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By Larry M. Southwick

There have recently been executives at major metals companies who have recommended that Greenfield Projects not be pursued. Greenfield includes not only new geographical locations, but also new technologies and new types of feed materials. In the middle part of the 20th Century, two such projects were successfully commercialized to recover nickel from Cuban lateritic ores. One project (at Nicaro) used the Caron ammonia-ammonium carbonate leach and the other (at Moa Bay) a high pressure acid leach. How both of these projects dealt with these Greenfield issues will be reviewed, based on the original reports that described the research and development of the plants. This study will include a review of the critical ore characterization and sorting issues, as well as the extractive metallurgical, product recovery and equipment selection and sizing problems and how they were solved at each stage of project development, from laboratory through one or more pilot scale plants to start up and operation. In one case, a major revision of the plant was made after several years of operation to correct operating, equipment selection and materials of construction problems that hindered economical operation. These descriptions will provide a guide through the complicated and critical issues that in recent times have caused many companies to give up on similar development. Even with the more advanced analytical and computational tools available to today’s mineralogists, engineers and metallurgists, the basic concepts with which these projects successfully addressed their sets of problems are still required. In addition, upper management, now perhaps further removed from hands-on experience than was common then, will see how complicated problems require intense and detailed effort to avoid failure in the field and capital blowouts. Build it and we will make it run, kicking the can down the road and borrowing operating and design concepts incorrectly on technological issues, or nine year olds on a sugar high making financial decisions are not philosophies by which to succeed with Greenfield Projects.

Jan 1, 2014

By Georges Houlachi, Akram Alfantazi, Maysam Mohammadi

Manganese ions in zinc electrowinning electrolytes form a protective MnO2 layer that ultimately decreases Pb contamination in the zinc product. In this study, the effect of dissolved Mn2+ on the electrochemical performance of Pb, Pb-Ca and composite Pb-MnO2 anodes was investigated. The properties of the MnO2 layer formed on these anodes were studied and compared. Potentiodynamic polarization and cyclic voltammetry experiments were performed in 180 g L-1 sulphuric acid to study the electrochemical reactions occurring on the anodes. The anodes were subjected to galvanostatic polarization at 50 mA cm-2. The morphology and uniformity of the MnO2 layer on the anodes were examined using scanning electron microscopy (SEM). Experimental results revealed that the MnO2 layer formed on the composite anode was more compact and uniform compared to that formed on the Pb and Pb-Ca anode. It was also observed that the cell mud formation rate, and consequently manganese ions consumption, depended on the anode type. Although initial formation of the MnO2 layer decreased the oxygen evolution overpotential, its growth might negatively affect electrocatalytic activity of the anodes.

