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By R. Washnock, P. James

"INTRODUCTION Abstract Tankhouse iron control through application of new treatment technology to mitigate conventional bleeding losses is considered. Implementation is discussed and the treatment economics explored. A representative case is assessed. Treatment benefits and application drivers for specific scenarios are noted. Background Hydrometallurgical ore processing has become a significant metal extraction/production avenue in recent decades. In copper mining; the focus for this examination, around 25% of global primary copper production and nearly 50% of US production result from various hydrothermal leaching extraction approaches coupled to Solvent Extraction/Electrowinning (SX/EW) metal production. Generally such processing is favored over pyrometallurgical processes for lower ore grades and as such is finding growing use and is expected to remain a key processing route looking forward with average world-wide ore grades falling as known ore reserves become exhausted. Target Problem And Motivation In hydrometallurgical processing the production circuit may be thought of as a chain of interlocked recirculation loops (Figure 1). Leaching dissolves the target metal from the ore along with other ore components which contaminate the Pregnant Leach Solution (PLS). Iron is a common component in copper ores and, as a result, occurs fairly ubiquitously in copper Pregnant Leach Solutions (PLS) generated by leaching. Leached components migrate through the production circuit from left to right (Figure 1) through a net combination of chemical and mechanical transport mechanisms. Selectivity at the recirculation loop interfaces tends to retard rejected component migration through the production process. As a result, overall relative contaminant migration fluxes are slower than the target metal (copper) and the contaminants tend to build up relative to copper in the more upstream portions of the processing circuit over time with iron often being a significant contaminant. Further, while copper is continuously removed from the system in appreciable amounts, little contaminant exit occurs and the absolute contaminant amounts and concentrations also increase throughout the EW circuit over time."

Jan 1, 2018

By G. Riveros

A new, continuous fire refining process for copper has been developed and tested at the 5 tph pilot scale. During oxidation, the blister copper flows through a packed bed of crushed refractory bricks counter-current to a hot oxygen containing gas. The resulting desulphurized copper flows then directly into a packed bed of charcoal for deoxidation. By controlling the air to natural gas ratio, both temperature and reducing conditions can be controlled. Based on extensive laboratory scale measurements of the rate of copper oxidation and reduction, the process concept was developed aided by process modeling and simulation. The industrial-pilot scale installation built at the ENAMI Paipote smelter in Chile, consists of two cylindrical, compact reactors, operating in line, with a designed capacity of 5 t/h of blister copper. The results of the industrial-pilot tests confirmed the feasibility of the new process. The blister copper processing capacity was increased to 10 t/h with satisfactory sulphur removal. The degree of oxidation as well the copper temperature was controlled with relative ease. The specially designed siphon block allowed for smooth tapping of the oxidized copper and separation of refining slag. The reduction of oxidized copper in the packed bed of charcoal appeared to be very effective while control of the degree of reduction according to the height of the bed ensured control of the oxygen content in the refined copper at the required level.

Jan 1, 2007

By T. Bhambhani, J. Jankolovits

Sphalerite flotation using copper sulfate has been performed in the industry for decades and the mechanism of Cu activation is well established. Despite its ubiquity, many practical questions surrounding copper sulfate persist. It is not clear how iron selectivity is achieved in zinc circuits given the propensity of iron sulfides to be activated by copper. Also, the large variation in copper sulfate dosages across different plants and ore types cannot be explained. Lastly, Zn flotation with greatly reduced copper sulfate dosages attracts significant interest and has been demonstrated in certain laboratory settings, but no information is available on why those laboratory solutions have not been adopted in plant practice. Flotation studies are presented that demonstrate that Zn flotation with very low copper sulfate dosages is possible when using certain novel collectors that are not practised in the industry. However, these reagent schemes are impractical because of a heretofore unappreciated and critical role that copper sulfate plays in Fe rejection. With both very low and standard copper sulfate dosages, copper sulfate influences both Zn flotation and Fe rejection. The results highlight the multifaceted role of copper sulfate in zinc flotation and the need to holistically consider complex systems’ behaviour to understand flotation reagent mechanisms and optimise plant performance. Keywords: Sphalerite flotation, metal activation, copper sulfate, iron rejection

