureau of Mines and applied to a 370° to 535° C distillate of Wilmington, Calif., crude oil. Separation procedures employed were isothermal and molecular distillation, chemical treatment, silica-alumina adsorption, and gel permeation chromatography. Characterization and analysis were accomplished by gel permeation chromatography correlations and mass and nuclear magnetic resonance spectrometry. These data should be useful in improving petroleum processing and utilization and in achieving the energy conservation inherent therein.

Jan 1, 1974

By J. D. Marchant

As part of its mission to assure the maximum recovery and use of the Nation's mineral resources, the Bureau of Mines, investigated an improved procedure for producing rare earth-silicon alloys. For example, a charge consisting of 681 grams of mixed rare-earth oxides, 309 grams of ferrosilicon (75 wt-pct Si), and 182 grams of aluminum metal along with a flux consisting of 681 grams of CaO and 45 grams of MgO was reacted at 1,500° C in an induction furnace. Good slag-metal separation was achieved. The alloy product contained, in weight-percent, 53 RE, 28 Si, 11 Fe, and 4 Al with a rare earch recovery of 80 pct. In current industrial practice rare earth recoveries are usually about 60 pct in alloy products that contain approximately 30 wt-pct each of rare earths and silicon. Metallurgical evaluations showed the alloys prepared in this investigation to be as effective in controlling the detrimental effect of sulfur in steel and cast iron as the commercial rare earth-silicon-iron alloys presently used in the steel industry.

Jan 1, 1980

By John C. Edwards

A two-dimensional, time-dependent, mathematical model has been developed that describes fire spread along the walls of a ventilated duct. The model is based on the assumption that the leading edge of the fire zone propagating along the wall surface coincides with the isotherm for the fuel ignition temperature. The model includes gas-phase energy transport via radiation and forced convection inside the duct and solid-phase energy transport by conduction into the fuel lining. Product gases emitted from the fire zone are assumed to mix uniformly with the ventilation gas to produce an optically dense gas mixture at the combustion temperature that enters the preheat region. Numerical solutions of the model equations for a coal-lined duct (simulated coal mine entry) have been used to investigate the effects of tube radius, air velocity, combustion temperature, and optical density of the soot-laden gas upon the terminal fire spread rate.

Jan 1, 1977

By Robert F. Chaiken

A novel approach to eliminating environmental and public safety hazards that are associated with fires in abandoned coal mines and waste banks involves the use of in situ combustion technology developed by the Federal Bureau of Mines to accelerate the burning of the wasted coals in place. This technology would be used under exhaust ventilation control conditions that would allow for total management of the hot gases produced. Combustion stoichiometries would be optimized to minimize unburnt combustibles and to maximize the heat content of the gas products, which will be exhausted at one or more fan locations. When necessary, scrubber systems would be employed to remove air pollutants, such as sulfur dioxide; heat utilization systems (process heat, steam, and electricity) would also be employed to offset operational costs. Ultimately, complete burnout would solve the fire and acid water formation problems of the abandoned coal mine or waste bank. Pertinent technical data for burnout control are derived and discussed in terms of the important material and operational parameters. In general, it is believed feasible to operate a burnout system in an existing abandoned mine or waste bank fire at thermal power levels in the range of 10 to 100 Mw, and at exhaust gas temperatures of 1,000° C (1,830° F).

Jan 1, 1980

By M. L. Skow, Maurice Deul, M. G. Zabetakis

This Bureau of Mines report presents a brief summary of the explosion trends in United States coal mines for the past 160 years. These trends show that in spite of the overall improvements in mine safety, the number of fatalities from ignitions of methane has actually increased in recent years. Suggestions are made of procedures that can be utilized to reverse this trend.

