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By R. Karl Zipf, Z. T. Bieniawski

"Fracture mechanics plays an important role in studies of geologic materials such as rock and coal. Yet fracture data are scarce for rock and most limited or unreliable for coal. A testing system was developed which can apply mixed mode loads to a crack tip in many rocks and geologic materials. It is possible to subject the test specimen to pure mode I, various mixed modes and a nearly pure mode II fracture load. The system is currently used to study the mechanics of fine fragment formation in various coals. Experimental measurements include KI and KII' fracture velocity and acoustic emission.INTRODUCTIONA major research program at The Pennsylvania State University is directed to understanding the fundamental mechanics of fine fragment formation in various coals. The program represents an effort to reduce the incidence of coal workers pneumoconiosis (black lung) in coal miners. The principal source of the respirable coal fragments is the cutting operation which forms and liberates the particles by a fracture process. Present understanding of the mechanics of the events which form and liberate these particles is meager (Cook, 1982).Current knowledge of the fundamental mechanisms of coal dust generation and entrainment in terms of the underlying fracture mechanics is critically needed to improve and possibly control the processes involved. Whether the cutting operation is done with a 'continuous miner' cutting machine, a plow or a longwall shearer, it is fundamentally a problem of mixed-mode crack propagation. When a cutting tool interacts with coal, it causes numerous cracks to propagate through the intact material. Numerous larger fragments are broken free, but another quantity of undesirable fine fragments is also created. The formation of these respirable fragments may be a direct result of the crack propagation process; hence, a thorough understanding of the fracture mechanics of coal is required to minimize production of the unwanted fine fragments.In most rock engineering applications, the rock material properties are of secondary importance to the rock mass properties; however, for rock fragmentation and rock cutting problems, it is rock material properties such as fracture toughness which are of prime interest (Bieniawski, 1980). Several rock cutting and rock failure theories have been proposed, but it is only very recently that fracture mechanics concepts have been successfully applied to the study of rock cutting mechanics. All cutting models seek to predict the cutting forces and the cutter geometry necessary to cause rock breakage and chip formation given some fundamental mechanical properties ~f the rock. Such models have wide applications in drilling, tunnel boring and mining problems. Nelson et al., (1985, 1986) has provided a very useful correlation between the laboratory measured fracture mechanics properties of rock and the performance of the disk cutters on tunnel boring machines."

Jan 1, 1989

By Richard J. Mainiero

Traditional techniques for the experimental determination of toxic fumes produced by the detonation of high explosives are not applicable to blasting agents. To detonate properly, blasting agents require confinement, a significant booster, charge diameters of 3 inches (7.5 cm) or greater, and charge lengths greater than two-times the charge diameter. Without these conditions, blasting agents will not detonate at full order, leading to a misrepresentation of the gaseous products. A facility for detonating large, confined charges in a controlled volume has been constructed at the Pittsburgh Research Center’s Experimental Mine. The facility consists of a portion of mine entry (once used for full-scale mine explosion research and demonstrations) enclosed between two explosion proof bulkheads. Total volume of the chamber is 9,666 ft (274 m). The chamber is equipped with an air circulating system and is3 3vented using the mine's airflow. Up to 10-pound (4.5-kg) charges can be detonated in the chamber using a variety of confinements. For a typical test, the blasting agent is confined in a 4-inch (10-cm) schedule 80 steel pipe and initiated by a 3-inch (7.5-cm) diameter, 1-inch (2.5-cm) thick Pentolite booster. This combination of confinement and initiation yields a detonation velocity of about 4,000 m/sec for ANFO. This velocity is in line with that measured for blasting in the field. Twenty four 2-inch thick steel plates are suspended around the pipe bomb to stop shrapnel that would otherwise seriously damage the chamber. Following detonation of an explosive in the chamber, a circulating fan is run for about 10 minutes to uniformly mix the chamber atmosphere. Fumes samples are taken out of the chamber through 1/4-inch (0.6-cm) Teflon or polyethylene2tubes for analysis. The fumes are analyzed using bubblers or Vacutainers to collect samples for analysis by the analytical chemistry lab. The technique described here has been employed to determine the fumes produced by the detonation of a variety of ANFO formulations and commercial explosives. This technique may be developed as a standard test to measure fumes produced by blasting agents or may be used to provide data with which to develop a computer model that will reliably predict the expected fumes production based on chemical composition.

