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By Emmanuel Pornillos

Dado que en el Perú, la actividad minera utiliza el minado subterráneo para la explotación de minerales, se revalúa el uso de estos en pasta cementada para el relleno de las labores subterráneas, así como los relaves desaguados para su disposición superficial. En ese sentido, el presente texto señala las experiencias de diseño y operacionales de sistemas múltiples para la aplicación de relaves en superficie y subterráneo en el Perú, de forma que se pueda optimizar la selección de equipamiento y una operación robusta.

Sep 1, 2013

The arbitration process, and its drawbacks: Any time you have taken part in a major arbitration, and the decision, when it comes out, is not what you thought it would be (which is bound to happen occasionally), the normal reaction is something like æthe arbitrator got it wrongÆ. Again normally, when you have cooled down a bit, and you look in more detail at the decision, you can see, probably, æwhere he got it wrongÆ (it is only male arbitrators who get it wrong). Ultimately, when reason prevails, and you reflect on it, you can see that what really happened was that you failed to get the arbitrator to see what you were getting at in the point or points concerned. This is doubly frustrating, when you consider what has been involved in getting to this point, having been through it all at least twice. An alternative to this process may be the dispute review board.

Jan 1, 1999

By James F. Holzbach

Although Disputes Review Boards have been used for some time, they had not received wide publicity at the time Monroe County first used one. Public owners frequently resist adopting new contracting practices. This paper discusses an owner's experience with Dispute Review Boards, from learning about them to their use on two (2) projects. The experiences of potential and actual contractor claims are compared to a claim on an earlier contract and the ensuing litigation. Suggestions for possible use for Owner-Engineer disputes and recommendations for use are provided.

Jan 1, 1995

By Jian Liu

The dissolubility of a natural sphalerite (ZnS) in the entire pH range was theoretically calculated, and its practical dissolution in an aqueous solution at different pH values in an inert environment, together with its surface properties after dissolution, was fully investigated. The results of the investigation indicate that the total concentration of Zn (CZnT) decreases significantly with the increase of pH value, while the pH value is set below 8; however, it reverses when the pH value reaches 8. Such a tendency is similar to that of the theoretical calculations, although the experimental CZnT were much higher than those of the theoretical calculations. The X-ray photoelectron spectroscopy (XPS) of the sphalerite surface after its dissolution under alkaline solution shows that a polysulfide (Sn 2-) surface layer with a binding energy (BE) value of 162.96-163.25 eV is present on the surface, and the percentage of Sn 2- increases significantly with an increase in pH value; the undissolved and dissolved sphalerites under the acidic solution have a negligible difference in S2p peaks. The surface S/Zn ratio of all dissolved sphalerites shows a marked Zn enrichment and S deficiency. An atomic force microscope (AFM) view of the sphalerite surface, after its dissolution under the alkaline solution at a pH of 12, shows that the surface is significantly different in morphology from that of the undissolved one.

May 1, 2012

By E. Uzun

"In this study, H2SO4 and HCl leaching behaviour of an ore sample containing 1.87% of Ni, obtained from the Karaçam (Eskisehir-Turkey) lateritic deposit that started operation recently was investigated. Acid concentration, temperature and reaction time were investigated as variables by comparative leaching tests and the optimum leaching conditions were selected on teh basis of Ni, Fe, Co and Mg behaviour. For H2SO4 leaching, optimum leach parameters were 95°C, a 12 normal H2SO4 concentration and 90 minutes of reaction time, and under these conditions Ni and Fe dissolutions were 97.6% and 95.4% respectively. On the other hand, 70°C, an 8 normal HCl concentration and a reaction time of 90 minutes were found to be the optimum parameters for HCl leaching, and Ni and Fe dissolutions found were 97.1% and 97.8%, respectively.INTRODUCTION Today, nickel and various nickel compounds are obtained from sulphide and lateritic nickel ores (Moskalyk & Alfantazi, 2002). Even though about 72% of the world's nickel reserves constitute lateritic ores, only about 42% of nickel is produced from these ores. The decrease in production from sulphide deposits, on the other hand, and increases in the use of nickel in the iron and steel, and battery production sectors, and especially the production of nickel cast irons in recent years, have accelerated the importance of making use of lateritic deposits (Luo et. al., 2010; Chang et. al., 2010). In the beneficiation of sulphide nickel ores, mostly pyrometallurgical methods are used. On the other hand, about 39% of lateritic ores are beneficiated by pyrometallurgical, and 61% are beneficiated by hydrometallurgical methods (USGS, 2009). In laterite beneficiation, the ore properties are of significance; that is to say, limonitic ores are eneficiated by high pressure acid leaching or via the Caron process, nontronitic ores are beneficiated by high pressure acid leaching or heat treatment (smelting), and ores containing serpentine by pyrometallurgical methods (Berezowsky, 2004; McDonald & Whittington, 2008a; Dreisinger et. al., 2015)."

