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By R. G. Knickerbocker, A. L. Fox, J. Koster, P. R. Perry

"During the past several years, alunite from the Marysvale (Utah) region has been the subject of investigation by the Electrometallurgical Section of the Bureau of Mines. The nature and occurrence of this mineral, with considerable data on the Utah deposits, together with a number of results of preliminary experiments, have been given in a previous report. 6/ The geology of the Marysvale region has been reviewed recently. 7/The present paper reports the results obtained by a method involving the sintering of alunite with boric acid and subsequent treatment of the sinter to produce alumina and potassium sulphate.The preliminary work just mentioned had given indications of the separation of sulphate salts high in potassium from fusions of alunite with borax glass.During the course of further work along those lines, fusions of boric acid and alunite were tried. No separation of salts was obtained, but it was observed that rather complete removal of so3 from the alunite occurred and that the sinter could be leached with water to give a solution contain¬ing most of the potash and a residue containing most of the alumina. The reaction that takes place can probably be written 8/:"

Mar 1, 1939

By G. L. Oldright, John D. Sullivan

"The present article is the second of a series of papers dealing with the dissolution of copper minerals in various reagents. Work done on the problem has been carried out at the Southwest Experiment Station of the United States Bureau of Mines, in cooperation with the Department of Mining and Metallurgy, University of Arizona. The first paper4 dealt with the dissolution of azurite, malachite, chrysocolla, and tenorite. Preceding articles5 have also dealt with other factors involved in the leaching of copper ores.Cuprite (Cu20) is usually considered as a mineral which is not adaptable to sulphuric acid leaching. Hofman,6 in describing leaching by sulphuric acid, states: ""Cuprite is decomposed into CuO and Cu; and ore carrying cuprite has to be oxidized (weathering, roasting) before treatment."" Greenawalt7 says: ""When acted upon by dilute sulphuric acid, it is partly reduced to metallic copper and partly oxidized into copper sulphate. When heated with strong acid it is entirely oxidized to sulphate."" Work to be described in this article was undertaken to ascertain the conditions whereby all the copper in cuprite could be converted into the soluble sulphate."

Dec 1, 1929

By R. C. Ellman

Significant effects of in-the-mill drying on the pulverization of lignite have been demonstrated in an experimental impact-type pulverizer by tests in which the primary variable was temperature of the sweeping gas. Reduced power requirements and increased product fineness were observed as the extent of drying was increased. Pulverization with in-the-mill drying was studied in comparative tests made on lignites from five mine sources. All of the lignites responded in a similar manner; however, differences in the pulverizing characteristics of the individual lignites were significant. For one lignite, the electrical input to the pulverizer driving motor with minimum sweeping-gas temperature was 33.9 kw.-hr. per ton, decreasing to 14.0 kw.-hr. per ton with a sweeping-gas temperature of 658° F.; for another lignite, at comparable operating conditions, the electrical input decreased from 59.1 to 19.0 kw.-hr. per ton. In the first case, the product fineness increased with increasing temperature of sweeping gas from 65.2 to 79.2 percent through a 200-mesh sieve, and in the second case, from b2.7 to 86.9 percent through a 200-mesh sieve.

Jan 1, 1962

By A. R. Taylor

Using solution calorimetry, the following heats of reaction were determined: (1) NaCN(c) + 1/Cu20(c) + 129H20(l) ? CuCN(c) + NaOH?128.5H2O ?H = -13.44±0.10 kcal/mole, (2) HCN(2) + NaOH?128.5H20 ? NaCN(c) + 129.5H20(l) ? = -2.52±0.02 kcal/mole. From these reactions, the heats of formation for CuCN(c) and HCN(2) were calculated to be 22.7±0.4 kcal/mole and 24.9±0.4 kcal/mole, respectively. Reaction 2 was made to check the consistency of literature values for heats of formation of HCN and NaCN. Adiabatic calorimetric measurements between 10° and 400° K showed the entropy and heat capacity of CuCN(c) to be 21.51±0.06 eu and 14.58±0.04 cal/mole deg, respectively, at 298° K. A broad anomaly in the heat capacity was found in the temperature range 285°-320° K. The heat of transition associated with this anomaly was less than 1 cal/mole, the sensitivity of the measurements.

