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By Eugene S. Perry

The only outstanding development in Montana oil or gas fields during 1935 was the extension of the Cut Bank oil and gas field 7 miles southward. This field is now about 20 miles long and 3 to 8 miles wide, with 218 producing oil wells and 39 producing gas wells. Average daily production of the oil field during December, 1935, was about 6700 bbl.; total production for the year 1935 was approximately 2,020,770 barrels. The Cut Bank field in northern Montana is in a flat to rolling glaciated area used mainly for grazing purposes. Oil and gas occurs in sandstones and shaly sandstones in the Kootenai (Dakota) formation of Lower Cretaceous age at depths ranging from 2700 to 3000 ft. Prominent anticlinal or domal structure is not present, but small plunging anticlines occur locally. Strata dip westward from 75 to 200 ft. per mile. The field lies on the western flank of the Sweetgrass arch, a broad gentle upwarp over 150 miles long. Localization of oil and gas appears to be due either to pinching or lensing out of the sandstone beds, or else silting of the sandstones with clay minerals so that porosity becomes low. Within the field offset wells show marked variation in initial production, which suggests that differences in porosity of sandstone is the controlling factor. The gas-producing portion of the field is entirely updip (east) from the oil-producing portion, and the producing horizons are the same. Initial production of oil wells ranged from about 50 to about 200 bbl. per day, and initial open flow of gas wells ranged from about one million to about 37 million cubic feet per day, with an average of 11 million cubic feet. Initial gas pressures were slightly greater than 700 lb. per sq. in. Oil is brought to the surface by pumping. Both rotary and standard churn-drilling equipment are used. In the remaining 14 oil and gas fields but little new activity took place other than the drilling of offset wells and wells in proven territory. Continuation of "acid treatment" of wells in the Kevin and Pondera oil fields led to reconditioning of many old wells and the drilling of a number of new wells within these fields. Acid treatment of the oil-bearing horizon, which is the dolomitized and silicified Madison limestone of Mississippian age, has proved quite satisfactory, and some "bone dry"

Jan 1, 1936

I. PRESIDING OFFICER. At all business meetings of the Institute the President, or, in his absence, the First Vice-President, or, in the absence of both of them, any other Vice-President or Director, chosen by the meeting, shall preside. At all other meetings of the Institute the President, or, in his absence, one of the Vice-Presidents, shall preside. If none of these be present the meeting shall elect a Chairman. II. ORDER OF BUSINESS. At each business meeting of the Institute the order of business shall be as - follows : 1. Reading of minutes-of preceding meeting. 2. Report of the President. 3. Report of the Treasurer. 4. Report of the. Secretary. 5. Election of Directors. 6. Reports of Standing Committees. 7. Reports of Special Committees. 8. Special Orders. 9. Miscellaneous business. This order of business may be changed at any meeting, by a vote of a majority of the Members and Associates present. At all sessions of the Institute, other than business meetings, the order of pro¬ceedings and the time of adjournment shall rest in the discretion of the presiding officer. III. SECRETARY OF THE INSTITUTE. The Secretary shall keep a record of the proceedings of all meetings of the Institute. He shall be custodian of the corporate seal, of the minute books, and of all legal documents belonging to the Institute. He shall have charge, on behalf of the Institute, of all correspondence except such as pertains directly to the office of the Treasurer. He shall notify all Officers and Directors and all members of committees of their election and appointment; shall issue notices of all meetings of the Board, and of the annual and other business meetings of the Institute; and shall; in calling, special meetings of the Directors, specify the objects of such meetings. He shall act as clerk at all the meetings of the Board of Directors and at all meetings of the Institute. The Secretary shall be custodian of all technical or scientific papers submitted to the Institute for its consideration, shall have general charge and supervision of the editing and proof-reading of all material published by the Institute, and of the distribution thereof, and be ex officer Chairman of the Committee on Publications. On the first day of May following the year in which each volume of Transac-

Jan 1, 1925

By Ralph H. Sweetser

AT the joint session of Blast Furnace and Open Hearth Committees, April 7, 1937, at Birmingham, the subject of the quality of basic open-hearth pig iron was so well presented and discussed from so many different viewpoints that it was the general opinion that progress had been made and that such meetings were conducive to the advancement of the art of making pig iron of the right quality for the open-hearth man to produce the most satisfactory quality of steel. It was agreed that there is a decided differentiation between the chemical analysis of pig iron and the "quality" of pig iron. Paul J. McKim said that open-hearth furnace operators frequently make reference to certain types of iron as "bad iron," "dirty iron," "cold metal," etc., claiming that when using these irons, although they are within specified chemical analysis, it is impossible to produce quality steel. Mr. McKim gave a list of the suggested causes of those "certain types" of bad irons that have a thoroughly respectable analysis but a thoroughly disreputable character. Another open-hearth man, P. A. MacIsaac, of Nova Scotia, said that The effects of iron that is below standard in analysis or in that mysterious property called quality, are well known to all open-hearth operators. It has been shown that iron of this type results in the production of steels on which the rejections of finished product run high. What is to be done about it? I would say that the burden of producing high-quality iron should be placed squarely on the shoulders of the blast furnace man, even as that of making good steel is shouldered by the open-hearth man. It is the purpose of this paper to bring out into the open this "mysterious property called quality"; that is, in those "certain types" of basic pig iron that make it impossible to produce quality steels; and at the same time to point the way for the blast-furnace man to be able to shoulder the burden that Mr. MacIsaac and all other open-hearth men and foundry-men have placed upon him. Silicon, sulphur, phosphorus and manganese are not the guilty elements because these are known, specified and usually kept within the