Jan 1, 2017

By A. Jafarnia

Aluminum alloys are frequently grain refined during solidification in order to promote the formation of an equiaxed grain structure in the casting. The application of Ti-based grain refiners and/or Ti containing master alloys for improving mechanical properties may result in formation of Al-Ti based intermetallics. Although the grain refinement produces many desirable qualities in aluminum castings such as improved castability and mechanical properties, the addition of Ti to Al-Si foundry alloys may lead to the formation of some undesirable intermetallic particles such as AlTiSi and cause a number of operational problems such as nozzle blockage due to segregation and agglomeration of aluminide particles within the nozzle. There are several questions to be clarified when minor amount of Ti is added to Al-Si alloys. They include nucleation and growth of AlTiSi particles, their morphologies and orientation relationships with aluminum matrix and the dissolution of these intermetallics during the course of solidification and/or post solidification treatments. The current study was initiated to study the process and possible mechanism of aluminide dissolution and the related phenomena such as segregation and agglomeration. It reports the results found during reheating of laboratory prepared Ti-added A356 alloy at three temperature ranges of below solidus, mushy zone and above liquidus.

Jan 1, 2004

By M. Clotilde Apua, A. F. Mulaba-Bafubiandi

"The efficiency of hydrochloric acid (HCl) leaching of gold from low grade gold-bearing material has been investigated in the presence of sodium hypochlorite (NaOCl) to produce in situ chlorine gas which is an oxidizing agent able to oxidize gold metal to its soluble forms. The effect of concentrations of HCl, NaOCl, and mixtures of HCl + NaOCl was sought. Iron and potassium present in the feed were leached and consumed all the HCl. Gold found as inclusion in pyrite was not exposed to the lixiviant. Therefore, leaching of gold from low grade gold-bearing material in aqueous chlorine solution is not an effective process for now.INTRODUCTIONHydrometallurgy of gold is commonly based on cyanide leaching solution. Due to the environmental concerns related to cyanidation and mercury processes, and inefficiency of cyanide gold leaching to dissolve refractory ores, sustainable alternative lixiviant systems, capable of generating gold (I) and gold (III) complexes must be studied. Amongst non-cyanide gold lixiviants there is the chloride/chlorine system (Hilson and Monhemius, 2006; Senanayake, 2004; Pilsniak and Trochimczuck, 2007; Wang et al., 2007; Reeves et al., 1999; Khodadad et al., 2008).In practice, the most oxidizing agents utilized for the leaching of gold as chloride, are chlorine (Cl2) or hypochlorite (HOCl) which are either generated in situ by suitable reaction or added in solution (Adamson, 1972). The dissolution of gold concentrate using hydrochloric acid, sodium chloride and sodium hypochlorite (Cl-/HOCl system) were studied (Puvada and Murthy, 2006). The effect of NaOCl and NaCl concentrations were also investigated. The leaching was performed under the following conditions; time: 4h, solid–liquid ratio = 1:4, at room temperature. It was found that the increase of the NaOCl concentration from 25 to 75 g/L did not have any meaningful effect on the recovery of gold which was about 30% (experimental conditions; S/L ratio = 1:4, NaCl concentration: 25 g/L, HCl concentration: 0.35 M). It was also found that from 25 g/L to 200 g/L NaCl, the recovery of gold rose from 30% to 40% (experimental conditions; S/L ratio: 1:4, NaOCl concentration: 25 g/L, HCl concentration: 0.35 M)."

