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By V. Dementiev

Pyrite cinders is a complex raw material, in which the valuable metals are: Au(2.04 g/t), Ag(35.0 g/t), Cu(0.38%), Zn(1.1%) and Fe(56.0%). In this case high costs for mining and ore processing are not required. The hydrometallurgical treatment of pyrite cinders using thiourea, sulfite and cyanide solutions are examined in this paper. It was found that thiourea leaching is ineffective due to high consumption of thiourea and sulfuric acid. The cyanidation on pyrite cinders was conducted. Various options of the preparation of the products for the subsequent cyanidation have been examined. The tests on cyanidation process optimization were conducted. The effectiveness of these cementation methods by metallic iron or extraction for copper recovery from water phase has been shown. Zinc precipitation can be found in the form of carbonate. In order to recover noble metals from cyanide solutions, the cementation onto zinc dust was tested. The developed technology provides for recovery at 49-56%Au, 20-25%Ag, 22.5%Cu and 50%Zn during NaCN (1.4 kg/t) and CaO (6 kg/t) consumption. The results of pilot plant testing are the basis for technical regulations in order to design a pyrite cinders treatment plant. The technology has been examined in pilot-plant conditions. In this case the recovery of 54.5%Au, 45.3%Ag, 30%Cu and 49.9%Zn was achieved to provide saleable products. Keywords: pyrite cinders, thiourea leaching

Sep 1, 2012

By M. Pelser, C Aldrich

"The presence of calcium and magnesium in the hydrometallurgical processing of base metals, results in a number of process difficulties. These problems range from the contamination of the final product (where the final product is a precipitate) to high energy consumptions and large bleed streams during electrowinning. Calcium poses an additional problem in sulphate solutions owing to the low solubility of its sulphate salts. This can easily lead to a process stream that is supersaturated with calcium sulphate, resulting in unwanted solids formation within the process equipment.Several processes are reviewed for the control of calcium and magnesium. Of these, fluoride precipitation was selected for experimental investigation. This method involves the addition of a soluble fluoride to precipitate CaF2 and MgF2. The experiments showed high selectivity for calcium and magnesium over the base metals. The experiments also showed magnesium precipitation to dominate for calcium to magnesium molar ratios greater than 1:3.To avoid the domination of magnesium precipitation, a flow sheet is proposed whereby only a portion of the base metal stream is subjected to fluoride precipitation. For the precipitation, a 10% excess of ammonium fluoride is used to remove the maximum amount of calcium and magnesium. After precipitation and solid-liquid separation the split-stream is returned to reduce the overall calcium and magnesium concentration of the base metal stream."

Jan 1, 2003

By Y. Q. Qui

In the bauxite flotation process for desilication, the middling treatment mode is the important factor to raise the flotation recovery of the preparation concentrate. The middling treatment mode mainly depends on A/S and the size composition. However, similar ratio of A/S should not be the single factor of re-dressing, size composition plays an important role also. Re-dressing the middling mixed with the tailings of concentrated to the rough ground for desilication and the concentrate of scavenged to the fine ground for desilication to raise the recovery of 5.83%, when compared two flow sheet schemes.

Jan 1, 2014

By S. S. Lu

In sodium oleate and salicylhydroxamic acid systems, sequence of floatability of three sulfate minerals is: barite>celestite>gypsum, in lauryl amine system is: gypsum>celestite>barite. XPS and infrared spectrum analysis are used to find that it is chemical reaction between sodium oleate and three minerals, physical adsorption on the surface of minerals for lauryl amine, and it is chelating reaction between salicylhydroxamic acid and three minerals possibly. Theoretical calculation on chemical bonds in crystal structures of three minerals is carried out, finding that breaking degree of Mn+?O2- in crystal structures of three sulfate minerals is closed related with floatability.

