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By Tamas Kekesi, Gergo Rimaszeki, Tibor Kulcsar

The efficient purification of soldering waste material can be achieved in a single operational step by the electrolytic refining in pure hydrochloric acid - tin-chloride media. The complex formation of the ionic species may offer a beneficial level of natural inhibition. Using the PCR (periodic current reversal) technology, is efficient in affecting the morphology of the cathodic deposit. In order to optimize the process, the investigation of the solution stability and the electrode reactions is essential. The natural tendency of the Sn(II) oxidation and precipitation can be overcome by properly controlling the concentration of the main components and the ratio of Sn(IV)/Sn(II) in the electrolyte solution. Polarization curves were obtained for different concentrations tin and hydrochloric acid. Conclusions referring to the electrode reaction were derived from the overvoltage - current plots. The morphology of the deposit can be correlated with the exchange current density, also determined from the polarization curves. The cathodic current efficiency and the morphology of deposited metal are affected by the distribution of tin species and the principal electrolysis parameters.

Jan 1, 2011

By J. Sadaki, G. Dodbiba, S. Murakami, T. Fujita, S. Matsuo, H. Ono, K. Okaya

Printed circuit boards (PCBs) from discarded personal computer (PC) and household appliances were crushed by mechanical crushing or water explosion to remove mounted parts. More parts were stripped from PCB for PC composed of epoxy resin than from PCB for household appliance composed of phenol resin. In an attempt to raise the copper grade of PCB by removing other components, a carbonization treatment was investigated. The crushed PCB without surface-mounted parts was carbonized under a nitrogen atmosphere at 1073K. After screening, the char was classified by size into oversized pieces, undersized pieces and powder. The copper foil and glass fiber pieces were liberated and collected in undersized fraction. The copper foil was liberated easily from glass fiber by stamping treatment. On the other hand, tantalum capacitors were collected from mounted parts. The tantalum-sintered bodies were separated from molded resins by heat treatment at 723 to 773K in air atmosphere and screening of 0.5mm. Silica was removed and 70% of tantalum grade was obtained after more than 823K heating and separation.

Jan 1, 2011

By P. Czaja

The paper presents a patented and copyright protected concept of constructing a shaft lining that goes through rock masses having strong rheological properties and being susceptible to leaching. In the case of salt layers, especially at significant depths (over 900 m) the relative convergence of the heading contour may amount to 40 ?/year. That results in the fact that any other method of securing the shaft lining, e.g. by making it flexible, will not be sufficient to ensure the stability of the shaft reinforcement geometry. In the new shaft lining concept the excessive rock creep into the outbreak inside the shaft diameter will be removed by local and controlled leaching of the shaft cheeks by means of fresh water directed through a porous medium at the contact layer behind the watertight tubing lining. The paper presents the structure of such a lining and an outline of the construction technology. In order to implement such a lining, a typical tubing will be applied. Separate design and manufacturing will be required for the technological rings used to control the leaching process behind the lining.

Aug 1, 2013

By Thomas Hauquin, Olivier Deck, Yann Gunzburger

"In this study, 2D numerical modeling of a room-and-pillar mine is conducted along with the calculation of all terms of the mechanical energy balance. Simulations of different geometrical and geomechanical configurations are performed in order to investigate the conditions that favor a high seismic energy release (instability) during the excavation (removal) of one single pillar. At first, classical stressstrain simulations enable us to estimate the elastic and quasi-static response of the mine. Then, owing to the implementation of new functions in the modeling code, the seismic energy released when the pillar is removed is calculated. The obtained values are found to be in agreement with those calculated analytically using a modified energy balance based on the works by Cook (1967) and Salamon (1984).It is shown that the mine’s proneness to release large amounts of seismic energy, after sudden removal of one single pillar, mainly depends on three parameters: the initial extraction ratio of the mine, the depth of the exploited seam and the Young’s modulus of the surrounding rock mass compared to that of the ore. Moreover, it is pointed out that the magnitude of the seismic energy can be greater than that of the stored elastic energy, meaning that the dynamic (seismic) transient stresses should not be neglected when compared to the quasi-static stresses, particularly when trying to prevent the risk of rockburst and collapse in underground mines."