Jan 1, 2012

By VÍCTOR VÁZQUEZ-VÁZQUEZ, GUILLERMO TIBURCIO-MUNIVE, María M. Salazar-Campoy, JESÚS L. VALENZUELA-GARCÍA, OFELIA HERNÁNDEZ-NEGRETE

This study examines a process for the recovery of precious metals from difficult minerals that exhibit refractory characteristics to cyanidation: low extraction of metals and high consumption of leaching reagent. A mineral sample from Monte del Favor Mine, located in Hostotipaquillo, Jalisco, Mexico, was physically and chemically characterized by X-ray powder diffraction (XRPD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), fire assay and atomic absorption spectroscopy (AAS). Two stages of leaching were carried out, first to eliminate manganese from the sample using sodium sulfite (Na2SO3) as a reductive reagent along with sulfuric acid (H2SO4), and second to dissolve gold and silver with hydrochloric acid (HCl) and sodium hypochlorite (NaClO). The results show extractions of around 96 percent for manganese (Mn), 98.73 percent for silver (Ag) and 83 percent for gold (Au). The usefulness of high acidity and Na2SO3 to obtain better results in Mn and Ag leaching are discussed along with the roles that HCl and NaClO play in Ag and Au dissolution values.

By Batric Pesic

Silver dissolution with thiourea was studied by using the rotating disk technique. The major parameters studied were: thiourea concentration (0-0.5M), ferric sulfate concentration (0-0.5M), sulfuric acid concentration (0-0.5M), and the effect of many foreign ions (Mn, o.i, Co, Ca, Na, etc.). Temperature effect was studied in the range 5-35 .C. The activation energy was 5.4 Kcal/mole. The dissolution of silver was first order with respect to ferric sulfate, and the secord order with respect to thiourea. Among the additives, copper had a dramatically negative effect. The strong oxidants such as hydrogen peroxide and manganese dioxide were also detrimental for silver dissolution. Silver does not dissolve with thiourea in the absence of ferric ions. Sulfuric acid does not participate in the dissolution reaction either. Chemically, the most important parameter for silver dissolution is the ferric sulfate/thiourea ratio. Thus, in the solutions with excess of ferric sulfate, a solid silver-thiourea complex is formed, which precludes transfer of silver into solution. In the solutions with the excess of thiourea, the free thiourea reacts with formed solid silver-thiourea complex and silver goes into the solution. The solid silver-thiourea complex was characterized according to its chemical composition. The complex contains 6.54%C, 2.49\H, 14.77%N, 16.09%0, 21.62%8, and 37.13% Ag. This composition corresponds to a Ag2so4.3'1U.2ff:i0 compound The soluble silver species are present in the solution as the dimers of AgTU+3 complexes.

Jan 1, 1989

By Elizaveta Cheremisina

In steelmaking process lime serves as flux. Rapid lime assimilation and slag formation of the desired composition have a significant effect on the refining reactions. It is important to know the rate limiting step of lime dissolution to control and improve the converter process. Kinetics of pure CaO and industrial lime dissolution in model slag has been studied in the range of temperatures 1300 –1600°C. Lime samples were prepared in cylinder form and immersed in the melt for predetermined time. Considering the total mass balance of CaO in the slag and linear dimensions of lime samples, mass transfer coefficients were derived. Diffusion coefficients were calculated under conditions of non-stationary diffusion. The derived activation energy of less than 200 kJ/mol indicates that diffusion is the limiting step in the process of lime-dissolution in slag.