Jan 1, 2014

By K. van Netten, T. P. Ernst

"Froth flotation has been used successfully for about a century in the beneficiation of both coal and mineral particles. With the on-going trend towards lower feed grades, however, there is a need to transform this technology in ways that can deliver ultrafast separations, with strong selectivity, and recovery, covering a broader size range. It should be recognised that the hydrophobic effect, with its highly selective and long-range interactions, will most likely underpin any new technology. We identified the separation of the concentrate from the tailings as the rate determining step of conventional flotation technology. This limitation was then addressed by developing a novel flotation technology, insuring the formation of a concentrate that could be separated more rapidly from the tailings. We introduced a novel binder medium, a highly concentrated water in oil emulsion, to act as the focal point for hydrophobic adhesion, effectively replacing the air bubbles used in conventional flotation. The hydrophobic particles adhere to and become embedded within the binder, forming saturated agglomerates that float upwards. Moreover, by forming these large and resilient agglomerates, the product can be quickly dewatered over a screen and separated almost immediately from the tailings. Remarkably, this new binder permits residence times in the order of a few seconds under batch conditions. This paper examines the performance of the technology as a function of the oil wt% added to the slurry. The paper also examines the performance of the technology as a function of the particle size, showing a decline as the particle size exceeds 0.50 mm.INTRODUCTIONFroth flotation involves the collision and adhesion of hydrophobic particles to rising air bubbles, the carrying of those particles from the bubbly-pulp zone into a froth zone, and subsequent drainage and migration of the pulp to achieve the final concentrate (Wills, 2006). Within a Jameson Cell the feed slurry and air bubbles are brought into intense contact within the active area of the downcomer, achieving rapid kinetics of hydrophobic particle adhesion to the air bubbles (Harbort et al., 1994). However, once the bubble laden product and tailings emerge from the downcomer there is the need for separation of the concentrate from the tailings, an inherently slower process. In other devices such as mechanical cells the initial kinetics of particle adhesion are far slower, relying on the turbulent eddies throughout the cell, while in a column the kinetics rely upon an even slower process of bubble interception with suspended and settling particles (Gorain, 2007). However, in all cases the driving force for segregating the bubbles from the tailings, and the drainage of the froth are inherently the same. We do note, however, recent advances by Galvin and co-workers in achieving so-called Fast Flotation, utilizing a system of inclined channels to dramatically increase the segregation rate of bubbles from the tailings, permitting much higher gas and feed fluxes to be applied, achieving up to a ten-fold throughput advantage (Dickinson et al., 2014). Any further improvement within the existing flotation paradigm would require the introduction of centrifugal forces, but this would also require the formation of much finer bubbles than is typically used given the tendency of relatively large bubbles to reach a limiting slip velocity due to deformations and increased drag. Across all flotation devices we argue the rate determining step remains the segregation of the bubbles from the tailings."

Jan 1, 2016

By L. M. Guayacán-Carrillo, G. Armand, A. Noiret, D. Seyedi, S. Ghabezloo, J. Sulem

"The main purpose of this paper is to analyze the convergence measurements in a drift excavated in the Callovo-Oxfordian claystone. The drift axis is in the direction of the major principal horizontal stress whereas the stress state is quasi-isotropic in the drift’s section. The initial geometry of the drift being circular, the anisotropic character of the deformation is taken into account by assuming that the drift shape evolves in an elliptical shape. The convergence measurement data on six different points around the drift are analyzed to identify the main axes of the deformation ellipse, following the methodology proposed by Vu et al. (2013, Rock Mech Rock Eng, 46, 231-246). Then, using the semi-empirical law proposed by Sulem et al. (1987, Int J Rock Mech Min Sci, 24, 145–154), the convergence evolution is fitted independently for each axis of the ellipse. This method permits to distinguish two effects: the face advance effect and the time-dependent behavior of the ground. The results for the two directions of the ellipse axes show very close values for the parameters describing the time-dependent properties of the ground, the distance of influence of the face, and the extension of the decompressed zone around the gallery. Such model can provide valuable insights for predictions of the convergence evolution in the long-term. INTRODUCTIONDeep disposal of radioactive waste has been studied in France for more than two decades. The French National Radioactive Waste Management Agency (Andra) began in 2000 the construction of an Underground Research Laboratory (URL) with the main goal of demonstrating the feasibility of a geological repository in Callovo-Oxfordian claystone. Several research programs have taken place to improve the knowledge of the rock properties and its response to the excavation progress. The optimization of supports design for long-term behavior is an important point to develop. A network of experimental drifts has been constructed with variations on: excavation method, structure geometry, supports system and orientations with respect to in-situ principal stresses’ directions. In each drift different sections have been instrumented to monitor the convergence evolution and the rock deformation. Continuous monitoring of the excavated zone around the drifts revealed the development of a fractured zone (extensional and shear fractures) induced by the excavation. The extent of this fractured zone depends on both the drift orientation and the in-situ stress field (Armand et al., 2014). Indeed, the fractures distribution has an important influence on the convergence of the drifts."

