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By T. Nesane, S. S. Mnyakeni-Moleele, L. C. Murulana

The effectiveness of two synthesized ionic liquids, 1-(benzyloxy)-1-oxopropan-2-aminium 4-methylbenzenesulfonate (1-BOPAMS) and 4-(benzyloxy)-4-oxobutan-1-aminium 4-methylbenzenesulfonate (4-BOBAMS), were evaluated for mild steel corrosion inhibition in 1.0 M hydro-chloric acid solution, using electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (PDP), and gravimetric techniques. Organic moieties responsible for the adsorption process on mild steel surface were investigated using Fourier transform infrared spectroscopy (FTIR). Gravimetric analysis revealed that the inhibition efficiency of 1-BOPAMS and 4-BOBAMS increased with concentration, with maximum inhibition values of 90.32% and 97.91%, respectively, at the highest concentration of the inhibitors. Gibbs free energy (ΔG°ads) values indicated a strong interaction between the mild steel surface and the molecules of the ionic liquids, and that the adsorption process was spontaneous. These values also show that the inhibitive nature of ionic liquids against mild steel corrosion is caused by a mixedtype of adsorption film formed on the steel surface. The Langmuir adsorption isotherm was used to describe the adsorption of ionic liquid molecules onto the mild steel surface. Polarization curves showed that 1-BOPAMS and 4-BOBAMS have a similar effect on both the anodic and cathodic half-reactions, indicating that they prevent the dissolution of mild steel through both physical and chemical process. Nyquist plots were defined by incomplete semicircle capacitive loops, showing that the charge transfer mechanism controls the corrosion of mild steel in acidic solution.

Apr 1, 2021

By N. Hamlef

In this study, the effects of heat treatment on phase formation and surface morphology of the Cr-Pt coated system are investigated using X-ray diffraction and electron microscopy techniques. The CrPt andCr4Pt (Cr3Pt - A15 type) phases were formed after heat treatment of the coated samples. Heat treating at 1000°C renders a distinct island coating morphology that is non-continuous in nature. A diffusional model is proposed for this coated system with regards to the surface morphology formation after heat treatment.

Jan 1, 2014

By D. F. Malan, P. M. Couto

We propose a layout design for the UG2 Reef where weak geological alteration layers are present. The collapse of the Everest platinum mine in South Africa indicated that these layers substantially weaken the pillars. The popular Hedley and Grant pillar strength formula cannot be used where these alteration layers are present. Underground investigations at Everest mine and numerical modelling of the layout were conducted using the TEXAN code and a limit equilibrium model. Simulations of a collapsed area and an intact area allowed for a preliminary calibration of the model. This was subsequently used to explore modified layouts for these ground conditions. An alternative is to compartmentalize the blocks of ore using barrier pillars. The numerical modelling predicted that the barrier pillars appear to remain stable even in the case of large-scale collapses, provided their width exceeds 25 m. Main access routes into the mine can be protected by a double row of pillars at least 15 m wide to provide a safe travelling way. As a cautionary note, these conclusions are based on the model calibration and this needs to be refined in future. Calibration of the limit equilibrium model remains a challenge owing to the large number of parameters involved.

May 3, 2023

By C. C. Birch

Due to grade estimation uncertainty, two statistical errors can occur. The Type I error is where material is classified as ore and mined, despite the true value being below the break-even grade. This material is dilution. The Type II error is where the material is estimated to be below the cut-off grade and is classified as waste, although the true grade is actually above the break-even grade. This material is not mined and is lost. The uncertainty was assumed to follow a normal distribution in a previous study. For this study, estimated block values are compared to those determined after mining (the best estimate of the true grade). This actual data from four mines shows that the uncertainty follows a Laplace. There is no single solution regarding adjusting the cut-off grade away from the break-even grade, considering estimation uncertainty, that could be applied to all gold mines. However, adjusting the cut-off grade downwards (up to 22% for one mine) is noted when optimizing the profit considering grade uncertainties. This type of adjustment could open up significant mining areas and extend the life of the mine.

