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By W. L. Eaton

This report is the second in a series concerning the Bureau of Mines program for microfilming maps of abandoned mines in the Pennsylvania anthracite region; a catalog of the microfilmed maps of mines in the Wyoming Basin of the Northern anthracite field is presented. The first report I.C. 8274, published in 1965, was a catalog of microfilmed maps of mines in the Eastern Middle anthracite field. Additional catalogs will be published as the microfilming of significant mining areas is completed.

Jan 1, 1968

By C. B. Kenahan

A summary of Bureau of Mines research on recycling, reuse, and disposal of mineral-, metal-, and energy-based wastes is presented, accompanied by an extensive bibliography of related publications. The Bureau's waste recycling and disposal program is directed toward the following four main areas of research and development: (1) extraction of mineral, metal, and energy values from urban refuse; (2) upgrading and recycling of automotive and related ferrous and nonferrous scrap; (3) recovery, utilization, and stabilization of mine and mill processing wastes, and (4) recovery and reuse of values from industrial waste products. This publication updates Bureau of Mines Information Circular 8529, which was issued August 1971.

Jan 1, 1973

By John A. Breslin

Size distributions and concentrations of particulates emitted from diesel engine exhausts were measured with cascade impactors. Samples were taken from the exhaust of two types of engines using three types of fuel and operating under five different engine speed and load conditions. The measured mass median diameters of the diesel particulates were typically about 0.3 um. There was no significant difference in mass median diameter between engines or fuels and only a slight dependence on operating mode. Concentration measurements ranged from 14.2 to 250.9 mg/cu m, and calculated mass outputs, from 52 to 3,443 mg/min. Significant differences in mass output were found between engines, fuels, and especially between different operating modes. The quantity of clean dilution air that would be required to reduce the particulate mass concentration below the 2.0 mg/cu m respirable dust standard for coal mines was greater than the dilution air required to meet the standards for noxious gases for both engines tested.

Jan 1, 1976

By John P. Coughlin

Software techniques developed by the Bureau of Mines Denver Research Center for real-time microseismic data analysis are presented. These techniques focus on the simple acquisition of P-wave arrival times and their use in event location. The paper discusses in detail software techniques to separate microseismic events from mining noise such as drilling and from very large events such as rock bursts. Incorporation of these techniques has enhanced the reliability and accuracy of computer-based monitoring of microseismic activity in ongoing research by the Bureau.

Jan 1, 1982

By F. Fraas, H. H. Storch

"In the second paper 4 of this series, data were presented concerning the decomposi¬tion of polyhalite by saturated salt solutions. It was found that uncalcined polyhalite upon leaching with boiling saturated sodium chloride solutions yielded a brine in which the (K2 Mg) /304 ratio was considerably higher than that obtained from the calcined material, and for this reason appeared more suitable for the production of potassium chloride. It was found, in fact, that the leach liquors from uncalcined polyhalite deposited a mixture of KC1 and NaC1 upon evaporation and subsequent cooling, whereas those from calcined polyhalite yielded mixtures which contained not only potassium and sodium chlorides but also large quantities of glaserite, K3Na (S04)2. Hence it was decided to study the evaporation of the uncalcined poly—halite leach liquor and postpone experiments on the calcined polyhalite liquors until such time as a process for further removal of sulphate was developed.A considerable body of equilibrium data is available in the literature on thesystem K+ Mg++ — Na+ Cl—S04 =,— H20 for temperatures up to 83º C. Owing, however, tothe lack of data other than that corresponding to the invariant points and the complete absence of data for temperatures of 100 to 115°C., and owing to the fact that supersaturation phenomena render unsafe the prediction of the behavior of such a system upon evaporation, it was considered essential to obtain the necessary data by actual evaporation and analysis of the brines thus obtained."