By John D. Bardill

This report covers magnetic surveys in the Dannemora arca , which was part of a general survey of magnetite deposits in New York started in 1943 . The objective of these surveys was to afford a basis for the selection of exploration projects .

Jan 1, 1947

By O. C. Ralston

The Bureau of Mines has under development on a technical scale an electrolytic process for treating oxidized ores of zinc , using caustic soda as an electrolyte . Whereas the Bureau process can alternately make either solid zinc or zinc dust , the following paper , from the Ludwigshafen research laboratory of the well -known I. G. Farbenindustrie , A. G. , of Germany, deals only with production of zinc dust from sodium zincate solutions and may well serve as introduction to the subject for American metallurgists . The Bureau of Mines pioneered in the idea ; a study on laboratory scale by H. J. Morgan and 0. C. Ralston was made early in the First World War, and published in Transactions of the American Electrochemical Society . The Eckardt paper , translation of which follows , goes more thoroughly into the preparation of electrolytic zinc dust , and later publications of the Bureau of Mines will deal with broader details and application of the idea to treatment of lowgrade ores and metallurgical intermediates , which is the point where Eckardt left off . 4 The Eckardt report became available through operations of Field Information Agency , Technical ( FIAT ) of the Office of Military Government for Germany (US ) , which made bibliofilm copies of the files of internal technical reports of many of the German industrial establishments , Eckardt's report is dated April 1939 and was taken on FIAT Microfilm Reel MM 106 , frames 82-101 , which is on file as Publication Board Document 41411 in Office of Technical Services of the U. S. Department of Commerce , Washington , D, C , Eckardt points out that the normal source of zinc dust is the blue powder of the zinc retorts , which decreases in volume every year owing to technologic improvements in zinc smelting. I. G. saw the importance of making a

May 1, 1948

By Aner W. Erickson

Magnetite iron deposits on Tolstoi Mountain were examined as part of the investigations by the Bureau of Mines of iron and copper ores on Prince of Wales Island. The Tolstoi Mountain project was a part of a program for investigating mineral deposits in Alaska, under the general supervision of R. S. Sanford, acting branch chief.

Jan 1, 1948

By Constantine C. Popoff

During 1946 several limestone deposits near Fortson, Snohomish County, Wash., were examined by the Bureau of Mines. These examinations were part of a long-range investigative program of regional mineral supplies required by the anticipated industrial development of the Pacific Northwest. The .study outlined in the following paper was specifically undertaken to disclose new sources of high-purity limestone and to appraise, their economic aspects. The deposits examined -namely the Galbraith, Climax, and Hi, Hi -are somewhat similar in physical features and geologic environment. They are lenticular and belong to the same formation of metamorphosed sediments that underlies the prominent Whitehorse Ridge.

Jan 1, 1949

By H. C. Ko

Calorimetric determinations of low-temperature heat capacities and the standard enthalpy of formation were made by the Bureau of Mines for aluminum sulfide, A12S3. The standard entropy (S°), enthalpy of formation (?Hf°), and calculated Gibbs energy of formation (?Gf°) at 298.15 K are 27.93±0.05 call deg-mole, -155.6±0.9 kcal/mole, and -153.0±1.0 kcal/mole, respectively.

Jan 1, 1976

By W. N. Cathey

Many materials including carbides, silicides, phosphides, borides, nitrides, oxides, and metals were studied by the Bureau of Mines as potential fuel cell catalysts for electroreduction of oxygen in a 1[N]H2S04 electrolyte. The objective of this study was to assess the potential of abundant, low-cost materials as substitutes for platinum or to increase the catalytic efficiency of platinum. Several compounds were rejected because of their reaction in the corrosive environment of the oxygen electrode. However, some of the remaining were the most active catalysts. Activity of carbides such as tungsten carbide could be improved by doping with platinum-group metals, by varying stoichiometry, or by sputtering on a layer of platinum. While no catalysts were found with activity as high as platinum, some compounds were shown to be deserving of further investigation.