Jul 2, 2022

By E. Garab, M. Pillalamarry, E. Develo

"Recent geological exploration at Rosh Pinah mine revealed that the mine’s major production is shifting towards the western orefield, which will increase the demand for air flow to be supplied to this area. A snapshot of the ventilation survey carried out in December 2014 at the western orefield drill drive B (WOF-DDRB) showed that the air flow was well below the required standards. In order to improve the existing conditions, possible options were considered and simulated using Ventsim™ software.The best option found was to replace the existing western orefield fans with the larger fans from the inactive southern orefield workings, to increase the air flow in the DDRB district. Simulation showed that as much as 20 m3/s of air can be received at the working faces of WOF 30, compared to the previously received amount of 1.37 m3/s. The economic analysis indicated that the above option can reduce the ventilation cost by N$1.9 million annually. It was also noticed that after implementing this option together with other projects, the ventilation conditions in the mine were greatly improved and currently give no cause for concern. IntroductionA good mine ventilation system should be capable of providing adequate quantity and quality of air to all working faces, and is critical to the occupational health, safety, and comfort of underground employees (Luxbacher and Ramani, 1977; Exikis and Kapageridis, 2006). No ventilation system can remain adequate indefinitely; as the mine workings are extended, the ventilation characteristics such as system pressures, air volumes, leakages, and airway resistances change considerably. Continuous improvement of the ventilation system is needed to ensure compliance with health and safety regulations (Lovejoy, 2010). It also ensures that the right quality and quantity of air is delivered to all the necessary areas at the lowest possible cost. This can be achieved by identifying inefficient airways and poorly ventilated areas in the mine and planning how best to upgrade them.The latest geological exploration shows that the focus of production at Rosh Pinah mine is shifting towards the western orefield (WOF). As mining progressed, the working areas have advanced away from the main fans, which increased the resistance to air flow drastically and resulted in increasing demands being imposed on the main fan in order to supply an adequate air flow. This process also created more leakage paths between the fan and the working areas, which has caused the air to short-circuit before it can reach the faces. Consequently, a much larger quantity of air has to be circulated by the fan so that the stipulated quantity reaches the face, which increases operating costs (Singh et al., 2004)."

Jan 1, 2016

By R. Weideman, K. du Preez

Biological sulfate reduction has become a successful treatment alternative for acid mine drainage and Mintek is developing biological processes for treatment of highsulfate mine waters. Treatment of these high-sulfate waters is achieved by sulfatereducing bacteria that reduce sulfate to produce sulfide as a product, in the form of H2S and HS− at neutral pH. This introduces the opportunity to apply treated effluents from biological treatment processes for the recovery of metals, such as copper, from metallurgical waste streams. This study models the kinetics of copper sulfide precipitation from a complex bioleach liquor. The results indicated a rapid rate of reaction and the formation of covellite, suggesting the potential to use biogenic sulfide to recover copper as a metal sulfide product.

Jan 1, 2023

By D. Odendaal, S. Bharat, R. D. Cromarty

The aim of this investigation was to determine the effect of high-temperature heat treatment on the electrical resistivity of charcoal. Samples of two different wood types (eucalyptus and black wattle) were pyrolised in a retort at a temperature of 700°C and the resulting charcoals heat-treated in an induction furnace at temperatures from 800°C to 1800°C and residence times from 60 to 120 minutes. After cooling, the resistivities of the samples were measured at room temperature using the four-point probe technique. It was found that as the heat treatment temperature increased the electrical resistivity of the charcoal decreased, approaching an asymptotic value at higher temperatures. Longer residence times decreased the resistivity, but this effect was not pronounced.

Oct 3, 2023

By B. P. Watson, D. P. Roberts, R. A. Lamos

The Upper Group 2 (UG2) chromitite reef is a shallow-dipping stratiform tabular orebody in the South African Bushveld Complex, which strikes for hundreds of kilometres. Mining is extensive, with depths ranging from close-to-surface to 2 500 m. Pillars are widely used to support the open stopes and bords. Little work has been done in the past to determine the strength of pillars on the UG2 Reef and design was done using formulae developed for other hard-rock mines. This has led to oversized pillars with consequent sterilization of ore. In this paper we describe a back-analysis of stable and failed UG2 pillars on the Bushveld platinum mines, and provides a strength formula for UG2 pillars. The formula may be used cautiously on all Bushveld platinum mines with similar geotechnical, geometrical, and geomechanical conditions to the pillars in the database.