Jan 1, 1938

By J. W. Pamplin

SOME 40 miles east of Tampa is the center of the Florida pebble phosphate deposits. These are of Pliocene age and consist of several members of the Bone Valley formation.1 Physically the phosphate-bearing formation, locally called the "matrix," varies in thickness from nothing to about 25 ft., usually averages 10 ft., and consists mainly of clay, quartz and phosphate pebble, the latter particles varying in size from colloidal to one inch diameter. The pebbles range in color from dark gray, through white, to cream, and in hardness from that which must be broken with a hammer to that which can be scratched with the fingernail. They assay from 66 to 80 per cent bone phosphate of lime (called "B.P.L." in the trade) or tricalcium phosphate (Ca3P20s) and are secondary apatites. They form from 15 to 50 per cent by weight of the matrix, Over the matrix lies a varying thickness (5 to 40 ft.) of overburden composed of quartz and clay. Briefly, mining consists of two operations2 in open pits about 200 ft. wide by ½ mile or more in length. In the first step overburden is removed by large electric draglines at the rate of about 700 cu. yd. per hour. This is followed closely by hydraulic mining of the matrix at the rate of about 300 cu. yd. per hour. This matrix yardage is moved from an improvised sump in the floor of the pit to an ore-dressing plant, some-times a mile distant, by one, two or three "pit-cars" (pumping units) working on a 12-in. pipe line called the "rock line" to distinguish it from the high-pressure water line feeding the hydraulic giants, which is known as the "hydraulic line." This 700 yd. of overburden and 300 yd. of matrix-1000 yd. in all-amounts to about 1500 tons of material moved each hour. The over-burden is dumped into the mined-out pit alongside the pit being mined. The matrix moves to the ore-dressing plant at the rate of about 7 ½ long tons in 4000 gal. of water per minute-a ratio of approximately one to two by weight, or one to six by volume. This constitutes the "mill heads," but in the pebble district it is called the "matrix."

Jan 1, 1938

By G. C. Broadhead

The lead district of Southeast Missouri covers an area of over 3000 square miles, including Maries County on the west, Jefferson on the east, Franklin on the north, and part of Madison on the south, or parts of ten counties. A general section of the rocks of the southeast part of this region would be about as follows, numbering from the top: 1. Sandstone (the second of Missouri geologists),.... 20 feet. 2. Chert beds—beds of passage below,...... 126 " 3. Magnesian limestone, chert, and quartzite,. .. 100 to 300 " 4. Lower magnesian limestone,......100 to 150 " 5. Gritstone and lingula beds,....... 50 " 6. Ozark marble beds,........5 to 20 " 7. Sandstone and conglomerate,. .. .. 5 to 90 " 8. Porphyry, Archæan 9. Granite, The thickness is approximate, for it is not possible to obtain the correct thickness of the various beds. No. 1 may be seen as detached outliers or loose masses of a hard sandstone or quartzite, and is found on the hilltops in the southern part of Madison County, in like topographical position in Reynolds County and the western part of Washington County. No. 2 consists of alternations of chert, clay, and quartzite. It is the formation which contains most of the limonite deposits of Central and Southern Missouri. In Reynolds County shafts have penetrated it 75 feet. Outcrops there and in Madison would indicate it to be at least 125 feet thick. Fossils obtained in various places prove it clearly to be of the age of the calciferous saudrock of the New York system, and Nos. 1 and 2 may also be referred to the age of the second sandstone of Missouri. No. 3 consists chiefly of thick beds of ash, drab and flesh-colored magnesian limestone, both coarse and fine-grained. These beds, where they occur, in Washington, Jefferson, and the southern part of Madison Counties, contain a good deal of quartz in drusy cavities. In Washington County the limestones are beautifully ramified by a system of connected drusy cavities generally lined with minute quartz crystals arranged in botryoidal and mammillary forms, and called " mineral blossom " by the miners. This is the lead-bearing rock of Washington County, but in the southern part of Madison it does not appear to be galeniferous. It is also undoubtedly the equivalent of

