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By Sara Hornby

After almost half a century of experience in using DRI/HBI in electric arc furnaces (EAFs), and taking into account the decrease of natural gas cost in the USA, it is interesting to revisit some trends and controversial issues around this alternative iron source. This paper reviews aspects like the evolution of iron ore quality and its influence on EAF operation; DRI stockpiling and transport, regarding the risk for selfcombustion; optimum charge design; cold DRI/HBI charging (fifth hole, bucket, transporter); hot charging (ways and results); carbon content, metallization and silica in DRI/HBI, and its influence on EAF operation and performance; oxygen / carbon balance; chemical energy and DRI/HBI charge.

Aug 16, 2017

By V. Svalbonas

The process of grinding mill quality assurance brings with it associated truths and myths. When the mill quality assurance process took its first great steps forward in the late 1970s and early 1980s, they were in response to the conditions existing, in our industry, at those times. In the late 1990s, we are faced with different conditions, and problems, and need fresh solutions. Yet the system developed for the early 1980s has produced no new approaches for the late 1990s, becoming instead more hardened and entrenched. This lack of development and actual resistance to research is now costing the industry significant amounts of money in late start-ups and useless scrap loss.

Jan 1, 1999

By V. Svalbonas

The process of grinding mill quality assurance brings with it associated truths and myths. When the mill quality assurance process took its first great steps forward in the late 1970s and early 1980s, they were in response to the conditions existing, in our industry, at those times. In the late 1990s, we are faced with different conditions, and problems, and need fresh solutions. Yet the system developed for the early 1980s has produced no new approaches for the late 1990s, becoming instead more hardened and entrenched. This lack of development and actual resistance to research is now costing the industry significant amounts of money in late start-ups and useless scrap loss.

Jan 1, 1999

By Wilfredo Serrano

El presente artículo describe la historia, características, especificaciones, ventajas de la máquina WS Morococha de gran volumen. Dicha máquina fue diseñada en 1966 en el asiento minero de Morococha y es utilizada para concentrar minerales por el método de flotación de forma económica. Entre las principales ventajas tenemos: gran volumen y capacidad por unidad, bajo costo de inversión y mantenimiento, la operación es independiente en cada máquina, su alto radio de concentración permite obtener rougher concentrados limpios directos y que en las paradas no se pierden el volumen del mineral retenido y el punto se descarga en la parte superior. De forma que esta máquina concentradora de minerales por flotación de concepción y desafíos mejorados, desarrolla mayor eficiencia y selectividad.

Mar 1, 1976

By F. H. Samuel, H. Tahiri, S. Valtierra, H. W. Doty, A. M. Samuel

L'affinage des grains dans les alliages d'aluminium consiste à augmenter le nombre de sites de cristallisation de la phase a-Al afin d'obtenir une structure fine. Les alliages mères de type Al-Ti-B sont largement utilisés comme raffineurs des grains. Cette étude a pour but d'établir des mécanismes convenables d'affinage des grains dans l'alliage A356 en utilisant cinq alliages mères et deux températures de coulée (750°C et 950°C). Les résultats montrent que la phase a-Al prend une forme selon l'alliage mère ajoute; les échantillons coules a haute température montrent une taille de grain plus grosse; les températures de germination et de croissance augmentent avec I' augmentation du Ti ou du B et la taille des grains diminue. L'alliage mère Al-4%B montre une puissance remarquable en comparaison d'autres alliages mères. Pour cet alliage mère, le titane résiduel dans l'alliage A356 réagit avec le bore pour former TiB2 qui, par la suite, agit comme un germe actif pour la phase a-Al.

Jan 1, 2006

By Enrique Roy Dionisio Calderon

O presente trabalho mostra a concepção de um modelo que permite gerar uma superfície de mínimo consumo de redutor (carbono) em Altos-Fornos. No seu desenvolvimento foram consideradas as condições de equilíbrio das reações de redução, os balanços de massa e de energia e parâmetros operacionais. Sua aplicação à redução em Altos Fornos é exemplificada para situações reais, baseada em banco de dados operacionais de uma usina siderúrgica. Foi possível, a partir de planos de corte nestas superfícies, gerar diagramas binários do tipo CR-RD (Consumo de Redutor-Fração de Redução Direta), com possibilidade de serem gerados “on-line” no processo. Dentre os resultados obtidos, destaca-se a identificação de inviabilidades termodinâmicas importantes do forno. Dentre elas o modelo permitiu, através de seus “outputs” gráficos, prever e acompanhar o fenômeno de “gelada de forno”, conferindo desta forma maior segurança operacional ao processo.