Jan 1, 1979

By S. L. May

Investigations by the Federal Bureau of Mines indicate that hafnium and zirconium compounds of acceptable purity can be extracted from Nigerian zircon concentrates. Chlorination and caustic soda fusion techniques were used to extract 85 to 95 percent of the valuable metals from the concentrate. The extracted hafnium and zirconium compounds were purified by recrystallization of the oxychlorides or by formation of complex salts during chlorination. The zirconium-hafnium product of the recrystallization method contained 15 parts per million of uranium, and the product of the salt-complex method contained less than 10 parts per million of uranium. The hafnium was separated from zirconium by solvent extraction methods. A zirconium product containing 0.3 percent hafnium and a hafnium product containing 4 percent zirconium were obtained. At the request of the Atomic Energy Commission (AEC), work was started to develop techniques for processing Nigerian zircon concentrates in commercial installations presently engaged in producing zirconium and hafnium metals from ores. The Nigerian zircon has a high hafnium content, but the presence of uranium and thorium is a problem not normally encountered in processing zircon concentrates.

Jan 1, 1961

By Robert F. Droullard

The Bureau of Mines has investigated techniques of using gross alpha or beta detectors to continuously measure working levels. Both methods measure radioactive particulates collected on a filter paper using a constant airflow. Inherent-error studies indicate a value of about ±3 percent for the gross alpha method and about ±8 percent for the beta method in typical mine atmospheres. However, the beta method avoids problems associated with alpha detectors and is therefore more useful. Applications of these continuous working-level detectors include work area monitoring of exposure levels in underground openings, such as mines and caves, and calibrating personal dosimeters exposed over extended time intervals.

Jan 1, 1977

By S. C. Termes

The Bureau of Mines conducted research on the flocculation of various minerals with insoluble cross-linked starch xanthate (ISX) to determine its potential as a beneficiation technique for low-grade, highly dissem-inated ores and for selective desliming. Covellite, chalcocite, pyrite, pyrrhotite, chalcopyrite, bornite, sphalerite, galena, and molybdenite fines flocculate with ISX. Floc formation, floc size, and settling rate are dependent on pH, with the pH dependence differing for each mineral. Quartz is not flocculated by ISX. Experiments to obtain selective flocculation of sulfides from quartz were attempted. Good selectivity was only obtained for the bornite-quartz system. postflocculation separations resulted in flocculated bornite in grades as high as 92 pet. Evidence is presented that the flocculation of many of the sulfide minerals with ISX may involve covalent bonding of the xanthate group to lattice metal site(s).

Jan 1, 1983

By L. C. IlsLey

A list of permissible mine equipment, tested and approved prior to Jan 1, 1937, was published in Bureau of Mines Information Circular 6942 • .ll The present list inc ludes additional equipment approved during the calendar yea r 1937. The ma terial has been listed und er the same. headings as th ose used. in Information Circular 6942. The number that appears at the beginning of each it em represents the number o f this type of ma.chine appr.oved including the machine in questi on; for instance, the miing ma.chine numbered 70 was the seventiet h co al cutting ma chine design for which approval has been isnued. All of the equipment listed represents new designs except that covered by the first item, that is, 57 under the • heading nLoading Machines and Conveyors. 11 This item covers the approval of the 500-volt design of a machine the 250-v olt design of which was approved on January 17, 1935. The system under wich these devices were tested permits the manu-. facturer., after his equipment has passed certain tests prescribed by the 'Ui"eau of Mines, to mark his equipment with a seal showing that it has been approved by the Bureau. These tests are designed to insure t hat equipments hav,e the minimum requirements for safety in use. The only object of the :Bureau in making such tests and publishing lists of permissible equipment is to help decrease the hazards of mining.

Apr 1, 1938

By C. H. Elder

An experimental degasification program using a vertical borehole and vacuum pump to drain gas from the gob area of a longwall panel was successful at Bethlehem Mines Corporation, Cambria Division, No. 33 coal mine. Sixty-one million cubic feet of methane has been exhausted during a 9-month period. Daily production time in the panel increased as a result of lower methane levels in the returns. Removal of large quantities of methane in this way and the exclusion of it from the ventilating system will provide reduced cost in mine ventilation and provide a safer environment for the mine.