Oct 30, 2017

Distal air-fall ashes are widespread deposits that may record volcanism many hundreds of kilometres from their source. They are characteristically thin, fine-grained and have a low preservation potential usually being either eroded, or reworked and incorporated in overlying sediments following deposition. The most likely sites of accumulation are deep sea, lake and swamp environments where low energy conditions favour preservation. Post-depositional alteration of predominantly glassy volcanic ash is commonly extensive hampering identification of such layers in the geological record. As a result air-fall tuffs are poorly represented in the rock record and furthermore are commonly misinterpreted. Southeast Queensland during the late Triassic hosted active silicic volcanism and a number of fault-controlled basins in which coal-bearing sediments were accumulating. Silicic volcanics of late Triassic age are represented by the Brisbane Tuff in the Brisbane city area, the Chillingham Volcanics to the south of Brisbane and extending into New South Wales, the North Arm and Mount Byron Volcanics to the north of Brisbane, the Aranbanga Beds exposed around Gayndah and the Agnes Waters and Muncon Volcanics which occur northwest of Bundaberg. Stephens (1986) interprets these Volcanics as the remnants of a major silicic igneous 'province which he likens to modern continental orogenic margins. The Ipswich, Tarong and Callide Basins of southeast Queensland all contain coal measure sequences of late Triassic age that accumulated in alluvial plain environments. A Dicroidium flora is common to all and palynol.ogical evidence indicates a late Triassic (Carnian) age (de Jersey, 1975; Stevens, 1981). The coal seams of the three basins are characterised by their thickness (up to 25 m) and the presence of abundant thin, laterally persistent, kaolinite claystones (tonsteins) that show a marked similarity of morphology, texture and mineralogy. Detailed studies of the Ipswich Coal Measures (Falkner, 1986) suggest a volcanic air-fall origin for the tonsteins of the Ipswich Basin. Similar.tonsteins from the Tarong and Callide Basins provide evidence for widespread silicic volcanism during the late Triassic in southeast Queensland.

Jan 1, 1987

By Zhiguo Chang, QINGXIANG CAI, Ebelia Manda, IZHAR MITHAL JISKANI, XIANG LU, Wei Zhou, Saleem Raza Chalgri

The concept of mine safety is highlighted in the literature of sustainable mining but not extensively discussed. This study analyzes various aspects of underground and surface mine safety and emphasizes its importance in the context of sustainable mining. More specifically, this research attempts to find the relationship between mine hazards and demographic characteristics, examine and compare the perceptual difference among miners, and determine the impact of mine hazards on workplace safety and safety climate. Descriptive analysis, chi-square test, independent samples t test, and linear regression modeling were conducted to achieve study objectives. Results confirmed that mine hazards were significantly associated with age and experience. Miners perceived lower levels of management safety practices, followed by supervisor safety, coworker safety, and job safety. The analysis showed that underground miners reported lower safety scores than surface miners. There was a statistically significant difference between miners’ perception of safety climate (p < 0.05). The results showed that the higher prevalence of mine hazards predicts poor workplace safety and a low safety climate. The regression models revealed that mine hazards have a significant effect on workplace safety (p < 0.05) and safety climate (p < 0.05). In conclusion, the distinctive model of mine safety presented here contributes to the monitoring and design of comprehensive safety interventions and helps to better understand how certain factors interact on multiple levels to influence the overall safety of the industry. In this study, some suggestions are put forward to provide directions to develop a sustainable mine safety system.

Mar 27, 2020

By J Chan, T Baumgartl, A Plante, C Peltre, P D. Erskine

Mine soils are often organic matter and carbon poor due to disturbance, topsoil stockpiling and mixing with spoil. They present an opportunity to observe the accumulation of soil carbon arising from rehabilitation or ‘green carbon’ through organic matter inputs and may be considered for carbon credits. Soil carbon is known to improve multiple soil characteristics and is viewed as an indicator of soil health.When attempting to estimate soil carbon levels in the Australian coal mining regions, both coal and black carbon (BC) need to be quantified. Coalmine soils contain coal particles that are difficult to distinguish from organic matter using standard carbon analyses. BC, a material arising from the incomplete combustion of organic matter and fossil fuels, displays some similar characteristics to coal and is ubiquitous in Australian soils due to bushfires. The presence of coal and BC complicate the determination of green carbon levels in mine soils.A method to quantify coal and BC in mine soils from the Bowen Basin using thermal analysis and multivariate curve resolution is presented. By determining BC and coal contributions it is then possible to calculate green carbon levels in rehabilitated mine soils. Calculated green carbon levels are compared with bulk density as soil quality indicators.CITATION:Chan, J, Baumgartl, T, Erskine, P D, Peltre, C and Plante, A, 2014. Distinguishing carbon fractions in coalmine rehabilitated soils, in Proceedings Life-of-Mine 2014 , pp 491–498 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 16, 2014