Jan 1, 2014

By G. Semenchenko

Heterotrophic microorganisms Pseudomonas aureofaciens, microscopic fungi Fusarium sp. and their combinations with some chemical substances were used for gold leaching from refractory ore and flotation concentrateof Akbakaj deposit. All biological additives raised the speed of noble metals dissolution. The best results of gold extraction from ore were in the presence of bacteria or their associations with other solvents and from flotation concentrate in the presence of fungus - 30 % of additional amount of gold. The maximum extraction of gold speed value was during the first 8 hours of process. The electronic-microscopic researches of the ore samples showed almost complete decay of pyrite and arsenopyrite under bacteria influence whereas at chemical leaching most of these minerals stayed uncrushed. The presence of microscopic fungi in flotation concentrate during leaching provided full distraction of pyrite, but some crystals of antimony and arsenopyrite were undestroyed. During cyanide leaching of flotation concentrate there were accumulation of antimony and incomplete pyrite decomposition. Keywords: gold bioleaching, bacteria, fungi, complex solution

Sep 1, 2012

By T. Chmielewski

Unique mineralogical and petrological properties of black shale in the copper ore deposit of the Foresudetic Monocline (SW Poland) resulting from three lithological layers have been described in terms of its unfavorable behavior in the ore processing circuits. A concept of processing of a part of the black shale fraction from the flotation circuit of the concentrating plant by separating a by-product enriched in the shale matter was presented. This by-product represents the tailings of the first cleaning flotation and, as a hard-to-treat circulating middlings, overload the cleaning operation in the flotation circuit. It was found that the investigated by-product cannot be effectively up-graded using standard xanthate flotation. This is due to a fine dissemination of sulfide minerals in the dolomitic and clay shale particles significantly enriched in organic carbon. The content of the organic carbon is similar to that in the petrographically "pure" black shales. After a comprehensive examination of the shale by-product it was recognized that the investigated middlings can be regarded as a specific shale concentrate for individual processing. The effect of non-oxidative leaching of middlings with sulfuric acid on their further flotation was presented. It was shown that non-oxidative leaching is a selective process, in which calcium and magnesium carbonates decomposition leads to effective liberation of sulfide minerals which were finely disseminated in the hydrophilic carbonate gangue. Leaching of the flotation feed with sulfuric acid selectively decomposes carbonate minerals and consequently enhances flotation results. Saturation of leaching slurry with gaseous carbon dioxide favorably creates non-oxidative conditions and leads to a great decrease of the electrochemical potential of sulfide particles as well as hinders their solubilization. Partial carbonates leaching from middlings resulted in evident liberation of valuable minerals. Consequently, it resulted in an increase of both recovery and grade of concentrates obtained by flotation of shale by-product after non-oxidative leaching.

Jan 1, 2014

By Sanjeeva Latchireddi

The effective utilization of the energy in comminution devices depend on how efficiently the broken particles leave the breakage field as soon as they reach product size. In crushers the transport of broken particles smaller than CSS is done by gravity (vertical) thus allowing the energy to be applied to new particles. However, in AG/SAG mills, gravity becomes the energy field and the transport of particles is horizontal which needs a suitable discharge mechanism and has been found to have significant effect on grinding efficiency. The material transport in AG/SAG mills depend on how efficiently the discharge system (grate and pulp lifters) operates. Material transport plays a significant role on efficiency of horizontal grinding mills ? AG/SAG/Ball mills. The magnitude of benefits that can be achieved with efficient material transport in AG/SAG mills has been demonstrated in a Greenfield milling operation at Mirabela Mineração?s SantaRita Nickel operation located in northeastern part of Bahia in Brazil. This grinding circuit was commissioned in October 2009, which was designed as a typical SABC circuit to grind 4.6 mtpa (575tph) to produce a P80 of 125um with 10-12% ball charge in SAG mill. However, it has been operating as ABC circuit without any grinding media in SAG mill. The nameplate design capacity has been achieved in few days and has gradually increased to an average of +800 tph and still it is operating in ABC mode. The milling circuit commissioning resulted in small and relatively simple measures to rectify, which was reflected in the rapid commissioning of the milling circuit and it achieved the nameplate capacity within days. The Santa Rita grinding circuit consists of one 30?x 15.4? 8.5MW SAG Mill fitted with Outotec patented Turbo Pulp Lifters (TPL TM ) in close circuit with HP400 short head pebble crusher and one 20? x 28.4? 5.5MW Ball Mill in closed circuit with Warman cyclone cluster fitted with 10 x 26? CAVEX cyclones. This paper examines the comminution design process, operating philosophies, experiences, post commissioning optimization, and future development works. Evaluation of the milling circuit performance relative to the design criteria is also discussed. Keywords: Autogenous Grate (AG), Semi-Autogenous Grate (SAG, Turbo Pulp Lifter (TPL)

