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By D. H. Desy

The Bureau of Mines studied the properties of copper that had been oxide dispersion-strengthened with 2 vol pct of either yttria or alumina. Compounds of copper and aluminum or yttrium, coprecipitated from aqueous solution, were converted to oxides; the copper was reduced, compacted, sintered, and extruded. For the resulting copper-dispersoid composites, room temperature tensile properties after annealing in hydrogen, elevated temperature tensile and stress-rupture properties, and electrical conductivity were determined. Compared with oxygen-free copper, copper-2 vol pct alumina or yttria had improved strength after annealing between 400° and 1,000° C, and improved elevated temperature strength, with little loss in electrical conductivity.

Jan 1, 1969

By H. Reginald Hardy

This report is Volume II of a three volume final report dealing with the microseismic monitoring of a longwall coal mine. The research presented in Volume II is concerned with the evaluation of field techniques for obtaining seismic velocity data required for computing microseismic source locations. The report describes the evaluation of a number of different field techniques and the seismic velocity data obtained at the Greenwich mine site where the micro-seismic studies, described in Volume I of the final report, were carried out. Three different methods were employed to evaluate seismic velocities, namely; surface refraction, down-hole, and transmission. In all cases the seismic sources were either located on surface (mechanical impact) or near-surface (explosive charges). It was found that a mechanical energy source could be conveniently utilized to determine shallow velocities and make bedrock-regolith interface depth determinations. For deeper velocity determinations suitable explosive charge sources Here required. In general, refraction data did not always plot in a linear manner and some subjective interpretation was necessary. The down-hole method was found to be useful for incremental vertical velocity evaluation, however, the transmission method provided the most consistent average vertical velocity data. At the Greenwich site seismic velocities were found to be anisotropic with values ranging from 9,551 to 10,739 feet per second depending on direction.

Jan 1, 1977

By J. H. Bilbrey

A recording thermobalance ,vas used to determine the rates of oxidation of mol-ten tin over the temperature range 550°-900° C. Oxidation rates were found to vary widely for a given temperature, as previously reported by other investigators. 1 X-ray diffraction data indicated that the probable cause of these variations was the development of preferred orientations in the crystals forming the oxide film. No reasons for the differences in degree of preferred orientation were discovered. For relating the weight of the oxide formed (w) to the time of oxidation (t) an equation of the form wn = kt was found to best represent the experimental data. INTRODUCTION In the course of conducting investigations on the feasibility of using selective oxidation techniques for the purification of various metals in the molten state it was soon discovered that data on the oxidation of molten metals and alloys were very scarce. In contrast to the many hundreds of publications on the oxidation of metals in the solid state there are relatively few articles on the rates of molten-metal oxidation. In view of this scarcity of data, it was decided to institute a series of investigations into the oxidation processes of molten nonferrous metals and alloys with the expectation that the information derived could be put to practical use in developing and improving refining processes based on selective oxidation. This report is the first of a series in which oxidation data for molten nonferrous metals and alloys are presented.

Jan 1, 1955

By G. A. Bole

"This paper presents a review of the literature and is an epitome of work acne and articles published by Schurecht, Robson and Andrews', in the investigation of the feasibility of making basic refractories from dolomite, was carried on successively by these men, at the Ceramic experiment Station of the Bureau of Mines, Columbus, Ohio.Scope of the work.The dolomite refractories investigation of the Ceramic Station includes a study of the many fluxes which could be used to aid in the dead-burning of dolomite and also a complete survey of the iron oxide-alumina-silica field as fluxes. The temperature of calcination and the resulting properties have been carefully investigated, and the most desirable calcines chosen for further investigation in the making of dolamite bricks. Many binders and the several methods in common use of fabricating bricks commercially were tried, and a thorough study was made of the properties of the most successful ware,Previous Investigators.Even before the World War, considerable work was done on dolomite this war greatly accelerated the efforts of the many Investigators."

Jul 1, 1924

By E. E. Maillot

In 1943, diamond drilling by the Bureau of Mines, comprising 11 holes which totaled 1,295.6 feet, showed that the pegmatite at Black Mountain consisted of shallow lenses in interbedded biotite-quartz-schist and impure quartzite. The average thickness of the pegmatite was 9.7 feet. Mineralization had a zonal arrangement. Beryl was most abundant near the footwall contact of the pegmatite. The average estimated beryl content of the pegmatite exposed at the surface was 0.81 percent, and the highest content of any pegmatite area was 1.75 percent. Other economic minerals were scrap mica, feldspar, spodumene, and lepidolite. Representative samples of the Black Mountain deposit failed to yield high-grade boryl concentrates by straight flotation owing to the presence of considerable spodumene. By employing heavy medium separation to remove the spodumene, 75.4 percent of the. BeO wan recovered in a flotation concentrate assaying 10.4 percent BeO.