By R N. Lamb, A N. Buckley

Experiments have been carried out to establish whether time-of-flight secondary ion mass spectrometry (ToF-SIMS) is able to differentiate monolayer and multilayer coverage of thiol collectors on sulfide minerals. The systems investigated were those for which x-ray photoelectron spectroscopy is able to provide an independent determination of the extent of coverage, and included diethyldithiophosphate (DTP) and 2-mercaptobenzothiazole (MBT) on chalcocite, DTP on Ag2+MS prepared by sulfidising metallic silver, and isobutyl xanthate (BX) and MBT on galena. For monolayer adsorption of MBT on chalcocite, peaks from MBTû but not Cu(MBT)û ions were evident. For multilayer coverage, Cu(MBT)2û ions were clearly present, notwithstanding the fact that other data had identified the principal multilayer species as Cu(MBT). For adsorbed DTP on copper and silver sulfides, DTPû and metal(DTP)Hû peaks were observed for monolayer and multilayer coverage. Although the multilayer species was expected to be predominantly metal(DTP), metal(DTP)2û ions were evident for multilayer (but not monolayer) coverage. For the PbS/BX system, intact Pb(BX)2 or Pb(OH)BX ions were not detected for multilayer coverage, although Pb-containing ions heavier than PbBX were. Indeed, for all the systems studied, ToF-SIMS was able to differentiate monolayer from multilayer coverage. In general, however, the SIMS evidence alone might not be sufficiently definitive to effect the differentiation. In the case of collector adsorption on copper and silver sulfides, if the multilayer species detected had been the metal monothiolate only, and had not involved the formation of some metal dithiolate, then ToF-SIMS might not have been able to provide an unequivocal differentiation of the two coverage conditions.

Jan 1, 2005

By T Bednarz

The present work proposes a distributed collaborative immersive virtual reality framework for prospective applications in the mining industry. A human-centered approach is described, with people being placed in the central position and surrounded by tasks that are to be carried out. Those tasks can be then achieved through synchronous or asynchronous communication, interactions using properly constructed user interfaces, virtual and/or augmented realities and computer vision. Several examples of such arrangements are presented. One of the applications facilitates an e-learning experience by providing a very familiar object – a book – as a target for users to interact with. Importantly, this system has the potential to provide an ‘enhanced’ teaching medium, as humans tend to remember events/situations better when they experience those events in person, when the immersive factor is involved. The immersive virtual reality environment enables a user to interact physically with various 3D objects and experience behaviours, which in turn reinforces the idea that doing leads to learning. This prototype system can be implemented as an efficient and cost effective e-learning and training platform for different engineering domains. At another level, the same technology can be used in the tele-operation of mining equipment for the future mine.

Nov 22, 2011

By A. Desbiens, A. Pomerleau

During the summer of 1994, a new PID-based control strategy was installed on line B of the grinding circuit at the Kidd Creek Division of Falconbridge Ltd. Part I of this paper described the methodology used to select the appropriate control strategy using a phenomenological dynamic simulator. Part II presents the implementation of the control strategy. Prior to the controller installation, it was necessary to solve various problems related to the process, such as a cyclic behaviour of the rod mill feed tonnage, a problem related to the mill water source and the calibration of the flowmeters. Once these problems were solved, the control strategy was accomplished in two steps. Step 1 corresponds to the installation of control loops to regulate the pump box level and the cyclone overflow density. Step 2 describes the implementation of a loop to control the cyclone feed density. According to Part I, a loop to control the circulating load is also part of the original design. However, reasons are given to explain the rejection of this loop. For both steps, technical procedures such as filtering, process identification and controller tuning are detailed. Finally, the operator’s interface is briefly described.

Jan 1, 1997

By Thomas Clark

This report presents a review of the distribution and exploration potential of platinum-group elements (PGE) in Québec; it is based on published and unpublished analytical data. This qualitative evaluation of the PGE potential, whether in PGE-dominant deposits or in Ni-Cu-dominant deposits with co-product PGE, is based on interelement ratios such as Ni/Pd, Cu/Ir, Cu/Pt, and Cu/Pd. Good PGE targets, i.e., deposits associated with magmas fertile in PGE, are identified. Less favorable PGE targets, i.e., deposits associated with PGE-depleted magmas, are also mentioned. The importance of exploring for deposits similar to those at lac des Îles and East Bull Lake (Ontario) is emphasized.