Feb 1, 1931

By Terry S. Cory

This report covers magnetic field strength measurements vs range and frequency in low-medium coal mines. Both quasi-conductor-free and conductor-proximity areas were investigated. The program covered 5 mines, 4 seams, 6 measurement sets, and 3 geographic areas. The results have been summarized in terms of maximum communication range expected per seam and noise condition. Scatter gain is further explored as a simple measure of energy coupled to conductors.

Jan 6, 1978

By G. W. Birge

Carbonizing properties of the principal coal beds of Butler County, Pa., are described in this report by the Bureau of Mines. Eight samples, representing the Upper Freeport, Lower Freeport, Upper Kittanning, Middle Kittanning, Lower Kittanning, Clarion, and Brookville beds, were carbonized at 900° C. by the Bureau of Mines-American Gas Association (BM-AGA) method. Butler County coals rank as high-volatile A bituminous and are generally characterized by high sulfur content compared with Appalachian coals used for industrial coking. If cleaned, the Brookville and one sample of Upper Freeport coal would be acceptable as the major component of metallurgical coking blends. The other Butler County coals tested would be unsuitable for this purpose because of either excessive sulfur or poor coking properties.

Jan 1, 1962

By S. C. Termes, P. E. Richardson, R. L. Wilfong

"The Bureau of Mines conducted research on the flocculation of various minerals with insoluble cross-linked starch xanthate (ISX) to determine its potential as a beneficiation technique for low-grade, highly disseminated ores and for selective desliming. Covellite, chalcocite, pyrite, pyrrhotite, chalcopyrite, bornite, sphalerite, galena, and molybdenite fines flocculate with ISX. Floc formation, floc size, and settling rate are dependent on pH, with the pH dependence differing for each mineral. Quartz is not flocculated by ISX. Experiments to obtain selective flocculation of sulfides from quartz were attempted. Good selectivity was only obtained for the bornite-quartz system. Post flocculation separations resulted in flocculated bornite in grades as high as 92 pct. Evidence is presented that the flocculation of many of the sulfide minerals with ISX may involve covalent bonding of the xanthate group to lattice metal site(s). INTRODUCTIONBecause of the increasing interest in selective flocculation as a beneficiation technique for low-grade, highly disseminated ores and for selective desliming, the Bureau of Mines has been investigating the flocculation behavior of several cross-linked starch derivatives containing chelating groups. This report dis cusses the flocculation of sulfide mineral fines by insoluble cross-linked starch xanthate (ISX).Polymeric materials such as ISX, which contain a chelating group of known re¬activity towards specific mineral surfaces, were first proposed by Slater, Clark, and Kitchener (1), 3 Kitchener (2), and Attia and Kitchener (3) as selective flocculants for mineral fines with particle aggregation possible through a bridging mechanism. ISX appeared to be attractive as a sulfide mineral flocculant because (1) alkyl xanthates are known to react selectively with sulfide minerals"

Jan 1, 1983

By Ralph Husack, J. W. Eckerd, G. A. Brady

The effect of gamma radiation on Pennsylvania anthracite and on reactions between anthracite and other materials was studied using a shielded , selfcontained 23,000 - curie cobalt 60 source . When anthracite was exposed to air at 65° C the reaction with oxygen was greater in the presence of radiation. than in its absence . Although drop- shatter tests indicated that exposure to radiation decreased the resistance to breakage of anthracite , this evidence of structural weakening was not supported by the results of grindability or particle- size studies . Irradiation caused definite changes in the gases evolved from evacuated samples of anthracite ; the percentages of hydrogen and carbon dioxide were increased, and the methane concentration remained unchanged . Carbon monoxide was evolved only from the unirradiated samples . Electron paramagnetic resonance (EPR ) measurements indicated large differences between evacuated samples and those exposed to air . There was little or no difference between irradiated and unirradiated samples , except that the free- radical content of unirradiated samples of anthracite increased progressively with higher temperatures of evacuation , but in the case of irradiated samples , no such behavior was found . Attempts to produce carbon disulfide and calcium carbide by reacting anthracite with sulfur up to 120 ° C , and with calcium oxide up to 400 ° C , were unsuccessful .