Aug 17, 2017

By Xu Weimin

The existing copper electrorefining tankhouse of Jinchuan Nonferrous Metals Complex (JNC) was commissioned in 1986 for refining blister copper anodes. Blister copper is produced by reverberating chalcocite separated from converter high grade nickel-copper matter by means of flotation. Special chemical analysis of the anodes shows, a composition of 93.02 - 95.72 % copper, 3.0 - 4.96 % nickel and 0.5 - 1.23 % sulfur. The wide range of composition makes the electrorefining process fairly different from others throughout the world. The initial nickel content of 20 ppm and sulfur 40 ppm or more in copper cathodes are reduced to 8.5 ppm and 11 ppm respectively. Since 1986 the tankhouse has undergone significant evolutionary modifications and implementations to ameliorate cathodes quality desirably. The important fact is that the N-additive was utilized through many studies and pilot and field trials successfully. While our primary purpose is to improve chemical quality of the cathodes, tankhouse capacity is increased considerably and the process is perfected satisfactorily. The tankhouse is described with special emphasis on JINCHUAN PROCESS. The upgrading of our product by the utilization of the N-additive is highlighted. The other aspects of the tankhouse including spent electrolyte treatment and by product nickel sulfate manufacturing are briefed as well. Key words: JINCHUAN PROCESS, anode, cathode, electrolyte, electrorefining, N-additive.

Jan 1, 1993

By I. E. Odom

The physiocemical properties and industrial uses of the clay mineral montmorillonite are reviewed. Montmorillonite is the most abundant species of the smectite clay mineral group and is the predominant mineral composing bentonite deposits. The crystal structure, chemical composition, exchangeable ion type, and small crystal size are responsible for several unique properties, including a large chemically active surface area, a high cation exchange capacity and interlamellar surfaces having unsual hydration characteristics. The type of exchangeable ion Na, Ca and/or Mg has a major influence on industrial and chemical uses of montmorillonite because of their hydration characteristcs. Natural occurrences of Na montmorillonite in commercial quantities are geographically limited, but Ca-Mg montmorillonite deposits are known world wide. Foundry, well drilling, pelletizing and civil engineering constitute the major uses of montmorillonite, but the total array of uses of montmorillonite exceeds that of any other mineral.

Jan 1, 1986

By N. S. Dalal, X. Shi

"This study reports a new property of the important NAD(P)H-dependent flavoenzymes, glutathione reductase, lipoyl dehydrogenase and ferredoxin- NADP oxidoreductase, that can catalyze a one electron reduction of metal ions such as chromium(VI) and vanadium(V). During the enzymatic reduction process, molecular oxygen is reduced to H2O 2 , which reacts with the reduced metal complexes to generate hydroxyl radicals. Since the hydroxyl radicals have been suggested to play an important role in Cr(VI) toxicity, this study provides a basis for a recent observation that Cr(VI) mutagenesis is strongly oxygen dependent. These results also point to an enzymatic pathway for the metabolism of some metal ions and concomitant generation of hydroxyl radicals. l. INTRODUCTIONThe purpose of this communication is to report that some important NAD(P)H-dependent flavoenzymes (glutathione reductase, lipoyl dehydrogenase and ferredoxin-NADP+ oxidoreductase) can catalyze one electron reduction of metal ions such as chromium(VI) and vanadium(V) and simultaneously reduce molecular oxygen to generate Hi02 and, eventually, the ""OH radical. This finding is significant because (i) the known substrates for the flavoenzymes are organic species and not metal ions, and (ii) the report on the enzymatic formation of the ""OH radical provides a new pathway for understanding the mechanism of genotoxicity of some non-ferrous metal ions. For example, it has been suggested that OH radical is likely to be the major species responsible for Cr(VI) genotoxicity [1-5). The 'OH radical is generated through the reaction of Cr(V) complexes with cellular Hi02 [4,5]. Cr(V) itself is known to be generated from Cr(VI) in various biological systems, in particular, microsomes [ 6), mitochondria [7] and mitochondrial electron transfer chain complexes [8]. However, no specific enzyme responsible for the Cr(V) generation has been identified except possibly glutathione reductase [4]. In this study we have used ESR and spin trapping techniques to show that the flavoenzymes can generate Cr(V) and provide a catalytic redox cycle for 'OH formation in such reactions. Herein we present our results on Cr(VI) and summarize those on other systems. Correspondence address: N.S."

