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By W. Soetaert, P. Dhar, H. R. Kota, M. Thornhill, S. Roelants, I. V. Chernyshova

Yeast-derived bola-amphiphiles have attracted considerable attention for their applications in various industrial sectors in recent years. However, only a few studies on this class of surfactant were reported to be relevant to mineral processing applications. In this paper, one of the novel surfactants, acidic glucolipid obtained from Candida bombicola sophorolipids and modified by using Penicillium decumbens naringinase substrate has been evaluated for its interaction with chalcocite and calcite minerals because of a new Cu-ore Nussir deposit in Norway containing calcite impurity. The interaction of glucolipid biosurfactant with copper sulphide and carbonate minerals was investigated with zeta potential, adsorption and FTIR studies, and also by Hallimond tube and bench scale flotation tests using pure minerals and Nussir copper ore, respectively. The results illustrate collector adsorption and flotation of copper sulfides at neutral pH. The bench-scale flotation results demonstrate that copper sulphides can be selectively floated from carbonate and silicate gangue minerals. This study underlines the glycolipid’s high potential for its use as collector for flotation of valuable copper sulphide minerals. Keywords: Flotation, biosurfactants, adsorption

Jan 1, 2020

By C. Zangerl, K. F. Evans, S. Loew

ABSTRACT: Settlements above fractured crystalline rock masses are rarely observed and in the past, geotechnical engineers would not expect substantial subsidence to occur in association with a deep tunnelling project. However, recent high precision levelling measurements along the Gotthard pass road in central Switzerland, have revealed up to 12 cm of subsidence along sections that pass several hundred metres above the Gotthard highway tunnel. Large-scale consolidation resulting from tunnel drainage and pore pressure changes in the rock mass are believed to be the contributing mechanism. This paper presents results from an extensive numerical modelling study focussing on the processes responsible for this subsidence. Results derived from 2-D discontinuum (i.e. distinct-element) and continuum (i.e. finite-element) modelling show that both discrete fracture deformation (i.e. fracture closure and shear) and poro-elastic consolidation of the intact rock matrix equally contribute to the observed magnitudes and shape of the surface subsidence trough. RÉSUMÉ: Des tassements aux dessus de massifs cristallins sont rarement observés et par le passé les géotechniciens ne prévoyait pas de subsidence significative associée avec des projets de tunnel profond. Cependant, de récentes campagnes de nivellement haute précision le long de la route du Col du Gotthard (Suisse centrale), ont mis en évidence des subsidences atteignant 12 cm sur des sections passant plusieurs centaines de mètres au-dessus du tunnel routier du Gotthard. Le mécanisme invoqué pour expliquer ce phénomène est la consolidation à grande échelle due au drainage du tunnel et aux variations de pression de pore dans le massif rocheux. Cet article présente les résultats d’une modélisation numérique intensive mettant l’accent sur les processus responsables pour la subsidence. Ces résultats obtenus grâce à des modèles 2-D discontinus (p. ex. éléments distincts) et continus (p. ex. éléments finis) montrent que la déformation sur des fractures discrètes (fermeture de fractures, cisaillement) ainsi que la consolidation poro-élastique de la roche intacte contribuent également aux magnitudes et aux géométries de subsidence observée en surface. ZUSAMMENFASSUNG: Beachtliche Oberflächensenkungen in einem kristallinen Gebirge, deren Ursache im Vortrieb eines mehrere hundert Meter tiefgelegenen Tunnels liegt, wurden bisher nicht erwartet und beobachtet. Dennoch wurden nach dem Bau des Gotthardstrassentunnels, entlang der Gotthardpassstrasse Oberflächensenkungen mit einem Maximalbetrag von 12 cm bei der Auswertung von Präzisions-Nivellements entdeckt. Dieser Maximalbetrag wurde in einem granitischen Gneis gemessen. Die örtliche Übereinstimmung zwischen dem maximalem Senkungsbetrag und dem maximalem Wasserzufluss zum Tunnel, und die zeitliche Abfolge von Tunnelbau und auftretenden Oberflächensenkungen lassen hydromechanisch gekoppelte Prozesse als Ursache dieser Gebirgsverformungen vermuten. In dieser Arbeit werden die Ergebnisse ausgedehnter prozessorientierter numerischer Simulationen präsentiert. Resultate aus den 2-D Diskontinuum (d.h. distinct-element) und Kontinuum (d.h. finite element) Simulationen zeigen, dass beide Verformungsmechanismen, d.h. an diskreten Brüchen und der intakten Gesteinsmatrix, gleichbedeutend für die beobachteten Senkungsbeträge und der Form des Setzungstroges verantwortlich sind.

