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By Rogerio de Oliveira Baldoino

The sedimentary phosphate deposit of Bayovar is located in a very dry area of Peru (desert of Sechura) which is close to the Pacific coast. It consists of seven superposed layers (beds) which call for different strategy of concentration. The ore is composed predominantly by apatite (84% in weight basis) plus silicates (16%). In order to treat the ore from beds 1-5, a suitable standard mineral processing circuit (composed of scrubbing, screening, attrition and desliming) started its operation in 2010, yielding 3.9 Mt/y of concentrate assaying 30% of P2O5. To concentrate phosphate from beds 6-7, however, it is necessary to carry out further cationic reverse flotation of silicates, at neutral pH, to yield a concentrate, which meets market specification. The new process was developed in laboratory scale by a collaborative program conducted between Vale S.A. and the University of Sao Paulo-Brazil. A pilot plant has currently been running in order to confirm the very good results yielded in laboratory scale. The successful accomplishment of flotation in the current beneficiation flow sheet will enable a capacity expansion of 1.9 Mt/y of concentrate assaying 30% of P2O5. As water resources are very limited at Bayovar region, all the steps of concentration, including flotation, must be performed with seawater, which must be continuously recycled. This work addresses some relevant topics related to the use of seawater in the reverse cationic flotation of silicates: influence of temperature, water quality (ageing and chemical composition) and collector type (ether amine versus condensate). The results indicate that condensate amine works better than ether amine. If flotation is conducted with the former collector, the separation process is able to tolerate changes in temperature (25-40oC) and water quality caused by either evaporation or ageing. Keywords: phosphate, flotation, seawater, temperature, ageing, concentration, salt

Sep 1, 2012

By W. G. Miller, J. D. Scott, D. C. Sego

ABSTRACT An overall study was conducted to evaluate the properties and processes influencing the rate and magnitude of consolidation for oil sands fine tailings produced using different extraction processes. As part of the overall study, a comprehensive description of physical and chemical characteristics of fine tailings generated by caustic and non-caustic processes was carried out. Ultimately, the influence of these fundamental properties on the compressibility, hydraulic conductivity and shear strength properties of the fine tailings was assessed. The characteristics of the fine tailings are presented in terms of index properties, mineralogy, specific surface area, water chemistry, liquid limits, particle size distribution and structure. A difference in water chemistry was concluded to be the cause of substantial differences in particle size distributions and degree of dispersion of the comparable caustic and non-caustic fine tailings. The degree of dispersion was consistent with predictions for dispersed clays established by the sodium adsorption ratio (SAR) values for these materials. A linear variation of increasing dispersion with increasing SAR up to a SAR value of about 40 has been suggested, above which fine tailings are completely dispersed. The observed dispersed or flocculated structures (viewed using a scanning electron microscope) supported the predictions based on SAR values.

Jan 1, 2010

By W. M. Husslage

The permeability in the blast furnace shaft is adversely affected by low temperature reduction degradation of sinters. The fundamental cause is an expansion of the iron oxide phase resulting from reduction of hematite to magnetite. The present study showed that expansion behavior during the hematite / magnetite reduction step and the resulting microstructure are strongly influenced by the reduction temperature (viz. partial oxygen pressure), the reducing agent and the nature of the hematite. The reduction rate is of minor importance. A reduction mechanism is proposed, explaining the dilation behavior and the magnetite microstructure. The results can provide better insight into reduction degradation behavior.

Jan 1, 1998

Synthetic and commercial activated carbons are characterised for several chemical and physical properties. A range of techniques is used to establish correlations between physicochemical parameters and gold- adsorption activities. The most important parameter in the carbon activation process for a product with a high gold-adsorption activity is the activation temperature. High activation temperatures yield products with large micropore volumes which provides sites that are ideal in size for adsorption. The surface area of an activated carbon is not necessarily a good measure of its adsorption activity. Surface oxygen-containing functional groups are identified by Fourier transform infrared spectrophotometry to be comprised mainly of ethers and hydroxyls. These functional groups line the edges of the micropores imparting a polar character to the pore and aid in the solvation of the adsorbate. Oxidants such as nitric acid result in a proliferation of surface carboxyl groups. resulting in a negatively- charged surface that is not conducive to the adsorption of gold.