By George Rice

SOME form of longwall mining is generally used in Continental Europe; also in Great Britain where the coal is weak and friable, or the coal bed provides material for pack walls and filling, or where the bottom is soft and squeezes up easily, or the roof is pliable, or the bed is thin and brushing provides building material, or the thick multiple seams are mined in layers, such as the 24-ft. seam at Weymss, Scotland or the 10-yd. pitching bed near Coventry, England. Pillar methods have been retained in British fields where the coal beds are from 5 to 9 ft. (1.5 to 2.7 m.) thick, and free from thick partings or binders or without draw slate, which would provide waste rock for pack walls, or where the roof is hard and requires shooting to bring down and also the bottom or floor is comparatively hard. The room-and-pillar system, by which probably 95 per cent., of the coal of the United States is produced, is now found in only a few mines in Wales, where it is known as the pillar. and .(single) stall method. The American room-and-pillar system is not equivalent to the bord-and-pillar or stoop-and-room system. The essential difference between the bord-and-pillar and the average American room-and-pillar system is probably due to natural conditions. The majority of the coal mines in the United States have a depth of less than 700 ft. (213.m.). The bulk of the coal mined in Europe comes from a depth of more than 1200, ft., while the deepest mines in Great Britain, Belgium, and France reach 3500 to 4000 ft. In deep workings wide spans are impracticable, even with the use of abundant timber; accordingly, as the mines in the United States become deeper the rooms will become narrower and the pillars thicker, and the bulk of the coal will be extracted on the retreat. It is generally conceded, without reference to the cost of production, that the larger the pillars left on the first mining, the more thoroughly can the, coal be extracted. In Europe complete extraction is generally compelled either by the lessors or by the governments; whereas in this

Jan 2, 1921

By T. L. Joseph

Sulfur balances calculated from operating data covering thirty-five blast furnaces indicate that approximately 92 per cent. of the total sulfur charged enters with the coke, 7 per cent. with the ore, and 1 per cent. with the stone.. Most of the sulfur is carried from the furnace by means of the slag, the total amount eliminated being the product of the slag volume and the percentage of sulfur it contains. Additional sulfur in the charge must be eliminated either by increasing the percentage of sulfur in the slag or the quantity of slag. From relations found between slag volume and coke consumption and sulfur in the coke and slag volume, curves have been prepared showing the relative value of blast-furnace coke as its sulfur varies from 1 per cent. CHARCOAL was the predominant blast-furnace fuel until 1838, when it was found, by the operation of a 2-ton experimental furnace, that anthracite could also be used. This information was a stimulus to the iron industry, particularly in eastern Pennsylvania where anthracite was available at low cost. The production of anthracite pig iron increased steadily and, in 1855, its tonnage exceeded that of charcoal iron. Of the 680 furnaces in operation in 1874, the 226 using anthracite produced nearly one-half the total tonnage. In 1869, the production of coke furnaces exceeded that of charcoal furnaces and, in 1875, coke surpassed anthracite as a metallurgical fuel. In 1907, the output of anthracite pig dropped well below a million tons and its present significance is largely historical. In recent years, the production of coke has gone hand in hand with the production of pig iron and it has gradually attained the position it now occupies as a universal blast-furnace fuel. Charcoal, however, has great merit as a blast-furnace fuel chiefly because of its freedom from ash and sulfur. The harmful effect of the latter and the necessity of keeping the percentage of this element in pig iron at a minimum are well recognized. Other contaminating elements can be reduced to specified limits in the steelmaking process, but the control of sulfur belongs essentially to the blast furnace. The purpose of this paper is to point out the distribution of this impurity in blast-furnace

Jan 9, 1924

By R. J. Linney

Reserve Mining Co. produces 5 million tons of iron ore pellets per year. The finished product runs about 65.50 pct Fe, with 7.75 to 8.00 pct SiO2. Less than 12 pct arrives at the blast furnaces smaller than % in. This plant was originally designed to produce 3.75 tons annually—not 5 million. To handle the increased tonnage a fifth fine crushing line was added, and some very minor changes were made. When production can be stepped up 33 1/3 pct without extensive additions or changes—within the short period of a year—basic engineering has been sound. Operators of the plant consider it the best design job they have seen or heard of, and competent authorities have said that start-up was quicker and easier than for any previous large-scale minerals beneficiation plant. One big advantage is the elbow room allowed. Generally speaking, there is an eternal conflict between operator and designer over space. The designer has his costs per cubic foot, and he is keenly aware that if he permits the number of cubic feet to rise unnecessarily, total costs will be too high. But this was a new operation, and on a large scale. There were no proven standards to go by. Realizing this, Reserve's engineers provided ample and efficient access to machinery, allowing extra space for unanticipated situations. In three years of production this planning has paid off handsomely. Gravity Flow Saves Time and Money: This plant is on a rocky hillside, the car dumper about 270 ft above Lake Superior. In locating buildings and placing machinery the designers mad= good use of gravity flow, at considerable financial savings. In the concentrator building from rod mills to filters, gravity carries the material between all stages of the operation except one—the closed circuit pumping of concentrate between cone classifiers and ball mills. Since no machine is located directly above any other, an observer can stand on the truck ramp adjacent to the offices and laboratory and see practically every phase of activity in the huge building. The first mill section started in August 1955. After a day's run several modifications were made on auxiliary chutes and launders where spillage had occurred. This procedure was followed for the first

