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By C. C. Shale

Electrical resistivities for various coal ashes in air and in a nitrogen atmosphere are given over the range 100° to 1,500° F. Resistivity of low-carbon ash in air is very high at low temperature, rises to a maximum at about 250° F, decreases very rapidly with increasing temperature to about 800° F, then decreases gradually to approach an asymptote at 1,500° F. Resistivity of high-carbon ash in air follows this same general trend at values which are much lower and are proportional to the carbon content. After the carbon has been burned off, resistivity of the remaining ash approaches the high values corresponding to low-carbon ash of similar chemistry. Two factorial experiments show the effects of temperature, particle size, chemical content, and compressibility on the resistivities of four fly ashes of widely different chemical composition in the temperature range proposed for coal-fired turbines. Resistivities of all low-carbon ashes tested fall in the range 106 to 107 ohm cm at 1,500° F and should be removable by electrostatic precipitators. Ashes containing carbon in excess of about 8 percent, however, have low resistivity (as determined in nitrogen), especially at high temperatures. Therefore, high-carbon materials may not be collectable in precipitators because the resistivity is below the minimum value necessary for precipitation. Consequently, high carbon residues from partial combustion of coal probably could not be removed effectively at high temperatures.

Jan 1, 1968

By C. W. Davis

Before listing the laboratories and the work performed there, it is proper to make clear what is done and what is not done by Federal bureaus, States, and Territories, as well as by countries to the north and south of the United States. FEDERAL Bureau of Mines. - The Bureau of Mines does not make assays or analyses for individuals or firms unless the samples are part of the ore-testing and ore-dressing investigations of the Metallurgical Division on representative ores from mining districts and of possible benefit to the entire mineral industry through published reports. All significant results obtained in this way are made public. Any mineral sample sent to this Bureau for simple identification will be examined.

Jan 1, 1938

By John Henderson

If you missed this year?s Texas State Holmes Safety Association meeting, you missed a great one. On January 23 & 24, 2009, we held the meeting that was rescheduled when Hurricane Ike threatened Corpus Christi in September 2008. Sixty-five persons from across the state attended the meeting held at the Holiday Inn Emerald Beach. The weather was 82 degrees, and the sky was clear and perfect for a safety meeting. Evaluations submitted by the attendees gave the presentations, the networking, and even the food top marks. There were eight councils represented; Big Country, Central Texas, Costal Bend, Heart of Texas, Hill Country, North Texas and North Central. Presentations included Workplace Examinations, Emergency Preparedness, Screen Safety, Contractor Responsibilities, Powered Haulage, Supervising for Safety, and Basic Inspections of Slings and Rigging. Mr. Edward Lopez, SC MSHA District Manager, gave the State of the District Address.

Jan 1, 2009

By E. C. Perkins

Preliminary experiments are reported utilizing bacteria to leach manganese from a variety of domestic low grade manganiferous materials. In two large leaches manganese extraction ranged from 71.7 to 92.5 percent, and the products analyzed over 48 percent manganese. Nutrient requirements and leaching time experiments were made. The mechanism of leaching is not understood, but is different than the mechanism encountered in the microorganism accelerated leaching of copper in the presence of sulfide minerals.

Jan 1, 1962

By K. C. Dean

Horizontal and vertical air classification systems were tested individually and in simulated tandem use for the recovery of ferrous and nonferrous metals and of other noncombustible and combustible products from shredded urban refuse. The horizontal air system with a larger tonnage throughput was used to obtain preliminary separations, and a smaller capacity vertical system was used as a cleaning device. Air elutriation, magnetic separation, and screening of shredded minus 6-inch municipal refuse recovered 92 percent of the metal in a relatively clean iron product contaminated only by adhering coatings or entrapped materials, recovered 97 percent of the combustibles in a 97-percent combustible product, and rejected 88 percent of the nonmetal noncombustibles. Cleaning of the preliminary combustible fraction produced a 98-percent paper product while rejecting other combustibles (plastics, rubber, textiles, etc.) into a 94-percent combustible product. Retreatment of the preliminary noncombustible fraction produced a relatively clean glass product.

Jan 1, 1971

By H. O. McDonald

The Bureau of Mines reviewed the chemical vapor deposition (CVD) literature on the nonmetal binary and ternary compounds of the group IVB, VB, and VIB elements, with emphasis directed to the following nonmetals: B, C, N, O, and Si. This review examines each of these binary and selected ternary compounds of the group IVB, VB, and VIB elements as coatings and gives some of their preparative methods, uses, and properties. A total of 259 references were found for these compounds of the nine elements. This review was utilized in the Bureau's research to provide abrasion-, erosion-, and corrosion-resistant coatings in order to conserve critical metals and protect various metallic surfaces in metallurgical, mining, and energy conversion systems.