Jan 1, 2003

By T. Marin, J. E. Seccatore, M. Cardu

The most energy-intensive process in the mining industry is particle size reduction – comminution. The first phase of this process is blasting to fragment the rock from the initial Boussinesq’s halfspace size. Scientific literature demonstrates that the output of a blast in terms of fragment size distribution can be manipulated by varying the specific charge (powder factor) and charge distribution. This study focuses on the influence of blasting on the internal resistance of the blasted fragments; in particular the influence of the spatial distribution of charges. Small-scale blasts were performed on 14 marble blocks using different powder factors and charge distributions. Three control blocks were fragmented by mechanical means for comparison. The results show the correlations between charge distributions and the specific energy of mechanical comminution. Opportunities for adjusting charge diameter and distribution in opencast blasts to improve the performancet of comminution circuits are discussed.

Aug 8, 2024

By J. P. Garnier, T. Bhambhani, J. A. Garcia, N. Renaud

Most flotation plants use a static reagent scheme, i.e., a set combination of collectors, frothers, and modifiers. This scheme is usually developed and refined over time to deliver optimal (not necessarily the highest) performance when the major ore types are fed to the plant. However, when ore types or mineralogy coming to the plant change substantially (and this often happens as different areas of the pit(s) are mined and crushed at the same time), there are upsets in the process, typically leading to lower recoveries. Adapting to this variability is usually done only when performance drastically suffers, and the changes made may be too late and bring additional variability in performance. The premise for SmartFloat™ is that the reagent suite needs to be dynamic, adapting continuously to changes in the ore and operating conditions. Solvay has combined advanced analytics and data science techniques with its expertise in flotation reagent chemistry to systematically and automatically achieve the above, and in real time. Thus, SmartFloat™ is optimizing the reagent suite continuously, removing the additional variability created by belated human interactions resulting in a better and more stable process. In addition, this advanced approach allows for continuous improvement by identifying poor performing ore domains and improving the reagent suite using Solvay’s FM-100 approach to design appropriate solutions.

Jan 1, 2023

In Chapter 1 we mentioned that up to three components are considered to represent the variability of regionalized variables : a deterministic component, a correlated component, and a random component. In Chapter 2 we considered some of the models based on the assumption of randomly distributed values: the random component was assumed to be the only one present. In Chapters 3 to 11, more general but also more complex models were described, based on the assumption that the values were correlated with the possible presence of random noise. In this chapter we introduce a model used to analyse non- stationary data, for which a deterministic component (or drift) must be assumed. This model will be used for estimation purposes, and the corresponding optimal linear estimation procedure is known as universal kriging. The theory of universal kriging is much more complex than the theory of kriging. Fortunately, in the majority of mine valuation problems the drift can be ignored and the simpler form of kriging can be used.

Jan 1, 1978

By R. O. Heckroodt

After a brief review of the characteristics of clay minerals and their origin, a summary is given of the industrial uses of different types of clay materials. The mining and beneficiation of clays are discussed, with special reference to the upgrading of certain types of materials. The occurrence and resources of the more important varieties of clays are dealt with in some detail, viz residual kaolin derived from granite and sediments, brickmaking clays, refractory clays, bentonite, and palygorskite. The Republic of South Africa is well endowed with a wide spectrum of clay materials, with one important exception. Kaolin suitable for paper coating is not known to occur in the Republic, and efforts to beneficiate and treat local materials to achieve the desired properties have so far been unsuccessful.