Jan 1, 2020

By N. Schreithofer, M. Aspiala, R. Serna

The novel attachment timer apparatus presented in this paper serves as a diagnostic tool that allows the detection of changes in bubble-particle attachment probability and therefore floatability caused by alterations in the chemical environment and particle properties. The apparatus consists of six identical capillaries where bubbles with defined size are produced simultaneously in a measurement chamber. The bubbles at the capillary tips are placed in contact with the submerged particle bed for specific time periods, controlled with the help of automatic actuators. The advantage of the instrument is that hundreds of bubble-particle contacts can be measured automatically within a short time period. Microscopic pictures of each measured bubble are taken while recording the movement of the bubble before, during and after contact with the solid particles. The recorded pictures can be used to determine the actual bubble size and its corresponding deviation, and to detect the attachment of particles. The attached particles are collected in a detachable chamber for subsequent characterization. Furthermore, the device is portable and can be taken to the mineral processing plants for quick evaluation of particle-bubble attachment efficiency with particles and process water sampled directly from real processes.

Jan 1, 2017

By Arturo Carranza Edwards

Sedimento II oceanographic cruise, on board of the B/O El Puma, shows a new high anomaly or phosphate associated with shelf sediments from the south Mexican Pacific. Recently, were found two anomalies in the Gulf of Tehuantepec, that are located to the east of this new anomaly, that is related to muddy sands and rock fragment debris. The latter shows values of 17% P205. The phosphate occurrence is probably associated with red tides locations that usually are found in sites where sediments are phosphates enriched. These findings suggest that south Mexican Pacific is of potential interest for P205, in waters with high nutrients values. The possibility of a more regional occurrence of phosphate, from California to Chile is suggested.

Jan 1, 2000

By W. J. González

"With the increasing demand for minerals, technologies to maximize mineral recovery are paramount to a mine’s economic success. Many mining process waters have the potential to form calcium-based inorganic scales, which inhibit effective mineral recovery. Often, the solution to inhibit these deposits is the implementation of a chemical antiscalant program. This paper examines the application of a fouling analyzer to continuously monitor the formation of inorganic scale in mining process streams. The fouling data can be used to compare antiscalant programs and to optimize antiscalant feedrates. Case studies validate the ability of this technology to help optimize mineral recovery processes.INTRODUCTION The mining industry uses significant quantities of water. From quarrying, to crushing, to flotation, leaching, and refining, water is often the integral motive force to move slurries, separate or agglomerate fines, and extract and purify minerals. As well, water is used in a number of ancillary applications at mines, including dust suppression, gas scrubbing, and utility processes such as boiler, cooling, and waste water operations. For many processes, the quality of water being used is inconsequential. However, for certain processes, such as flotation, leaching, and desorption / stripping, water quality plays a key role in the ability of the operation to economically recover the target minerals. Dissolved solids such as calcium and magnesium salts can concentrate in process waters, exceed their solubility limits, and precipitate as scale on metal surfaces such as feed and transfer pumps, piping, and equipment. Some of the more common scales that form in mining operations include calcium carbonate (CaCO3, or calcite) and calcium sulfate (CaSO4, or gypsum), and to a lesser extent, calcium and magnesium silicate compounds. Any scale that deposits in a process stream will negatively impact mineral recovery, and increase the operational costs of the mine site. Whether it is acid washing a scaled heat exchanger in a carbon strip at a gold operation, replacing plugged emitter tubes in a leaching operation, or hydroblasting process lines in a scrubber unit, there are costs associated with labor, cleaning chemicals, repairs, and replacement parts. These costs pale in comparison to the potential costs of downtime and lost production, should the scale deposits occur in a process that is critical to the recovery of the target mineral."

Jan 1, 2014

By W. J. González

With the increasing demand for minerals and the decline in the quality of ore reserves, technologies to maximize recovery are critical to a mine?s economic success. Many mining waters exhibit the potential to form hardness-based inorganic scales, which inhibit effective mineral recovery. Often, a continuously-fed chemical deposit control program is implemented by the mine site to inhibit these scales. The use of retractable scale coupons is the current industry standard for monitoring these programs; however, a key drawback to their use is the limited, and sometimes untimely amount of information they provide. A proprietary fouling analyzer has been developed that can be used to continuously monitor the formation of inorganic scales in mining process streams. Consequently, it can be used to continually, and more effectively, communicate the efficacy of an antiscalant program, thereby providing the ability to compare different scale control programs and to optimize their feedrates. Case studies presented validate the applicability of this technology to help optimize mineral recovery.

