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By Euler De Souza

"Underground operation ventilation energy requirements constitute a significant portion of mine energy consumption (40–50%) and total energy costs (25–40%). In general, mine ventilation systems are energy inefficient; the author has found several systems that operate at efficiencies below 65%. This paper presents how engineering design principles can improve the performance and efficiency of ventilation appliances, resulting in reduced power consumption and operating costs. Case studies demonstrate that, by retrofitting ventilation appliances using proper engineering concepts, systems will operate at efficiencies well above common operating efficiencies, resulting in a drastic reduction in costs and base electrical and energy loads.RÉSUMÉ Les besoins énergétiques nécessaires à l’aérage d’une exploitation souterraine représentent une part considérable de la consommation d’énergie d’une mine (de 40 à 50 %) ainsi que des coûts totaux liés à l’énergie (de 25 à 40 %). De manière générale, les systèmes d’aérage d’une mine sont loin d’être écoénergétiques ; l’auteur a trouvé plusieurs systèmes fonctionnant à des rendements inférieurs à 65 %. Cet article présente les principes de conception technique qui peuvent améliorer la performance et l’efficacité des systèmes d’aérage, entraînant une réduction de la consommation d’électricité et des coûts d’exploitation. Des études de cas montrent qu’en les rénovant à l’aide de concepts techniques adéquats, les systèmes d’aérage fonctionneront à des rendements bien supérieurs aux rendements habituels d’une exploitation. Ces rénovations donneront lieu à une réduction considérable des coûts ainsi que des charges électriques et énergétiques de base.INTRODUCTIONIncreasing electricity supply problems in North America have encouraged an industry-wide evaluation of energy consumption, resulting in a more urgent emphasis on energy-efficient design and operation for all energy-consuming systems. Electricity is the main mode of energy supply and the mining industry is affected by the increasing cost of this commodity (Natural Resources Canada, 2017). Ventilation systems normally operate 24 hours per day, 365 days per year, and account for 25–40% of the total energy costs and 40–50% of the electrical consumption of a mine operation (De Souza, 2013). Ventilation engineers are under ever-increasing pressure to reduce ventilation energy consumption and be cost effective."

Jan 1, 2018

By Bernardo J. Jiménez, Harlem Lora, Roberto Acosta Mora

Circunvalacion Norte project is currently the most important infrastructure project in Costa Rica. It is the last segment of the urban perimeter highway. Site investigation of local geotechnical conditions were studied by SPT, CPT, pressuremeter tests and boreholes. A static load test was executed as a proof test with an associated ultimate resistance of 12056 kN (2710 kips). Drilled shaft design was done using PMT tests and axial nominal resistance varied between 4000 kN (900 kips) and 6000 kN (1350 kips). A total of 416 drilled shafts were constructed in 15 months with drill performance of 32 m/day (105 ft/day). Drilled shaft lengths varied between 4,0 (13 ft) m and 40,0 m (130 ft). Selfconsolidating concrete was used to achieve an adequate workability even in high densities rebar cages. Several site conditions proved the importance for maintenance of the working platform, predrilling of rock sockets and having spare parts to avoid increase in project’s cost. New procedures were taken to prevent concrete segregation on excavations near underground water flow. Monitoring the quality of the shafts from CSL test showed less than 3% of the shafts presented a considerable anomaly, which proved that the adopted construction method and materials were adequate. For the concrete anomalies, successful remediation was performed by means of grout at the base of the shaft with two different types of drilling methodology depending on the concrete anomaly.

By M McCarthy

Over the last six years Mandalay Resources has increased production rates and improved safety outcomes at its Costerfield mine in Victoria, Australia. This mine is an underground operation utilising narrow mining techniques to extract vertical veins, and produces up to 80 000 equivalent ounces of gold per annum, in both gold and antimony value.The operational challenges of narrow vein mining include controlling overbreak when veins being mined are only 300 mm wide. The mine has developed methods and modified equipment to suit extraction of these veins. Productivity improvements over the period have involved development of a stoping method and equipment to suit 1.8 m wide development drives. Over the last five years and during a skills shortage, recruitment, training and retention of personnel has been key to keeping corporate knowledge and skills to execute a careful efficient mining technique to minimise overbreak.Managing an underground operation close to nearby residents has unique challenges. Historically Victorian residents had family members work as underground miners; however, in the current day with few underground operations in this jurisdiction, community knowledge of mining has decreased. The Costerfield Operations are only 100 m from the nearest residence and the company values community engagement, partnership and investment with local Heathcote organisations.The mine has invested substantially in executive coaching of its leadership team early, which has paid dividends in problem solving potential of that team and ensuring the operation delivers on its promises to all stakeholders. The operation has become safer and employees are now more aware of their individual contribution in producing safe, efficient gold and antimony that benefit the whole operation, community and the region.CITATION:McCarthy, M, 2016. Costerfield – a narrow vein case study, in Proceedings International Mine Management Conference, pp 331-338 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jun 22, 2016