Jan 1, 2015

By G. Szilvay, P. Kinnunen, J. Salminen, V. Miettinen, O. Salmi, J. Mäkinen

This paper demonstrates experimental studies on bioprocessing of different waste streams. In Part I of this paper three tailings from mining industry were bioleached with mixed acidophilic culture in order to solubilize valuable metals, like copper, nickel, zinc and manganese to leaching liquor. Bioleaching resulted in > 70 %, > 85 %, 100 % and > 70 % leaching yields for Cu, Ni, Zn and Mn, respectively. However, contaminants like arsenic and chromium were not leached efficiently and they will cause challenges in residual solids and sometimes also in metal recovery from leaching liquor. Bioleaching resulted in 99 % leaching yield for copper. Part II demonstrates mine water treatment and also gold recovery from process liquids with biosorption method. The novelty of biosorption was finding that certain fungal species were able to be cultivated to self-immobilized systems, which are easier to operate than traditional suspended biomass methods. Biosorption resulted in more than 90 % removal for all contaminants, but was also seen to be gold selective.

Jan 1, 2014

By M. Bigdeli Karimi

In this study, the effect of strain level and holding time in semisolid temperature range via SIMA process on AS21 Mg alloy was investigated. Some cylindrical samples of this alloy with 1cm in height and 2.5cm in diameter (H/D=0.4) were compressed to 10%, 20%, 30% and 40% at 300-C. Then, the samples were reheated in semisolid temperature range at 614°C for various times. The results of optical microscopy and image analysis showed that with increasing of strain and holding time, dendritic structure changed to equi-axed structure, gradually. Also, the best conditions to obtain good globular structure were achieved. Furthermore, it was seen that after compression and reheating, Mg2Si intermetallics with Chinese script morphology converted to dispersed-fine particles which were distributed into the ci-Mg grains.

Jan 1, 2007

By William James Kempson

This paper discusses ore handling systems in shafts. These are considered from the loading facility at shaft bottom all the way through to the discharge mechanism in the headframe. These systems will be discussed from the following perspective: i. Intrinsic safety of the systems ii. The efficacy of the systems to perform consistently iii. The maintainability of the systems iv. Overall system cycle times Particular emphasis is placed on the following specific areas: 1. The Shaft Bottom Loading Facilities The various shaft loading systems currently in use are discussed, the selection parameters surrounding these are quantified and the specific selection criteria are outlined. 2. The Various Skip Configurations In this section the various skip configurations in use around the world will be described and the specific design details associated with these will be highlighted. The advantages and disadvantages of these systems will be compared and the overall efficacy of these will be discussed. 3. The effect of the loading and skip configurations on the Load Cycle Times. The overall cycle time which can be achieved by a shaft system is strongly dependant by the speed and efficiency with which the ore can be loaded and transported out of the mine. The potential of the various systems to be optimized will be discussed. The emphasis of this paper is to highlight the lessons which have been learned with respect to ore transport system design and provide a common basis against which these can be compared in future applications.

May 1, 2013

By Hasini Wijayaratne

Anode cover material, a mixture of crushed electrolyte and alumina, is a crucial part of an aluminium reduction cell because of its important role in maintaining overall heat balance. However, until recently little attention has been given to understanding or controlling its composition and quality. The thermal conductivity of anode cover material determines the extent of the heat loss from the top of the cell. This will change as a function of the granulometry and composition of the applied cover as well as over time as the cover material consolidates on top of the cell. The ability to measure or predict the thermal conductivity of fresh and ageing cover is an important tool for managing cell heat balance. Recent studies have shown that granulometry or more correctly, voidage is likely to be the predominant determinant of thermal conductivity of anode cover materials. We have developed equipment to measure the thermal conductivity of granular cover material and tested the relative importance of composition (ratio of alumina to crushed electrolyte) and granulometry/voidage on cover thermal conductivity. In general, our results confirm that granulometry is the dominating factor. Generally, high voidages contribute to lowering the thermal conductivity especially when particles are mostly fine. However the relationships between granulometry, voidage and thermal conductivity are complex due to the varying nature of heat transfer between particles. Aging of granular cover material occur during cell operation forming a consolidated crust due to exposure to heat and fumes over time. Structure and thermal behaviour of this consolidated crust is also important in understanding the overall properties of cover. This paper presents the outcomes of laboratory studies conducted in order to understand the thermochemical behaviour of anode cover material and in particular, the role of fines in anode covers mixtures.