Jan 1, 1993

By Anna Wasilkowska

The study concentrates on the effects exerted by microstructure, deformation history and uniaxial stress conditions (temperature, stress state, strain rate) on the mechanical properties offerritic TRIP-aided steels for automotive applications. In low-alloyed TRIP-steels it is quite difficult to separate the effect of the austenite to martensite phase transformation from the influence of the ferritic matrix contributing to the yield stress and uniform elongation. Investigation of transformation kinetics of retained austenite as a function of the deformation temperature show that using the parameter k to characterize the retained austenite stability allows to identify regious of different temperature sensitivity separated by a transition temperature of 10±5°C. The observed low strain-rate sensitivity of the flow stress is an intrinsic property of the ferritix matrix and points to defomtation governed by slip. The ultimate tensile strength is much stronger affected by temperature than the yield stress. The influence of the temperature on the elongation is complex, because of the heating of the specimens by 60-l20°C at moderate and high strain rates. The increase of the total strain can be understood in terms of thermal softening of the ferrite. On the other hand, the steep increase of the stress during dynamic testing is an effect of accommodated elastic and plastic strains in the matrix. The strain- hardening exponent is dependent on the conditions imposed during testing. The martensite transfomtation rate is lower and the critical stress for martensite nucleation is much higher under compression compared to tensile loading. In secondary tensile tests, the yield stress increases steeply, and the ultimate tensile strength and the total elongation depend linearly on the amount of pre-straining. The results confirm that in the range of 8=10-4 s-l the TRIP-effect governs room temperature plasticity. Keywords: TRIP-steels, mechanical properties, strain rate sensitivity, temperature sensitivity, austenite stability

Jan 1, 2003

By K. L. Johnson

Networks of monitoring wells were established prior to mining at four longwall mine sites in the Appalachians to monitor the effect of mining on water levels, water quality and well yield. Two of the sites were located in stream valleys and the other two sites were located on hilltops. The depth to the mined seam ranged from 500-850 feet with the deeper cover being associated with the hilltop sites. Maximum declines in groundwater levels during and after mining were an order of magnitude less in the stream valley aquifers than in the hilltop aquifers. However, water levels in hilltop wells located outside the area immediately above the panel were unaffected. Water quality changes in wells as a result of longwall mining were negligible at all four sites. Increases in aquifer transmissivity and well yield were much more pronounced in the stream valley aquifers than in the hilltop aquifers. The significantly larger recharge area for the stream valley aquifers than that for the hilltop aquifers may partially account for the differing responses of these two classes of aquifers to longwall mining. These observations appear to be consistent with the stress-relief fracture model for Appalachian Plateau groundwater hydrology proposed by Wyrick and Borchers in 1981.

Jan 1, 1986

By Hiren J. Shah

The urban environment and geology create unique challenges for design and construction of deep foundations. The effect of these is prominently experienced in New York City. Three such project case histories are presented in this paper. The first project is a multi-use development. Relatively unusual glacial geology was observed at the site during the subsurface investigation phase. This played an important role in the selection of deep foundations as well as during construction. The design and construction aspects of the pile foundations, settlement estimates, a pile drive test program during design, piling equipment and production pile installation are discussed herein. A relatively smaller project is the second case history. A combination of drilled and driven deep foundations was employed in one area of the project due to its unique conditions. In another area of the project, an addition to a structure required the use of supplemental foundations to resist new additional loading. Tight space and load sharing with the existing foundations were important considerations in the design and construction. Finite element modeling of the existing and completed structure was performed which was an interesting aspect of the project. The third project case history involves a very large multi-billion dollar project in which various different types of deep foundation elements were used. The aspects requiring the use of such a variety of types and sizes of deep foundation elements included: geologic conditions, re-use of existing foundations, protection of adjacent infrastructure, construction staging, restricted space, loads, deep excavations, cost and schedule.

Jan 1, 2011

By R Ayothiraman

Tunnel excavation may induce adverse effects on nearby existing structures/foundations in urban areas. Accurate prediction of tunnelling effects on pile foundations of nearby structures in the urban environment poses a major challenge during design. Several studies have been undertaken to understand the mechanisms of the soil-tunnel-pile interaction, which focused only on influence of tunnelling on nearby existing building and foundations. However, effect of pile loading on existing tunnels did not receive enough research attention so far. So it is essential to measure the response of existing tunnel-lining due to loading on newly constructed pile to assess to the safety against the additional forces/moment caused by pile loading and to evaluate the critical distance for the proposed construction of any structures from the tunnel location. This paper presents result of three-dimensional (3D) finite element analysis carried out in ABAQUS to investigate the effects of pile loading on existing tunnels embedded in cohesive soil. It is found that the effects on tunnel lining depend on horizontal separation distance between pile and tunnel as well as location/elevation of pile tip with respect to tunnel location.