Jan 1, 1972

By J. F. Barkley

During the present war emergency, under the urge of the Federal Government to store coal, the following questions are frequently asked by coal users: (a) Will the coal lose any, of its heating value in storage? (b) Will it slack and give a smaller-size coal? (c) Will its burning characteristics change in any way? (d) Will it catch fire from spontaneous combustion? (e) What precautions should be taken when coal is stored? DISCUSSION (a) Loss of Heating Value Studies by the Bureau of Mines show that the loss of heating value of coal in storage commonly has been overestimated. Various types of storage tests were made on New River, Pocahontas, Pittsburgh gas, and Sheridan (Wyo.) coals. The following is quoted from Bureau of Mines Bulletin 136, Deterioration in the Heating Value of Coal During Storage, by H. C. Porter and F. K. Ovitz (p. 8):

Jan 1, 1943

By H. H. Schrenk, L. B. Berger

"INTRODUCTION The Bureau of Mines frequently receives requests for information and advice regarding the equipment necessary for establishing laboratories for the analysis of mine atmospheres. Such requests are made by mining companies, State mining departments, and other agencies concerned with the safety of mining operations. In many instances it is desired to install a complete laboratory, which will necessitate purchase of suitable gas-analysis apparatus and all the minor but important accessory equipment needed to carry on this type of work. Although publications that describe methods and techniques applicable to the analysis of mine atmospheres are available, it is not within the scope of such publications to give detailed information on laboratory equipment or design. Persons unfamiliar with laboratory practices and gas-analysis procedures may find it difficult to decide upon the proper equipment for their particular needs and to itemize the various accessories that must be obtained to set up a complete laboratory.The purpose of this circular is to discuss the different types of equipment that may be used in the analysis of mine atmospheres, with particular regard to the application and limitations of each type. Information on the various accessory equipment needed in a laboratory for the analysis of mine atmospheres is given also, and suggestions on laboratory design are included. As much of the necessary equipment may be obtained from laboratory supply houses, the information should aid in arriving at estimates of the cost of proposed laboratories.The procedures involved in the analysis of mine atmospheres are not described; such information is contained in publications referred to in this circular."

Feb 1, 1948

By M. J. Ferrante

Low-temperature heat capacities and high-temperature enthalpies for syn¬thetic Cu2S and CuS were measured. This investigation is part of the Bureau of Mines goals to provide thermodynamic data essential to the more efficient processing of copper ores, and thereby minimize the current dislocations in energy, environment, and mineral supply. Heat capacities were measured with an adiabatic calorimeter from 5 to 310 K, and resulted in S°298 = 27.76 for Cu2S(c) and S°298 = 16.05 cal/deg mole for CuS(c). Low-temperature values are tabulated for Cp°, S°, -(G°-Ho°)/T, and H°-Ho°. Enthalpies were measured with a copper block calorimeter from 298.15 to 1,600 K for Cu2S(c,1) and 298.15 to 780 K for CuS(c). The thermal behavior of CuS showed no transitions or other significant anomalies for the low- or high-temperature investigations. Cu2S showed reversible transitions at 376 K with an isothermal heat absorption of 0.865 kcal/mole, 720 K with an isothermal absorption of 0.280 kcal/mole, and approximately 1,400 K (congruent melting point) with a heat of fusion of 3.070 kcal/mole. High-temperature data are tabulated for H°-H°298, Cp°, S°, and -(G°-H°298)/T. Enthalpies are also expressed in equation form. The low¬and high-temperature data were combined with data from the literature to cal¬culate and tabulate ?Hf°, ?Gf°, and log Kf as a function of temperature.

Jan 1, 1978

By Arcy P., D&apos Banister

Several gold-antimony geochemical anomalies were outlined near Stibnite, Idaho, using the humus sampling technique. Several hundred reconnaissance humus samples were collected and analyzed by a combination fire-assay atomic absorption method. The results partially outlined several gold-antimony anomalies and are very encouraging for further work in this part of Idaho.