Jan 1, 1990

By Fred Tarquinio, Giovanni Bonita, Lars Wagner

"A new embassy for the Peoples Republic of China is under construction in Washington, DC. The 475,000 square feet (44,125 m2) structure has five levels below ground and four above, making it the largest embassy in Washington DC. A vertical soil nail wall was used as the primary support of excavation system for the project. The soil nail wall was irregularly shaped, benched in areas, and up to 98 feet (29.9 m) in height. The soil nail and shotcrete system consisted of approximately 1,600 soil nails and 50,000 square feet (4,645 m2) of exposed shotcrete wall surface. Design and construction challenges included soft soil conditions, inside wall corners, underground utilities, seismic impacts from blasting, and logistical and political factors. Overall, wall movements were lower than expected, with maximum horizontal movement less than 0.25% of the total height of the excavation.INTRODUCTIONThe proposed Embassy of the Peoples Republic of China in Washington, DC, will consist of about 475,000 ft2 (44,125 m2) of building space and contain up to four fl oor levels above ground and fi ve levels of basement (Figure 1). When completed, the building will be the largest embassy in Washington, DC. The architect for the project, Pei Partnership Architects, along with the world-renowned architect I.M. Pei, made effi cient use of the site by inserting the building into the existing slope. Consequently, excavations reach heights up to 98 feet (29.9 m) on the southern side of the property and 42 feet (12.8 m) on the northern side.The soil nail and shotcrete system consisted of approximately 1,600 soil nails and 50,000 square feet (4,645 m2) of exposed shotcrete wall surface. The location of the building relative to the property line called for tight excavation requirements, including precise wall positions and shotcrete tolerances. Design and construction challenges included soft soil conditions, inside wall corners, arched walls, underground utilities, seismic impacts from blasting, and logistical and political factors.SITE INVESTIGATIONInformation obtained from the geotechnical investigation revealed about 10 to 20 feet (3.1 to 6.1 m) of a loose to medium dense fi ll material placed during previous site activities. The fi ll material was underlain by a silty sand and sandy silt residual soil derived from the natural weathering of the underlying bedrock. This soil sequenced naturally from a medium dense to very dense material through natural weathering of the underlying bedrock. This soil sequenced naturally from a medium dense to very dense material through natural weathering processes in the rock. The underlying bedrock was locally characterized as a gneiss. A water table elevation about 17 feet (5.2 m) above the fi nal excavation level was revealed, except in the “radius” area, where a leaking water main/hydrant generated a high local water table."

Jan 1, 2007

By Fred Tarquinio, Giovanni Bonita, Lars Wagner

"A new embassy for the Peoples Republic of China is under construction in Washington, DC. The 475,000 square feet (44,125 m2) structure has five levels below ground and four above, making it the largest embassy in Washington DC. A vertical soil nail wall was used as the primary support of excavation system for the project. The soil nail wall was irregularly shaped, benched in areas, and up to 98 feet (29.9 m) in height. The soil nail and shotcrete system consisted of approximately 1,600 soil nails and 50,000 square feet (4,645 m2) of exposed shotcrete wall surface. Design and construction challenges included soft soil conditions, inside wall corners, underground utilities, seismic impacts from blasting, and logistical and political factors. Overall, wall movements were lower than expected, with maximum horizontal movement less than 0.25% of the total height of the excavation. INTRODUCTIONThe proposed Embassy of the Peoples Republic of China in Washington, DC, will consist of about 475,000 ft2 (44,125 m2) of building space and contain up to four fl oor levels above ground and fi ve levels of basement (Figure 1). When completed, the building will be the largest embassy in Washington, DC. The architect for the project, Pei Partnership Architects, along with the world-renowned architect I.M. Pei, made effi cient use of the site by inserting the building into the existing slope. Consequently, excavations reach heights up to 98 feet (29.9 m) on the southern side of the property and 42 feet (12.8 m) on the northern side.The soil nail and shotcrete system consisted of approximately 1,600 soil nails and 50,000 square feet (4,645 m2) of exposed shotcrete wall surface. The location of the building relative to the property line called for tight excavation requirements, including precise wall positions and shotcrete tolerances. Design and construction challenges included soft soil conditions, inside wall corners, arched walls, underground utilities, seismic impacts from blasting, and logistical and political factors."