Jan 1, 1991

By G. Raspa

The paper describes a computer procedure for evaluating and selecting recoverable reserves in a mine worked by sublevel stoping. The boundaries of the volume to be mined are optimally defined by means of the 3-dimensional Lerchs-Grossmann algorithm, separately applied to both sides of the panels. The procedure, which has been developed for Masua Mine (Sardinia), also provides for smoothing the optimized boundaries, positioning the drilling drifts, interactive design of drilling fans and calculation of tonnage and grade of each volley. These tonnages and grades form the input of another procedure evolved for production planning.

Jan 1, 1987

By O. Bazhko

Regular analysis of different streams is important for the control of hydrometallurgical processes. Various physical and physical-chemical methods are applied for this purpose. Many modern methods require costly equipment and are subject to interferences. Therefore, redoxtitration methods remain of interest. The use of different types of oxidizing and reducing agents as well as redox indicators enables many cations and anions to be rapidly and accurately analysed. Sometimes redox titrations require the prior preparation and addition of masking agents. Selective, sensitive and low-cost methods of redoxtitration of copper and SO2 in plant conditions are described.

Jan 1, 2009

This paper presents a quantitative approach to the problem of determining design capacity and field dimensions of underground coal mines using room- and-pillar mining systems. In evaluating these design variables, relationships among mining costs, number of production sections in mines, location of central shafts, mine field dimensions, section production, mine output, and cost of production losses due to underground man-traveling are analyzed. Thereby the unit cost of coal is expressed as a function of the design variables as well as input parameters such as seam angle, seam thickness, seam depth, underground traveling speed of men, mine recovery and plant recovery. The problem is then formulated as a nonlinear optimization model in terms of minimizing the unit cost of coal subject to a set of constraints and solved analytically for flat seams and numerically for inclined seams. Sensitivity analysis of the variables is also included in the paper.

Jan 1, 1987

By Lene Hansen

Sulphuric acid plants now and then see unexpected increases in SO2 emissions. Our experience is that it is not always easy for the acid plants to pin point the exact reason for the SO2 increase. Sometimes a catalyst bed is sacrificed even though reliable emperature readings and gas analyses could have verified satisfactory activity, hence the leaking heat exchanger is never discovered and after the shutdown the SO2 emissions are still too high. This paper will look into some basic catalyst management tools: Good record keeping is a necessity for collection of representative catalyst samples, reliable operating data is an inevitable starting point for all analysis and trending of operating data is a must for plant optimisation and troubleshooting. In addition these catalyst management tools will give a continuous updated knowledge of the catalyst status in each bed providing the basis for a more effective replacement strategy. The most typical reasons for increasing SO2 emissions will be presented together with easy guidelines for cross-checking of operating data, temperature optimisation and good record keeping.

Jan 1, 2009

By W. J. C. Pothas

This paper describes the state of the art in backfilling techniques used on East Driefontein Gold Mine. Areas covered are the preparation plant, the distribution plant, the pipeline network and finally placement techniques. The in-situ performance of placed backfill has been assessed by the Chamber of Mines Research Organization, and results to date will be shared. Details of the backfill expansion programme that will enable this facility to be made available to all working places are included. Benefits obtained by the introduction of backfilling are described, together with certain management aspects to be considered in the control of quality and quantity of support supplied via a pipeline.

Jan 1, 1988

This paper summarises some observations regarding the way SAG and AG mills work based on the last ten years of pilot plant operation, grinding circuit design and operational reviews for various projects in Australia and overseas. The main purpose is to promote discussion on key factors influencing breakage in a SAG mill. The focus of the paper is on two questions: ? How do mill lifters and liners really work and have an effect on grinding? ? How does the mill charge composition impact on grinding performance? The focus of the paper is on observations of mill behaviour in both pilot plant trials and plant operation, particularly on Cadia ore. DEM, by others, and JKSimMet modelling of SAG mill performance have greatly assisted in forming the ideas expressed in the paper and both are valuable tools in developing our understanding of the comminution process. Put in the `extreme' form the major observations and conclusions expressed in this paper are that: ? the main purpose of mill lifters is to reduce mill liner wear and not to promote rock breakage; ? the often promoted theory that balls impacting the ?toe of the charge? is a dominant form of breakage is incorrect; and ? fines production in a SAG mill is primarily a function of the rock load mass, with a secondary dependence on ball load for any given circuit configuration.