Sep 1, 2012

By A. S. Choudhary

Most of the coal reserves in India are of drift origin and have very poor washability characteristics and a high level of near gravity materials. At least 30 new coal wash plants are expected to be set up in the next 5years.In such a scenario, adequate sampling followed by sink float test work for washability analysis becomes very critical for designing these new plants. For coal sampling purpose, stipulations of different standards are sometimes formidable and on the border of ?impracticality?; sometimes are self contradictory in terms of gross sample weight vis-a-vis minimum number of particles required in each size fraction and in each relative density fraction and also the minimum mass in the latter. Validation of the generated data is another important aspect of washability analysis. These issues can easily be addressed by using straight forward mathematical relationships, well known RR plots and by using simple MS Excel tool, etc.

Sep 1, 2012

By S. A. Kondratyev

"The present research work aims at disclosing the dependence of flotation concentrate recovery and its grade on the physically adsorbed collecting reagent properties, viz., surface pressure in the reagent film at gas-liquid interface, velocity of reagent species spreading over the said interface, relation between interaction energies of collector molecules within a film and with water dipoles.When using a single collecting reagent it is possible to improve the flotation concentrate grade in two ways, namely, by reducing collector consumption rate or using a weaker reagent. According to the proposed mechanism, a decrease in the physically sorbed species of the collector leads to a decrease in the rate of removal of the kinetic restriction of a flotation contact formation. As a result, the recovery of the useful component is reduced and the content of valuable components in the flotation concentrate is increased. The relationship between the spreading velocity of physically sorbed species at the gas-liquid interface and the recovery and quality of the flotation concentrate has been experimentally proved. Reduction in collector consumption lowered the valuable component recovery at a higher grade of the concentrate.The reasons were established for a rise of valuable content in the flotation concentrate if a weaker collector was used. It is justified that the use of a weaker collecting reagent with a shorter hydrocarbon fragment declines physically sorbed species of collector. The spreading velocity of collector derivatives at gas-liquid interface tends to lower along with less participation physically sorbed species of collector in formation of a flotation aggregate. The spreading velocity is determined for products of interaction between butyl-and ethyl-xanthates and lead nitrate at gas-liquid interface. It is found that the spreading velocity of butyl-xanthate derivatives is higher than that of ethylxanthate derivatives.The research work gets insight into the nature of relation between useful component content in the flotation concentrate and the useful component recovery. It is pointed out that adjusting the collecting activity of a collector makes it possible to influence a useful component content in the froth product thus gaining a compromise between wanted grade and recovery parameters."

Jan 1, 2018

By Hamid-Reza Manouchehri

"The triboelectric charge attributes of feldspar, quartz and wollastonite minerals, after contacting different triboecharging medium made of different materials, were considered. Their charge acquisitions by different size fractions of minerals were monitored and accordingly their energetic work function values were estimated. Moreover the separation behaviours of these minerals through the electric field of a laboratory free falling separator were determined and the effects of some chemical reagents on separation their separation characteristics were studied.Finally an attempt was made to translate the findings from single mineral systems to a complex silicate ore, containing quartz, feldspars, wollastonite and some other silicates. The results show favourable prospect to apply the triboelectric separation technique for beneficiation such a complex raw material."