Jan 1, 1964

By G. V. Sullivan

This report summarizes the results of a preliminary study concerning manganese extraction from low-grade dolomitic materials from the Philipsburg district in Montana by the Dean-Leute ammonium carbamate process. Studies were made to determine the relationship between the variables involved in treating these materials by a roast-leach process and the amount of manganese extracted. The variables studied were the roast temperature, the roast particle size, the molar ratio of NH3 to CO2 in the leach solution, the liquid-solid ratio in leaching, the leach time, and the size of the particles being leached. The roast-leach studies were statistically designed, and the experimental results were evaluated by an analysis of variance.

Jan 1, 1962

By Kenneth L. Cashdollar

The Mine Safety and Health Administration (MSHA) and the West Virginia Office of Miners? Health, Safety, and Training (WVOMHS&T) investigated the explosion at the Sago Mine in West Virginia, which occurred on January 2, 2006, and resulted in 12 fatalities. As part of the investigation, the agencies requested that the National Institute for Occupational Safety and Health?s (NIOSH) Pittsburgh Research Laboratory evaluate the effects of explosions on specific mine ventilation seals and other structures and objects at its Lake Lynn Experimental Mine (LLEM). The results of the LLEM study would assist MSHA and WVOMHS&T in a more thorough understanding of the various questions that arose during their investigations of the explosion. Six large-scale explosion tests were conducted in the LLEM from April to October 2006. The protocols for these tests, and in particular the procedures for constructing various Omega block seals, were developed mainly by MSHA and WVOMHS&T. NIOSH developed the experimental procedures at the LLEM that would provide the required range of explosion pressures against the seals. Three 40-in-thick seal designs using Omega 384 low-density block were constructed in the LLEM and exposed to various explosion pressures. These seal designs are referred to in this report as the ?2001 design,? the ?hybrid design,? and the ?Sago design.? The 2001-design Omega block seal (80 in high) located in crosscut 2 of the LLEM survived all six explosions, with pressure loadings up to 51 psi. The 2001-design Omega block seal (88 in high) in C-drift was destroyed during Test 2, which subjected the seal to a head-on explosion that resulted in a pressure loading of 51 psi. The height difference between the two seals and the orientation of each seal to the explosion were contributing factors. The higher seal would be weaker for the same seal thickness. The hybrid Omega block seal in crosscut 3 survived an explosion at a pressure loading of 25 psi and failed during another explosion at a pressure loading of 39 psi at the seal. Based on these tests, it seems that the hybrid seal design is weaker than the 2001 seal design. The Sago Omega block seals were constructed in crosscut 3 and C-drift before Test 3. The crosscut 3 seal survived a pressure loading of 18 psi and was destroyed during an explosion at a pressure loading of 35 psi at the seal. The C-drift seal survived a head-on explosion that resulted in a pressure loading of 21 psi and was destroyed during an explosion with a pressure loading of 57 psi at the seal. Based on these LLEM tests, it seems that the Sago seal design is weaker than the 2001 seal design, yet it still complied with the requirements of 30 CFR 75.335(a)(2) that were in effect at the time of the mine disaster. During these LLEM explosion tests, the distance of seal debris travel was also measured. In Test 5, the C-drift seal was destroyed during a head-on explosion that resulted in a pressure loading of 57 psi, and the seal debris was thrown over 500 ft. In Test 6, the C-drift seal was destroyed during a head-on explosion that resulted in a pressure loading of 93 psi, and the Omega block debris was thrown over 900 ft. During these tests, the explosion pressure effects on other structures and objects were also documented. Unless otherwise specified, all of the pressure data listed in this report represent the highest recorded smoothed (averaged over 10 ms) explosion pressure loadings. The information in this report was used by MSHA and WVOMHS&T as supporting data in their analyses and investigative reports of the Sago Mine explosion.