Jan 1, 1949

By Margaret R. Egan

This Bureau of Mines report presents results from experimental studies on wood crib fires in an intermediate-scale fire tunnel. Gas concentrations, smoke particle characteristics, heat release rates, and ventilation rates were determined. These measurements form a data base for wood, which can be used with previous analyses for coal and future studies of other mine combustibles, to comprehend the potential hazards of these materials in underground mine fires. A knowledge of the combustion products emitted from these materials will benefit fire detection and control. Results show the changes in burning rate and heat release rate produced by different crib configurations and ventilation rates. Also included are the effects that the burning rate has on smoke characteristics and gas production.

Jan 1, 1986

By J. L. Shultz

The investigation of organic compounds in respiratory coal dust by high-resolution mass spectrometry has shown that the organic components differ (1) with particle size, (2) with rank of coal, (3) in coals of same rank from different coal seams, and (4) in respirable mine dust and respirable coal dust (prepared) from the same mine. The eight respirable mine dusts studied are from coal seams in the Appalachian region where the incidence of coal workers' pnumoconiosis is relatively high. The molecular weights of the major organic components vary greatly among these respirable mine dusts; three show strong concentrations of polynuclear aromatic hydrocarbons.

Jan 1, 1972

By J. S. Dunning

The objective of this research by the U.S. Bureau of Mines was to determine the effects of AI additions on the sulfidation resistance of Fe-Cr-Ni alloys. A series of Fe-Cr-Ni alloys with and without -additions of 4 pet AI were tested in a wet S vapor atmosphere at 677 C. A study of the morphology and composition of corrosion scales indicated a different corrosion mechanism for AI-free alloys compared with AI-containing alloys. Aluminum-containing alloys formed a compact, tightly adherent layer at the metal-scale interface that reduced corrosion rates by a factor of 3 to 10 compared with that of AI-free alloys. The thin, adherent AI-containing scale limited inward diffusion of 0 and S to the base metal and outward diffusion of Ni from the base metal. Aluminum-containing alloys formed a three-layer scale in oxidizing-S environments, while AI-free alloys formed a less protective two-layer scale.

Jan 1, 1989

By T. A. Henrie, J. D. Marchant, E. S. Shedd

Cerium metal was electrowon in a fluoride bath from cerous oxide and tapped from the cell during prolonged operation . Electrolyte constituents were CeF , BaF₂ , and LiF. Twenty- seven pounds of metal of 99.8 percent purity were produced at a rate of 3 pounds per hour and tapped from the cell . Principal impurities were molybdenum , aluminum , oxygen , and carbon . The operating parameters , such as electrode geometry , bath compositions , and oxide feed rate , were investigated . Anode reactions were found to be important factors in cell operation . Stable cerous oxide reacted more uniformly at the anode surface than ceric oxide . Electrowinning was conducted in crucible hearths consisting of both frozen electrolyte and molybdenum metal . Both materials proved satisfactory and did not react with the molten cerium . Stable cerous oxide was prepared by carbothermic reduction and used as a feed material . Cell design proved to be an important factor in continuous cell operation . Complementary to the investigations of electrowinning of cerium , the metal was purified by electrorefining in a chloride electrolyte .

Jan 1, 1964

By Laurel A. Powers

The Bureau of Mines process for recovering Ni and Co from low-grade domestic laterites uses a reduction roast followed by an ammonia, ammo-nium sulfate leach. This investigation examined the waste streams of the process for their potential environmental impact and focused on the laterite residue produced. The U.S. Environmental Protection Agency's extraction procedure (EP) toxicity tests and column leaching showed that leachable metal concentrations would be low enough so that the residue would not be considered a hazardous waste under present definitions. Under nonacid leaching conditions, about the same amount of metal was extracted from laterites as from their residues, and the leachates were similar to water samples from an undisturbed laterite deposit. Washing tests on the laterite residue showed that ammonia and ammonium sulfate concentrations were reduced according to equilibrium stage calculations, resulting in residues that would be acceptable for revegetation. With water washing only, the residue would not be considered a hazardous waste even though significant amounts of Ni and Co were absorbed from entrained leach solution onto the residue. Washing first with fresh leach solution and then with water prevented this absorption and thus improved the overall metal recovery.