Jan 1, 2003

By S. V. Bogdanov, S. I. Grishaev

"The article presents the materials about the appropriateness of the use of rental indices to assess the effectiveness of the use of deposits of rare earth elements (REE). The authors suggest from the standpoint of rent payments to rate for the owner the possibility of using the anticipated rental income as the indicator for the analysis of preferences and economic significance of enrichment of extracted raw materials in the emerging field of rare earth metals (REE). Usually from ore mined at the fields, for flotation technology to produce concentrates with collective REE, then they are subjected to chemical-metallurgical processing of the received products are divided into pure oxides, chemical compounds or isolated from them pure metals and alloys. This commercial product is shipped to the buyer. REE were a non-renewable natural resources, so the calculations for determining differential and specific rent showed that during the development of the technologies of mineral processing of a specific field it is necessary to consider what the expected rental income depends on the magnitude of differential rent is related to the volume of production of REE for the whole planned period of exploitation of natural resources. This income is determined by the amount of stock field. For long-term exploitation of the deposit is observed in almost direct proportional dependence between the annual differential rent and the rental income. The decrease in rents in the long run is determined by the change in the composition of ores included in the extracted raw materials and the balance between light and heavy REE. The largest 70% reduction of the rent projected for ""cerium"" fields, while for ""yttrium"" these losses are considerably smaller. Tomtor, Chuktukon and Katuginskoye Russian deposits are characterized by a level of rent that is comparable to the mastered foreign sources of REE. Thus, the enrichment of minerals with REM in the domestic deposits is quite competitive at the world level. INTRODUCTION Deposits of rare earth metals (REE) are non-renewable resources that should be developed and used so that it would be possible to provide a reduction due to payment of appropriate resources for future generations. This compensation, due to the reduction of natural resources, can be carried out both in natural and in economic terms (1). When analyzing economic compensation options, particular attention should be paid to rental income in assessing the attractiveness of using different REE deposits. It is known that absolute and differential rents are summands when calculating the value of natural rents. The value of the absolute natural rent is proportional to the unit price of the product obtained from mineral raw materials and sold on the commodity market. Limitations, as well as the use in production processes and business, contribute to the gradual reduction of natural resources, which increases their consumer value and affects the price of commodity products from primary raw materials."

Jan 1, 2018

By Sergey S. Gudkov

In the current climate of changing the approach to mining and treatment of mineral resources, processing technologies are being developed that require little maintenance and are economically as well as ecologically sustainable. This may also involve the development of entirely new ways of ore processing. One promising approach is to use bioleaching for the pretreatment of gold refractory ores to cyanidation. Capital costs for vat bioleaching of concentrates and ores are very high and cannot be applied for small or medium-size deposits. IRGIREDMET JSC carried out bio heap leaching test work on refractory ore samples from three Russian deposits. Following this biological treatment a combination of flotation, vat bioleaching, and cyanidation are used to recover gold. After heap bioleaching, gold recovery was 75-80 per cent. It was found that efficiency of heap bioleaching process depends on ore feed size. High duration of this process is another feature and it lasts for about a year. This process can be also used for carbonates in the combination with other process during which acid generation occurs. The results of our studies have shown that this technology is amenable for refractory gold ores. Its introduction allows an increase gold recovery and to solve a number of environmental problems. Keywords: heap biooxidaton, the refractory of the ores, the degree of oxidation, arsenopyrite, pyrite, CIL