Jan 1, 1960

By George A. Connell

BORAX, a sodium borate and the principal sodium salt of boric acid, has been surrounded with romance and with a certain amount of mystery. Its early history is not entirely known but it has been contended that Marco Polo in his travels in the Orient introduced this material to the West during the Middle Ages. Without doubt its first source was from Central or Eastern Asia and perhaps from Tibet. The well-known fluxing properties of borax probably introduced its earliest use that of a soldering flux in the manufacture of jewelry. This use, as well as the remote location of most borate deposits, added greatly to the romance associated with the thought of borax. COMPOSITION The common element in all borates is boron but this element has never been discovered as such in any deposit, because of its great affinity for oxygen. Incidentally, this makes its manufacture extremely difficult and expensive. Elemental boron undoubtedly has many properties that make it quite valuable but the extreme cost involved in producing it from its oxidized form prevents its general use or manufacture. The common element in all borates is boron but this element has never been discovered as such in any deposit, because of its great affinity for oxygen. Incidentally, this makes its manufacture extremely difficult and expensive. Elemental boron undoubtedly has many properties that make it quite valuable but the extreme cost involved in producing it from its oxidized form prevents its general use or manufacture. The common element in all borates is boron but this element has never been discovered as such in any deposit, because of its great affinity for oxygen. Incidentally, this makes its manufacture extremely difficult and expensive. Elemental boron undoubtedly has many properties that make it quite valuable but the extreme cost involved in producing it from its oxidized form prevents its general use or manufacture of disodium tetraborate (Na2B4O7.10H2O), and, further, can be considered as the acid salt of monosodium metaborate. However, the term "acid salt" might imply that borax gives an acid reaction in solution, which is not true, since solutions of borax are decidedly alkaline, giving a pH of 9.2. Boric acid, also known as boracic acid, has the chemical formula H3BO3; it occurs in nature as the mineral sassolite. Sassolite has been

Jan 1, 1949

By Robert T. Howard, Morris Cohen

IT has long been realized among metallurgists that a fast, reliable method for the quantitative determination of the percentage of microconstituents in an alloy would be of great benefit in studies of equilibrium and transformation in the solid state. For example, Polushkin1 has shown that the compositions of two coexisting phases in a a binary system at a given temperature may be calculated very simply with the aid of two alloys lying in the two-phase field if the relative amounts of the two phases in each alloy can be determined. Recently, Grange and Stewart2 have traced the course of the austenite-martensite reaction in a series of commercial steels by making visual estimates of the percentage of martensite formed as a function of cooling temperature. The correlation of mechanical properties with structure, a subject of wide-spread current interest, is likewise dependent upon quantitative microanalysis.3 Yet, there are very few investigations described in the metallurgical literature, wherein methods of quantitative microscopy are employed. Usually, the relative amounts of the microconstituents are estimated in a qualitative or semiquantitative way. The authors were faced with this problem some time ago in studying the kinetics of austenite decomposition. Several aspects of, this research could not be treated satisfactorily by other quantitative tools, such as specific volume,4 magnetic,5 dilatometric,6 electrical resistance7 or x-ray measurements.8 It became necessary to find an impersonal quantitative method that could be applied to microstructures. Fortunately, it was noted that geologists and petrographers had coped with quantitative microscopy to a considerable degree in their attempts to evaluate the mineral contents of rocks. A number of excellent articles were found on this subject, and since they appear to be unknown generally to many metallurgists, the first part of the present paper is concerned with a review of the literature in some detail. With this survey as a background, the authors have adapted the so-called methods of point-counting and lineal analysis to metallography, as described in the second part of the paper. Austenite-martensite structures were selected for illustration not only because they are important in many ways, but because such fine intermixtures are notoriously difficult to estimate visually. LITERATURE SURVEY Perhaps the earliest work on quantitative microscopic analysis goes back to Delesse9 (1848) who proved mathemati-