May 1, 1969

The Bureau of Mines has successfully used sulfur hexafluoride (SF6) as a tracer gas to measure mine air flows under conditions where conventional methods have failed. SF6 was employed experimentally to measure accurately recirculation of return into intake air caused by leakage through an old stoped area, to check for potential leakage from an adjacent mine, to trace 10,000 cfm of "lost" air from an intake airway, and to measure transit air time through uranium mines. It proved useful as a means of accurately measuring airflow volumes in airways of large cross section and very low flow velocity, and in determining the recirculation resulting from underground cooling plants.

Jan 1, 1974

By L. C. IlsLey, R. A. Kearns

"The electrical section of the Bureau of Mines has obtained copies of all available State safety rules and regulations in order to make a study of those portions of the codes relating to electrical equipment. While it has been found almost impossible to compare the several codes as a whole, comparison of those regulations dealing with a single subject has proved both interesting and instructive.Sixteen states have rules or enactments having reference to telephones and the present paper covers a compilation of these references. It is believed that data of this kind will be of service to commissions or other bodies contemplating the revision of existing codes.The compilation taken from the various codes follows: State Rules and Regulations.California.Sec. 5 (Par. c) Telephone communication shall be maintained between a co-operative station and each mine which it supplies. If the foreman in charge of a station does not reside thereat, his residence also shall be in telephone communication with each mine supplied by his station.Sec. 8 (Par. a) Whenever a fatal accident occurs in or about any mine, notice thereof shall be given promptly by telephone or telegraph if possible, followed by a notice in writing to the chief inspector, by the superintendent or other person having immediate charge of the work at the time of the accident."

Jun 1, 1921

By E. J. Gleim

To make a thorough survey of a coal mine in order to eliminate hazards, the competent safety engineer must be familiar with mere than one branch of engineering. It is essential that he know the properties of mine gases and the methods of detecting them, as well as hew to prevent dangerous as accumulations. It is also essential that he understand the action of overlying strata when the coal is removed, and the proper methods of protection by timbering or other suitable means of support. He must know the value of protective clothing in reducing injuries and mast be informed as to the correct handling and use of explosives to avoid premature blasts, misfires, and ether failures in blasting practice. He must understand hew to operate locomotives and cutting, loading, and various other types of machines to be able to recommend effective safeguards for protecting the men who use them in addition to being informed as 'to these and many ether activities connected with the mining of coal, he must net overlook electrical engineering if he wishes to combat the fire, shook, and ignition hazards attendant upon the use of electrical machinery and circuits in and around the mine intelligently. There are many points relating to safely in the selection, maintenance, and use of electrical circuits and equipment that are perfectly obvious to the electrical engineer but perhaps are not se evident to those not trained in this particular branch of engineering. Engineers of the U.S. Bureau of Mines who have made a special laboratory study of electricity as related to safety in minus haw e also made inspections of electrical installations at a large number of bituminous mines. These inspections have revealed practices and conditions that not only do not contribute to safety but that add nothing to efficiency and economy in the operation of the mine.