Sep 1, 2012

By H. D. Yu

In this paper, an evaluation about the process mineralogy of the rich iron mine in Mongolia with comprehensive methods is given; this provides foundation of the comprehensive recovery of iron and cobalt in the ore. The research shows that the iron?s grade is 61.23%, Co?s grade is 0.02%, the ore is rich iron ore and its Co content also reaches border mining grade. For the ore, if want get high grade iron concentrate powder, must identify the mineral composition and the occurrence of iron and take into ac-count the recovery of Co content as associated resources. Chemical phase analysis results show that 86.35% of iron exists in magnetite, which means that the theoretical recovery ratio of iron is close to 86%. Minerals spectrum analysis confirmed that the magnetite containing a small amount of Mg, Al, and other impurities, the actual iron minerals to 70.28%, which means that theoretically iron grade iron concentrate only close to 70.28%. Based on the result of iron chemical phase analysis, by investigating the liberation of sulfide minerals and gangue, the recovery index of iron can be forecasted, when grinding fineness is 35%, 45%, 55% and 65% bellow 0.074mm,theoretical content of Fe in iron concentrate separately is 67.71%,67.88%,68.78%,and 69.43%,accordingly the theoretical recovery of Fe is 87.38%,87.05%,86.92% and 86.63%. From the perspective of process mineralogy, the forecast mineral beneficiation indicators show that the ore is easy sorting ore, iron processing operations have higher recovery rate, but wants sorting of high-grade iron ore concentrate still need appropriate grinding fineness. Furthermore, associated element Co, existing mostly in pyrite and pyrrhotite, is valuable in the ore. Pyrite and pyrrhotite have ideal liberation under grinding, so cobalt can be easily enriched in sulfide concentrate.

Jan 1, 2014

By A. M. Muhamedilova, S. M. Narbekova, L. V. Semushkina, D. K. Turysbekov, N. K. Tussupbayev

The research and development of new, more selective collectors in order to improve flotation efficiency represent one of the main priorities in the development of innovative technologies pertaining to flotation separation of various substances and minerals. The use of collectors’ mixtures is considered as the universal instrument for ensuring necessary proportion of chemically and physically sorbed collecting reagents in every individual case. Currently hard-dressed, refractory ores and man-made raw materials, which are characterized by low content of valuable components, fine dissemination of mineral assemblages and similar technological properties of constituent minerals, are widely involved in the recycling processes. The possibility of processing tailings, which are left after flotation beneficiation, has been considered in the case study of tailings of the Zhezkazgan beneficiation plant and the Tishinsk copper ore deposit with utilization of the modified multifunctional flotation reagents. Modified poly-functional collector is the mixture of composite Aerofloat, TC-1000 and butyl xanthate. Reactants ratio is 1:1:3. The advantage of the suggested flotation reagents is that they are composed of two polar groups and have a long hydrocarbon radical. This structure, being in the water during flotation process, plays a dual role: first, as a collector adsorbing on the mineral surface it produces metal complexes with polar groups in the form of bridges; second, apolar radicals flocculate valuable slimed components, thereby intensifying flotation process. It has been shown that flotation of Zhezkazgan tailings with utilization of the lesser modified reagent amount compared to butyl xanthate has enabled to produce crude copper concentrate with 13.0 % copper grade and 80.22 %recovery. Compared to the baseline technology, copper content of crude concentrate has been increased by 5.1 % and the recovery by 31.4 %. It is shown that tailings flotation of the Tishinsky field by applying modified collector allows for increase of the of useful components extraction in a collective concentrate with: copper 9.63 %, lead for 8.41%, zinc 9.2 %, iron 2.73 %, gold 3.57 %.

Jan 1, 2018

By G. Önal

Recovery of nickel and chromite from the tailings has been studied on the samples with 0.214 % Ni and 5.10 % Cr2O3 content and taken from Orhaneli Chromite Concentration Plant. Mineralogical examinations of the samples showed the existence of chromite, olivine, pyroxene, chrysotile, anti-gorite, chlorite, idingite, tremolite and calcite together with trace amounts of millerite, pentlandite, pyrite, pyrrhotite, hematite and limonite type iron oxide minerals in partially serpantinized dunite type particles. In order to recover chromite from Chromite Concentration Plant tailings Mozley Table and Knelson Separator are used and concentrates containing approximately 42% and 46% Cr2O3 are produced respectively with 40% recovery. Most of the nickel remained in the tailings. Therefore, acidic leaching tests are performed in order to dissolve nickel from these tailings. Effects of particle size, acid concentration, temperature, leaching time and solid/liquid ratio on the nickel leaching efficiency are investigated. The optimum leaching conditions are found as 250 g/L acid concentration, 1/5 solid/liquid ratio, 2 hours of leaching time and 60°C temperature, almost all nickel is dissolved at the optimum conditions and acid consumption is about 841 kg/t. Repeated leaching tests are carried out in order to have enough Ni content in the leach liquor for the further treatment of solutions. After repeated leaching tests, leach liquor contains 3 kg/m3 Ni, 48 kg/m3 Fe, 2.2 kg/m3 Si, 23 g/m3 Cr and 590 kg/m3 H2SO4. Ni is recovered from that solution by precipitating with H2S followed by HNO3 dissolution and precipitating Ni as hydroxide with 63% Ni content. Leach cakes are subjected to the gravity separation (Mozley table) to recover the remained chromite and a chromite concentrate with 47% Cr2O 3 content is produced with 53% recovery. As a result of the abovementioned tests, a conceptual process flow sheet is proposed for the treatment of these chromite concentration plant tailings.