May 1, 2001

By A. H. G. Mitchell

Most, if not all, of the six recognised post-Cretaceous, predominantly andesitic mineralised belts in the region are now thought to be subduction-related magmatic arcs. The Inner Carpathian arc and the Eastern Bosnia or Drina-Rhodope arc host numerous vein and replacement deposits with epithermal features and Zn-Pb+/-Ag as the predominant economic minerals. In contrast, the south Apuseni Mountains have produced over 1 600 t Au from epithermal veins but very little Zn-Pb. Recent age determinations and geophysical data from the Baia Mare district of the Inner Carpathians suggest that mineralisation succeeded volcanism by 1-2 m.y. and accompanied crustal extension and the cooling of a large, mushroom-shaped pluton whose boundaries define the mineral district. In the south Apuseni district, mineralisation can be explained by mixing of meteoric with low-salinity metamorphic water expelled during intrusion of mafic rocks into the middle or lower crust. The more continental or cratonic crust in the Drina-Rhodope and Inner Carpathian arcs precluded the input of low-salinity, Au-bearing metamorphic water; the Zn-Pb deposits formed where convecting meteoric water mixed with saline water, possibly introduced through carbonate rocks in the basement

Aug 1, 1996

By B. Benmokrane, G. Ballivy

"RésuméLe mécanisme de transfert des charges et le processus de décohésion le long des scellements d&apos;ancrages scelles dans des massifs rocheux sous des charges de tensionnement peut être examine par instrumentation de l&apos;ancrage à l&apos;aide de jauges de déformation. Dans ce contexte il est présente ici les résultats d&apos;une étude, en vraie grandeur sur chantier, ayant porte, d&apos;une part sur des essais d&apos;arrachement conventionnels et d&apos;autre part sur des essais déflagrée barres d&apos;ancrages instrumentées et scellées à l&apos;aide d&apos;un coulis de ciment dans un massif rocheux sain et compètent. Les résultats décrits ici, particulièrement les profits de contraintes de cisaillement le long de l&apos;ancrage, obtenus à partir des valeurs de déformations relevées sur les jauges, ont permis de préciser le niveau de chargement correspondant à la décohésion initiale du coulis de scellement, d &apos;examiner l&apos;effet de la décohésion sur la distribution des contraintes et de caractériser le fluage du système barre d&apos;ancrage/coulis de scellement.ABSTRACTThe load transfer mechanism and the debonding process along grouted rock anchor, subjected to tention loads, can be examined through the instrumentation of the anchor with the aid of strain gauges. In this context, the resultsof a full-scale site investigation including classical pull out tests and creep tests are presented in this paper. These tests were performed on instrumented bars which were cement grouted in a competent rock mass. Results presented in this paper concern, among others, shear stress pro/ties along the grouted anchors which were determined from strain values obtained from the strain gauges. These results have been used to: (1) predict the load level corresponding to initial debonding of the grout; (2) study the effect of debonding on shearstress distribution along the anchor; and (3) characterize the creep behavior of the bar anchor/cement grout system."

Jan 1, 1991

A series of petrological studies were carried out on the characteristics of alteration and mineralisation in mainly structural-controlled (Deep Star, Meikle, Deep Post) and predominantly lithological-controlled (Post-Betze-Screamer and West Leeville) gold deposits in the northern district of the Carlin trend, Nevada. Alteration and mineralisation in these deposits are hosted in a sequence of calcareous clastic units of the Devonian Popovich Formation, into which have been emplaced a number of Jurassic intrusions, and syn- to post-mineral Eocene dikes. Four hydrothermal events have been recognised in these deposits: an initial Devonian base metal system and early diagenesis; a Mississippian stage of alteration in conjunction with burial metamorphism; contact and hydrothermal alteration and base metal-gold mineralisation associated with the emplacement of the Jurassic intrusions; and a Carlin-style gold system related to Eocene magmatism.

Jan 1, 2004