Jan 1, 1947

By Olav Klomstadlien

The lean, but extensive iron ore deposits of the Dunderland Valley north of Mo i Rana, Norway, are the raw material base for Rana Mines, a division of the state-owned A/S Norsk Jernverk steel mill. The iron bearing minerals are magnetite and specular hematite. The magnetite/hematite ratio varies considerably both within each deposit and from one deposit to another. The ore bodies that lend themselves to mining have generally a thickness of 30-60 m grading 30-35% Fe and 0.15-0.25% P. The grain size varies from 0.05 to 2.5 mm. The fine grained ores are hard while the coarse grained ores are soft and easy to grind. The A/S Norsk Jernverk steel mill operates both a sinter and a pellet plant, and this necessitates production of two types of concentrates. The present flowsheet is shown in [Fig. 1]. The crude ore from the pits is crushed in a 1.07-m gyratory crusher with an open side setting of 12.7 cm. The crusher product is transported by rail to the concentrator located 25 km from the mines. The ore is fed by twelve 1.22 X 1.83 m vibratory feeders onto conveyor belts which carry the ore to a surge bin ahead of the autogenous mills. The feed rate is automatically adjusted to maintain a set power load at a level suitable for the ore type being processed. The mills operate in closed circuit with twelve dual-drum screens equipped with a 0.8-mm screen cloth. Oversize is returned by gravity to the mill feed while undersize flows to the gravity separation section which consists of Humphrey spirals in three stages. The ores are very heterogenous and analysis may vary quite considerably. The quantitative need for concentrate in the steel mill may also change rapidly. The process in the concentrator must therefore be easily changed, and consequently alternative process lines have been established. This is indicated with the dotted lines in the flowsheet. Apatite is removed by flotation by fatty acids to give a final sinter concentrate of 63% Fe and 0.020% P or less. Pellet concentrate contains about 65% Fe and less than 0.020% P. The fineness is about 1500 Blain.

Jan 1, 1981

The world's production of petroleum in 1926 amounted to nearly 150 million long tons, of which India contributed 0.72 per cent. In 1927, this figure jumped to some 172 million long tons, of which the Indian proportion, on a practically stationary production, fell to 0.64 per cent. In 1928, there was another substantial rise in the world's production, which reached the figure of over 181 million tons. In 1929, there was another jump to over 202 million tons, but in 1930 the world's production fell to about 193% million tons, in 1931 to about 187 million tons, and in 1932 to about 183 million tons, while in 1933 the production rose again to about 202 million tons, in 1934 to about 215 million tons, and in 1935 to 233 million tons1. Decreases were shown by Poland, Sarawak, Egypt, Rumania and France. All other important producers showed an increase in production, by far the largest being due to Iraq, as a result of the opening of the pipe line to the Mediterranean. The United States contributed 60.9 per cent of the world's supply in 1935, Russia 10.7 per cent, Venezuela 9.4 per cent, Rumania 3.9 per cent and Iran 3.1 per cent. In 1928, India contributed 0.64 per cent, which fell to 0.60 per cent in 1929 and rose to 0.62 per cent in 1930, 0.63 per cent in 1931, and 0.64 per cent in 1932, and fell again to 0.62 per cent in 1933, to 0.60 per cent in 1934 and to 0.50 per cent in 1935; her position on the list of petroleum-producing countries fell from eleventh in 1929 to twelfth in 1930 to 1933, her place being taken by Trinidad and to thirteenth in 1934 and 1935, owing to the production by Iraq. The production of petroleum in India (including Burma2) increased slightly from 322,025,280 gal.3 in 1934 to 322,662,336 gal. in 1935, the highest figure in the history of the industry. The increase in 1935 is due to an increase of some 4 million gallons in Assam, almost offset by a decrease of 31/2 million gallons in Burma. This increase in output in 1935 was accompanied by an increase in estimated value amounting to Rs. 22,73,550 (£170,944).

Jan 1, 1937

By Gerhard Derge

THE chemical and physical properties of slag systems are of special interest to metallurgists, for nearly all metals are in contact with molten slags during the primary reduction from their ores and then during the subsequent refining and alloying processes that determine their ultimate use, These processes are carried out at high temperatures and involve such complex chemical systems that fundamental scientific knowledge of the properties and behavior of these slags is inadequate. Various hypotheses have been proposed to explain known slag characteristics. The commonest of these regard the molten slag as constituted of compounds that are dissociated in varying degrees into their constituent oxides, as illustrated by Schenck1 and the recent papers of Chipman and co-authors.2-5 Another proposal is that these compounds dissociate by completes or partial ionization, the evidence for which has been reviewed by Martin and Derge.7 Whatever hypothesis is favored, the exact formulation of these compounds is incomplete. It is based on three principal types of information: I, Studies of solidified slag samples by X-ray diffraction, petrography, and similar methods that can be used at room temperature, The correlation of this information with the high-temperature properties of the molten slag is uncertain, 2. Studies of slag-metal equilibria, which have the advantage of providing observations on the molten slag at high temperature, However, even these data present problems of interpretation because they require a complete knowledge of the metal phase, 3, Direct measurements of properties of molten slag at the temperature of greatest metallurgical interest. Viscosity, electrical conductivity, specific heats, and similar properties have been measured, but the data of this type are widely scattered and frequently difficult to interpret, Additional direct measurements of properties of molten slag that can be interpreted in terms of chemical behavior are required, and this paper shows that the standard physical-chemical measurement of reversible electrode potentials, which measure the activity of specific constituents, is a fruitful source of such information, The purpose of this investigation, therefore, was to find an electrode combination that would yield reversible electromotive force measurements when dipped into the molten slag to be studied. Slags of the systems CaO-SiO2 and CaO-A1203-Si02 were chosen for study because graphite containers could be used and the data could be correlated with those for viscosity, conductivity, and other proper-