Jan 1, 1983

By Jr. Harty

Intensive work on the deoxidation of steel with manganese-silicon alloys by the U. S. Bureau of Mines has shown that the use of those alloys, which may be produced from our domestic manganese ores, would decrease the ferromanganese requirements of a very large tonnage of our steel by from 60 to 80 per cent and in some cases by 100 per cent. The open-hearth heats made with these alloys have been of excellent quality. The tonnage of our ferro-grade ores Which has been made available by the bureau's ore-dressing studies, combined with the products resulting from such processes as those developed by the bureau and by Bradley for Cuyuna ores, should easily fill our reduced ferromanganese requirements when manganese-silicon alloys and ordinary Spiegel are used in the way described in this report. There are no technical difficulties in the application of this practice, and any difficulties involved in its wide and immediate application would only be those arising from habituated ideas of the necessity of ferromanganese. General acceptance of this practice and development of the available sources of domestic ferro-grade material by already proven processes should make this country independent of foreign ores. This paper resents the results of work done under a cooperative agreement between the Pittsburgh Experiment Station of the United States Bureau of Mines and the Carnegie Institute of Technology, the Metallurgical Advisory Board, and the University of Pittsburgh, Pittsburgh, Pa.; between the Mississippi Valley Experiment Station of the United States Bureau of Mines and the Missouri School of Mines and Metallurgy, Rolla, Mo.; between the North Central Experiment Station of the United States Bureau of Mines and the University of Minnesota, Minneapolis, Minn.; and between the Rare and Precious Metals Experiment Station of the United States Bureau of Mines and the University of Nevada, Reno, Nev.

Jan 1, 1931

By Seymour Wasserman

To develop noise control designs for secondary crushers in Taconite plants. Taken into consideration: 1. Acoustical criteria 2. Day-to-day operational considerations and maintenance accessibility 3. Materials of construction 4. Adaptability of design to other Taconite plants having crushers 5. Cost of noise control treatment.

Jan 1, 1977

By Joan C. Biordi

[Composition profiles for atomic, radical, and stable species, as well as temperature and area expansion ratio profiles, have been determined for a nearly stoichiometric CH4-02-Ar flame and one to which 0.3 percent CF5Br inhibitor had been added. Net reaction rate profiles were calculated for all the observed species. For the normal flame, these and the mole fraction profiles gave rate coefficient information about the elementary reactions in the methane flame, for example, CH. + 0 4- H2CO 0 H, k4 = 1.05 X 1014CM3 mole-1sec-1 for 1,550§T 0,725' K; CO + OH 4 C02 + H, k6= 4.7 X 1011 for 1,350{T X1,750° K. Comparison between the inhibited and normal flame showed that A] and [CH3] were significantly reduced at the lower temperatures in the inhibited flame even though in the hot gas region the [E] [OH!, and [0] were essentially the same in both flames. The CF3Br disappears very early in the flame, relative to the fuel, and the reaction primarily responsible for its disappearance is H v CF3Br 4 HBr + CF3, where k7 is found to be 2.2 X 1014 exp(-9460/RT) for 700-1,550° K. Reaction of the inhibitor with methyl radicals provides for the relatively small amounts of CH3Br observed, but CH3 + Br2 - CHs Br + Br must also occur. The HBr formed reacts rapidly with H atoms to form H2 and Br, but the reaction is soon "balanced" in the flame as may be demonstrated by calculation of the equilibrium constant at various temperatures. The fluoro-carbon fragment produced in reaction (7) also reacts rapidly, in part with methyl radicals to give the observed elimination product CH2CF2 Later in the flame, above -1,400' K, F2CO is formed from the reaction CH2CF2 + 0 P F2CO + CH2 and k., -1.5 X 1013 at 1,600° K. The rather slow decay of carbonyl fluoride is attributed to reaction with H atoms according to the sequence F2CO I H - HF + FCO and FCO + H HF + CO.]

Jan 1, 1975

By Kenneth E. Hay

The Bureau of Mines collected coal and coal waste aggregate material from two different mine sites to determine their strength characteristics for use in concrete. The concrete would be placed underground as support walls for ground control in adverse conditions or unique mining applications. A standard mix design was established for a "wet" mix using a water-to-cement (w/c) ratio of 1.0 to facilitate pumping into place. Later, material was collected from four more mine sites and used to make 2-by 2-by 2-ft test blocks with the same w/c ratio. A pull-out cone device and borehole shear tester were used to determine the in situ material strength of the test blocks. These techniques will provide a simple and quick way of determining support wall strength in an underground environment. Test results from the pullout cone de-vice showed a good correlation of 0.98 to test cylinder compressive strengths of the same mix. Results of the borehole shear tester were inconclusive.