Sep 1, 2009

By Terry S. Cory

This report covers antenna design, analysis, and development work suited for use with a wireless radio communication system operating at medium frequency. The work includes the test and evaluation of prototype vehicular antennas developed during the program.

Jan 12, 1978

By C. Ortuglio

The effect of cracking by increasing the free space above the charge on the composition and yields of the volatile products from carbonization of Pittsburgh-bed coal and one industrially used blend from Eastern United States and one from Western United States was investigated with the BM-AGA carbonization apparatus. Increasing the free space above the charge from 1 inch to 3 inches, to 6 inches, and to 9 inches resulted in lower tar yields and increased gas and light oil yields. Anthracene and naphthalene yields were increased; quinoline and benzene insoluble fractions of both the tar and pitch increased considerably with increased free space, although the carbon content of the tars and pitches increased only slightly. Increased cracking, occasioned by the increase in free space, resulted in a decrease in the yields of tar acids, tar bases, neutral oils, olefins, aromatics, and paraffins and naphthenes. Gas composition was relatively constant; hydrogen and methane tended to increase and ethane decrease. Results of the investigation are being used to design a unit to upgrade the volatile products of carbonization by cracking the hot products as they leave the carbonization chamber.

Jan 1, 1970

By B. J. Scheiner

A ferrous chloride-oxygen leaching system was investigated by the Federal Bureau of Mines to determine its effectiveness for recovering copper and silver from a tetrahedrite concentrate that had been pretreated to remove a majority of the antimony. The pretreated concentrate contained coppers, silver, lead, zinc, antimony, and arsenic. Parameters affecting metal extraction (such as temperature, pressure, amount of ferrous chloride, and initial hydro-gen ion concentration) were studied. Copper extraction of 98 pct was achieved by leaching 4 hours at 40 pounds per square inch gage (psig) and 100° C. Copper was recovered from leach solutions by cementation with iron, and the resulting ferrous chloride was recycled. Leaching the residue with cyanide followed by electrowinning recovered 99.7 pct of the silver. Iron, antimony, arsenic, and sulfur reported to the tailings.

Jan 1, 1978

By M. A. Elliott, H. H. Schrenk, L. B. Berger, John C. Holtz

 Previous reports of this series/7/8/ presented data on the composi- tion of exhaust gases produced by Diesel engines operating under various conditions possible in underground workings. In all previous experiments, the engines tested were in proper mechanical condition; that is, they were adjusted and maintained in accordance with the manufacturer's instructions. In discussing the results of these tests in relation to the use of Diesel engines underground, the importance of maintaining engines in proper mechanical condition was emphasized, although no data were presented to indicate the effect of engine maladjustments on production of harmful and objectionable constituents of exhaust gas. It is the purpose of this report to present such data and to reemphasize the importance of adequate maintenance for Diesel engines used underground.

Apr 1, 1943

By F. E. Spencer

This Bureau of Mines report provides a complete mathematical description of the algorithm employed by a general multiphase chemical equilibrium program developed particularly for the purpose of studying problems in coal combustion, although the generality of the program will allow its application to any equilibrium system in which an appreciable gas phase is present. When applied to coal combustion problems, the program predicts composition and quantity of slag and unconsumed carbon phases as well as calculates accurately the composition of the gas phase including trace species such as free electrons and ions which are important for predicting electrical properties.