Mar 8, 2011

By D. Yu, Y. Thibault, D. Paktunc

"Prereduction and flux-aided direct reduction of chromite provide significant advantages in reducing energy consumption and greenhouse gas emissions during ferrochrome production. In this investigation, a comparative evaluation of the influences of several alkali fluxes was carried out based on experimental observations supplemented by advanced material characterization and thermodynamic predictions. Direct reduction of a chromite ore with alkali fluxes at 1300°C for 1 hour produced (Cr,Fe)7C3 type alloys with Cr/Fe mass ratios from 0.7 to 2.3. Among the alkali fluxes, reduction aided by NaOH resulted in a high degree (85%) of Cr metallization with the ferrochrome alloy being Cr4.2–4.6Fe2.4–2.8C3. The formation of liquid slag, which facilitated Cr metallization, was limited by the formation of NaAlO2 between 800 and 1300°C. This, in turn, restricted the collection and transport of the charged ionic Cr species (i.e. O2–) to graphite particles. Under the conditions studied, ferrochrome particles were often small and largely unliberated, which would make the physical recovery of ferrochrome challenging. At 1400°C, the amount of liquid slag increased, enabling the growth of alloy particles. Direct reduction of chromite aided by NaOH is promising as an alternative technology to conventional flux-based smelting in electric arc furnaces. IntroductionConventional smelting processes are energyintensive (Riekkola-Vanhanen, 1999) with the energy requirements greater than 4 MWh/t (Naiker and Riley, 2006; Beukes, van Zyl, and Neizel, 2015), and the greenhouse gas emissions can be significant, exceeding 10.5 t CO2 per ton Cr in ferrochrome produced (International Chromium Development Association, 2016). These include emissions occurring on-site (smelter), emissions due to electricity production, and emissions due to upstream processes. Overall energy requirements are influenced by the degree of prereduction and smelter charge temperature. Significant reduction in electricity consumption can be realized if the charge is prereduced before feeding to the submerged arc furnace (Niayesh and Fletcher, 1986). This consideration has led to the development of several prereduction technologies, with the most important example being the Premus process. In comparison to the conventional smelting processes, this prereduction process lowers the overall energy consumption and greenhouse gas emissions by about one-third (Naiker, 2007)."

Dec 1, 2018

By Gilberto Yanarico Apaza

"El presente texto señala las pautas necesarias para realizar una evaluación técnica integral de la influencia del collar de bolas para las operaciones de molienda, afectando al desgaste de los revestimientos de los molinos convencionales. Para la determinación del collar de bolas es necesario realizar los análisis granulométricos con la finalidad de obtener el F80 y el P80 de las muestras obtenidas en la alimentación y producto de los molinos, definir el índice de trabajo (Wi) y consumo de energía. Asimismo, se debe considerar el porcentaje de la velocidad crítica, las dimensiones de los molinos, la densidad de los medios de molienda (bolas), el porcentaje de la carga de bolas, las características geométricas de las bolas para molienda y el diámetro real de bolas, que influye de forma inversamente proporcional en la tasa específica del consumo observada."

Jul 1, 2015

By Ralillie Lopes Carvalho

O presente trabalho apresenta um estudo da influência do tratamento de nitretação a plasma sobre a dureza de lâminas utilizadas em prensa-facas de um picador de toras industrial. Tais peças são fabricadas em ligas com alto teor de Cromo e Carbono, assemelhando-se quimicamente aos aços para trabalho a frio AISI da série D. Para o estudo em questão, pequenas amostras das lâminas receberam tratamento térmico de têmpera e duplo revenido,e posteriormente foram nitretadas a plasma por 30, 90, 180, 360 minutos, em temperatura de 450°C, com pressão fixada em 2 Torr e mistura gasosa de 20%N2 e 80%H2. Logo após foram realizadas análises metalográficas com auxílio de microscópio óptico, ensaio de dureza superficial e perfil de dureza com microdurômetro em escala Vickers. Os resultados mostraram que para todos os tempos de tratamento houve endurecimento superficial em relação ao material não tratado, onde o tempo de 180 minutos propiciou a formação de camada com maior valor médio de dureza superficial “1171,20 HV”.