Jan 1, 1986

By E. B. Swanson

Atlantic seaboard refining and marketing companies , dependent largely upon other producing and refining areas for the crude and refined petroleum needed to meet the demand for petroleum products within the Atlantic Coast States , reported an increase in 1929 receipts of 2,542,000 barrels of crude petroleum and 13,479,000 barrels of gasoline over the quantities received during the preceding year . The relatively large expansion in gasoline receipts undoubtedly resulted from the unexpected increase in gasoline consumption which characterized the petroleum industry during 1929. Gasoline receipts from California increased 6,354,000 barrels and shipments from foreign countries were 5,381,000 barrels in excess of the 1928 figures , while receipts from Gulf Coast ports , the major source of outside supply, declined 811,000 barrels . Shipments of domestic crude oil by tanker from Gulf Coast ports during 1929 continued the average annual increase of approximately 7,000,000 barrels which has been recorded during the five years of this annual survey . These shipments have increased from 72,556,000 barrels during 1925 to 99,828,000 barrels during 1929. Shioments of Mid- Continent crude by pipe- line to Atlantic Coast refineries have , on the other hand , dropped from 11,903,000 barrels in 1925 to 1,409,000 barrels during 1929. Receipts of foreign crude oil declined 1,461,000 barrels from the preceding year . : Gasoline demand within the Atlantic Coast area reached a total of 123,345,000 barrels , an increase of 15.7 per cent over 1928. Gasoline production increased 4,157,000 barrels , while tanker receipts were nearly 11,000,000 barrels larger than in 1928. Indicated shioments from Appalachian refineries were somewhat larger than in the preceding year . Gasoline production showed an average of 33.5 per cent of the crude throughout , as compared with 31.5 per cent in 1928 and 32.7 per cent in 1927. Cracking operations accounted for 44.6 per cent of the gasoline produced , as compared with 40.6 per cent in 1928 and 35.3 per cent in 1927. Gas oil and fuel oil production averaged 52.8 per cent of the crude throughput , as compared with 55.1 per cent in 1928 and 49.5 per cent in 1927 , the decline reflecting the smaller quantities of foreign crude refined during the year .

Nov 1, 1930

By Charles L. Kimbell

Available statistics on 1991 worldwide consumption of selected non fuel mineral commodities shown in table 12 indicate downturns for all but 3 of the 15 listed commodities. It should be stressed that in most instances, the consumption declines were primarily the result of lower levels of use in the former U.S.S.R. and the former centrally planned economy nations of Eastern Europe. However, several commodities suffered use cutbacks in market economy countries. In the case of the nonferrous metals covered In the table, the differences in performance between market economy countries and the former centrally planned economy states are immediately evident from the table itself. Among these important commodities, refined lead, primary magnesium, and refined tin registered downturns for market economy countries as well as among the centrally planned economy countries. Also notably, cadmium use showed no significant change from 1990 levels in either group of countries. Global consumption of iron ore fell by 3.4 % or about 31 million tons, and this was a greater decline than that logged for production of marketable iron ore and related products, which was down by only 3.0% or almost 28.2 million tons. Thus, it would seem that for another year there was a net addition to stocks. The 1991 drop in iron and steel scrap use was about 5.5 % or about 18 million tons, on the percentage basis somewhat greater than the 4.8% or 36.9 million ton drop in global steel production. Although consumption of iron ore and iron and steel scrap are not broken down by region in table 12, it seems almost assured that the pattern of 1990 continued into 1991: drops in use in the former U.S.S.R. and Eastern Europe were the overwhelmingly dominant declines and accounted for much, although not all, of the global decline, whereas among market economy countries as a group, there were upturns for both materials. On a global basis, it would appear that the slight shift in the ratio of pig iron to scrap in steel furnace charges noted in 1990 continued into 1991, this shift being toward a slightly larger proportion of pig iron with a corresponding decline in the share accounted for by scrap.