Jan 1, 1946

By J. J. Bodmer

The substances or materials employed in this manufacture, are the same as those used in the preparation of mortar and concrete, viz., the different kinds of lime and sand. Instead of, or in conjunction with, sand there may be used calcined clay, blast-furnace slag, clinkers or ashes from furnaces, natural puzzolana, powdered chippings from stone quarries, etc. Of the different kinds of sand, pitsand—siliceous sand, as it commonly occurs mixed with gravel—and the sand found on the seashore, where the salt has been washed out by long exposure, whilst out of reach of the tide, may be used. The purer the above-named materials are from admixtures of clay, earth, or organic substances, the more complete will be their combination with the lime, the quicker will the manufactured brick or block set, and the more satisfactory will be the quality which it ultimately attains. For this reason, subdivided blast-furnace slag is preferable in most cases to sand, and the only sand which, in reference to setting capacity, is analogous to blast-furnace slag, is the volcanic sand occurring in different localities in North and South Wales, as an almost pure calcined silica. The lime used for the manufacture may be either slaked or unslaked. In the first case, (slaked), in order. to obtain satisfactory results, the lime must be strongly hydraulic. The use of unslaked lime, however, is by far preferable. A process for using fresh or unslaked lime has been patented in England by Major-General Scott. Lime thus prepared is called " selenitic lime," and consists of a mixture of fresh (unslaked) lime with sulphate of lime, or plaster of Paris. The graystone lime, for instance, found by the Medway, is mixed with from 5 to 7 per cent. of plaster, which has the effect of keeping the lime from slaking when water is added. This mixture also partakes of the nature of cement, and when used for mortar, or concrete, attains in a shorter time a greater degree of hardness than the same lime would ever have obtained after being slaked. Bodmer's process for the manufacture of artificial stone bricks consists chiefly in the use of automatic measuring, forwarding, and mixing apparatus, by means of which the materials are supplied and unite in a continuous stream, and are accurately measured. They

By I. I. Gardescu

Rumania produced during 1936 some 62,500,000 bbl. of oil. Of this production, 99 per cent comes from an area running east and west along the southern foothills of the Carpathian Mountains just north of Bucharest. This almost rectangular area measures 20 by 40 miles and is located in the districts of Dambovita and Prahova between the cities of Targovigte to the west and Mizil to the east. The remainder of the production is about evenly divided between the oil fields north and east of Mizil in the Buzh district and those to the north on the eastern flanks of the Carpathian Mountains in the district of Baciiu. The Transylvanian Basin to the north and west of the Carpathian Mountains has produced to date only dry gas from its numerous salt domes. Bucsani Field The Bucgani oil field produced 15,600,000 bbl., or 25 per cent of the total production of Rumania in 1936. Bucgani is a deep-seated salt dome 7 miles south of the old Moreni oil field. A slight surface doming, not dissimilar to the topography observed on some of the oil fields of the Californian basin, called attention to the area. It is the southernmost oil field and, together with the deep-seated and prolific Boldesti field, points to the great oil possibilities of the deep-seated domes along the northern edge of the Rumanian plains south of the Carpathian foothills. The Government is the principal owner of the oil and gas subsurface rights in the areas south of the foothills. The acquisition of leases by the operating oil companies may be made either by application for an exploration permit, the company being assigned part of the acreage in case of successful wildcatting, or, if the area has already been declared as proven territory, through competitive bidding. A block of 164 acres was auctioned recently for $200,000, or $1200 per acre. The largest producer in the Bucgani oil field is the Steaua Romana, which produced 39.5 per cent of the total for the field. The Steaua Romana is a post-war company and 50 per cent of its shares are owned by the British Steaua and the Steaua Franpaise and the other 50 per cent by a group of Rumanian banks and by the Government. The Colombia,