By Calvert D. Iles

Open-pit mines in the US and throughout the world are typically characterized by increasing operating costs and decreasing ore grades. Thus, companies must continue to improve their use of human and technological resources to remain competitive in the marketplace. Duval Corp. has historically been very sensitive to mining costs, in part because of relatively low grade copper-molybdenum ore bodies. These concerns have resulted in three haulage system generations at the 218 kt/d (240,000 stpd) Sierrita-Esperanza open-pit mine south of Tucson, AZ. Each generation has exceeded the performance of the one replaced. The latest system of portable crushers and conveyors reduces hauling costs by combining both hardware and technique. Savings are achieved not only bysubstituting conveyors for haul trucks, but also by permitting the crusher-convey or system to closely follow mining as the pit deepens and/or mining areas change location. The Duval system is capable of easy and inexpensive relocation in varying site configurations in relatively short time periods. Its implementation in active mining areas results in minimum disruption to both the mine operation and mine design. This haulage concept allows the mining engineer maximum freedom to design an open pit for profit rather than for equipment. Maximum savings with a portable system are achieved by minimizing truck haulage costs. At Sierrita, for example, the yearly estimated operating cost savings for each thousand feet of +10% truck ramp replaced by conveyors is about $1 million per portable crusher. A savings of $30 million could be achieved fora three-portable system overa 10 year period simply by reducing the average truck Iiftto the crusher by 30 m (100 ft), There is also the added capital expense of buying trucks to cover the additional 30 m (100 ft) of lift. Relocation costs are an important consideration in a portable system. Direct costs can become a significant operating expense if frequent relocations are necessary to take full advantage of potential haulage cost savings. A site preparation cost of $375,000, for example, would add an additional operating cost of 2.8¢/t(2.5¢/st) for a system handling 13.6 Mt/a (15 million stpy), assuming one move a year, In addition to the direct cost of site preparation, such as installation of retaining walls, apron feeder slots, and equipment pads, there is the cost of site renovation after abandonment. Indirect relocation costs, while less tangible and more dependent on specific mine design and scheduling, can be of significance. A slowdown in the mining rate or a less efficient mining plan can result from a site not being immediately available for mining after abandonment. Conversely, mining in narrow areas can be adversely affected if two or three month lead times are required for site preparation.

Jan 4, 1983

By Carlandrea Albonico, Salvatore Miranda

The paper describes an innovative geotechnical engineering solution that has been provided within the scope of the Galataport Project, in Istanbul, Turkey. Among all interesting geotechnical works included in the Project, this paper presents the design principle, adopted technologies and performance controls related to the Multi- Purpose Bottom Plug (MPBP). This original geotechnical engineering solution has been employed for the deep basement excavation in Karaköy and consists of a combination of seepage control, ground improvement, and load bearing elements, which have been executed with double-fluid jet grouting, pseudo-elliptical jet grouting and permanent micropiles, respectively. The paper highlights the importance of employing cutting-edge technologies within the foundation engineering field and state-of-the-art electronic control devices, in parallel with the essential human expertise, in order to obtain the desired results in this high-profile Project.

Nov 1, 2022

By NEFE NONE

Possible New U.S. Half-Dollar. - Tile George Washington Commemorative Coin Act, H.R. 3133, was introduced in the House and approved by the House Banking Committee. It would allow the minting of at least 10 million commemorative silver half-dollars the size of the same coin produced before 1965. A companion bill, S. 1228, was introduced in the Senate. Taxes and the U.S. Minerals Industry. - The General Accounting Office completed a report to Congress on "Assessing the Impact of Federal and State Taxes On the Domestic Minerals Industry." the study presents a quantitative method to assess the effect of taxes on profitability, and suggests ways to use taxes or tax credits to help marginal mine operations and possibly to increase mineral production, Limited copies of the 139-page report are available free of charge from U.S. General Accounting Office, Documents Handling & Information Sevices Facility, P.O. Box 6015 Gaithersburg, Md. 20760.