Jan 1, 1993

By Dennis R. Dolinar

Screen material in the form of welded wire mesh and geogrids are used in underground coal mines to prevent the fall of small pieces of rock from the roof between roof bolts. Further, if the screen is installed during the production cycle, roof fall injuries can be reduced significantly. Therefore, the National Institute for Occupational Safety and Health (NIOSH), because of the safety implications, conducted an evaluation of screen materials commonly used in U.S. coal mines to determine their support characteristics and identify the parameters that could affect their performance with respect to controlling the fall of rock from the roof surface. To evaluate the load and stiffness characteristics of the screen, a test frame was designed and installed in the Mine Roof Simulator (MRS) at the NIOSH Pittsburgh Research Laboratory (PRL). With this test set up, the screen is bolted at four corners of the frame and a center load is applied. The test set up allows for up to 20 in of screen deflection while the load and screen defection are continuously recorded. A series of tests were conducted to evaluate the effects of various parameters such as bolt tension, the type of load bearing surface and the size of bearing plates on welded screen performance. The most common screen material used in U. S. coal mines is an 8-gauge wire welded in a 4-by-4-in spacing or aperture. The peak screen load was normally limited by wire breakage. The conditions at the bearing plate influence the nature of the wire breakage. However, the screen stiffness was controlled by slippage at the bearing plates, and by weld and wire failure. The size of the bearing plate had a significant effect on the performance of the welded screen. Therefore, the design capacity of the 8-gauge screen is evaluated based on plate size. For a 6-by-6-in bearing plate the average peak load is 2,900 lb with a stiffness of 250 lb/in. For an 8-by-8-in bearing plate, the average peak load is 4,500 lb with a stiffness of 430 lb/in. These test results are based on a 4-by-4-ft bolt spacing. A geogrid mesh was also tested.

By J. D. Spagnola

The Bureau of Mines conducted research to obtain comparative data on the extent of reduction of galena and sphalerite with molecular hydrogen and with hydrogen from the thermal cracking of ammonia and methane at various time intervals. Galena reductions of 95 to 99 percent were obtained with H2 and with decomposed NH3 while reductions of 70 to 80 percent were obtained with cracked CH4? Sphalerite reductions of 99 percent were obtained at 1,000° C with Hz and with decomposed NBs; however, complete volatilization of the free zinc from the remaining concentrate and the subsequent recombination of zinc and sulfur vapors resulted. A promoted iron catalyst brought about a decrease of 100° C in the temperature required for complete decomposition of ammonia. It was found that H2S retards NB3 decomposition and that nitrogen retards the reduction of galena by H2? A mixture of N2 and He in about the same ratio as that obtained by the thermal cracking of NBs gave about 15 percent less reduction of galena than was obtained with decomposed NB3; this indicates that a portion of the hydrogen obtained by NBs decomposition is in an active form.

Jan 1, 1965

By W. M. Myers

The U. S. Bureau of Mines conducted an investigation to determine the cause of the deterioration of Portland cement during storage and transportation , and to discover a means of preventing it . All available printed sources of information on this subject have been examined and a bibliography has been compiled . The subject has also been discussed with the leaders in the cement industry ; the present report is the result of their cooperation , and is based principally on information thus obtained . Deterioration of Portland cement during storage over any considerable period of time has long been noted ; closely related to it is deterioration of cement during transportation, which involves not only the time factor of storage but also exposure to varied climatic conditions . Deterioration in both cases is due to hydration of the cement by absorption of moisture from a humid atmosphere , or by exposure to actual rain-fall . After hydration cement possesses no cohesive power ; the degree of deterioration is directly proportional to the degree of hydration . The amount of deterioration of Portland cement during storage has been accurately determined in an investigation by the Structural Materials Research Laboratory , in cooperation with the Portland Cement Association . Cement stored in a shed in cloth sacks retained 80 per cent of its original strength after three months storage ; 71 per cent after six months ; 61 per cent after one year ; and 40 per cent after two years . The deterioration of Portland cement during storage and transportation was noted particularly in France during the World War . Information concerning cement used by the American Expeditionary Forces was furnished by Lt. Col. H. S. Spackman and Major E. C. Eckel , U. S. R. , who had charge of practically all matters concerning cement used by the A. E. F. The cement used by the A. E. F. came from the following sources : 42,000 tons was French , Swiss , and Spanish cements ; 120,000 tons was English cement ; 55,000 tons made in plants operated by the A.E.F .; 500 tons ( Not over) from America . Deterioration was most marked in cement from the first source .