Jan 1, 1936

By George W. Healy

The direct retorting of zinc sulfide concentrates in the presence of lime and carbon was examined on a laboratory scale with ten-gram charges of loose mix or fifteen-gram ones of pellets. A slow stream of nitrogen swept through the furnace tube over the boat of reactants, carrying with it the zinc vapor, which condensed on a rolled-up steel sheet near the exit, permitting weight of zinc produced to be obtained after completion of a run. Variables explored were percent of theoretical reagents, temperature, and time. During the runs gas samples were analysed periodically, and the content of CO2, CO and nitrogen were obtained. The quantities of the carbon gases could be calculated because the nitogen flow rate was measured. The gases were also examined for sulfur species, but neither COS nor SO2 could be detected at maximum sensitivity. Zinc recovery increased with excess carbon and lime and with temperature. It ranged from 77% at a ten percent deficiency to 90% at a ten percent excess at 1100°C. Going to 1200°C and theoretical reagents gave 93% recovery. Increasing time from 200 minutes to 300 minutes increased zinc yield by up to 10%. Results from sphalerite and a commercial concentrate from AMAX gave generally similar results. The reaction rate of zinc sulfide as sphalerite and of calcined sphalerite indicated that the latter reacted almost twice as fast, and recovery of zinc was five percent higher. Though the retorting step using sulfide, lime, and carbon proved to be non-polluting, it was feared that on storage the calcium sulfide in the residues would decompose, giving off noxious gases. Consequently the stabilization of the residues by oxidation was essayed. Because of the presence of unreacted zinc sulfide, the first product of oxidation was S02. Reaction of CaS to CaSO4 was incomplete, going from 20% at 800°C to 90% at 1200°C. Thus the non-polluting nature of the process as a whole is in doubt, and its economics are likely to be unfavorable compared to the traditional way of calcining the concentrates, followed by retorting of the oxide with carbon.

Jan 1, 1982

By Charles E. Munroe

At the outset of the war the uncontrolled production and possession of explosives obviously became a serious menace to the safety of persons and property and the successful conduct of military opera- tions. Even in the years immediately preceding the entrance of the United States into the Great War explosives were employed in attempts to wreck munitions plants as at Eddystone, Pa., or to inter- rupt transportation and conveyance by demolition of munition-laden cars as at Black Tom Island, N. Y., or by attacks on ships, bridges, and viaducts. Outrages with explosives, such as that which Holt inflicted on the Senate reception room, United States Capitol, were not infrequent, and often caused serious loss of life and injury to persons as well as destruction of property. The regular manufacturers of explosives were keenly alive to this menace and early took such steps as lay within their power to meet it as is shown by the following letter:

Jan 1, 1921

By Fred Kissell

The Bureau of Mines has developed the shearer-clearer--a new type of dust control system for longwall shearers. The system partitions the airflow around the shearer into a clean split and a contaminated split. The dust cloud is confined to the vicinity of the coal face, while the shearer operators remain in the clean split on the gob side of the machine. The shearer-clearer operates on the principle that each water spray moves air like a small fan and can be positioned to direct the dusty air towards the face. The hardware is inexpensive and can be installed in a single shift. It consists of several strategically mounted water sprays and one or more passive barriers. Laboratory testing indicates reductions 1n shearer operator dust exposure as high as 97 pct. Preliminary results from an underground demonstration in one mine also indicate that considerable dust reductions at the shearer may be obtained. In conjunction with the development of the shearer-clearer, dust surveys were conducted in three other mines to determine if some shearer spray systems currently in use partition the flow in a manner similar to the shearer-clearer, and if so, whether this partially accounts for markedly cleaner conditions on some longwalls. Results from these surveys indicate this to be the case. A feature of the cleaner longwalls was a downwind orientation of their water sprays, which is a key element of the shearer-clearer system. The shearer-clearer system described in this report was designed for an Eickhoff EDW 300 shearer working a 7-foot coal seam. The testing to date has concentrated on cutting directions counter to the primary airflow. The development effort continues for different mining equipment and conditions. It is expected that different systems will be required to accommodate the range of conditions occurring underground. Application of the system presented here to conditions different than those described is not likely to produce the same results.

Jan 1, 1981

By J. J. Drost

The feasibility of basic oxygen furnace (BOF) offgas heat recuperation by preheating scrap was investigated on a pilot plant scale by the Bureau of Mines. In this study, offgases generated during the oxygen blowing of a molten pig iron and scrap charge were passed through a static bed of shredded auto scrap. Scrap quantities varying from 100 to 180 pounds and representing from 22 to 40 percent of the 450-pound BOF metallic charge were preheated in this manner. Average scrap bed temperatures of 1,650° F for 100 pounds of scrap and 1,150° F for 180 pounds of scrap have been achieved during the blows. As compared to cold scrap used in the normal BOF practice, it was found that by preheating scrap, usage could be increased by 43 percent. The thermal energy recovered by this preheating method can account for up to 44 percent of the energy necessary to melt the scrap.

Jan 1, 1974