Jan 1, 1971

By Robert P. Vinson, Fred N. Kissell, Edward D. Thimons

Because of the high number of accidental methane gas ignitions in metal and nonmetal mines, the Bureau of Mines searched for a simple guideline that would allow mine personnel to evaluate the methane hazard in a given mine. Air samples were collected by the Bureau in 53 metal and nonmetal mines and analyzed for trace evidence of methane gas. Samples were collected in the returns and at the working faces. Those mines classified as gassy by the Mine Safety and Health Administration had a significantly higher average methane concentration than those classified as nongassy. Of the 9 gassy mines sampled, 7 had methane concentrations above 100 ppm, whereas only 1 of the 44 nongassy mines had a concentration above 100 ppm. The 100-ppm concentration may be used as a simple and convenient guideline for forecasting the methane hazard in a mine, whether or not the mine is classified as gassy. There was no consistent correlation between commodity mined and methane concentration, nor was there a correlation between mine depth and methane concentration. Neither of these factors can be considered a guideline for predicting methane hazards.

Jan 1, 1979

By H. R. Shell

The work on synthetic mica and related subjects is being reported in a series of technical articles (see Supplementary Bibliography), each of which describes some special aspect of the subject. This is the final report on chemical analysis of the fluoride-containing silicates. A condensation of this report has been published (26).3/ Chemical analysis affords one of the best means of ascertaining the final com-position of either a heterogeneous mass or a single pure crystal, particularly where some constituents may be volatile. The analysis of fluoride-containing silicates was not so well known or understood that highly accurate results were commonplace. For example, on synthetic mica a university laboratory reported 11.6 and 9.2 percent fluoride when at least 13.3 and 11.3 percent were present, respectively; a commercial testing laboratory reported 9.14 percent as compared to 12.6 percent; and a glass company reported 7.0 percent as compared to 9.0 percent present. No intimation is made that these analysts could not have done better, but the point to be stressed is that the methods in use were long, tedious, and generally required a certain familiarity for best results.

Jan 1, 1956

By Charles E. Munroe

"It has been recently learned that certain foreign manufacturers are offering far importation into this country detonators at greatly reduced prices, some of these detonators being of such low grade (No.4), that their use would greatly increase the dangers in blasting.Detonators and electric detonators are used in initiating the explosion of the various high explosives that are now so extensively employed in a great variety of mining operations. Originally a large number of different grades (or ""strengths"") of detonators and electric detonators were marketed, the grade number indicating the weight of the charge of fulminating material contained in the copper case of the detonator. As late as 1914, a report of the Bureau of Mines (Bulletin 80, A primer an explosives for metal miners) shows that grades Nos. 3, 4, 5, 6, 7, and 8, containing from 0.54 to 2.00 grams each, were being offered for use. However, the writer bad observed as early as 1896, when the more insensitive types of explosives like nitro-substitution explosives began to be introduced for use in mining and other blasting operations, that use of a high-grade detonator was essential to insure certainty of discharge."

Mar 1, 1921

By Eugene T. Sheridan

The annual survey of the fuel-briquet industry by the Bureau of Mines, United States Department of the Interior, revealed that 21 fuel-briquet plants in 11 States were in operation and reported production in 1956. The demand for fuel briquets in the United States has gradually declined since 1948, and the number of operating plants has decreased from 36 to 21. Also, the annual productive capacity of the industry has decreased, although not a proportionate amount because most of the plants that were abandoned were small and in most instances had a designed capacity of less than 25,000 tons per year. In 1956 the 21 active plants had an annual capacity of 3.7 million tons (table 2), which was only 20 percent less than the total capacity of the 36 plants in 1948. This indicates that most of the larger plants have remained active, even though operating at reduced rates, and the average capacity of the industry has increased from 130,000 tons per plant in 1948 to 177,000 tons in 1956. Since 1948 operating rates have decreased from 67 percent to 41 percent of annual capacity.