Jan 1, 1981

U.S. Gold Commission Established. - The President, with the authorization of Congress, has named a gold commission made up of 17 individuals, most of them Government officials, to study U.S. policies related to the role of gold in domestic and international monetary systems and report its findings and recommendations to Congress. U.S. Lead Exposure Ruling. - On June 29, the Supreme Court upheld the Government's right to set lead exposure levels for employees at the workplace. The Court ruled in favor of the Occupational Safety and Health Administration (OSHA) in a challenge by a group that alleged that OSHA had failed to conduct a cost-benefit analysis prior to issuance of the lead standards. It was the Court's contention that Congress did not require such an analysis when it empowered OSHA to establish workplace standards. The petition to the Court was made by the Lead Industries Association Inc., Battery Council International Inc" American Iron and Steel Institute, St. Joe Minerals Corp., and other lead mining and consuming firms.

Jan 1, 1981

By S. C. Schmelter

The destabilizing effect of water pressure on rock mass stability is examined quantitatively by the finite element method. A coupled code that accounts for the simultaneous effects of rock mass deformation and transient fluid flow is used for this purpose. The traditional soil mechanics assumption of an incompressible fluid is shown to be untenable for the analysis of porous, fractured rock slopes. A Mandel-Cryer effect, a transitory but elevated and potentially destabilizing water pressure following a cut, was not observed.

Jan 1, 1997

By M. Bustin, A. Hosseinian, G. Preisig

Hydraulic fracturing and hydraulic shearing techniques are essential for the development of unconventional oil & gas and geothermal resources. Such techniques will also play a key role in the development of CO2 sequestration, and management of high stresses encountered with deep mining. However, the optimal design of hydraulic injections is often limited by continuum treatments of the rock mass without consideration of the influence of the natural fractures present. These may interact with the hydraulic fracture to promote offsets or arrest, or may cause the natural fractures to undergo shear and dilation. Given the limited access to the rock afforded by deep boreholes common to oil & gas and geothermal projects, advanced numerical modeling is critical for understanding key mechanisms and interactions. In this work, we first present a coupled hydromechanical distinct-element model focusing on the propagation of a hydraulic fracture. Normal and shear displacements arising from the generated hydraulic fractures are subsequently integrated into a fracture flow model for detailed analysis of specific flow behaviour and fracture permeability. For this, a scanned 3-D profile of a natural fracture is used to correlate surface roughness to dilation as a function of shearing. Fracture flow is computed at different time steps corresponding to different fracture propagation states and geometries. Modeling results indicate that the opening of a tensile hydraulic fracture is accompanied by millimetre-scale shear displacements associated with slip and wedging between adjacent blocks. This may leads to a mismatch between the upper and lower walls of the fracture if asperities are irregular and strong enough. However, fluid-induced tensile fractures have low Joint Roughness Coefficients (JRC), and associated millimetre-scale shear displacements are too small to ensure a significant offset of asperities that prevent a fully-elastic closure when the hydraulic fracture is depressurized. Injection of proppant is thus critical to keeping hydraulic fracture apertures open. Future work is planned that will see the models calibrated against field data including microseismic event locations, magnitudes and source mechanisms, tiltmeter deformations, stress change, and pore pressures.

Jan 1, 2015

By Martin L. Smith, Robert L. Hautala

The objective of blast optimization can be approached either in a qualitative sense of designing a blast which will be "trouble free", or quantitatively in the sense of minimizing overall mining costs. Blast design simulators and fragmentation models have become an accepted tool in blasting over the last decade. Numeric simulators are very useful for solving quantitative problems, but are limited in their ability to address more qualitative problems such as post-blast bench condition. Also, current blasting models are limited by the complexity of site-specific blasting and are not functionally suited to mathematical optimization. As a result a great deal of expertise is still needed in optimizing a blast. The following describes the application of an expert system approach to integrating both a symbolic model of the expertise of the blasting engineer for attaining a trouble free blast, and a numeric optimization model relating fragmentation to unit operations from drilling to grinding. Research into this application of a coupled modeling approach to blast design is being carried out to develop a modeling methodology which will provide a suboptimal design for qualitative design goals as well as minimizing blast related costs.