Aug 16, 2017

By Raquel de Carvalho Reis

A fosfatização é um pré-tratamento superficial que tem como principais funções: a lubrificação, proteção contra corrosão e proteção contra abrasão. Os metais fosfatizantes mais comumente utilizados são o zinco, manganês e o ferro, sendo o zinco o mais aplicado nas indústrias siderúrgicas, automobilísticas e de linha branca. Atualmente, grande parte das pesquisas relacionadas aos processos de fosfatização é referente ao fosfato de zinco, sendo escasso o estudo sobre fosfato de manganês. O objetivo deste trabalho foi estudar a cinética de formação da camada de fosfato de manganês em aços baixo carbono, analisando a influência do substrato na formação da camada fosfatizada. As análises foram baseadas na obtenção das curvas de ganho de massa, sendo caracterizadas por microscopia eletrônica de varredura. Os resultados indicaram que para o substrato constituído essencialmente de martensita revenida, uma maior quantidade de carbonetos resultou em uma menor taxa de ganho de massa, pois estes funcionam como sítios ativos no processo de fosfatização, fazendo com que exista uma maior densidade de núcleos.

Aug 16, 2017

By Luciana Pirone de Oliveira

O cobre é encontrado na natureza na forma de óxidos ou sulfetos e sua obtenção na forma metálica é usualmente alcançada através da pirometalurgia e eletrólise. Em ambos os processos há, além do gasto com energia, a geração de grande quantidade de passivos ambientais. Neste contexto a redução via plasma de hidrogênio se apresenta como uma alternativa promissora, pois valores significativos de carga metálica podem ser obtidos em temperaturas inferiores aos processos usuais e tendo como resíduo apenas vapor de água. Neste trabalho procurou-se investigar a influência do fluxo de hidrogênio na eficiência da redução do Cu2O por plasma de hidrogênio em baixa temperatura. Os experimentos foram realizados em reator de plasma pulsado CC nas vazões de 100, 200, 300 e 400 cm3/min, com temperatura constante de 300°C por 1h e pressão de 4Torr. A eficiência da redução foi determinada através de um balanço de massa e as análises dos produtos da redução foram feitas por difração de raios-x (DRX) e microscopia eletrônica de varredura (MEV). Os resultados parciais ratificam a redução a plasma como nova rota para a produção de cobre metálico e demonstram que as variações do fluxo de hidrogênio têm pouca influência na eficiência da redução.

Aug 8, 2018

By D. Harrington

The primary objective of this paper is to discuss the hazards and furnish a list of recommendations for the safe operation of quarries and related works. They have been compiled from Bureau of Mines publications covering the safety experience of engineers before and during the year in the mineral industry,5 from a publication of the National Safety Council, Inc.,6 from explosives recommendations made by various explosives manufacturers,7 and from suggestions obtained from quarries visited. The second objective is to describe and illustrate safety devices, practices, and quarrying methods. The quarrying and related industries of the United States had a lower accident-frequency rate than either the metal- or coal-mining industry as reported for 1942.8 However, the quarry industry ranked eleventh in 15 major industries during 1942 in lost-time accident fre¬quency; metal mining ranked fourteenth and coal mining fifteenth.

Jan 1, 1950

By Maurice Guillaud

The most striking innovations on diaphragm-wall construction plant are those associated with continuous real-time trajectory monitoring of the excavating tool (either a grab or a hydro-cutter). The recent equipments are fitted with clinometers and gyrometers to control deflection, rotation or deviation from the vertical, thus allowing to install diaphragm-walls with a verticality accuracy of less than 0.3%. One of the greatest advantages of extensive use of on-board IT systems on the Hydrocutters and hydraulic grab machines is that it aids quality control by automatically producing complete real-time reports of all excavating data (verticality, depth, type of ground, rate of progress, stoppages, etc.). These reports are available to the Engineer, providing the total transparency required for Works Supervision and the Quality Assurance Plan. They also provide the Contractor with input data for databases used for optimising efficiency and progress criteria on future jobs.