Jan 1, 2007

By Yoshinobu Fukumori, Testuya Watanabe, Futoshi Shikata, Hiroyuki Tokumitsu, Hideki Ichikawa, Masahito Miyamoto

Nano-particulate systems have attracted much attention recently in pharmaceutical field as drug carriers and functional components of pharmaceutical dosage forms. This paper describes our approaches in design and preparation of nano-particulate systems, including lipid nano-emulsions, chitosan nanoparticles and thermosensitive acrylic nanoparticles, for certain pharmaceutical applications mentioned below. The lipid nano-emulsions with their particle size smaller than 100 nm were prepared for gadolinium neutron-capture therapy (Gd-NCT) of cancer by a thin-film hydration method with sonication, and intraperitoneally injected into Greene's melanoma (melanotic No. 179)-bearing Syrian hamsters. This provided such a high gadolinium concentraton in tumor as 107 µg/g tumor (wet basis) at 48 h after administration. As an alternative gadolinium nano-carrier for Gd-NCT, biodegradable and highly gadopentetate-loaded chitosan nanoparticles (Gd-nanoCPs, 426 mTI in particle diameter and 9.3% in Gd content) were prepared by a novel emulsion-droplet coalescence technique. A significant tumor-killing effect could be obtained when Gd-nanoCP suspension was injected intratumorally twice 24 and 8 hours before neutron irradiation into B 16Fl O melanoma-bearing mice and subsequently thermalneutron was irradiated toward tumor site with a flux of 2 x 109 n/cm2/sec for 60 min. As one another application of nanoparticles, a novel acrylic composite latex with a hydrophobic core and a thermosenstively swellable shell was designed for fabricating microcapsules showing thermosensitive mode of drug release. The microcapsules with the composite latex-dispersing membranes exhibited an exceptionally rapid on-off response of drug-release in a thermosensitive manner.

Jan 1, 2000

By Chuan-Jian Zhong

Gold-based nanoparticles in the size range of a few nm have attracted increasing interests in catalysis, sensors and biomedical applications. The study of the unique catalytic properties of nanosized gold was inspired by the pioneering work of Haruta on the nanogold-catalyzed CO oxidation (1-4). There have been a number of excellent reports discussing both fundamental and application aspects of gold nanoparticles in catalysis (3-8). Our work reported herein is aimed at investigating the preparation and application of gold and its alloy nanoparticles for potential applications in fuel cell catalysis. Fuel cells operating by electrochemical oxidation of hydrogen or methanol fuels at the anode and reduction of oxygen at the cathode are attractive power sources due to their high conversion efficiencies, low pollution, lightweight and high power density. While methanol offers the advantage of easy storage and transportation in comparison with hydrogen fuel cell, its energy density (~2000 Wh/kg) and operating cell voltage (0.4 V) are much lower than the theoretical energy density (~6000 Wh/kg) and the thermodynamic potential (~1.2 V). The poor activity of the anode catalysts and inefficient activity or issue related to "methanol cross-over" at the cathode electrode are associated with the loss of about one-third of the available energy at the cathode and the other one-third at the anode. Extensive studies have been focused on Pt-group metals (Pt+Pd+Rh+Ru+Ir (PGM)) for both anode and cathode catalysts. A major problem is the poisoning of Pt by COlike intermediate species (9,10). Recently, oxide-supported gold nanoparticles in the <10 nm size range have emerged as one of the best catalysts for CO oxidation (1-3,11), and for water gas shift reaction in reforming stage using 5 nm Au on Fe2O3 (6). Gold and its alloy with other metals in the nanosize range present new alternatives (2,12). Whether the unique properties of gold nanoparticles can be exploited for addressing these problems is a focus area of our work. The ability to harness the large surface area-to-volume ratios and the unique surface sites of nanoparticles in <10 nm size range, especially in heterogeneous catalysis, constitutes a major driving force in fundamental research and practical applications of nanoparticle catalysts. It is this size range over which the metal particles undergo a transition from atomic to metallic properties. The understanding of factors controlling the morphological and surface reconstitution associated with such a size range is of fundamental importance to the ultimate exploration of nanostructured catalysts. We have been investigating the interfacial structures and properties of core-shell types of nanoparticles consisting of gold or alloy nanocrystal cores and organic monolayer shells that were prepared by twophase synthesis (13) and processing (14) protocols. Important attributes of such nanoparticles include controllable size monodispersity, processibility, and stability towards size- and composition-tunable catalysis (15-21). Some of these attributes were studied for understanding their electrocatalytic properties in the oxidation of methanol and reduction of oxygen, which are of fundamental interest to fuel cell technology.