Jan 1, 2007

By G. van Aswegen

The geometry and morphology of a set of low-angle fractures around a stope in a deep Witwatersrand gold mine are explained in terms of extension fractures forming under variable conditions of stress. Primary extension fractures (E1) form some distance ahead of an advancing stope along the s1, s2 plane. With stope advance, a couple of these fractures end up in a stress regime conducive to transpressional shear and a secondary set of extension fractures(E2) is formed at a high angle to the primary fractures. i.e. at a low angle to the stope. As the E2 fractures are undermined, they migrate into a stress regime of transtensional shear and a third set of extension fractures (E3) may develop between E2 fractures. These have sigmoidal shapes, being parallel to the E2 fractures at the E2 discontinuity where s3 is negative, and curved through the unfractured rock between E2 fractures where s3 is positive at the instant of fracturing. The fractures all display fractographic features characteristic of dynamic extension failure with striae indicative of the direction of rupture propagation and the local, instantaneous orientation of s1.

Jan 1, 2012

By D. Mjonono, S. T. L. Harrison, N. Maliela, A. Kotsiopoulos

The improvement of coal waste management practices, through the co-disposal of waste rock with sulphur-lean fine waste tailings (<1 mm in size), can potentially mitigate acid rock drainage (ARD). On exposure to natural oxidants, the sulphide compounds present in mine discards generate acidity, creating a cyclical oxidation process intensified by iron and sulphur oxidising microorganisms. To inhibit the emergence of ARD, a stable mine dump may be constructed that is structurally stable and incompressible through the mixing of complementary waste fractions that reduce voids and access to acid generating surfaces. However, large voids manifest as scale increases, due to decreased particle interlock, enabling the unrestricted access of oxidants leading to the early onset of ARD. To avoid this phenomenon, enhanced packing approaches based on geochemical and geotechnical characterisation tests were employed to improve bed stability. These were assessed for long-term prevention using aggressive oxidative conditions typical of heap leaching applications. Favourable results were obtained for both blended and multi-layered systems. However, long-term success was most notable in beds with alternating layers of waste rock and fine waste tailings with co-mingled systems being more susceptible to failure. Deconstructed co-disposed beds provided valuable insight into post-leach structural transformations. Results indicated that relative changes in initial coarse discards to fine waste ratios were most notable in blended systems. Mass fractions of the comparatively more mobile fine wastes increased axially down these test columns that ultimately resulted in increased contact of oxidants with the acid generating waste discards. Conversely, more consistent ratios were observed in multi-layered configurations. In these systems, near impervious hardpans were created by the moisture retaining fine tailings, forming stable structures with neutralising barriers sustained at each alternating layer. Consistent with post-leach geotechnical characteristics, static acid-base accounting tests showed that the uppermost sections of blended systems were more susceptible to oxidation due to structural failure with fine particles migration, while the more stable multi-layered configuration evenly maintained neutralising capacity. Keywords: Acid rock drainage (ARD), bed structure, mobility of fine particles