Jan 1, 1937

By L. F. Stutzman, George Thodos

The friction factor plot presented by Cornell and Katz4 and developed for the flow of fluids through consolidated formations has been directly adapted for handling fluid flow problems involvitrg both linear and radial flow. In this adaptation the friction factor plot is used directly for the solution of problems and thereby eliminates the use of conventional equations which are specific to laminar (Darcy) or turbutent flow. This upproach overcomes the disadvantages inherent in the use of these conventional equations. It eliminates the necessity of checking the type of flow occurring in order to identify the specific equation which must be used. In radial flow problems, because of the increasing mass velocity of the fluids as they approach the wellbore. the type of flow may no longer remain laminar. Consequently, it is necessary to use more than one equation in a problem and to identify the range over which each equation should be applied. Finally, in practice it has been found that much of the flow of gases through consolidated media occurs in a range that is neither laminar or turbulent. For this transitional region, no convenient equations are available. The method and presented friction factor plot are appficahle to both liquids and gases. INTRODUCTION The flow of fluids through unconsolidated media in packed beds has been treated extensively by a number of investigatorsl,2,3,5,7,8 Most of these studies present friction factors as a function of modified Reynolds number similar to those developed for conventional fluid flow through pipes. These friction factor plots are presented for linear flow; however, Elenbaas and Katz have extended these concepts to apply to radial flow. All of these studies on unconsolidated materials require a knowledge of packing properties such as sphericity. porosity, and particle diameter. Sphericity and particle diameter cannot be defined at the present time for consolidated formations such as those commonly found in gas or oil reservoirs. As a result many investigators have not utilized friction factors and Reynolds number in the study of fluid flow through consolidated media. However, Cornell and Katz4 present a plot (Fig. 1) for the flow of fluids through consolidated porous media, in which the friction factor defined as: The turbulence coefficient, P, is related to the formation permeability, K, as presented in Fig. 2. Three different types of flow may exist in the flow ot

Jan 1, 1957

By J. O. Betterton, W. K. Noyce

I~JTI HE work on the indium-zirconium system is part A of a larger investigation of zirconium-phase diagrams with solute elements, silver, cadmium, indium, tin, and antimony, which is intended to provide information about the metallic valency of zirconium. The system is an ideal example since the sizes of indium and zirconium atoms are nearly the same, and the solute and the solvent occur in the same row of the periodic table. The only solute from Group III B which had previously been added to zirconium was aluminum' and it was of interest to determine whether indium would dissolve appreciably in alpha zirconium and stabilize this phase in the same manner. Experimental Procedure The experimental methods used in the indium-zirconium work are similar to those described earlier for the silver-zirconium system.' Reactor Grade 1 iodide zirconium of 99.95 pct purity* and indium of 99.99 pct purity were arc cast, and then annealed in silica capsules with protective foils of zirconium and molybdenum. Annealing temperatures and times varied from 1 day at 1300°C to 43 days at 550°C. The compositions of the alloys were detcrmined by an individual chemical analysis of the actual metallographic specimens after two or more sides were examined to insure the absence of solute segregation. Calibrated thermocouples were used throughout, and the uncertainty in the temperatures reported, owing to calibration error, furnace control, and measurement of the small temperature gradients near the capsules, is believed to be well within ±2°C. Typical impurities in the alloys were found by a neutron-activation analysis of four different alloys. The results are given in Table I where the ranges of values will be seen to compare favorably with the usual values for iodide zirconium. With respect to oxygen, nitrogen, and carbon the absence of any unusual amount of these elements compared to iodide zirconium was indicated by the alloy hardness values, since hardness is increased sharply by the presence of these elements. The value for 0 pct In, obtained from the alloys by extrapolation, is 58 2 7 VPN which is in the low part3 f the normal range of hardness found in iodide zirconium. Results of the Experiments The zirconium-rich portion of the indium-zirconium phase diagram from the annealing experiments is shown in Fig. 1. Indium was found to

Jan 1, 1959

By H. H. Reamer, B. H. Sage

An experimental investigation was conducted upon five different paired samples of oil and gas from a field in Louisiana. The study, with each pair of samples, included the measurement of the formation volume and the volume of the liquid phase for three mixtures of the oil and gas. The gas-oil ratio varied from approximately 200 to over 40,000 cu ft per bbl and measurements were made at temperatures between 40" and 250°F. The gravity of the tank oil for the five samples under investigation varied between 38.0" and 55.8" API. The composition of the oil and gas samples and their mixtures is submitted 'References given at end of paper. Manuscript received at the office of the Petroleum Branch February 21, 1950. in tabular form. A number of diagrams depicting the effect of temperature and gas-oil ratio upon retrograde dew-point pressure are presented. INTRODUCTION During the past two decades a fairly large number of investigations were made of the volumetric behavior of naturally occurring hydrocarbon mixtures. The earlier work of Beecher and Park-hurst' and a more recent report on samples from Dominguez Field2 are typical of research of this nature. Such studies have been used in estimating the volumetric behavior of fluids in producing fields other than those from which samples were taken. Progress has been made3.4.5 in correlating the influence of pressure, temperature, and composition upon the specific and formation volume of hydrocarbon mixtures of relatively low gas-oil ratios, but attempts to extend this correlation to higher ratios have not been particularly successful. The influence of composition upon the volumetric behavior of such systems cannot be simply related to a single parameter such as gas-oil ratio. In order to aid in the extension of the correlation of the volumetric behavior of mixtures of oil and gas to higher ratios, a rather complete study was made of five different pairs of samples from a Louisiana field. The complexity of the influence of composition upon the volumetric and phase behavior of such systems in the regions of retrograde condensation was indicated by earlier Work,6,7,8,9,10 and it is doubtful if simple correlations can be established in these regions with the information currently available. The terminology employed in this paper is identical to that utilized earlier."