Jan 1, 2011

By J. E. Carrasco, J. D. Stinnette, R. A. Alvarez

"Chuquicamata Underground Mine is one of the main projects for the Chilean government copper company (CODELCO). Underground mine project has been under construction since 2013 and presents a solution for the lower production levels of the open pit and prolongs the life of the mine for the next 40 years. Currently, around 2000 workers operate in the mine daily. Dozens of trucks and heavy machines drives through all main routes and access in the mine. As a mine under construction not all the infrastructure necessary to operate safely in the mine has been completed. Risk of a truck or fixed facility fire is always a challenge to keep under control. One important part of fire simulation relays on what we can do prevent a fire and what can be done with the existing infrastructure to control a declared fire and start evacuation plans. This study has been made as a feasible emergency plan to implement, in this case, of a mine under construction, were limited resources are available. Several fire scenarios have been made to support all the emergency plan strategy and a detailed step by step procedure indicates what the elements of a fire emergency plan and risk analysis are.INTRODUCTIONThe main objective of this study is to describe the importance of fire risk analyses (FRAs) and different methods to be used before commencing fire simulation and methodology steps utilized for a fire emergency plan strategy (EPS) at the Chuquicamata underground mine. It also describes how to classify zones which are going to be affected by fumes and gases propagation derived from the exact location of a fire event. Fire simulation study is helpful to determine the impact on a ventilation system with the main purpose of providing relevant information to complement emergency plans and stablished control techniques in ventilation design and its operation. Most fire simulation studies only concentrates in simulation techniques on itself. But what is the next following step in developing an emergency plan? How can we evaluate, classify and treat risky areas? This study is focused mainly in the phases before and after a fire simulation process. Phases corresponds to a good FRA and how output data can be used for an EPS."

Jan 1, 2019

By S. Spigarelli

The creep response of the AE44 magnesium alloy was studied by means of constant load creep tests carried out at 125 and 150°C, obtaining that at the latter temperature the minimum creep rate observed under an applied stress of 100 MPa was two orders of magnitude lower in the investigated alloy than in AM50. The minimum creep rate dependence on applied stress was described by a conventional power-law, e = Aon , where A was a temperature dependent parameter and n was the stress exponent, resulting in a n value close to 30, i.e. by far larger than those observed in commercial alloys with similar Al content. This large difference in creep response was attributed to the precipitation of rare earths (RE) intermetallic phases distributed in the grain boundary zone in form of an almost continuous network of dispersoids that were observed by means of scanning electron microscopy.

Jan 1, 2006

By C. Groccia

As the search for new ore bodies drives mines to be developed at greater depths, the associated high stress environments present challenges for rock support design. Excavations in highly stressed brittle rock are often subject to large volume increases due to rock failure, a phenomenon known as rock mass bulking, which can result in significant wall convergence. Support systems need to be designed to minimize the amount of bulking and to accommodate large wall convergences. In order to design such a support system, empirical guidelines are often used to predict the amount of bulking. However, the empirical guidelines that are currently available are based on a limited number of case studies and consider few input parameters, which may result in an inaccurate bulking assessment. This paper describes methods of collecting quantitative field data at Creighton mine in Canada to better understand rock mass bulking and to further develop the empirical guidelines for bulking assessment for tunnels in highly stressed grounds. Measuring

Aug 1, 2013

By He Zhexiang

The settlement properties of tailings modified by flocculants were investigated at the Shizhuyuan Mine, with the aims to screen for the most effective flocculants and the optimum dosage rates for tailings sedimentation. The settlement rate was used as the indicator of effective tailings sedimentation. Calcareousness and three polyacrylamides (F1, F2 and F3) were selected for settlement property evaluation. The results proved that sole use of calcareousness or any of the polyacrylamides had no apparent effect on the tailings sedimentation, while a remarkable acceleration of sedimentation could be observed with a combined addition of calcareousness and polyacrylamides, among which the addition of polyacrylamide F2 together with calcareousness is the most effective. The optimum dosage rate of F2 and calcareousness is 50g/t and 3kg/t respectively. The density of tailings slurry has an effect on sedimentation at the early settlement stage, with lower density generating quicker initial settlement.