Jan 1, 2020

By K. Grossauer, W. Schubert

For tunnelling in poor and heterogeneous ground a reliable on-site short-term prediction is required to allow a safe and economical construction. With the use of absolute displacement monitoring data and advanced software for evaluation of the data in combination with a routine update of the geological model a considerable increase in the reliability of the short-term prediction could be achieved. The paper deals with theoretical considerations, numerical studies and case histories from alpine tunnels in heterogeneous rock. Tunnelbau in schlechtem und heterogenem Gebirge erfordert auf der Baustelle eine verlaessliche Kurzzeitprognose, um ein sicheres und wirtschaftliches Bauwerk gewaehrleisten zu können. Die Verwendung von absoluten Verschiebungsmessdaten und deren Auswertung mit Hilfe von hoch entwickelten Softwareprogrammen in Kombination mit einer laufenden Aktualisierung des Gebirgsmodells ermöglicht eine erhebliche Erhöhung der Verlässlichkeit von Kurzzeitprognosen. Dieser Beitrag beschäftigt sich mit theoretischen Ansätzen, numerischen Modellen und Fallstudien von Tunnelvortrieben in heterogenem Gebirge. La construction de tunnels dans la montagne hétérogène de faible résistance exige un pronostic fiable à court terme sur le chantier, afin de pouvoir garantir un ouvrage sûr et économique. L&apos;utilisation des données de mesure de décalage absolues et de leur évaluation à l&apos;aide de logiciels sophistiqués en combinaison avec une mise à jour courante du modèle de la montagne permet une augmentation considérable de la fiabilité des pronostics à court terme. Cette contribution présente des approches théoriques, des modèles numériques et de cas pratiques de progressions de tunnels dans des montagnes hétérogènes.

Jan 1, 2003

By I. J. Barker

This paper argues that the scale up of furnaces and the supply of electricity are going to be two major issues that will affect the ferro-alloy industry in the near future, and that economic factors will drive this development. The most common type of furnace for producing ferroalloys at present is the submerged-arc furnace with three electrodes, fed from a three-phase AC electrical supply. The scale up of this technology has now reached a fundamental constraint, which is caused by the electrical reactance of the secondary circuit. If the economy of any further scale up is to be achieved in the future then a different technology will have to be used. The supply of electrical power in future is likely to become amore complex issue than it is at present. Existing submerged-arc furnaces tend to run at fairly steady loads, but the ability to swing the load under demand-side management may offer advantages, and may allow a furnace to obtain cheaper power from the organizations that supply this power. This will have to be counterbalanced against the nuisance factors incurred by having a varying load in the operation of the furnace. Various options are therefore discussed in this paper. The possibility of scale up of Søderberg electrodes is discussed, as well as the use of DC power and multiple electrodes. Some of the issues with load swinging are also examined. A particular scenario is also briefly presented to show that considerable further scale up of ferro-alloy furnaces is still possible.

Jan 1, 2011

By S. Potgieter-Vermaak

The main mineral components of the so-called heavy sands (or black sand) are the titanium, zirconium and iron-bearing minerals, rutile, zircon and illmenite, accompanied by various minor and trace amounts of silicates or phosphates, often present together with the rare earth elements. The investigated samples originated from Richards Bay Minerals (RBM) in South Africa, which is jointly owned by BHP Billiton and Rio Tinto, the largest titanium slag producer in the world. The present study focused on the characteristics of samples originating from various points in the separation plant. The heavy-mineral fractions and concentrates of a representative suite of samples were investigated using various analytical techniques to establish the differences in morphological and elemental compositions at the different points in the plant. These techniques included: reflected light microscopy, micro-raman spectrometry (MRS), scanning electron microscopy coupled with energy dispersive X-ray analysis (SEM/EDX) and structural and chemical analyser (SCA). All samples comprised a heterogeneous population of zircon and rutile grains with diverse physico-chemical properties, expressed by large differences in colour and trace element chemistry of single grains. The elemental composition proved the presence of the rare earth elements that appeared to coexist with both Ti and Zr minerals. The percentage of grains hosting inclusions, such as anatase, monazite, quartz, spessartine, augite, epidote and actinolite, varied for each sample and could be uniquely characterized by Raman investigations. Keywords: heavy mineral sands, micro-ram an spectrometry, elemental analysis

By R. Altındag, D. Akbay

The point load index is a simple, fast, and inexpensive method for determining rock strength and can be applied both in the field and in the laboratory. There are, however, some disadvantages and limitations to the method, and the test results can be affected by the person carrying out the test, the rock characteristics, or the test device. In this study we describe an investigation into how the point load index value is affected by the shape of the conical platens used in the test. Point load index tests were carried out using different devices fitted with conical platens of different spherical radii, and on a modified device which circumvented the limitations/disadvantages. It was seen that the point load index value increased as the platen radius increased, as expected. In the case of testing using non-standard conical platens, an equation is proposed to normalize the point load index value with respect to the standard spherical radius value.