Jan 1, 2015

By J. W. Reynolds

Use of crushed waste rock recovered by sink-float separation from normal ore production for backfill is an established procedure at Commco's Sulhvan mme, Kimberley, British Columbia. Need for a safe method of placement in voids which were difficult to reach by gravity methods led to a co-operative venture with Radmark Engineering Ltd. in the development of a workable pneumatic transportation system for rock material. This paper reviews work done to date in a current program, and includes comments on the nature of the fill so placed, options for cementing such fill, implications for other aspects of mining and references to other applications of the system by other organizations who exchanged experiences with the Sullivan mine staff during the five-year period reviewed.

Jan 1, 1972

By P. Van Marcke, X. Sillen, G. J. Chen, I. Troullinos, A. Dizier, J. Leysens, X. L. Li, J. Verstricht

"In Belgium, Boom Clay is considered as one of the potential host formations for the disposal of the High Level radioactive Waste (HLW). The URL HADES at 223 m depth at Mol site was constructed in order to study the feasibility of HLW disposal in Boom Clay. Since 1995, the URL R&D programme has focused on large scale demonstration tests like the PRACLAY experiment.The PRACLAY in-situ experiments include a set of three tests: The gallery and crossing test, PRACLAY Heater test and PRACLAY seal test. The main aim of the Heater test is to study at a large scale the thermal impact of a HLW repository on the host rock. The test is housed in the PRACLAY gallery. A hydraulic seal, made of compacted swelling and low permeable bentonite annular ring was installed at the intersection between the heated and the non-heated part of the gallery. The primary objective of the seal is to provide undrained hydraulic boundary conditions for the Heater Test.The PRACLAY gallery was constructed in 2007 and the hydraulic seal was installed in 2010. The bentonite is hydrated by natural and artificial process. The swelling, total pressure and pore pressure of the bentonite are continuously measured and analysed by numerical simulations to get a better understanding of this hydration processes. The performance of the seal is tested systematically by means of gas injection breakthrough tests and permeability tests at interface bentonite / Boom Clay and in the Boom Clay around the seal.The PRACLAY Heater will be turned on at the end of Oct. 2014, since a sufficient seal swelling has been attained to fulfill its role for the PRACLAY Heater test. This paper will focus on the PRACLAY Seal test: How we understand the process behind the hydration of the bentonite and how we test the performance of the bentonite seal."

Jan 1, 2015

By David Penswick

Despite anecdotal evidence to the contrary, the mining industry is not in decline. Rather, the world?s largest mining companies are among the most consistently profitable companies in any industry. In many cases, profitable mining companies have been built around a few large scale, long life mines. These criteria for success ? size and long life ? have led to the current preference for deposits that can be exploited using open pit methods. However, developments in the science of block caving have resulted in this mining method achieving costs and productivities that are competitive with the largest open pits, while achieving widespread applicability. One implication of the low costs and widespread applicability of block caving is that some current open pits are possibly too deep.

May 1, 2003

By A. Bezama

For over a decade European countries have addressed contaminated sites by developing technologies for managing both polluted soil and groundwater. This development has not only been driven by health and environmental aspects, but also because of economic pressures, as the remediation and redevelopment of derelict areas can be a meaningful alternative to undeveloped areas for the establishment of new industrial, recreational, housing and service locations. In most developing countries, however, the subject of contaminated sites is a new environmental issue that authorities have recently started to deal with. Among these countries, Chile has just started to prepare the country's legal context as well as to foster the formation of research and investigation groups that will deal with the exploration, investigation and management of contaminated sites. That requires a comprehensive technical, scientific and legal support in this stage. Goal of this article is to present the state-of-the-art technologies for site remediation currently applied in industrialized countries, in order to identify the most interesting approaches that can be implemented within the Chilean situation, especially considering the influence of the copper mining industry on the soil and groundwater quality of the environment surrounding their production facilities.