Jan 1, 1970

By S. R. B. Cooke

Certain saturated and unsaturated fatty acids and a variety of resin acids were used as collectors for specular hematite, magnetite, and goethite. Vacuum flotation tests were used with each collector and mineral to delimit the fields of flotation and nonflotation as functions of concentrations of collector and of hydrogen ion. The experimental results of these tests lead to the following conclusions. The respective fatty and resin acids exhibit characteristic fields of flotation and nonflotation for the three iron oxides. The fields are somewhat similar, and specular hematite apparently is the most floatable mineral. The insolubility of some of the organic acids may seriously restrict flotation at low pH, although the saturated fatty acids, caprylic and capric, collect minus-100, plus-150-mesh specular hematite only in acid pulp. The presence of a lower "critical pH" is explained on the basis of the dissociation and hydrolysis of dilute soap solutions.

Jan 1, 1959

Develop a full-length-anchored roof bolt that is economical, nontoxic, nonflammable, and non-allergenic. Approach Grout roof bolts with a storable mixture of ultra-fast setting inorganic cement and water. How It Works A loose mixture of dry cement powder, and pinhead-size water droplets encased in waxy globules, are pack-aged in sausage shaped cartridges for storage and use. After the cartridge is inserted Into a drilled hole, the roof bolt is thrust In and rotated to mix the cement and water. The cement hardens in seconds, providing usuable anchoring strengths in minutes. Prior to filling of the sausage shaped cartridges, the microcapsules of water are Intimately mixed with the dry cement. The currently used grouting consists of a mixture of one part water (minimum) with three parts alpha-type gypsum cement and a minor amount of accelerator.

Jan 1, 1978

By Robert M. Becker

A thick-wall cylinder solution applicable to the evaluation of anisotropic elastic parameters is derived for the interpretation of stress relief data. For a restricted class of problems, a special relationship among certain orthotropic moduli yields stress distributions for the plane orthotropic problem that are identical to the corresponding isotropic case. A ring or hollow cylinder with these specialized anisotropic properties subjected to uniform radial loads is one of the problems in this class. Consequently, known stress solutions are used to develop the strains and displacements for a specialized orthotropic thick-wall cylinder under uniform pressures. The results are consistent with anisotropic equations used in the evaluation of in situ rock stresses.

Jan 1, 1968

By R. E. Mussler

Electrowinning of copper from chloride solutions in a diaphragm cell was studied by the Bureau of Mines. The copper powder product was shaken periodically from the cathode and removed from the bottom of the cell. The effects of copper concentration, brine concentration, copper chloride species, and cell voltage were investigated. Power consumption of 1.1 and 2.1 kW-hr/kg were obtained with cuprous and cupric chloride solutions, respectively.

Jan 1, 1975

By Wilbur I. Duvall

This report presents experimental data on the propagation of explosion- generated strain pulses in rock. Tests were performed in 5 different rock types, employing 10 different types of explosives. Charge sizes ranged from 0.5 to 50 pounds, and travel distances ranged from 2.5 to 70 feet. Analysis of the data shows that the experimental peak strain data satisfy an exponential decay propagation law of the form: ?R/W1/3 = Ke ?aR/W1/3. For a particular rock, parameter K is a linear function of the calculated detonation pressure or the calculated energy density of the explosive. For a particular explosive, K is a linear function of the elastic parameter of the rock, p2, a result, which is at variance with elastic theory. The absorption constant, a, is independent of type of explosive but dependent upon rock type. However, no definite relation between a and the physical properties of the rock could be established.

Jan 1, 1959

By Theodore Christos

The Bureau of Mines sponsored an investigation of the thermal oxidative degradation characteristics of certain solvents and hydraulic fluids used in underground mining operations. The following halogenated solvents were studied in view of their usefulness and their flame retardant property: tetrachloroethylene, C12C = CC12; 1, 1, 2-trichloroethane, CIH2CCHC12: and trichloroethylene, C12C = CHC1. The hydraulic fluids studied were representative of five groups approved by the Mine Safety and Health Administration for underground operation, namely: glycol-water solutions, mineral oil-water emulsions, synthetics other than phosphate esters, synthetic phosphate esters, and mixtures of phosphate esters with mineral oils and other ingredients. It was observed that the partially halogenated solvents present a greater potential toxic hazard than the fully halogenated materials, due not only to the easy production of hydrogen chloride but also to their ease of oxidation leading to the formation of phosgene and carbon monoxide. The pure phosphate esters exhibited the best thermal oxidative stability of the five groups of hydraulic fluids tested. A fluid containing phosphate esters mixed with mineral oils and other unidentified ingredients appeared to be the most hazardous On the basis that it produced very toxic acrolein and phosphine.