Feb 23, 2014

By I. Gaballah

Cadmium is toxic to plant, animals and humans. The council directive of the European Communities No 8315 13lEEC has fixed an upper limit of 200 ppb for the release of cadmium in industrial effluents. The conventional method of neutralization/prccipitation ( NIP ) is inefficient to reach this limit. The objective of this study is to test the efficiency of the trees modified bark to remove cadmium cations from industrial effluents after the conventional treatment by NIP. Laboratory scale tests with synthetic solutions show that the cadmium removal depends upon pH and initial concentration. About 99.9 %, 99 % and 96 % of the metal are removed from synthetic solutions containing 10, 100 and 1000 ppm respectively. Pilot plant trials ( 1 m3 ) with an industrial effluent bearing about 500 ppb of cadmium lead to the almost complete elimination of the cadmium ( final concentration is lower than the analytical detection limits < 20 ppb ).

Jan 1, 1994

By V. de Macedo Torres

There are technical and commercial limitations on using high fluorine copper concentrates in industrial copper smelters. The presence of more than 1000 ppm of fluorine in copper concentrates affects the sulfuric acid units generally integrated to copper smelters, and penalties are normally applied to high fluorine concentrate prices. Several process alternatives to this issue were studied at CVRD Technology Center (SUTEC): modifications on conventional sulfuric acid plants to use high fluorine concentrates, removal of fluorine containing minerals in flotation using depressants, selective leaching of fluorine minerals and sulfuric leach of copper concentrates. Finally, a hydrometallurgical process of removing fluorine was developed by SUTEC.

Jan 1, 1997

By G J. Lyman

Sampling of grain for mycotoxins is challenging in that some mycotoxins, such as Ochratoxin A (OTA), have very low permitted levels and the kernels carrying the mycotoxin may be highly localised within the bulk of the grain as ‘hot spots’. Sampling for genetically modified organisms (GMOs) can be fraught with similar problems, especially if the contamination is adventitious and random. Incremental sampling under these circumstances can be shown to lead to a high variance in the sampling result.A new design of sampler for grain and other free-flowing particulates has been developed that is effective in practically eliminating the sampling variance due to distributional heterogeneity (DH).This paper introduces the design and argues that the sampler should be free of sampling variance due to DH.CITATION:Lyman, G J, 2017. A new sampler for grain and other free-flowing particulates, in Proceedings Eighth World Conference on Sampling and Blending , pp 277–280 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2017

A new series of reports called ?Mineral Perspectives" (MP&apos;s) has been initiated by the Bureau of Mines with the publication of MP-1 titled, "Far East and South Asia" by K.P. Wang and the staff of the Bureau of Mines. This new series parallels the creation of the recently announced "Minerals Commodity Profiles" (MCP?s). Both series are designed to provide current information on important sectors of the mineral economy to assist professionals in government, industry, and education in monitoring supply-demand relationships that have significant impact on our domestic economy as well as on the international scene. The orientation of the "Mineral Perspective" series is a geographic one which examines the mineral situation of a region or a country. The "Mineral Commodity Profile? series examines individual mineral commodities. They are in this sense complementary.

Jan 1, 1977

By James J. Snodgrass

A new technique was used to obtain detailed sonic logging data in drill holes above the water table at a coal mine site in northeastern New Mexico. The equipment was developed under contract to the Bureau of Mines and the U.S. Department of Energy to indirectly evaluate the in situ structural properties of coal and overburden. The system comprises a hydraulically operated, wall-clamping downhole probe compatible with standard four-conductor logging cable, and a surface control module. Resolution of layering is 0.6 meter (2.0 ft), and a redundancy of data from separate receivers provides accurate timing measurements. Preliminary results in the settled overburden of an excavated long-wall panel indicated a low average velocity zone, extending approximately 18 meters (60 ft) into the immediate roof of the coal seam. Subsequent measurements improved the field and recording procedures to produce high quality waveforms from which both P and S arrivals may be visually interpreted. Over a representative section of interbedded sandstone, siltstone, shale, and coal, Vp and Vs varied considerably even within lithologic units. Compressional wave velocity in the coal seam, Vp = 1,740 m/sec (5,700 ft/sec), was in the range of variability of published data.