Oct 1, 2003

By R. A. Mantz, V. N. Balbyshev, A. N. Khramov, N. N. Voevodin

Corrosion protection properties of the hybrid organo-silicate coatings on aluminum substrate can be significantly improved by means of encapsulation of organic corrosion inhibitors within the coating material. In order to achieve sustained release of corrosion inhibitor and long-term corrosion protection, a secondary chemical equilibrium of either ion-exchange interaction with the coating matrix or cyclodextrin-assisted molecular encapsulation of the inhibitor has been employed. Several organic corrosion inhibitors, such as mercaptobenzothiazole, mercaptobenzimidazole, mercaptobenzimi¬dazolesulfonate, and thiosalicylic acid have been examined by a group of electrochemical methods including potentiodynamic scan, electrochemical impedance spectroscopy, and scanning vibrating electrode technique. It has been found that the formulations that contain ß-cyclodextrin demonstrate superior corrosion protection capabilities as the complexation equilibrium results in a continuing delivery of inhibitor to corrosion sites. The approach is considered a promising way for active corrosion protection of high-strength aluminum alloys when integrity of barrier coating is compromised.

Jan 1, 2004

By Paolo Prevedini, Antonello de Risi

"The city of Naples has one of the most ancient traditions of tunneling in the world, since Roman age until today. This was due to the softness of volcanic rock covering most of the city surface, this determined in centuries the excavation of many connected cavities, today still accessible. The building of metro lines promoted industrial tunneling construction: TBM, Raise Boring Machine, Vertical Shaft Machine and freezing technologies played a decisive role facing water pressure near the sea. MNspa is an advanced constructor with two lines built in parallel, mainly underwater. The planning of this infrastructure has been upgraded with the projects of international architects from all Europe, with installation of art masterpieces in station spaces while archeological excavations revealed artifacts since Paleolithic. The city expects to give a new image of the urban landscapes within the completion of all stations and consequent rehabilitation of interiors and external city spaces. A case study of Municipio square station, is chosen to explain the relevance of archaeological research in improving and developing the projects of Line 1 stations. In these pages, it will be explained how the engineering process required to deal with Art, Architecture and Archaeology to finally realize an extended urban renovation of Naples. 1 CITYSCAPE 1.1 Introducing the geological history of Naples In the evolution of the city, capital of the Magna Graecia and of consequent kingdoms, a new layer of buildings was added over the foundations of demolished walls of the precedent domination period: from the top of the Bourbons layer (the most common scenery of the city since 1734) to the Aragonese layer found just underneath it; then below stands the Angiovin city, which in turn is built above the Swabian traces; underneath the ancient traces of the Byzantine age are found just above the extended Latin age layer. The most ancient settlement, known as Parthenope, dates back to 1500 b.C. It sits below the Greeks remains of the city of Palepolis, which had been rebuilt under the name of Neapolis by Romans."