Jan 1, 1958

By Marvin E. Lane

This paper , which describes the mining methods and practices at the Hayden Creek lead mine of St. Joseph Lead Co. in southeast Missouri , is one of a series being prepared by the Bureau of Mines on mining methods , practices , and costs in various mining districts of the United States . The Hayden Creek mine is in the W 1/2 sec . 7 , T. 36 N. , R. 4 E. , St. Francois County , Mo. , about 1 mile southwest of the town of Frankclay ( fig . 1) . The mine is on the west edge of the mining district known as the Lead Belt . However , neither the ore body nor the underground workings are connected with those of any other mine in the district . In contrast with most operations in the district , underground haulage is entirely trackless , and nearly complete delineation of the large , well -defined ore body by drilling permitted comprehensive planning of development and mining in advance of shaft sinking . The ore differs in character and occurrence from that of the main ore deposits in the Lead Belt in that the lead mineral , galena , occurs in the dolomitic matrix enclosing granite boulders instead of in dolomite limestone .

Apr 1, 1957

By R. R. Falier, W. E. Rice

"PURPOSE OF REPORTThis paper presents the results of a series of tests made by the U. S. Bureau of Mines in cooperation with The Ohio State University Engineering Experiment Station as part of an investigation on the use of fuel in kilns.This report is preliminary and gives only enough of the test data to illustrate results and show the reasons for the successes and failures of the method of firing investigated; fuller details will be included in the final report.PERSONNEL FOR TESTSThe investigation is conducted under supervision of P. Nicholls, supervising fuel engineer, of the United States Bureau of Mines, and G. A. Bole, research professor, of The Ohio State University. These tests were made under direction of W. E. Rice, associate fuel engineer, assisted by R. R. Faller, assistant fuel engineer, of the United States Bureau of Mines; H. C. Harrison, senior research engineer (until October 1, 1930), C. R. Austin, senior research engineer (since October 1, 1930), and H. K. Van Sohoick, junior research engineer, of The Ohio State University. M. J. Rice, field engineer, represented the manufacturer of the stoker.PURPOSE OF INVESTIGATIONThe general aim of the investigation is to develop more economical methods of using fuel in kilns and to improve the over—all efficiency of the process of firing by methods that will produce ware of better quality. One phase of this investigation is the burning of coal on an automatic stoker to gain the advantages of control, constant rate of application of heat, and ability to burn cheaper coal than can be used in the hand—fired furnaces of kilns. It a stoker in to be used it is desirable that the coot of the installation should be low, the control of operation simple, and the distribution of heat in the kiln as good or better than with hand firing. These desiderata were sought in the stoker and furnaces that were used for the tests described herein. The tests were made to determine whether it is feasible to fire a large kiln with a single stoker, whether the use of a single furnace simplifies control, and whether the admission of all the hot gam at the center of the kiln will give symmetrical distribution of heat."

Aug 1, 1931

By L. H. Banning

This investigation was undertaken to obtain basic information necessary for the design and operation of a plant for recovering metallic values from nickeliferous laterite and serpentine of the Philippine Islands. It was divided into three parts: (1) Mineralogical studies and preliminary mineral dressing tests; (2) electric smelting of the ores, upgrading of ferronickel by blowing with oxygen, smelting laterite slag to produce crude iron, and the production of mild steel; and (3) nickel and cobalt recovery from upgraded ferronickel. Results of the investigation indicate that it should be feasible to recover nickel, iron, and possibly cobalt products from the laterite and ferro-nickel from the serpentine. Mineralogical studies were made on representative fractions of the laterite and serpentine tonnage samples and on five selected samples; mineral dressing tests were made only on laterite. The nickel occurs principally associated with hydrous iron oxides and chemically combined with serpentine; garnierite was the only discrete nickel mineral identified, and it was found in a highly decomposed serpentine. The bulk of the cobalt was found in wadlike manganese oxide material. Approximately twice as much chromite was found in the laterite as in the serpentine, By mineral dressing techniques, laterite was separated into two fractions: one fraction contained over 90 percent of the nickel and cobalt, and 83 percent of the iron; the other fraction contained 74 percent of the chromium. A cobalt concentrate (1.1 percent Co) was produced by a scrubbing and sizing procedure.