Jan 1, 2007

By László Guczi1

Nanosize model gold particles with varying size were fabricated by deposition of a 10 nm thick gold film onto SiO2/Si(100) substrate by electron beam evaporation followed by modification using low energy Ar+ ion bombardment. The change in particle size were monitored by the Au 5d valence band states determined by ultraviolet photoelectron spectroscopy (UPS). The gold/iron oxide interface was studied by iron oxide deposition on gold. It was found that the energy profile of Au 5d valence band states are strongly redistributed with decreasing the gold particle size mostly affecting at the lowest and at the highest binding energies. The size effect in the UPS spectra can be interpreted by the energy redistribution rather, than by narrowing the 5d states. The iron oxide deposition increases the catalytic activity in CO oxidation whether it is on gold nanoparticles or on a continuous 80 nm thick gold film. The activity enhancement is significantly larger in case of gold nanoparticles. The interface interaction is operative in enlargement of the catalytic activity even if gold particles are not exposed to the surface, but they are located below the iron oxide layer.

Oct 1, 2003

By J. Lee, K. B. Min, J. Rutqvist

Shear slip of fractures in fractured rock masses is a critical issue for many geological engineering applications, such as the design of underground nuclear waste repositories, enhanced geothermal systems (EGS), and geosequestration of CO2. This paper presents new development of the TOUGH-UDEC simulator for analysis of coupled thermal-hydraulic-mechanical (THM) processes in fractured porous media. As an alternative to developing a single coupled THM code in discontinuum, two existing wellestablished codes, namely TOUGH2 and UDEC, are coupled to cover coupled THM analysis of multiphase fluid flow, heat transfer, and deformation in fractured porous media. TOUGH2 is widely used for modeling heat transfer and multiphase, multicomponent fluid flow, and UDEC is a well-known discrete element code for rock mechanics, which have been verified and used by many groups all over the world. Although a sequential coupling of two codes is less efficient than having a single code in principal, a big advantage with coupling of TOUGH2 and UDEC is that both codes are well tested and widely applied in their respective fields. When linking two codes, the coupled equations cannot be solved simultaneously; they should be solved sequentially, with coupling parameters passed to each equation at specific intervals. After solving thermal-hydraulic equations through the TOUGH2 model, pressure (P) and temperature (T) information is delivered to UDEC model. Pressure information is directly stored at the center of each UDEC zone and domain, however, temperature information is interpolated from zone-centers to the corners nodes. After solving the mechanical equation through the UDEC model—considering new pressure and temperature—calculated fracture apertures are converted to equivalent permeability and porosity for TOUGH2 flow analysis. The solution was calculated by iteratively following an explicit sequence for numerical efficiency. Verification examples are presented to demonstrate the capabilities of the coupled TOUGH-UDEC simulator.

Jan 1, 2015

By Nabeel Khan

Annual oil production from the Canadian Oil Sands in Northern Alberta has been rising for several decades, and more ore and overburden are excavated each year from an increasing number of open pit mines. Overburden meeting certain specifications will be used to dam tailings and fill open pits, but the remaining material must be stored in overburden storage structures (OBSS). Well-designed overburden storage structures are more stable and cost less in the short- and long-term. The purpose of this paper is to explore OBSS designs that will be stable yet economical in the short- and long-term. The geological background of the site is briefly discussed, including the effect of each of the main geologic layers (recently deposited till and muskeg, Clearwater Formation clay shales, McMurray Formation oil sands, and the Devonian limestone) on the slope stability of the OBSS. Cost is considered in the analysis when balancing between minimizing costs (steeper slopes) and acceptable factors of safety (flatter slopes), all the while considering the financial consequences of failure. Potential failure planes are identified and probabilistic analysis is conducted on the critical failure surface. The variations in the factor of safety caused by varying pore water pressure, friction angle, and cohesion, are plotted and discussed.