Jan 1, 1950

By H. M. Rutherford

THE reflection method in seismic prospecting has aroused much interest in the past few years. The purpose of the present paper is .to present the method of reflections in the mapping of geologic structure and also to give some indication of its limitations. The reflection method is well adapted to the mapping of geologic structure in the Mid-Continent fields, and has been found most useful there. The refraction method is ideally suited to the finding of structures, such as domes, where the amount of relief is very large. This explains the brilliant success of the refraction method in the Gulf Coastal region of Texas and Louisiana. The additional fact that salt has a much higher velocity than the sur-rounding sediments made their discovery much easier. By the use of the reflection method, differences of relief of 25 to 50 ft. to the mile may be detected at a depth of 5000 ft., and the depth points accurately plotted on a map. This is hardly possible by the use of the refraction method. The reflection method has been in almost continuous use in the Mid-Continent area since 1926, but very little, if anything, has been published until recently(7) ? regarding either the method or the results. The dis-covery of several oil fields is now attributed to the use of the reflec-tion method. Reflection methods have been used by the Germans to find the thick-ness of the ice of several glaciers. (2,8) The depths there considered were of the order of only a few hundred feet. For the method to be of any practical value in this country, it must be able to work to depths of several thousand feet. As was indicated above, this is now possible, though there are many problems connected with the reflection method yet to be solved. The refraction method requires that the shooting be done over long ranges. It was necessary, for example, to take distances out to several miles in order to penetrate some five thousand feet. Naturally this uses a good deal of dynamite. In the reflection method the distances are much shorter and the amounts of dynamite are much smaller, within limits which will be noted below. The chief distinction between refrac-tion and reflection methods is to be found in the analysis of the seismo-gram. Refraction shooting makes use of only the first arrival of energy

Jan 1, 1932

Page Foreword. By Edmund M. Wise..................... 3 A.I.M.E. Officers and Dircctors...................... 4 Institute of Metals Division Officers and Committees............ 7 Institute of Metals Division Annual Award Certificate............ 8 Institute of Metals Division Lectures and Lecturers............. 9 Photograph of E. H. Dix, Jr., Institute of Metals Division Lecturer...... 10 PAPERS Acceleration of the Rate of Corrosion by High Constant Stresses. By E. H. Dm, JR. (Institute of Metals Division Lecture, T. P. 1204).......... 11 Variation of Internal Friction with Grain Size. By Clarence Zener and R. H. Randall. (T.P. 1146, with discussion) .............41 Changes in Damping Capacity during Annealing of Alpha Brass. By John T. NoRton. (T.P. 1168, with discussion)................49 An Electron Diffraction Study of Anodic Films. By R. A. HarrinQton and H. R. Nelson. (T.P. 1158).....................62 Determination of Orientations by Etch Pits. By Charles S. Barrett .and L. H. Levenson. (T.P. 1171, with discussion).............76 Process of Precipitation from Solid Solution, I—A Crystallographic Mechanism for the Aluminum-copper Alloys. By Carl H. Samans. (T.P. 1186). . . 85 Age-hardening of Aluminum Alloys, IV — Discussion of the Theory. By WilTJam L. Fink and Dana W. Smith. (T.P. 1083, with discussion). . . 95 Structure of Aluminum after Compression. By Charles S. BaRREtt and L. H. evensonON. (T.P. 1104, with discussion)................112 Recrystallization Texture of Aluminum after Compression. By ChaRlEs S. BarRett. (T.P. 1141, with discussion)................128 Plastic Deformation and Recrystallization of Aluminum Single Crystals. By J. A. Collins and C. H. Mathewson. (T.P. 1145, with discussion) . . . 150 Recovery and Recrystailization in Long-time Annealing of 70-30 Brass. By S. E. Maddigan and A. I. Blank. . (T.P, 1166, with disonssion).....170 Correlation of Deformation and Recrystallization Textures of Rolled 70-30 Brass. By R. M. Brick. (T.P. 1144, with discussion).........193 Tensile Deformation of Critically Oriented Brass Crystals. By H. L. Burghoff. (T.P. 1149).............................214 Recrystallization of Lead. By Paul A. Beck. (T.P. 1101, with discussion). . 222 Simple Method of Thermal Analysis Permitting Quantitative Measurements of Specific and Latent Heats. By Cyril Stanley Smith. (T.P. 1100, with discussion).............................236 Metallographic Study of Internal Oxidation in the Alpha Solid Solutions of Copper. By Frederick N. Rhines. (T.P. 1162, with discussion). . . . 246

Jan 1, 1940