Jan 1, 1962

By Charles D. Wood

"Selected Topics,? in reviewing the control of emissions from diesel engine powered equipment used in underground mining, explores these fields of interest: hydrogen as fuel; lubricating oil as a source of particulates; applicability of stationary source scrubbers; worldwide diesel exhaust scrubbers; instrumentation technology for measurement of N02; control of emissions through application of sensors and microprocessors; use of fuel additives; technology transfer of marine diesel practice; technology required to use 4-stroke, aftercooled, turbocharged, direct injection engines; oxidation and reduction catalysts for diesel engine exhausts. "Selected Topics? makes recommendations for research and provides a bibliography and lists of references.

Jan 1, 1979

By D. E. Kirby

In line with the Bureau of Mines' goal of providing technology to maintain a supply of minerals adequate to meet national economic and strategic needs, a method for recovering chromite from lateritic materials was investigated. Laterites are a large resource of Ni, Co, and Cr, critical metals of which the United States has insufficient domestic sources. A roast-leach method was developed by the Bureau to extract nickel and cobalt from domestic laterites. A concurrent effort was made to recover chromium from either unprocessed laterites or the leach residues. This report characterizes laterites and laterite leach residues. It describes a chromite recovery procedure using conventional industrial beneficiation equipment for sizing, low-intensity magnetic separation, and gravity concentration. Concentrates containing 20.0 to 22.4 pct Cr (29.0 to 32.7 pct Cr203) and with a 1.6:1 to 1.9:1 Cr-Fe ratio were recovered from laterites and residues containing 1.3 to 2.5 pct Cr with recoveries exceeding 50 pct. Because of their low grade and fine size, these concentrates would be suitable for preparing chromium chemicals. The direct beneficiation of laterites for chromite recovery resulted in the minerals containing nickel and cobalt concentrating in slime products. No iron oxide coproducts of acceptable grade were recovered from either laterites or residues.

Jan 1, 1982

By D. S. Burgess

About 100 tests of flammability were carried out with H2, CH4, and CO in mixtures with air using the Federal Bureau of Mines 12-ft-diameter spherical pressure vessel as an explosion test chamber. The LeChatelier approximation gave slightly conservative estimates of the limits of downward flame propagation (onset of significant pressure rise) using the following measured values for the individual gases, in percent: H2, 8.5; CH4, 5.25; CO, 13.0. No justification could be offered for using the LeChatelier law for upward flame propagation limits and indeed reported data suggest that calculated values would not be conservative. The observed upward limit for methane-air mixtures (4.85 pct) was less than the widely accepted lean limit for this fuel; those for lean hydrogen-air mixtures and carbon monoxide-air mixtures did not differ from the lowest accepted values. Diffusional effects on the propagation of single, binary, and ternary fuel mixtures are discussed.

Jan 1, 1982

By F. D. DeVaney

Metallurgists and coal-washing engineers have used heavy liquids for years in studying the characteristics of ores and coal. By such means true separations can be made between the various specific-gravity increments in the materials examined. To use of heavy liquids has permitted determination of the possible grades of tailings and concentrates by specific-gravity methods on any particular size, and therefore the size to which the ore must be crushed to free the valuable material. The simplicity of float-and-sink separation and the high degree of efficiency attained in the laboratory are factors that commend the method for commercial concentrations.

Jan 1, 1940

By F. D. DeVaney

Metallurgists and coal-washing engineers have used heavy liquids for years in studying the characteristics of ores and coal. By such means true separations can be made between the various specific-gravity increments in the materials examined. To use of heavy liquids has permitted determination of the possible grades of tailings and concentrates by specific-gravity methods on any particular size, and therefore the size to which the ore must be crushed to free the valuable material. The simplicity of float-and-sink separation and the high degree of efficiency attained in the laboratory are factors that commend the method for commercial concentrations.