Jun 1, 1922

"A coordinated, integrated research effort aimed at studying the scientific, engineering and medical aspects of the respirable dust problem is underway in the areas of dust generation, dust dispersion and dilution, dust characterization, interaction of dust and lungs, and relationship of seam characteristics to dust generation and mobility. (FIGURE 24) The Center's research program explores these concerns with the objective of refining existing strategies and developing new respirable dust control techniques that are consistent with the dust-lung interaction processes that lead to mine worker disability. The fundamental aspects of this work are applicable to the control of respirable dust problems in both hard rock mines and coal mines and to other dusts such as diesel-generated.Research projects in the Generic Mineral Technology Center for Respirable Dust have effected several improved methods for the preparation and characterization of the dusts needed by these projects. Superior procedures for generating ""standard"" dust samples have been developed and are in regular use in the laboratory. Questions raised during the course of some projects regarding ""stale"" versus ""fresh"" dust have led to the development of sampling techniques where the dust is directly collected in a surfactant. MSHA and CANMET have requested and received information on Center generated software. An equipment manufacturer, TSI, Inc., requesting input on modifying the inlet of an aerosol sampler has been assisted as a result of research that was conducted at the University of Minnesota.The objectives, scope and progress of all the research projects in the Center, in the form of abstracts and reports, have been detailed in Volume 1 of this series. Research papers written by the principle investigators and resulting from the findings of projects (FIGURE 25) and which are funded by U.S. Bureau of Mines grant number G1135142 have been published in Volumes 3 through 6 and Volume 8 of this series. Volume 2 relates the cooperation and interaction of the U.S. Bureau of Mines and the Generic Mineral Technology Center for Respirable Dust in research on the problem of respirable dust in the mineral industries."

Aug 31, 1989

By John B. Umhau

[This !m-i~!.al survey giver, statistice.1 data res;?~dirf ~:rimay ard ?eco~- dqr or scmn tin used in thL: United St,ztas by industries an? incluclcz d;ta on stop&apos;ics, ~urchares, ard plnrt losr.c.5. It is :i ml:anwe of consq~tion in terms of fir.is1icd -prcd.~cts nz6.e iry initid ti11 Sabric:,.torc,, that is, aon- cerns that purchzse virc,in zni s~col~d&apos;l~y i.i.5 ti:; 01&apos; tin c;cra.. rav materi,als ar,d co:lrrert them into !ror?ucts such F!: ti:i plz.te, ~lloyr;, and. c?hemic?ls; comy~nias ;~urchn.&apos;.ii~; alloys, ch:rr.ic,~l::, or tin vl?.tc fcr furthcr a:mflzc- ture ?rc: ~-.f>t i~ci~~dcd. Tilit r~lqe:;tionrr::ire submit tod to consunern ar,nt:incd no dofinition of rnr.oncl.:ryr me$.-i; but, ovrirq to ti~i-: a~counti~ procedure used s.l~o~c-:t 1&apos; thu scrnn hac i~-.rtergol:e ch?rri?~ of ovinerzhip or titlo, thc rc!coverod t! n !its b~en i-c<;,r(it.!rj L.S r,e~3r;d:q met.1. Tbv tin content ~f ]

Jan 1, 1938

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Jan 1, 2012

By Robert A. Jankowski

The Bureau of Mines has recently identified five major factors that contribute to high respirable dust levels on the six U.S. longwall faces having the most difficulty complying with Federal dust standards: (1) a poorly structured cutting sequence, (2) a poorly designed external water spray system, (3) marginal waterflow to the cutting drums, (4) minimal controls at the stage loader and crusher, and (5) the lack of effective controls for dust generated during support advance. The results of this survey illustrate the need to address all the major sources of longwall dust generation and the need for mine operators to implement a variety of control procedures to assure compliance. The Bureau of Mines will continue to assist mine operators in implementing improved dust controls and will work to identify and evaluate controls for dust generated during support advance.

Jan 1, 1983

By L. B. Berger

Each winter brings its toll of deaths and serious accidents from the deadly gas, carbon monoxide. Newspapers carry warnings to the public of the dangers of this gas, and frequent now items retort the finding of persons dead or unconscious from the effects of carbon monoxide, yet these accidents continue. Either those warnings are not read, or they are unheeded by people who feel that "It can&apos;t happen to me." It can happen to you - carbon monoxide is no respecter of persons, as evidenced by items appearing daily in newspapers all over the country. Carbon monoxide has been a threat to human safety as long as man has used fire to keep himself warm and to cook his food. The burning of any fuel that contains carbon may produce carbon monoxide. This is true of solid fuels such as coal, coke, and wood; of liquid fuels such as oil, gasoline, and kerosene, and of gaseous fuels such as natural or manufactured gas. In the process of combustion the carbon in the fuel unites the chemically with tat oxygen of the air to form carbon dioxide (CO2), however, if the supply of air is not adequate, combustion is incomplete and carbon monoxide (CO) will be formed.

Jan 1, 1943