Aug 1, 2021

By A. Doroudgar, H. Noferesti

Unstable rock failure or rock bursting is one of the most dangerous problems in deep hard rock mines. This type of failure, that occurs uncontrollably, is associated with a significant release of strain energy from the surrounding rock. In this study, the numerical simulation of unstable rock failure was carried out using the three-dimensional explicit Lagranian finite-volume finite difference method to identify the onset and location of unstable failure events in the model. On this basis, a numerical simulation of mine pillars with width-to-height ratios of 0.5, 2 and 3 was performed. A criterion was developed, based on the calculation of the elastic strain energy, to determine the prone areas for the initiation of rockburst in the models. The results of this study showed that, in softer loading systems, due to large amounts of stored elastic strain energy, an unstable equilibrium is established, which leads to the rapid transfer of strain energy to the rock in the form of violent failure. It was also found that the unstable failure starts at the corners and free surface of the model. The new criterion developed in this study may help predict the occurrence of rockbursts in slender pillars and the design of pillars to control human and financial losses caused by this phenomenon.

Nov 27, 2024

By K. Gharibi, A. Dehghani, S. Farrokhpay, M. Aghajanloo, M. Ostadrahimi

The effect of flotation operational parameters on froth stability and froth recovery was studied. Froth stability was measured using a special column. To determine the froth recovery, the froth height change model and froth height exponential model were used. It was found that since the interactions between the pulp and froth zones affect the time of froth formation, the exponential model is more suitable than the froth height change method for determining the froth recovery. The results showed that superficial air velocity and collector dosage have, respectively, the highest and lowest effect on the froth recovery, while froth recovery decreases sharply with increasing froth height.

Jan 1, 2021

By M. Mpofu, B. Maphalala, S. Khan, S. Ngobese, D. Roberts

This paper details an assessment of stemming practices at a South African opencast coal mine and their influence on ground vibration and air blast. Quantitative and qualitative analysis methods were used for the study. The parameters assessed for the quantitative analyses included stemming length, stemming material type, blast-hole depth, burden, and spacing. Pre-blast data from the mine was analysed to determine the deviation between actual and mine design stemming parameters. Mine design stemming length was also compared to the rule-of-thumb stemming lengths. Peak particle velocity (ground vibration) and air blast data from seismograph stations around the mine was analysed to determine the correlation between stemming length and excessive ground vibration and air blast. The qualitative analysis involved observations of blasting procedures at the mine to determine compliance with mine procedures. Some level of non-compliance of actual stemming parameters to design stemming parameters was found, which initially suggested that non-compliance may have contributed to excessive air blast. However, further analysis of the seismograph results indicated no direct correlation between stemming length and excessive air blast and ground vibration. Since stemming parameters are interrelated, it is crucial that all blasting procedures, including stemming, are executed in accordance with best practice, and recorded accurately. There is a need for digital systems for capturing on-bench blasting parameters, as the currently used manual data recording and reporting systems are inefficient and prone to error. Improvements to blast designs are possible through efficient and accurate data recording and reporting systems.

Jan 1, 2021

By S. Chai

Waste dumps are widely used to discharge stripped mine wastes in open pit mining methods. As mining progresses, the height of the waste dumps will increase gradually, which may induce sliding failure once the height exceeds a critical value. Therefore, estimation of the maximum dumping height is crucial to the life-cycle use of a waste dump. However, published information about the maximum height of mine waste dumps are extremely rare. In this study, the maximum dumping height is estimated based on the strength-reduction technique by numerical simulations. The influences of dump geometry and properties on the maximum height are investigated. The results show that the maximum dump height decreases as the dump slope inclination angle α or the unit weight of dump materials γ increases, but decreases when the shear parameters of dump materials (cohesion c and internal friction angle ϕ) increase. The maximum height starts to increase with the ground inclination β when shear failure occurs at the interface between the dump and the base. Furthermore the effects of the dump width B, Young’s modulus E, and Poisson’s ratio μ of dump materials on the maximum height are almost insignificant. Good agreement was found between numerical results available in the literature and those obtained in this study.