May 1, 2007

By D. Chadwick, J. W. Matousek

Between 1860 and 1890 -- from the time of the American Civil War to the last decade of the 19th Century -- nickel production in North America was dominated (even monopolized) by the output of the industrial complex of the Gap Nickel Mine near Lancaster, Pennsylvania and the American Nickel Works in Camden, New Jersey. In some years, from one sixth to one third of the world's metallic nickel supply came from this enterprise. Mining and smelting were conducted at Lancaster; a matte of high iron content was shipped to Camden for pyrometallurgical and hydrometallurgical refining to produce nickel metal, copper sulfate, and cobalt oxide. The high purity nickel product was rolled into sheet for marketing, primarily for coinage, as nickel had few other uses at that time. The undertaking experienced all of the problems that face the mining and metallurgical industries of today: declining reserves, high labor and fuel costs, high transportation costs, fluctuating demand and prices, pollution concerns, and foreign competition. The technical features of the geology; the mining, smelting, and refining operations; and some of the economic aspects are assessed. The view is taken from that of the present time -- seeking those lessons from history that we are supposed to learn or face the prospect of repeating the mistakes of the past.

Jan 1, 2005

By N. Dahata

B206 aluminum?copper alloy has a potential for wider use in the automotive industry due to its light weight and relatively superior mechanical properties as compared to aluminum-silicon alloys. The possibility of casting this alloy via Lost Foam Casting (LFC) has not been investigated in detail. Therefore, the effects of foam types (T170B standard untreated EPS and T175-brominated EPS), coating types (Styro Shield 5553 and Styro Shield 5554), copper level (4.5 wt % and 5.0 wt %) and titanium levels (0.5 wt % and 0.25 wt %) were related to fillability, microstructure and microporosity. The metal velocity in T175 EPS pattern was higher than that in T170B EPS pattern. For T175 EPS pattern, the total solidification time was 3% higher and the loss of temperature for decomposition of EPS was lower than those in the case of T170B EPS pattern. The grain size, porosity level and maximum pore size were quantified using Light Optical Microscopy (LOM) and image analysis. The casting with T175 EPS pattern showed larger grain size relative to that with T170B EPS pattern. The porosity level and the maximum pore size decreased significantly when the titanium level was increased from 0.05 wt % to 0.25 wt %.

Jan 1, 2007

By J. A. Maritz

"The Hedley and Grant formulation for pillar strength has been widely adopted by the South Africa hard rock mining industry. Today, some forty year later, this formula still provides the foundation for pillar strength calculations when designing for stability and utilising pillars in mine layouts. Various mine specific back analyses were conducted to adjust the equation parameters based on underground observations of failed pillars and comparing to the pillar stresses calculated using numerical models. In all these instances, the influence of shear stresses was ignored. The key to more representative pillar strength estimation is a better understanding of the pillar loading environment.In this paper, special mining cases are evaluated and the existence of shear stresses on the pillar loading environment is illustrated. By revisiting some back analysis data for optimisation of the equation parameters, recommendations were made in respect of the influence of the shear stress component and on how this should be considered in determining the pillar strength.INTRODUCTIONCommon practice on flat dipping, shallow and intermediate depth ore deposits in the South African hard rock and coal mining industry is to exploit the mineral resource using a room-and-pillar layout. The design methodology is mainly based on a Factor of Safety (FoS) approach, where the strength of the pillar is compared to the effective load on the pillar. In these environments, FoS values of 1.6 are applied as it was found to correspond to a probability of failure in coal mines of 0.001. As discussed by Ryder and Jager (2002) page 279: “For lack of anything else more substantial, the figure of 1.6 is generally used in hard rock pillar design in South Africa”. Dependant on the designed purpose of the pillar, the FoS might be selected as high as 2.0 where long term stability is required. The factors directly influencing the FoS include the pillar height (which is linked to the mining height), effective pillar width, a rock-strength factor and extraction ratio."