Nov 1, 2021

By V-P. Takalo, M. Natsvlishvili, M. Hicks, S. Khizanishvili

"The complexity of copper-gold ores leads to large variations in recoveries and concentrate grades in the processing plant. Detailed chemical and mineralogical studies revealed considerable variation in the ratios of chalcopyrite, chalcocite, and oxidized copper minerals in the ore types studied. The end-member ore types are chalcopyrite-dominated and chalcocite-dominated, while most of the ore types plot between these end-members. In addition, increasing amounts of copper oxide and sulphate minerals result in a decreased response to flotation. Good recoveries and concentrate grades can be achieved from the chalcopyritedominated ore type, while the more altered chalcocite-dominated ore type is more challenging to enrich. IntroductionRich Metals Group (RMG) Copper in Georgia (Figure 1) produces copper-gold concentrates from two open pit mines, Madneuli and Sakdrisi, both located in the Bolnisi mining district in South Georgia. RMG and Outotec began a cooperative project with the aim of improving the recoveries and metal grades in concentrate by gaining an increased understanding of the ore variability and developing more efficient procedures for ore blending, grinding, and flotation. This type of mineralogy-led approach has already been used for other complex ores such as iron oxide copper-gold ores (Hunt, Berry, and Bradshaw, 2011), for iron ores (Lund, Lamberg, and Lindberg, 2013), and for Kupferschiefer ore deposits (Rahfeld et al., 2018).The project started with process audits and mineralogical and chemical characterization of process samples, followed by detailed chemical and mineralogical characterization of six different ore types with simultaneous flotation test work on the same samples. Since neither the recoveries nor the concentrate grades correlate with the head grades of the ores, the modal mineralogical composition, together with the ore hardness, proved to be the most promising approach in developing the geometallurgical classification of these ore types."

Apr 1, 2019

By Piotr M. Kapias

Keywords: extraction, lead refining, Pb-Tl solutions, PbCl2-TlCl solutions. The theoretical part of the paper presents an analysis of the conditions of Tl extraction from Pb using different extractants and determines the activity coefficients in liquid solutions of Pb-Tl and PbCl2-TlCl. The dependence of the solution activity coefficients upon the composition and temperature is presented in the form of Krupkowski and Krupkowski-Fitzner equations. An analysis and evaluation were made of the influence of the methods of PbCl2 introduction into a Pb-Tl solution upon the efficiency of the Tl extraction process under thermodynamic equilibrium conditions. The analysis made it possible to formulate relevant equations describing the dynamics of the process of Tl extraction from Pb under stirring conditions as well as under the extractant injection into the liquid Pb-Tl solution conditions. In the part concerning experimental work, results are given for tests on the Tl extraction process from Pb-Tl liquid solutions of initial Tl content of approximately 0.05% mass using PbCl2 or, alternatively, Cl2(g) conducted in laboratorial scale. The tests made it possible to establish the influence of time, temperature, mass and the method of introducing the extractants into the liquid upon the level of Tl extraction from a Pb-Tl solution. Labels used in the text. WT1m - TI content in metallic phase, % mass WT1s - TI content in chloride phase, % mass wpTlm - TI content in metallic phase in initial state, % mass W°Tlm - TI content in metallic phase in equilibrium conditions, % mass m°m - initial mass in metallic phase mm - mass in metallic phase mPbC12 - lead chloride mass fed to the system MPbC12-TIC1 - mass in chloride phase MPb - lead atomic mass, g/mole MT1 - thallium atomic mass, g/mole K - Nernst distribution coefficient Xi - mole friction of solution component X°PbC12 - mole friction of PbC12 in saturated solution X°T1C1 - mole friction of T1C1 in saturated solution T - temperature, K R - gas constant, J/(mole K) k - kinetic equation constant, 1/(%-min.) ?i - solution component activity coefficient e - extraction rate, %

Jan 1, 2008