Jan 1, 1991

By A. Leppala

Scope of the Courier 300 System The fact that reliable on-stream analysis is a prerequisite for effective flotation control is hardly disputed today. Nevertheless, up to now no system has been available that includes all the equipment necessary for successful analysis. However essential an on-stream analyser is in itself, reliable and accurate assaying can only be assured after techniques for sampling, handling the slurries and computing the X-ray data have been developed for the purpose. The Outokumpu Company's Courier 300 System is a complete package that can be installed and handed over with the key. It includes the equipment needed for sampling and handling the slurries. It has been developed from the start to meet industrial demands. Obviously an on-line system must comply with far stricter standards than one designed for a laboratory. Assays are computed by an Outokumpu 316 digital data processor, which is an integral part of the system and controls its entire performance. The computer software is programmed as a standard package, including a highly advanced new model for assay computation. Analysis output is available for a process computer, report typewriter:, and recorders. The package also includes calibration for slurry assays at our pilot installation before delivery. A complete Courier System can analyse up to 4Z slurries and six elements in each slurry. Thanks to its modular design, it can be dimensioned initially to the customer's requirements and is easy to expand later at low cost. Being a mining company itself, Outokumpu has been able to utilize its own long experience in non-ferrous metallurgy - an important factor contributing to the success of the Courier system. History of the project and present installations The first on-stream analyser was installed at Outokumpu'a Pyhasalmi Con¬centrator at the end of 1967, after several years' development. Since then,

Jan 1, 1971

By Sam Lo Grasso, Carlos Herranz Calvo, Stuart Warren, Ted Giesing, Charles Marchesano

Mott MacDonald and Project Management Advisors are providing Technical and Project Management services for San Diego County for the Courthouse Commons Project. The Courthouse Commons Project involves the redevelopment of three downtown blocks owned by San Diego County and construction of an Inmate Transfer Tunnel between the County Central Jail and the San Diego Central Court. The tunnel will be 327 feet long, crosses the San Diego Fault and is being constructed using the Sequential Excavation Method (SEM). This paper discusses the history and procure‑ ment strategy for the project, the technical aspects of the transfer tunnel and the con‑ struction progress of the tunnel to date.

Jun 13, 2021

By Yiming Sun, John Stolz, Jakob Walter, Drew Mason

The Courthouse Commons SEM Tunnel was excavated within 6 feet of cover beneath two buildings in downtown San Diego utilizing high-precision geotechnical instrumentation. The excavated dimensions are approximately 25 feet in diameter and 328 feet in length connecting two in-service detentionlevel security buildings. Presupport includes large-diameter grouted canopy pipes and smaller pipe spiles. Initial support consists of fiber-reinforced shotcrete with lattice girders. This paper presents observed ground and structure behavior and lessons learned. During construction an unanticipated brick structure was encountered, and methods were developed to improve adhesion of shotcrete to sandy soil and to reduce rebound

Dec 1, 2022

By R Kahnt, S Jahn, D Baacke, M Eckart

Relocation into the Lichtenberg open pit mine of about 110 million m3 of sulfide-bearing and ARD-generating waste rock piled up on the surface is the most important and cost-intensive single surface restoration project conducted by WISMUT GmbH at the former Ronneburg uranium mining site. The waste rock comprises for the most part Palaeozoic shales, limestones and diabases with pyrite contents of up to seven per cent. Waste pile relocation began in 1992 and is scheduled to be completed by 2007. The approach used for relocation has been extensively described elsewhere (Jakubick et al, 1997; Hockley et al, 1997; Chapman et al, 1998; Paul, 2003). Following completion of the backfill that will be up to 60 m above the initial ground level, a dry cover will be placed on top of the backfilled mine wastes. The area to be covered amounts to about 220 ha. Design planning for the final cover placement of which is to begin in 2004 had to be based on a comprehensive cost-benefit analysis over and above compliance with legal requirements. The crucial question to be answered in this respect was to determine û in addition to the expenditure required to ensure reuse, radiation protection and soil protection û the extent to which additional time, effort and money were justified in order to minimise contaminant release from the unsaturated portion of the backfilled pit contributing to total releases into the ground water and possibly achieve savings in long-term operating costs for the on-site water treatment plant. Optimisation was based on contaminant balance modelling for the entire site reproducing dominant physical and geochemical processes. Among the specifics underlying the cover design is that contaminant release from the backfilled open pit must not be considered independently of that from the adjacent flooded underground mine and that a major part of the backfilled open pit will also be submerged. Following weighing of cover-related short- and long-term costs it was found that higher construction costs for the various cover options will not be offset by cost savings in the long-term water treatment. As a consequence of pit flooding, even a costly multiple cover including an impermeable layer will only insignificantly impact on concentrations and loads at ground water spill over points. As a result of comprehensive studies and investigations, a combined cover of cohesive soil material from on-site excavation overlain by a 0.4 m thick storage layer to restore natural soil functions for revegetation was derived and submitted for approval. Together with hydraulic measures, this approach is to meet any requirement in terms of radiology, water protection, stability, erosion protection, and reuse.