Jan 1, 2014

By N. ??dyanik, Z. Kugukaldinova, O. Mishurina, Y. Glazkova, E. Mullina

"This paper describes the process flow of a selective processing method for acidic mine waters formed in the copper sulfide industry and characterized by a high content of copper, iron, and manganese ions. The proposed method comprises a series of sequential processes: the 1st stage is the recovery of Cu2+ ions by precipitation, the 2nd stage is the recovery of Fe2+ and Fe3+ ions as a dispersed phase by acid-base precipitation, followed by recovery in the 3rd stage of Mn2+ ions by converting Mn2+ with an oxidizing agent into insoluble forms of manganese and subsequent recovery of the dispersed phase by electroflotation. The developed method was tested on the acidic tailing storage facility (TSF) water of a mining project in the Urals region. The practical results of the implementation of the developed method have shown that its implementation will allow to recover copper, iron, and manganese in the form of salable products with a simultaneous decrease in their concentrations in adjacent water bodies down to the applicable MPCs. The process is a simple one, does not require any sophisticated expensive equipment and can be implemented either as a standalone solution or as part of existing treatment facilities. INTRODUCTION As a result of unsustainable utilization of natural resources in Russia, only a small fraction is processed into commodity products, while the rest is systematically dumped as emissions, effluents, and other wastes, polluting the environment. By amount of waste and concentration of valuable components, those wastes can be classified as aqueous technogenic resources [1, 2]. Therefore, the development of processing methods for this mineral resource category is an urgent and priority task that will significantly improve the industry’s profitability and the environmental conditions in the respective regions. MATERIALS AND METHODS Following research methods were mainly applied in this study: lab-scale and pilot-scale tests in a diaphragmless two-chamber electric flotation cell; for solutions and recoverable process products — chemical analysis using photometric determination techniques for metal cations and atomic adsorption determination techniques for the processing products. The phase composition of the precipitates formed in the process was investigated by X-ray phase analysis in the general-purpose diffractometer with a copper anode DRON-1."

Jan 1, 2018

By S. Sarioglan

The bleaching of edible oils, industrial oils, and some chemicals may be achieved using natural and acid-activated clays. These materials remove impurities and pigments from the oils. In this work, a bentonite clay from Turkey (Somas bentonite) was activated with different concentration of H2SO4 and HCl at 70~90°C and 5~8 hours. Under these conditions several cations were removed from natural bentonite (Al, Mg, and Fe) and DTA-TGA, FT-IR curves of the solids obtained after acid treatment were examined. Treatment time and acid concentration increased the degree of destruction of the bentonite structure which was determined by ICP. Activated samples were tested in order to verify their capacity to bleach soybean oil and compared to standard commercial bleaching clays. The experimental results indicate that treated samples with H2SO4 have the same efficient in bleaching crude soybean oil with the standards and treated sample with HCl is more efficient in bleaching than the commercial products.

Jan 1, 2014

By Brabcova Z.