Oct 1, 2022

By F. Nakhaei, M. Le Roux, Q. P. Campbell, S. Botlhoko

The results of coal sink and float tests are plotted as washability curves. Analysis of these curves indicates the most effective method by which the coal can be cleaned. Sink and float experiments are samplingdependent, destructive, and use toxic chemicals. The present research introduces an alternative method based on a 3D imaging system called RhoVol, in which the density of individual particles is determined from mass and volume measurements. A quantitative error analysis was conducted on coal sample density measurements obtained by RhoVol, and the main factors influencing the errors identified and investigated. The results show that the drawback of this technique is related to its not being able to detect hidden concavities in the particle, resulting in an overestimation of particle volume. Furthermore, it is difficult to capture the impact of porosity and cracks on the volume of coal particles obtained from 3D silhouette images. This mismatch between the RhoVol data and sink and float test results has led to attempts to apply neural network (NN) and linear regression techniques to produce a fully reliable model for correction and estimation of coal density. The NN approach offers superior predictive capability over linear regression, and the estimated density distribution is in line with the sink and float analysis. The root mean square error in estimation of density using the NN model was less than 0.05 g/cm³.

Aug 2, 2022

By K. Dagdelen , S. K. A. Owusu

Uncertainty with regard to estimated grades and tonnages of a mineral deposit demands risk assessment in order to build investor confidence and attract the interest of other stakeholders in the success of a project. Uncertainties associated with Mineral Resource estimates can lead to unreliable production schedules and unpredictable cash flows. However, the techniques used in the mining industry to determine these uncertainties are inconsistent, because the important decisions taken in the process are solely dependent on the responsible Competent Person (CP), without limitations. This leads to disparities between different CPs’ results, using data-sets from the same drill-holes. The various standard codes for public disclosure provide guidelines and recommendations for the classification of Mineral Resources and Reserves but do not provide details on, for example, the amount of geological and geostatistical information needed to qualify for each category of Resources and Reserves. The parameters used to generate the classification categories are subjectively assumed by the responsible CP. In this paper we investigate the impacts of different CPs’ judgements on resource classification, using the same data-sets. The results underpin the need for the mining industry to develop a uniform Mineral Resources and Reserves classification framework that can minimize or avoid significant discrepancies that lead to potential misleading public disclosures.

Aug 8, 2024

By A. K. Raji, E. F. Orumwense, M. O. Ojumu

This research paper introduces a novel passive method for ocean mining using an electricpowered robotic subsea dredging crawler designed to operate in various subsea conditions, including unstructured and rough terrain. The electric-powered robotic subsea dredging crawler is equipped with two driving tracks and features a complex assembly of tank tread chain link, tank tread idler wheels, tank tread sprockets, bronze bushings, motor hub, motor mount, and a 12-volt direct current motor. To evaluate the performance of the electric-powered robotic subsea dredging crawler, it was compared with existing ocean hydraulic exploration crawlers, such as MK3 ROST, in terms of drive performance on an inclined ramp with five angles of inclination (0°, 15°, 20°, 25°, 30°). The experiment aimed to determine the maximum velocity, torque, and efficiency of the crawler at different angles of inclination. The collected data were analysed and plotted using Python, and the effect of the electric-powered robotic subsea dredging crawler’s weight on its driving performance was also considered. The results of this study demonstrate a quadratic relationship between driving performance and inclination angle, which can be used to optimise the electric-powered robotic subsea dredging crawler’s performance for future ocean mining robot drive applications.