Jan 1, 1980

By R. D. Leitch

Beside many other damaging effects of acid mine drainage, corrosion of pipe lines and pumps frequently adds much to mine operating costs. Not only is it often necessary to install special and relatively costly acid-resistant materials, but even these may require frequent replacements. It is not unusual for ordinary steel pipe to last only a few days in some highly acid waters, while other common materials, though more resistant, frequently last only a few weeks. In the spring of 1935, local PWA authorities offered to assign a number of persons to various problems under the direction of regular employees of the Bureau of Mines. It was believed that at least some simple tests on as many different kinds of acid-resistant pipes as could readily be obtained might produce interesting and valuable information for the mining industry. This paper describes the tests and some results that have since been noted.

Jan 1, 1938

By Yael Miron

Ammonium nitrate-fuel oil (AN-FO) mixtures are used as blasting agents in mining pyrite-bearing ores. The temperature of these ores can increase by the continuous, though at times slow, oxidation weathering of the pyrites. At elevated temperatures, AN-FO reacts exothermally with pyrite, and the reaction becomes self-sustained at 120° C ± 10° C. The Bureau of Mines has conducted an investigation to determine the reactivity of mixtures of AN-FO with pyrite containing ferrous sulfate. The results of tests in a heated vessel simulating a hot borehole demonstrate that small amounts of ferrous sulfate, a major product of pyrite weathering, initiate a self-sustained exothermic reaction with AN-FO at 80° C. Five pct by weight of urea was found sufficient to prevent a reaction among the three ingredients, at least within the limits of the test, which reached 180° C. Smaller amounts of urea and of potassium oxalate slowed down the reaction and delayed its onset to higher temperatures, but did not prevent it.

Jan 1, 1979

By Mark S. Sanders

The purpose of this work was to develop and field test improved knee protection for underground coal miners working in low seam mines. In a previous phase of this contract (Sanders, 1982), experimental knee pads were developed and field tested. The field test revealed several design deficiencies with the knee pads, and suggestions for improving the design were made. The work summarized in this report, therefore, consists of modifying the design and method of fabrication of the knee pads originally describes by Sanders (1982), and of field testing the improved design. The new prototype was shorter and wider than the original design, and used a neoprene pass-through strap design rather than a cloth strap molded into the pad itself. The new prototype was constructed by slush molding a hollow bladder that was then filled with foam. Initial reactions to the pads in the field test were very positive. However, after two months, the opinions about the new prototype became less positive. They were judged, generally, to be no better or worse than the pads usually worn by the field-test participants. Problems were encountered in the field with respect to durability. Water seeped into the inner cavity of many of the pads and caused the foam to deteriorate. It was concluded that it would not be cost-effective or feasible to significantly improve upon current commercially available knee pad designs.

Jan 1, 1986

By Kenneth H. Johnston

Information on oil and water production, volume of water injected, core analyses, and well completion data was collected on 28 Red Fork sand water-flood projects for comparison and evaluation of results. An average water injection efficiency of 35 percent, an average water-injected to oil-produced ratio of 16.8:1, and an average loss outside the flood pattern of approximately 45 percent of the injected fluid resulted in an oil recovery to January 1, 1969, of only 5.6 percent of the pore volume, or 9.1 percent of the initial stock-tank oil in place. The principal causes of poor oil recovery from these projects are the losses of large quantities of injection water from the flood patterns through oriented, natural fracture systems or zones of high permeability and excessive channeling of injection fluids from input wells to oil wells. For more efficient operation and a higher percentage of oil recovery from the Red Fork sand and other low-permeability-sand waterflood projects, directional orientation of both induced-and natural-fracture systems should be determined during early development. The success of a low-permeability-sand waterflood project depends to a large extent upon the orientation of the injection wells with the fracture system.

Jan 1, 1970