Jan 1, 1940

By H. D. Kline

This publication describes mining and milling methods and costs at the Madison mine of National Lead Co., St. Louis Smelting & Refining Division, in the Fredericktown district of southeast Missouri and is one of a series prepared by the Federal Bureau of Mines on methods, practices, and costs of mining and milling throughout the United States. The are bodies of the Madison mine are known for the complexity and diversity of their are minerals. Sulfides of copper, nickel, and cobalt occur in commercial quantities with lead sulfide, which is the most valuable metallic mineral in are bodies of the Bonne Terre formation in southeast Missouri. Several attempts were made by various operators to mine the complex ores and separate the sulfide minerals before 1927 when National Lead Co. became interested in the Fredericktown district. Operating then as the St. Louis Smelting & Refining Co., the company began mining and milling ores from the Madison mine in 1944 and has operated continuously since then. A recently built refinery produces copper, nickel, and cobalt metal from a concentrate containing iron sulphides and small quantities of copper, nickel, and cobalt sulphides.

Jan 1, 1961

By B. J. Moore

This publication contains analyses and related source data for 310 natural gas samples from wells and pipelines in 16 States. All of the samples were obtained and analyzed during calendar year 1978 as a part of Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted in the United States by the Bureau of Mines since 1917. In late 1965, the survey was expanded to include foreign gasfields. The analyses published herein were made by mass spectrometer and a special helium analysis appara¬tus, which are described in Bureau of Mines Bulletins 4862/ and 576.3/ The results of the investigation of the occurrences of helium are published annually to make the information available as soon as possible to the gas industry and the public in general. Twenty previous publications have presented the results of 11,573 gas analyses made prior to 197R. The first three, Bulletins 486,4/ 576,5/ and 617,6/ contain analyses and related source data on 5,218 gas samples collected from 1917 through 1960. The other 17

Jan 1, 1979

By John A. Kiefer

Ground fault and overcurrent protection criteria for coal mine a.c. distribution systems were examined under a Bureau of Mines funded investigation. The report begins with a literature review which discusses relaying topics including instrument transformers, ground-fault pickup methods, static relaying, and comparison of relaying techniques. A chapter on ground-fault relaying provides recommendations for maximum and minimum pickup levels as a function of maximum ground current and power system line-to-ground capacitance. Research in the area of phase overcurrent protection has resulted in a complete set of procedural recommendations for the selection and setting of overcurrent relays and current transformers, molded-case circuit breakers, and distribution system fuses in coal mine power systems. The final chapter, which discusses relay system maintenance, introduces a unique test set which was developed by KETRON and used to test the performance of relaying systems in coal mines.

Jan 1, 1980

Ecuador a gross domestic product (GDP) grew 8% despite a slowdown in production and sales of petroleum, the dominant economic sector. Crude petroleum exports, which amounted to about 35% of total exports in 1977, were valued et $484 million,2 a decrease of 14% from 1976 values. Petroleum export sales were depressed because foreign buyers were somewhat uncertain that State-owned Corporación Estatal Petrólera Ecuatoriana (CEPE) held legal title to the oil until final settlement with Ecuadorian Gulf Oil Corp. In addition to the legal complication, Ecuador maintained a relatively high export price for oil until late in the year. There was also a shrinkage of traditional U.S, markets owing to the Alaskan pipeline becoming operational and an increased availability of Mexican supplies. The export market was also affected by increased domestic production in Peru and Chile, which lessened their import needs, and the pressure of greater competition from the Middle East in supplying crude oil to Caribbean refineries. About 20.4 million barrels or 40% of Ecuador's total crude exports went to the United States. Only 27 wells were drilled in Ecuador during L977; of these, 16 produced oil, 3 were dry holes, and 8 were suspended. About 31 wells were planned for 1978. Three new oilfields were discovered during 1977; two by CEPE in northeastern Ecuador and one by the Argentine State oil company Yacimientos Petraliferos Fiscales (YPF), operating in Ecuador under a service contract. CEPE's two discoveries tested at 5,000 and 1.450 barrels per day, respectively. The YPF discovery tested at about 1,000 barrels per day. Ecuador altered its position regarding

Jan 1, 1981