Jan 1, 1982

By P. Somasundaran

Previous studies on semi-soluble minerals such as calcite (1) and apatite(2) and sparingly soluble minerals such as quartz (3,4) have given evidence for significant changes in their electrokinetic properties as a function of aging time. Such changes are relevant to mineral processing operations where the crushed ore particles might not have yet reached equili¬brium with the water that it is in contact with. In order that these changes be studied under controlled experimental conditions for long periods unattended or with fairly less intermittant attention, a streaming potential apparatus with an automatic streaming system was constructed. Also, a new streaming potential cell was incorporated into the system so that the effect of temperature, a variable coming into increasing usage in mineral processing operations(5), could also be studied. Conventional streaming cells(6) cannot be safely employed to conduct studies as a function of temperature since they have many glass joints that are prone to leakage, parti¬cularly under pressure, in the course of an experiment. This paper describes the new apparatus and some typical results that have been obtained with it far temperature effects.

Jan 1, 1973

By D. F. VanDine, H. George

"The possibility of spoil pile failure at the Kara Kara bauxite strip mine, Guyana, South America, is of major concern to the mine operators. The current mining technique requires the continuous operation of an 11 ms bucket capacity walking dragline on top of 18 metres of freshly spoiled uncompacted overburden material consisting of varying mixtures of kaolinitic clay and quartzitic sand. A field biased geotechnical study of undisturbed overburden and corresponding spoiled material has identified site-specific, non-linear correlations between vane shear strength, standard penetration resistance and spoil pile composition. Readily available geological exploration borehole logs has enabled a composite clay isopach map of the entire mining property to be drawn and critical areas to be zoned according to expected slope stability. Stability has been assessed using simple hand calculation techniques. Use of the resulting stability map provides the mine operators with a means of forecasting the need for appropriate preventative measures at varying stages of mine development, throughout the life of the mine.A similar investigation procedure could be employed at many presently operating and future strip mines.IntroductionThe Kara Kara bauxite stripe mine is located at Linden within the bauxite belt of Guyana in South America. The mining property covers a total area of 88 hectares of flat to gently sloping ground of which some forty per cent is being actively mined or being preparatorily stripped of overburden, prior to eventual mining (George and Gordon, 1979). The regional climate is tropic and humid. Temperatures vary from 16°C to 38°C and yearly rainfall averages 2600 mm, with at least 55 per cent of this precipitation occurring during the &apos;wet season&apos; months of May to July and December to January."

Jan 1, 1983

By Forrester P. I, Richardson W

Methane in coal mines is an ever present hazard resulting in loss of lives and serious economic consequences. For effective control of methane, ventilation alone may not be totally adequate in some situations. In order to deal with such cases, new methods for the control of methane are being researched. One such method based on biotechnology has been investigated in Canada in the past several years. This method involves bringing methane oxidizing micro- organisms into contact with coal to oxidize the methane released to non-flammable products.

Jan 1, 1988

By B. R. Mohal, S. Chander

"A new technique to determine wettability of powders is presented in this paper. In this technique the times for immersion of individual particles from air into liquids, defined as imbibition times, are measured. Through the measurements of imbibition times for a large number of particles, it is possible to determine homogeneity/heterogeneity of a powder sample with regard to its wetting behavior. Quartz particles give a very narrow distribution of imbibition times showing a homogeneous wetting surface whereas coal particles give a broad distribution indicative of the heterogeneous nature of its surface. The imbibition time measurement technique is considered to have certain advantages over other methods to determine wettability of powders in surfactant solutions. In this study we have also compared the imbibition times with the wetting rate mea¬surements obtained by a modified Walker test.INTRODUCTIONSeveral methods are available for determining wetting characteristics of sol¬ids. Each of the methods has been used in the past to obtain very valuable information for comparing wetting behavior of various solids in a given liquid or for comparing the wetting behavior of several liquids for a given solid. Each method measures a somewhat different aspect of wetting and therefore quantitative correlations between techniques have been difficult. A general approach is to use a method in which close similarity between the technique and the application (where results of wetting measurements are to be used) can be maintained. The objective of this investigation was to develop a method which could be used to determine the wetting characteristics of single particles in surfactant solutions. Wetting of individual particles is of importance in cap¬ture of dust particles by sprays of surfactant solutions.METHODS FOR DETERMINING WETTING — A BRIEF REVIEWThe various methods available for measuring wetting characteristics of solids include: contact angle, immersion/sink time, bubble pick-up, induction time, capillary rise, and displacement method measurements. Some of the methods are briefly reviewed in the paragraphs that follow."