Jan 1, 1973

By T. F. Mitchell

As a part of the program of investigation of domestic sources of manganese ore, mining engineers of the Bureau of Mines examined and obtained samples of ore from two properties in the vicinity of Bettie Mountain, Lander County, Nev. In addition, samples from three claims in the Carico Lake region, Lander County, Nev., were submitted by private interests. RS the ores were too low in grade to be acceptable for the direct production of ferromanganese, their amenability to concentration by ore dressing was investigated. The Black Bock property is 16 miles south of Valmy, Nev., and is owned by Western Alloys, Inc., Salt Lake City, Utah. The deposit is a replacement of sedimentary rock by manganese oxides. Ore occurs in two main ore bodies designated as the "upper bench" and "lower bench", which could be mined separately. Examining engineers obtained samples from each ore body, and laboratory experiments were made on each sample. The Black Eagle group of claims is in Lander County, Nov., about 43 miles southwest of Battle Mountain. Ore occurs as a replacement of manganese oxides in shale and chert. The 2-ton sample of ore used for laboratory testing was taken by a Bureau of Mines examining engineer from an adit that partly transversed a 28-foot bed of ore. The property is controlled by Western Alloys, Inc.

Jan 1, 1951

By Joseph Cervik, Maurice Deul, Albert Sainato

This Bureau of Mines report deals with water infusion of coalbeds, which can control methane emission at face areas during developmental mining and which may sometimes suppress dust. Studies show that water infused into the coalbed flows through the fracture system and displaces the methane in the fractures and prevents migration from the solid coal. Displaced gas migrates away from the face area that has been water infused and enters the return ventilation airways. A gradual decrease in methane emission is observed from the start of infusion until the infused zone is mined through. Depending on the permeability of the coalbed, infusion pressures ranged from 300 to 2,200 lb/in2. Face emissions in the Upper Kittanning coalbed were reduced by 89 pct; reductions of 38 to 79 pct were measured in the Pittsburgh coalbed depending on the relationship between the face cleat direction and mining direction. Respirable dust levels were reduced by about 75 pct on a longwall section in the Pocahontas No. 3 coalbed and by about 50 pct on a development section in the Upper Kittanning coalbed, but no statistically reliable reduction was found in the respirable dust levels in the Pittsburgh coalbed.

Jan 1, 1977

By K. O. Bennington

The thermodynamic properties of aegirine, of composition [(Na0.869Fe30+7362 Fe20+16Mn0.03Ca0.1121)(A10.141Sil 9738)(06)], were experimentally determined at the Bureau of Mines as part of its efforts to advance minerals technology. The standard enthalpy of formation determined by hydrofluoric acid solution calorimetry is AHf298 = -641.12±0.73 kcal/mol. The standard enthalpy of formation from the oxides is AH298 = -37.136±0.509 kcal/mol. Low-temperature heat capacities were determined by adiabatic calorimetry from 19.1 to 304.6 K. The derived standard entropy is S298 = 38.03±0.14 cal/mol?K. The heat capacity was measured over the range 348 to 1,198 K by differential scanning calorimetry. These experimentally determined data were combined with data from the litera¬ture to calculate the Gibbs energies of formation and equilibrium constants of form¬ation over the temperature range of the measurements. Standard enthalpies of forma¬tion are given as functions of temperature. The standard Gibbs energy of formation at 298.15 K is AGf298 = -600.36 kcal/mol.

Jan 1, 1984

By W. C. Smith

This Bureau of Mines report discusses how pull-test data can help establish polyester resin column length criteria for roof bolts in evaporite minerals. The study evaluates the effectiveness of partial to full columns of resin in anchoring 4-ft, No.6, grade 40 rebar roof bolts in potash, salt, trona, gypsum, and borate mine roofs. Pull tests were performed on over 600 roof bolts in 11 evaporite mines. Column lengths ranging from 6 to 48 in (fully grouted) were evaluated for each test site. In general, comparative results among all test sites indicate that pull-out loads in excess of 10 tons (force) were attained with resin-grouted bolts having 13 to 75 pet less than a full column of polyester resin. Ten tons (force) of load-carrying capability compared favorably, in terms of strength, with the calculated yield strength of the rebar used in the tests, which was 8.8 tons (force). The site-specific nature of each test site, due to the unique combinations of geology, mine-induced stresses, and other unknown parameters, prevented the establishment of valid generic column-length criteria. For these reasons, data to evaluate resin-column-length effectiveness are best obtained on a mine-specific basis.

Jan 1, 1987