Jan 1, 2015

By Guichao Wang, Geoffrey M. Evans, Graeme J. Jameson

"In this paper we present a new method for studying the detachment of particles from bubbles in a rotating turbulent eddy. The eddy is formed in a wall cavity in a two-dimensional water tunnel with transparent walls. When water flows through the tunnel, a vortical flow field develops in the cavity. The properties of the eddy can be modulated by changing the free-stream velocity of the water in the tunnel. Bubbles are pre-loaded with one or more particles in a fluidized bed flotation device located beneath the vortex cavity. Loaded bubbles are released one at a time into the cavity, and the motion of the bubbleparticle aggregate is studied using a high-speed video camera. The diameters of the particles and the bubbles, and the number of particles initially attached to the bubble, can be varied. The trajectories taken by the bubbles are quite complicated. In some cases, the bubble moves to the centre of the eddy, and particles rotate around its axis. If the rotational speed is sufficient, particles may detach due to centrifugal force. However, other modes were observed, including inertial detachment due to rapid changes in direction of the surface of the bubble, because of changes in trajectory of the bubble as a whole, or because of pulsations and oscillations of the bubble surface. Clusters of bubbles held together by particles were seen to form and reform. In the traditional explanation for the detachment of particles in flotation cells, it is assumed that particles detach from bubbles rotating in an eddy due to centrifugal force (Schulze, 1977). Although the conditions assumed in Schulze's theory may exist, it is only one of a range of phenomena that can lead to the detachment of particles from bubbles in a turbulent vortex.INTRODUCTIONThe recovery of particles by flotation methods is dependent on the particle size. The recovery in the existing flotation machines reaches a peak for particle size, typically in the range of 20 to 100 µm. This size range varies as a function of the particle’s properties (type and composites). For coarser particles, the recovery drops very quickly (Gaudin, Groh & Henderson, 1931; Jowett, 1980). If the upper size limit can be increased for flotation, dramatic savings in the grinding energy can be achieved."

Jan 1, 2016

By Waldbillig. D.

A baseline of the poisoning effect of hydrogen sulfide (H2S) fuel impurities on solid oxide fuel cell (SOFC) anodes was developed using polarization testing. After the baseline behaviour was characterized, tests to study the effect of various H2S concentrations on the rate and amount of cell voltage degradation and recovery were performed. Attempts were made to improve the rate and amount of recovery by various methods. Testing was very reproducible, but significant electrochemical performance degradation was seen after all H2S poisoning tests even at an H2S concentration of 0.1 ppm. Degradation is initially quite rapid, but after a period of time the rate of degradation levels off. After poisoning was complete, the H2S flow was stopped and the cells were allowed to recover. Some recovery was seen after poisoning, but cell performance was never fully recovered.

Jan 1, 2005

By David C. Cook

The milling complex, situated just east of the Cassiar townsite, receives raw ore from the tramline and processes it into 105,000 tons per year of milled asbestos fibre. The ore is passed through a concentrator, where a barren rock fraction is removed. The concentrated ore, representing 70% of the feed, is dried, stored and then milled into nine separate fibre classifications. The finished product is packaged into 100-lb bags and loaded into trucks in one-ton units. New air-handling facilities were added in 1977to provide additional air for environmental control.