Mar 1, 1989

By M. A. Verhaege, Stanislav S. Naboychenko, Vladimir I. Skorohodov, Olga Yu. Goriaeva

A new technology for the processing of secondary raw materials containing precious and Platinum Group Metals (PGMs) has been designed at the Laboratory of Heavy Metals at USTU. The technology is based on hydrometallurgical processing of the materials followed by sorption separation of the PGMs from the leach solution. Different versions of the technology can be realised depending on the type of processed material but the fundamentals are similar. Some parts of the technology can easily be integrated into existing flowsheets. The stage of sorption removal of platinum and palladium was tested on the site of the Joint Stock Company (JSC) "Uralelectromed" on pilot plant scale. A process was developed to obtain fine gold, silver, platinum and palladium. No waste is produced because all solutions are recycled. There are no gas emissions. Selective sorption of platinum and palladium from silver-containing solutions is possible even if the concentration ratio of silver to PGMs is one thousand to one. Sorption behaviour of the PGMs as a function of the bulk metal concentrations was studied. Recovery of 90-95% of platinum and 70-80% of palladium is possible.

Jan 1, 2000

By K Nguyen

The advances in computerised processors and digital microscopic imaging have enabled more studies that attempt to quantify textural information from rock images. However, a texture classification system designed for geometallurgy has always been challenging, as it combines general image analysis techniques and specific texture classifications in terms of the size, shape and orientation of mineral particles. In this paper, a novel texture analysis technique using grey level radial shell association (GLRSA) and spectral angle mapper (SAM) to discriminate between different geological images is outlined. The technique can be applied in routine analysis and characterisation of mineralogical and textural attributes which may correlate with variability in mineral processing behaviours. Using this texture analysis technique, a set of small texture reference images, a texturelet reference library, has been identified from a suite of drill core images. Rock types are classified according to the proportion of each texturelet type recognised. The library is site specific.CITATION:Nguyen, K, 2013. A new texture analysis technique for geometallurgy, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 187-190 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

By M Szwec, P Corbett, P Sheffield

Centennial Coal operates the Springvale and Angus Place longwall mining operations that extract coal beneath the Newnes Plateau in the Western Coalfields of New South Wales. Springvale and Angus Place mines have a history of difficult geotechnical conditions, where mining operations are conducted with a thick coal roof interbedded with numerous claystone units and relatively high levels of vertical and horizontal stress. The combination of a relatively high stress regime and weak laminated roof has led to numerous roof failures throughout the mine’s life.Following underground roadway development, the mine roadways can experience high levels of roof movement that can lead to roof falls. Two-point wire extensometers (known as ‘telltales’) are extensively used for roadway condition monitoring. Along with extensive other geological and geotechnical data, monitoring data is used to prepare geotechnical hazard plans that are then used in all areas of mine planning to allow for safe and efficient operation of the mine.This paper presents a case study of the use of a new software tool that allows time-scaled visualisation of monitoring data in the context of longwall and development face positions and installed strata support. It can be used in the identification of geotechnical risk factors and their interaction with the mining process to allow a more robust geotechnical hazard process. It interfaces directly with the widely used ExtoChart database software and can be presented with scale drawings of geological/geotechnical data to allow correlation of monitoring data with risk factors.CITATION:Corbett, P, Sheffield, P and Szwec, M, 2014. A new tool for extensometer data analysis and improved understanding of geotechnical risk factors, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference , pp 217–232 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 5, 2014

By Lon Santis, David Leidel, John Tatom, Meredith Hardwick

This paper describes the development and methodology of the Institute of Makers of Explosives’ Safety Analysis for Risk (IMESAFR), a risk analysis software program for commercial explosives operations. IME is a nonprofit safety and security association devoted to the safe and secure manufacture, transportation, storage, and use or disposal of commercial explosives in the US and Canada since 1913. The software methodology’s basis is the U.S. Department of Defense Risk Based Explosives Safety Criteria Team’s Safety Assessment for Explosives Risk (SAFER) software. A diverse group of industry and government experts contributed to modifications to SAFER that reflect commercial operations. IMESAFR is intended to supplement the American Table of Distances (ATD) and offer standardized methods of managing risk from a wide variety of commercial explosives operations where the ATD does not apply. The modifications made to SAFER primarily involved the addition of commercial activities and potential explosives sites (PES). A review of commercial explosives accidents and operations over the last 20 years served as the basis for establishing probability of event values. An industry survey of commercial PES types in the U.S. and Canada was conducted to identify and address critical differences in commercial structures as compared to the military structures in SAFER. The paper concludes with discussion of the potential uses for quantitative risk analysis (QRA) and a description of other explosion effects software

Jan 1, 2007