Jan 1, 1983

By N. S. Dalal, J. F. Mega, X. Shi, V. Vallyathan

Several studies have suggested that pulmonary toxicity to asbestos and silica may be mediated through oxidant-induced cell injury. We have reported recently that surface radicals associated with freshly fractured silica may be an imponant factor in cell injury and induction of pulmonary disease. Although the generation of oxygenated radicals in dust-cell interactions has been demonstrated, there are no data correlating the toxicity of a dust with the level of oxygen radical generation by the dust during its interaction with phagocytic cells. In the present study, we have investigated the in vitro generation of oxygen free radicals from human neutrophils and rat alveolar macrophages stimulated with freshly fractured silica, aged silica, amosite, crocidolite, chrysotilc, and a nontoxic dust, barite. Electron spin resonance (ESR) with the aid of a spin trap phenyl-N-ten-butyl nitronc (PBN) was used to measure the oxygen radicals generated during phagocytosis of the dusts. The relative toxicity index and ESR peak heights, on an equal surface area basis and normalized to barite as one, showed a direct relationship. The normalized toxicity indices and peak heights were: silica, 3.5 versus 2; chrysotile, 4 versus 2; crocidolite, 11 versus 8; and amosite, 26 versus 13. Addition of hydroxyl radical scavengers such as catalase, dimethyl sulfoxide, 1,3 dimethyl-2-thiourea (DMTU), sodium benzoate, and mannitol prevented the radical generation. Carmustine, a glutathione reductase- glutathione peroxidase inhibitor, caused a 5-fold increase in the radical generation. These results indicate that a nontoxic dust such as barite generates toxic oxygen radicals at a minimal level that can be quenched by the normal cellular defense system. For toxic dusts such as silica, amositc, chrysotile, and crocidolite, the potential for oxygen radical generation is enhanced by their surface propenies, physical dimensions, and the surface-based radical-generating redox sites. The enhanced radical generation may impair the cellular defense system, resulting in cell injury. Use of scavengers, chelators, and potentiating agents suggests the membrane-based oxidase system as the probable primary source of the radical-generating system. The data presented herein suggest the generation of oxygen free radicals as an important primary event in silica- as well as asbestos-induced cell injury.

Mar 1, 1992

By J. W. Sterner

The Bureau of Mines conducted studies on four makes of Japanese automobiles, three 1981 and one 1982 model years, received from three manufacturers to determine if their materials composition would present problems to the current technology used to process junk automobiles for metal recovery. One of each make of automobile was hand-dismantled to determine the materials composition. In addition, two nearly identical automobiles of each make were shredded at a commercial operation where all metal products and rejects were collected for analysis to determine metal and nonmetal distribution. The average weight of the four automobiles to be dismantled, less batteries, tools, and fluids, was 1,938.3 lb. The weight was distributed as 1,472.9 lb. ferrous and 115.6 lb nonferrous metals, 275.2 lb combustibles, 72.3 lb noncombustibles, and 2.3 lb electrical components. The dismantled automobiles, less gas tanks, fluids, tools, wheels, tires, and batteries, which were all removed from the automobiles that were shredded, contained an average of 1,389.1 lb ferrous and 101.6 lb nonferrous metals, 305.7 lb nonmetals, and 2.3 lb electrical components. In comparison, materials collected from the shredded automobiles averaged 1,304 lb ferrous metals, 80 lb nonferrous metals, and 341 lb landfill materials. There were no materials used in the manufacture of the late model Japanese automobiles that should present handling or processing problems to the steelmaking or secondary metal recyclers.

Jan 1, 1984

By J. F. Barkley

Under the procedure of the American Standards Association, with the American Society for Testing Materials as sponsor, the Sectional Committee on Classification of Coals has arrived at the classification of coals by rank as shown in Table 14/. The standard explains the term "agglomerating" used for classification under physical properties, as follows: Agglomerating Index. - Coals which in the volatile-matter determination produce either an agglomerate button that will support a 500-g weight without pulverizing, or a button showing swelling or cell structure, shall be considered agglomerating from the standpoint of classification.***. Pending the adoption of a method by the American Society for Testing Materials, the coke-button grading test5,/ afforded by the examination of the residue in the platinum crucible incident to the volatile matter determination, shall be used.

Jan 1, 1937

By Lawrence W. Scott

This report presents several systems for continuously monitoring the quality of air in underground mines that are being developed by the Bureau of Mines. Underground stations measure methane, carbon monoxide and nitrogen dioxide concentrations, air velocity, and air temperature. This information is transmitted over a single telephone pair to central stations located on the surface. The central stations display alarms and the data is selectably displayed on digital panel meters.

Jan 1, 1977

By M. J. Kovalik

Lower Sunnyside seam coal from Utah was blended with various proportions of char and high-temperature coke to improve the quality of the coke obtained from carbonizing this coal. The Hanson 5-pound carbonizer was used as a "screening test" for the larger scale Bureau of Mines-American Gas Association (BM-AGA) tests, which were correlated with industrial production. Eighteen carbonization tests were made in the BM-AGA 13-inch retort, with a coal charge of about 90 pounds; the cokes were evaluated by the standard ASTM tumbler test. Carbonization of blends containing char and coke breeze yielded less fissured and blockier cokes of significantly higher ASTM I-inch tumbler indices as compared with the value for the straight Sunnyside coal. It was found that the simultaneous addition of char and coke breeze yielded stronger cokes than that obtained by the addition of either one of these additives. Addition of a small proportion of Pocahontas No. 3 or Sewell coal to an optimum blend improved the resulting coke strength further.