Oct 2, 2025

By D. van der Westhuizen, H. Krieg, M. Kruger

In the field of Fischer-Tropsch synthesis catalysts, cobalt, platinum, and aluminium are the primary metal constituents of the conventionally used cobalt catalyst. While platinum recovery remains a focal point in this field, a recent endeavour by a South African company emerged, which aimed to recover cobalt and aluminium from spent Fischer-Tropsch synthesis catalysts for potential use in the agricultural sector. This study aimed to optimally separate cobalt and aluminium from spent Fischer-Tropsch synthesis catalyst for this purpose. It further leverages the OLI database to predict metal speciation during solvent extraction to aid with experimental planning. Shake-out tests were conducted to determine optimal separation. conditions, which were validated using three distinct methods: (i) evaluating the experimental error, (ii) comparing results with similar research, and (iii) validating results against the OLI database. The investigation revealed the pivotal role of the aqueous pH yielding effective separation at pH 3.13 ([H2SO4] = 2.5 × 10−4 M) when using 20 vol.% CYANEX 272 and 50 mol.% pre-neutralisation. Effective cobalt scrubbing was achieved with 50 g/L Al at pH 2.8, while successful stripping required 1 M H2SO4. Competitive interactions between complexing aluminium and cobalt species were observed when contacting with CYANEX 272 at a pH < 4. Equipment design analysis for a targeted separation efficiency of 87% dictated the necessity of two mixer stages and a settler measuring 1.5 m × 1.5 m × 6.0 m (height × width × length). This settler would ensure sufficient residence time for gravity separation at a flow rate of 10 m3/h.

May 27, 2025

By Nicolle Krusberski

Potential errors in XRF analysis are discussed and investigated with specific reference to the analysis of ilmenite samples. A selection of ilmenite samples was chosen and prepared using two XRF preparation techniques: pressed powder pellet and unroasted fusion bead. The merits of the two methods have been discussed in this paper for ilmenite analysis by XRF. Recommendations have been made regarding the use of pressed powder pellets especially with regard to the mineralogical effects that were evidenced during this investigation. The fusion bead technique was found to be far more accurate and able to meet short turnaround requirements provided the calibration methodology used is specific to the grade of samples analyzed.

Jan 1, 2014

By D. F. Malan, W. J. Theron

Practical mining aspects should be considered when conducting pillar designs for bord-and-pillar layouts. The current methodology for pillar design will result in increasing pillar sizes with depth. This affects the extraction ratio and will result in onerous ventilation requirements when cutting large pillars. A holistic approach, including all mining engineering requirements, is required to ensure that the rock engineering designs are optimized to ensure efficient mining operations and sustainable production. Bord widths should not only be a function of the rock mass ratings, but should also be selected to fit the specifications of the mechanized equipment. The use of a ‘squat pillar’ formula for hard rock is discussed in the paper and the formula based on the exponents of the Hedley and Grant pillar formula, is explored. The effect of abutments and geological losses on average pillar stress is also explored. These factors must be considered when designing layouts at increasing depths.

Nov 27, 2024

By T. J. Otto, G. C. Lindeque

Productivity is improved by increasing the ratio of output to input. In an operating open-pit mine, improving the productivity of heavy mining equipment (HME) enables the unit cost of production to be reduced. To optimize HME productivity, the Kolomela open-pit iron ore mine transitioned to an enhanced short-term mine planning (STMP) process that supports the application of a manufacturing-type operating model. At the core of the enhanced STMP process is a focus on integration across the open-pit mining value chain. The interdependencies between mining activities are highlighted and emphasized, thus ensuring that mining activities are synchronized. The improvements related to HME productivity were monitored from 2019 to 2020. The utilization of mining area in the Leeuwfontein pit improved from 71% to 90%, and the blasting frequency reduced by 14% while the average blast size increased by 17%. The distance travelled during shovel relocations between mining phases reduced by 16%, and the lost time associated with drills relocating reduced by 53%. These productivity improvements resulted in an 11% increase in the loading rate of the main waste shovel at Kolomela from 0.9 Mt/month in 2019 to 1.0 Mt/month in 2020. The enhanced STMP process can be adapted to other open-pit mining operations.

Nov 1, 2021

By M. Weir, J. R. Cutland, L A. J. Pronk van Hoogeveen

"A computer system for the design of open pits to mine stratiform orebodies has been developed for use at Nchanga Consolidated Copper Mines, Ltd. The particular requirements of such a system, for example, the accuracy of representation of geological detail and the ability to follow footwalls, arc described in this paper, together with the methods that have been adopted to satisfy them.A modified version of the Open Pit Design Program of Rio Tinto Zinc Consultants, Ltd. is incorporated in the system and the geological data are converted into a form usable by the computer by means of a pencil follower. Some of the uses which have been made of the system are described, with reference to the long- and medium-term planning of the Nchanga Open Pit, the major producing pit at Chingola Division."

Jan 1, 2014