Jan 1, 2016

By S Hall

Mining schools around the world, many unfortunately now closed, were often established to teach the techniques of narrow vein mining and associated processing to students studying part-time while working in the industry. This arrangement ensured graduates (or æassociatesÆ) had a mix of skills and knowledge invaluable to the industry.It is argued that there is still a need to educate students in these narrow vein techniques and that there will be a growing demand for such graduates with a high level appreciation of this type of mining. There is also a need for innovation in narrow vein mining and processing to develop specific technologies and allow the use of techniques applied in æbulk miningÆ to achieve improvements in productivity, safety and economic performance.This paper aims to review the situation with regard to education and innovation in narrow vein mining.CITATION:Hall, S, 2012. Narrow vein education - back to the future?, in Proceedings Narrow Vein Mining 2012 , pp 23-26 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 26, 2012

By S. Poirier, J. -M. Facteau

The gold mine sector is presently facing low gold prices as well as technological challenges. Its competitiveness and survival will depend on new mining methods and equipment to improve ore extraction. In 1999, Natural Resources Canada has invested new funds over a period of three years at CANMET’s Experimental Mine to establish the Narrow-Vein Mining Project. A team of engineers and researchers specialized in mining, mechanics and electronics engineering are working to meet the critical need of ore-extraction technology. CANMET’s programme in mechanization and automation for narrow-vein mining had, prior to 1999, realised several important achievements, many in co-operation with a consortium of mining companies(Soredem). The investment of new funds in this area will contribute to develop technologies to improve the productivity, as well as health and safety conditions of the narrow-vein mining industry. Several important impacts of this project will be monitored. In particular, a database of methods and equipment used in narrow-vein mining is being developed. A key thrust is to identify operators’ needs with respect to the development and automation of mining methods and equipment. Based on those needs, research and development projects will be created. The paper will present the objectives of the narrow-vein mining project and some of the results, including the web site developed to present the results of the project.

Sep 1, 2001

By Jean-Marie Fecteau

The gold mine sector is presently facing low gold prices as well as technological challenges. Its competitiveness and survival will depend on new mining methods and equipment to improve ore extraction. In 1999, Natural Resources Canada has invested new funds over a period of three years at CANMET?s Experimental Mine to establish the Narrow-Vein Mining Project. A team of engineers and researchers specialised in mining, mechanics and electronics engineering are working to meet the critical need of ore-extraction technology. CANMET?s program in mechanisation and automation for narrow vein mining had, prior to 1999, realised several important achievements, many in co-operation with a consortium of mining companies (Soredem). The investment of new funds in this area will contribute to develop technologies to improve the productivity, as well as health and safety conditions of the narrow vein mining industry. Several important impacts of this project will be monitored. Specifically, a database of methods and equipment used in narrow vein mining is being developed. A key thrust is to identify operators? needs with respect to the development and automation of mining methods and equipment. Based on those needs, research and development projects will be created. The main problems identified following meetings with mine operators are described with a few elements of solution and the Web site created for the broadcast of the results is presented.

Oct 1, 2001

By Gerald Sanders

Presentation Topics ? We?re Going to the Moon Again? ? What is Lunar Mining ? In-Situ Resource Utilization? ? What Are The Challenges to Lunar Mining? ? What is NASA Currently Doing?

May 1, 2009

By D. Meadows, P. Carrato, E. Wingate, K. Churchill

Extracting lunar ice, to be processed into pure water or hydrolyzed into oxygen and hydrogen, faces many challenges. On the Moon icy-regolith deposits that contain up to 10% water are found within Permanently Shadowed Regions (PSR) at both lunar poles, where temperatures approach -220 ⁰C. NASA has identified several technology gaps that exist in developing these resources including: • Excavating large quantities of icy-regolith • Delivering large quantities of acquired resources • Hardware that is lightweight and energy efficient • Hardware that is reliable and durable. NASA uses public challenges to incentivize innovative approaches to closing these gaps. The Break the Ice Lunar Challenge provides over three million dollars in prize money to teams that compete in developing solution to mining the Moon. This paper describes the rules for this challenge and presents some of the proposed solution.

Feb 1, 2023