This contribution deals with bubble adhesion on particle surface which consists of three steps ? the liquid film thinning, the film rupture and expansion of the three phase contact (TPC). Our attention is devoted to the third step ? to the description of the TPC expansion. Three-phase contact line expansion can be theoretically described using hydrodynamic and molecular-kinetic models. Both of these models were originally developed for the interaction of the bubble with horizontal plane in pure water. Our experiments deal mainly with the interaction of the bubble with the inclined plane in the solution of surface active agents. It was proved experimentally that molecular-kinetic model corresponds also to these conditions and this model was used for the description of the TPC expansion. The model is based on the theoretical description of the bubble contact angle on the three-phase interface. These contact angles change dramatically from 180o to equilibium (Young) contact angle close to 90o. Modificated ADSA method is used for the calculation of the contact angle. This method utilizes the Laplace equation of the capillarity; the bubble profile and the contact angle are evaluated using the set of experimental points around the edge of the bubble. The comparison of the experimental and calculated bubble profile shows a good agreement. The aim of the project is to describe the process of the TPC expansion during the adhesion of the bubble with the diameter up to 1 mm. Inclined planes were used instead of an experimental solid particle. Our experiments were provided in the solution of surface active compounds. The process of the adhesion was recorded using high-speed digital camera and images were evaluated using the image analysis software NIS-Elements. Calculations were performed using the MATLAB software. Keywords: bubble-particle interaction, adhesion, three-phase contact, contact angle

Sep 1, 2012

By F. L. Wang

The purification process of water-mining carnallite and rough potassium chloride concentrate from Qinghai Salt Lake Industry Group Co. Ltd. are investigated by the preprocessing-reverse flotation technology respectively. The results show that the impurities such as calcium sulfate and sodium chloride can be effectively removed from water-mining carnallite ore and rough potassium chloride concentrate by the new technology, the low-sodium carnallite is obtained and the final potassium chloride product greatly upgraded. The content and the recovery of KCl in the low-sodium carnallite are 25.78% and 97.50%, meanwhile the content of NaCl, CaSO4 in the low-sodium carnallite are 0.56% and 0.24%, and the removal of sodium chloride and calcium sulfate in the low-sodium carnallite are 97.48%, 85.10% respectively. The KCl content and recovery of high quality potassium chloride product are 98.25%, 96.70%, and CaSO4 content is 0.40% with 83.24% calcium sulfate removed in the high quality potassium chloride product.

Jan 1, 2014

By Caroline Olsen

The objective of this study was to achieve Zn activation control in an industrial Cu flotation circuit treating a complex Cu-Pb-Zn-Au-Ag sulphide ore at the LaRonde Division of Agnico-Eagle Mines Limited (Québec, Canada). In order to provide process relevant results, a laboratory testing methodology was developed to duplicate plant operational parameters. The action mechanisms of ZnSO4, TETA (triethylenetetramine) and NaHSO3used as depressants in order to limit ZnS activation were examined. Laboratory flotation tests with and without Cu2+ions (the ions responsible for ZnSactivation)were performed. All depressants showed equal or better flotation performance relative to baseline tests. For example, in the presence of Cu2+, the Zn recovery reduced from 32.2% to 17.5% in the copper rougher concentrate after adding ZnSO4(with a dosage of 50 g/t). TOF-SIMS analyses confirmed the relative decrease in surface Cu in the samples treated with ZnSO4and TETA. For the case with TETA, this indirectlyindicates the formation of a copper TETA complex in solution, thereby reducing available Cu for transfer. The TOF-SIMS and XPS data indicate that the addition of ZnSO4and NaHSO3resulted in an increase in surface metal hydroxides and SO3 on ZnS grains inhibiting both Cu and collector attachment.ZnSO4 was subsequently tested with success in the LaRonde concentrator. The addition of 40 g/t ZnSO4 at the conditioning (or cleaning) stage led to a 2% reduction in Zn content in the Cu and PM concentrate. Recently, improvements towards the control of copper sulfate addition in the downstream Zn flotation circuit resulted in the reduction of Cu2+ in process water. As this ?cleaner? water is recycled for Cu and PM flotation, the addition of ZnSO4 is now used only as required.

Sep 1, 2012