Jun 1, 2012

By Y. Guglielmi, C. Gout, P. Henry, P. Dick

The key questions about fault reactivation in shales concern the potential enhanced fluid displacement through a previously low-permeability aseismic shale formation. Here we selected a critically-stressed fault cross-cutting the underground research facility of Tournemire (France) which is located in Toarcian shales. Several inclined boreholes were drilled across the 8.5 m thick fault zone characterized by a fractured damage zone (FDZ) and a central 2.4 m thick complex core (FC) made of multiple shear bands with gouge intercalated with highly fractured lenses. The fault was pressurized using a straddle packer system defining a 2.4m long injection chamber normal to the fault surface. Three fault zone intervals were tested, two in the fault damage zone and one in the fault core. A three-dimensional displacement sensor set in the chamber allowed continuous synchronous coupled monitoring of fault movements, injection pressure and flow rate. An anticlockwise 0.22-to-0.05 mm fault slip was captured associated with a 10-to-100 hydraulic aperture increase of the fault. Preliminary analyses of the experiments show that leakage in the fault zone is controlled by strength and stress magnitude contrasts between the fault core and the fault damage zone. Fault damage zone discontinuities display a much higher peak static friction angle than the fault core shear zones, respectively of 34 and 22° that could be related to complex interactions between healing and sealing processes. Fault core leakage is much more dependent on strain than on effective stress variations. Discontinuous, pulse-like leakage, develops following complex failure processes that may simultaneously take place in the gouge zones and along the large pre-existing discontinuities. Such results may be of importance in evaluating fault seal integrity in oil and gas exploration, production or CO2 storage or underground excavations monitoring.

Jan 1, 2015

By M. Sokoto, H. Hata, K. Nishina, K. Haiki

Fluoride ions in zinc electrolyte cause corrosion to aluminum cathode plates at zinc electrowinning process, so we have developed an iron compound as a fluoride ion adsorbent used in zinc sulfate solution. The iron compound is synthesized from FeC13 solution with a small amount of sulfate ion by neutralizing reaction with Na2CO3 solution. The fluoride ions adsorbed on the surface of the iron compound are desorbed in alkaline solution and the iron compound can be reuse as a fluoride ion adsorbent. Moreover, if adsorption capacity of the iron compound decreases, it can be dissolved in HCl solution and re-synthesized.

Jan 1, 2008

By J. B. Rubenstein

This work demonstrates the feasibility of using confocal surface profilometry to measure and characterize wear of graphite anode surfaces. This method was tested using anode samples that were electrolyzed for 24 hours in a laboratory-scale magnesium cell with a high oxide molten salt electrolyte. The oxide produced accelerated wear on anodes designed for low oxide electrolytes. Contour maps, which are effective at displaying non-uniform wear, and total graphite consumption values were generated from the collected surface coordinates. Along with both qualitative and quantitative analysis capabilities, this measurement system was shown to have a fine resolution and a low detection limit.

Jan 1, 2004

By J. J. Benitez

MIBC (methyl-isobuthyl carbinol) was previously shown to enhance significantly sylvite flotation when used at the stage of preparation of amine dispersions. In this paper Atomic Force Microscopy (AFM) is used to study the effect of MIBC on deposition of octadecylamine (ODA) on the surface of mica. The AFM images indicate that amino terminated, and therefore hydrophilic, deposits of ODA are observed on the mica surface in the ODA dispersions free of MIBC. In the presence of MIBC a methyl terminated (hydrophobic) monolayer is obtained on the mica surface. The transition between the monolayer and bilayer phases is due to the presence of MIBC. Experiments carried out in distilled water reproduced the results obtained from the brine. Working in pure water instead of brine simplifies the preparation conditions and the analysis by AFM.

Jan 1, 2006

The original JKMRC AG/SAG mill model was developed over 30 years ago and has been upgraded a number of times since then, with the current published version being the Variable Rates model that is now over 15 years old. Since this model was developed further enhancements have been derived, some of which are applied in-house and some which have yet to be incorporated. The published and the commercially available model in JKSimMet is currently undergoing a comprehensive overhaul with a vastly extended data base for model evolution and validation. Improvements developed within the AMIRA P9 project, in-house development and a number of collaborative projects, are being incorporated into the upgraded model structure. Enhanced capabilities will include: power-based breakage rates scaling; a far wider mill filling range (from 10% to 40%) that exhibits peak in throughput as mill filling increases; higher ball loads; improved pebble discharge function; improved slurry discharge function incorporating important mill design and operational influences; and the new size dependent breakage function. The model will also be able to accommodate some influence of liner design and multi-component ores (blends of hard and soft components). This upgrade is still a work in progress but substantial changes have been made to date. This paper presents some of the new improvements and their influence on the predictive capability of the model.