Jan 1, 2002

By Shanjun Mao

This paper summarizes current achievements of Digital Mining in China, puts forward the concept, framework and key technology of Smarter Mining, and finally points out that there is still a long way to go in order to acheive Smarter mining.

Aug 1, 2013

By Francois Reizine

Infrared sensors will include scanning detectors and positioning sensors. The focus will be on 1, 2, and 4-color wavelength pyrometer systems which allow the accurate measurement of emissivity and, consequently, of the true temperature even in the presence of scale, slag, and fumes. Such sensors are being used in blast furnaces, BOF's, and galvanizing lines. Laser sensors will be presented using different principles of physics, mainly time-of-flight, pulsed infrared lasers for level measurement and dimensional measurement; triangulation lasers for width and thickness measurements; and laser Doppler velocimeters for velocity and length measurements, including mass flow, elongation, and tension control, cut-to-length applications. These sensors and systems are based on state-of-the-art technical developments to improve productivity and quality and reduce maintenance and downtime.

Jan 1, 2001

By Chao Lian, Hongxu Li, Hao Bai, Wei Wei

"Application of high-emissivity coating on inner walls in industrial furnaces increases the furnace thermal efficiency. The coating with high emissivity strengthens radiation heat transfer in the furnace, however, according to Wien's displacement law and Planck's radiation law, under heating temperature, the wavelengths of the radiation transfer are mostly between 1-5 µm, implying that increasing emissivity of the coating in near infrared band is more effective for higher thermal efficiency. In this paper, a new CuO-ZnO-based coating material sintered at 1600K was developed. The emissivity of the samples were measured and the result shows that, in near-infrared band, the emissivity of the sample reaches 0.98 at 773K with 13at.% of CuO doped in ZnO. In addition, the effects of CuO doping and use temperature on emissivity were also discussed. Furthermore, crystallization behaviors of ZnO-CuO sintering were investigated by DTA,XRD and SEM-EDS etc., which offered information for possible optimal design of the material.1. IntroductionIndustrial furnaces are widely used in various industrial heating. For example, the metal smelting furnace, ore sintering furnace in metallurgical industry; the distillation furnace, cracking furnace in petroleum industry etc,. The research on efficient energy saving technology has important significance. High emissivity coatings are widely used in many high temperature applications to effectively transfer the heat by radiation [ 1]. The theoretical calculation and experimental studies have shown that, coated high emissivity coating in the heating surface is an effective method to enlarge the infrared radiation power [2].At present, the infrared high emissivity coating has been widely used in China, and have been achieved remarkable energy saving effect. According to Wien' s displacement law and Planck' slaw, most energy of the black body at high temperature is radiated in the wavelength range of l-5µm; however it happens that many materials have the low emissivity within this range. Thus, it is important to improve the near-infrared band emissivity of materials [3]."

Jan 1, 2013

By A Hacket, M Haest, I Vitins

Infrared spectroscopy has the ability to accurately measure mineralogy of drill cores, allowing for better spatial characterisation of iron ore deposits and potentially improving the prediction of key mining and processing parameters at the deposit scale. BHP Billiton Iron Ore is using infrared spectroscopic drill core logging to provide fast and accurate mineralogy for diamond cores and reverse circulation (RC) samples.Mineralogy can be predicted from infrared spectroscopic drill core data with errors on estimates ranging from six to 12 weight per cent. The error on the clay estimates is significantly lower than for hematite and goethite content estimates. This manuscript presents the results from a study on a bedded iron ore deposit, hosted in the Brockman iron formation, for which infrared spectroscopic data were collected on all of the diamond and RC drilling. Results show that these mineralogy estimates improve drill core logs, the geology model and the metallurgical block model.CITATION:Haest, M, Vitins, I and Hacket, A, 2013. Infrared spectroscopic drill core logging - making inroads to deposit scale 3D mineralogy, in Proceedings Iron Ore 2013 , pp 251-258 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

Extensive infrastructure construction works were required for the development of the underground and open-cut coal mine at Ulan to a production capacity of 5 million tonnes of steaming coal per annum. The Ulan Mine development project was constructed in a two year period at a cost of $240 million. The infrastructure component included the construction of the mine site building works, civil works and 150km of railway, valued at $105 million. These works were successfully completed under a construction management agreement within two years. The separate elements of the project are described in detail in the paper.

Jan 1, 1983