Jan 1, 1969

By D. J. Bauer

The Bureau of Mines demonstrated the feasibility of fractionating lanthanide nitrates with a tertiary amine on lanthanum-cerium and thulium-ytterbium pairs. Optimum values were determined for pH, phase concentration, and percent chelation of metal ions in the aqueous phase. Percent extraction is markedly dependent on the concentration of lithium nitrate in the aqueous phase. Selective masking of the heavier element in each extraction system with DTPA or EDTA aqueous-phase chelating agents resulted in lanthanum-cerium separation factors of 8.5 and thulium-ytterbium separation factors of 3.4.

Jan 1, 1966

By G. M. Potter, J. B. Rosenbaum, Masami Hayashi

Most Japanese copper smelters are located in areas of concentrated industrial activity and high levels of atmospheric pollution. A review of unofficial sulfur dioxide emission control data from major Japanese smelters shows capture of 91 to 99.7 percent of the sulfur in the smelter feed. The bulk of Japanese smel ting capacity was constructed in the last 10 years. Six of the major sme lters use flash furnaces, and two use reverberatory furnaces. A prototype three-furnace continuous system is in use as a parallel train with reverberatory furnaces at one smelter. Most of the sulfur dioxide is manufactured into sulfuric acid. The remainder is captured by gas scrubbers that yield gypsum and sodium salts. Ready markets exist in Japan for the acid and other su lfur byproduc ts.

Jan 1, 1967

By Richard A. Winters

In 1985 at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied 9,400 acres of the 10,005-acre Duncan Creek Wilderness Study Area (ID-111-78) in order to evaluate the mineral resources. The study area is located in Owyhee County, 10, about 36 miles southwest from Bruneau, ID. No mining districts are in the study area, nor were any mines or claims recorded or found. The southern half of the area was covered by oil and gas lease applications, all of which were cancelled prior to June, 1985. No economic concentrations of minerals were found in the study area. INTRODUCTION This report describes the USBM (U.S. Bureau of Mines) portion of a cooperative study with the USGS (U.S. Geological Survey) to evaluate mineral resources and potential of the Duncan Creek study area at the request of the BLM (U.S. Bureau of Land Management). The USBM examines individual mines, prospects, claims, and mineralized zones, and evaluates identified mineral and energy resources. The USGS evaluates potential for undiscovered resources based on areal geological, geochemical, and geophysical surveys. Results of the investigations will be used to help determine the suitability of the study area for inclusion into the National Wilderness Preservation System. Although the immediate goal of this and other USBM mineral surveys is to provide data for the President, Congress, government agencies, and the public for land-use decisions, the long-term objective is to ensure the Nation has an adequate and dependable supply of minerals at a reasonable cost.

Jan 1, 1986

By L. G. Marshall

The geology, mining, beneficiating, types of products, and costs in terms of percent of total costs and of labor, power, and supplies of two crushed-limestone operations in Madison County, Iowa, are described in this paper. The operations are basically similar, differing in refinements in mining, product types, and markets. The operations are comparable as to personnel and as to weighted costs in terms of percent of total costs and in terms of man-hours, power, and sup-plies. The waste-to-stone stripping ratio is 1 to 0.8 at both operations, the powder factor is 0.29 pound of explosives per ton of stone, and daily production is 95 tons per man-shift. Both companies use crawler-mounted diesel shovels for loading, truck transportation, wagon drills, and dry screening.

Jan 1, 1963

By Calvin J. Konya

Overloaded blastholes and insufficient stemming are major factors in flyrock accidents at surface metal and non-metal mines, Accurate measurement of blasthole depth, stemming height, and water depth would reduce the overload and the probability of blow-out, flyrock, excessive ground vibration, and airblast. Problems result because current measuring systems are inaccurate and often difficult to used A literature survey determined measurement techniques and blasting parameters prior to 1970. Similar data were gathered for current practices in 11 iron mines, 30 copper mines, and 92 quarries. Most operations used a cloth tape to measure borehole depth and stemming height; approximately 10% of the operations had dry blastholes. Alternate measurement techniques were evaluated and discussed. Candidate measuring techniques with best potential for improvement over the present weighted tape method are disposable tapes or string chains, automated readout tapes, modified sludge level indicators and acoustic resonance methods.

Jan 1, 1981