Jan 1, 2012

By Lev Filippov, Saeed Farrokhpay

"Flotation process has had less success to recover nickel from laterite ores. Nickel in laterite ores is often finely disseminated in various minerals in very fine size. Therefore, fine grinding should be used to liberate nickel containing particles. Particles resulted from fine grinding are often very fine, and recovery of such particles is generally low using conventional flotation methods. One option to overcome this problem is enhancing the particle-bubble interaction by increasing the particle size and forming flocs. Selective flocculation of fine particle can be therefore the key to enhance the flotation performance of low grade laterite ores.INTRODUCTIONThe majority of the world’s nickel resources occur as laterite ores which are complex, low grade and expensive to treat using conventional smelting and high temperature and/or high pressure autoclave methods (Xu et al., 2013). While about 70% of the nickel resources are contained in laterites, only 40% of the world’s nickel production comes from these ores. Researchers have tried to improve the nickel laterite flotation recovery by using a number of feed preparation techniques. For example, in a study on a laterite ore sample from Australia, flotation tests on a narrow sized fraction of 38-75 µm resulted in only a small increase in the nickel content, from 1.0% to 1.4% (Quast et al., 2015a). In fact, no physical separation technique (including flotation) has been able to dramatically upgrade nickel in laterite ores (Quast et al., 2015b). Thus the challenge of processing low grade nickel laterite ores still exists. This paper aims to explore the possibility of applying selective aggregation in pre-concentrating of valuable minerals in nickel laterite ores."

Jan 1, 2016

By D. F. Sangster, P. J. Hood, G. A. Gross

"Some results are presented of an integrated geological and geophysical study of Precambrian magnetite-quartz iron-formation in the Kapiko Iron Range north of Nakina, Ontario. Detailed geological and topographical mapping was carried out in conjunction with detailed geophysical investigations such as vertical magnetic field, vertical magnetic gradient, hammer seismic, horizontal-loop electromagnetic and magnetic susceptibility surveys. In addition, oriented drill cores were obtained for magnetic polarization studies.Vertical-force magnetic anomalies within individual rock units showed a strong positive correlation with topographic relief. Moreover, magnetic intensity was found not to be quantitatively proportional to the magnetite content in the rocks, due to the presence of high remanent magnetization of the magnetite. Also, the remanent polarization direction was sub parallel to the plunge of the fold structure and mineral lineation in associated rocks.Vertical magnetic gradient measurements were found to be more accurate in locating buried contacts between magnetite-quartz iron-formation and country rock than the vertical magnetic force data.An in-situ magnetic susceptibility meter was used to measure the magnetite content of iron-formation, and the measurements were subsequently compared with vertical-force magnetic results.The results of the EM survey were inconclusive; some magnetite-rich zones produced anomalies in the out-of-phase component. whereas others did not. The reasons for such inconsistencies are not yet apparent.Longitudinal seismic wave velocities measured parallel to the bedding in magnetite-quartz iron-formation ranged from 10,600 ft/sec. to 14,500 ft/sec. The seismic velocity appears to increase with an increase in deformation of the rocks."

Jan 1, 1966

By J. D. Jones

The geographic occurrence of economic mineral deposits presents a variety of problems in modern tailings disposal operations. This paper presents case histories in several sectors of the mineral industry as well as the several stages of operations planning required for new designs, system expansion, reactivation of abandoned systems and upgrading to present environmental standards.

Jan 1, 1978

By F. Charette

The paper reviews the requirements of the instrumentation required to monitor mining excavations in a high stress environment, and the development plan to instrument the D-Bolt in such a fashion as to be able to follow the behaviour of the bolts in relationship to the ground movements and support performance. Recent field observations of D-Bolts under static and dynamic conditions are also presented. Also discussed is the assumed mechanical behaviour of the D-Bolt. D-Bolts are used in two (2) Canadian underground mines operating in high stress environments and tested in three (3) other operations.

Jun 1, 2012