Jan 1, 1978

By Seher Ata

"Virtual reality, a three-dimensional computer generated environment, has become recognized delivery system for many forms of education. This article describes the application of virtual reality to mineral processing education. An interactive mineral processing visualisation module has been developed at University of New South Wales (UNSW), Australia. The module provides students with an overview of a base metal concentrator, details about each stage of the process, as well as revealing how the mined ore progresses from stage to stage. The module also involves developing a number of instructional based plant layouts and flowsheets in the virtual environment that are intended to assist the user in understanding the essential components of the base metal concentrator.INTRODUCTIONVirtual Reality (VR) is the creation of an artificial environment that is experienced through sights and sounds provided by a computer (Squelch, 2001). The simulated environment is achieved through a host of technologies such as three-dimensional graphics, audio feedback and special peripheral devices to produce interactive environments.VR has been used in diverse fields including medicine (Riener & Harders, 2012), entertainment (Hsu, 2011), military (Manojlovich, Prasithsangaree, Hughes, Chen, & Lewis, 2003), manufacturing (Zimmermann, 2008; Jiang, 2011), and chemical processing (Schofield, Lester, & Wilson 2005; Squires, Andersen, Reklaitis, Jayakumar, & Carmichael, 2014). VR is also becoming recognized delivery system for many forms of education, including engineering education (Bell & Fogler, 1996; Bell & Scott, 1998; Shin, 2002). For example, virtual laboratories have been designed and developed to teach students fundemental features of the heterogeneous catalytic mechanisms and absorption columns (Bell & Fogler, 1995), the multi-phase and multi-component blast furnace iron making process (Babich & Senk, 2009) and to guide students to identify various safety measures while working in real laboratory (Bell & Fogler, 1996)."

Jan 1, 2016

By S. Nakamura, K. Fujiwara, S. Hirosawa, S. Tsukamoto, Y. Koshino, Y. Aruga

"In this study, hardness test, differential scanning calorimetry(DSC)and transmission electron micros copy were carried out to investigate the age-hardening behavior of Al-Mg-Si alloy with a Mg+Si concentration of 1.5mass%, and a Mg/Si ratio of 1.0. Pre-aging treatment was conducted for the solution-treated and then water-quenched specimen at 100, 80, 60, 40, 20 (natural aging), 0 and -20°C for 20min or 5h, followed by artificial aging at 170°C for 20min. It was found that when pre-aging time is prolonged from 20min to 5h, the bake-hardening response is deteriorated irrespective of the pre-aging temperature. In particular, the specimens subjected to pre-aging at 20-40°C for 5 h hardly increased the hardness with the subsequent artificial aging. From the results of DSC measurement, it was suggested that as pre-aging temperature is lowered, the amount of solute clusters formed during pre-aging, i.e. Mg-Si clusters and Si-rich clusters, is decreased, but the ratio of Si-rich clusters is increased, resulting in the deteriorated bake-hardening response.INTRODUCTIONIn recent years, Al-Mg-Si alloys have been widely used forautomotive body panels due to their excellent characteristics such as high strength-to-weight ratio and good formability. Their strength is increased not only by artificial aging during paint-bake treatment; i.e. “bake-hardening”, but also when kept at room temperature(RT);i.e. “natural aging”, in association with the suppressed bake-hardening response. Such a “negative effect of two-step aging” has been a serious problem because Al-Mg-Si alloy coils are unavoidably maintained at RT in the manufacturing process of body panels; e.g. shipping and storage. However, it was reported that pre-aging above 70°C before the two-step aging can restore the bake-hardening response, and such an improvement is related to the formation of solute clusters(Sato, 2006; Abidet al., 2010; Takaki et al., 2014; Zandbergen et al., 2015). From the comprehensive analysis by three-dimensional atom probe (Aruga et al., 2014 and 2015), it is believed that Mg-Si clusters formed during pre-aging transform into the strengtheningß"" phase, whereas Si-rich clusters formed during pre-aging act as a detrimental precursor of ß""phase. In this study, it was aimed to investigate the effect of pre-aging conditions, especially pre-aging temperature and time, on the formation of solute clusters during pre-aging, in order to elucidate the mechanism of the age-hardening behavior of an Al-Mg-Si alloy."

Jan 1, 2018