Jan 1, 2003

By L. Watkins, M. O’Kane, A. Weir, D. Portefield

BHP Iron Ore initiated a program in January, 1995 at their Mt. Whaleback operation in Newman, Western Australia to develop a decommissioning plan for the waste rock material. The primary research program includes the development of technology for the long term performance of the waste rock dumps with respect to vegetation, slope stability, surface runoff, erosion, and water infiltration. This paper evaluates field performance of cover systems constructed on a horizontal and a sloped waste rock surface. The cover system is constructed using suitable run-of-mine waste material to minimize closure costs. The moisture is subsequently released to the atmosphere as evapotranspiration. Rainfall entering the waste material is buffered due to the presence of the cover material thereby significantly reducing net percolation to the underlying waste rock. The objective is to control acid rock drainage by preventing moisture movement into and through the waste rock material. Two years of field data are presented to illustrate low percolation rates to the underlying waste rock and key performance characteristics of the moisture store and release cover system design. Field data collected to date demonstrates that a moisture store and release cover system constructed with suitable run-of-mine waste material has good potential as a final acid rock drainage control cover system at the Mt. Whaleback site. The performance of the cover system on a sloped surface was significantly altered as compared to placing the cover system on a horizontal surface.

Jan 1, 2000

By R Barritt, P Scott

Across the globe, it is a common scenario that tailings storage facilities (TSFs) are being decommissioned; however, their subsequent impact on the local environment and landscape can often be overlooked during the mine planning process. In addition, the requirement of a cover system for a facilities closure may not be a priority until the latter stages of the mine/mill operation when potential cover materials may have been utilised elsewhere or, worse, buried. Developing a conceptual design and closure plan for a TSF early in a mining venture is fundamental to its success once operations have ceased. If a cover system is a planned component for rehabilitation of a TSF, it is vital that its design is appropriate to the facility and any local site constraints, such as climate and cover system material availability. It is also strongly recommended that various cover system options are physically trialled at the site by using performance-monitoring instrumentation. Through this process, an informed decision can be made regarding the most appropriate cover system design to meet any regulatory and stakeholder closure objectives and criteria specific to the site in question; however, in order for the cover system’s performance to be determined through on-site trials, it is essential that an appropriate instrumentation design is utilised. Often, little attention is paid to the data that is being obtained, and its importance may only become apparent after several years of monitoring at an expense to the venture. This should not be the case. Many sites have used an appropriate initial planning stage to understand what is required for the successful closure of a TSF, how it can be achieved and how monitoring data can be utilised to prove, or otherwise, that a cover system design will be a success.CITATION:Barritt, R and Scott, P, 2015. Cover system performance monitoring for tailings – are we doing it correctly?, in Proceedings Tailings and Mine Waste Management for the 21st Century , pp 283–288 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 27, 2015

By O. Porterfield, M. O’Kane, M. Endersby

BHP Iron Ore initiated research programs in January 1995 to develop long-term plans for decommissioning waste rock material at its Mt. Whaleback operation. More than 2 Gt (2.2 billion st) of waste rock were deposited during the past 30 years. Ultimately, a total of 4 Gt (4.4 billion st) will be deposited in waste rock dumps constructed near the open pit. The Mt. Whaleback operation is located in a semiarid climate adjacent to Newman, Western Australia. The primary research program includes the development of technology for the long-term performance of the waste rock dumps with respect to vegetation, slope stability, surface runoff, erosion and water infiltration. This paper focuses on the design and implementation of a cover system to prevent water infiltration to the underlying waste rock. Data obtained from a laboratory program and from soil-atmosphere modeling was used to design horizontal field test plots. The construction of the horizontal surface field test plots is discussed together with the field instruments installed to monitor performance. The cover system is designed to maximize infiltration during wet periods for subsequent evapotranspiration while minimizing surface runoff. The result is a near-zero net infiltration to the underlying waste material. An important feature of the design is the use of run-of-mine waste material as the cover material. Monitoring is in progress and will continue for at least two annual wet/dry cycles. The optimum cover system should minimize the net infiltration of water to the underlying waste rock while maintaining physical and ecological integrity for long-term performance.

Jan 1, 2000

By B. K. Ayres

Modern management of uranium mine or mill waste storage facilities (WSFs) often requires that they be remediated or decommissioned with a cover system. In addition to creating a self-sustaining landscape that supports the end land use, cover systems are intended to reduce long-term risks to human and ecological receptors from the stored waste to acceptable levels. The performance and longevity of a cover system will be strongly influenced by the features or shapes of the WSF final landform. Hence, cover systems and landforms must be thought of as an integrated design. Based on the author’s experience, the most important elements of the design process for maximizing the potential of WSF final landforms / cover systems being sustainable over the long term are noted in this manuscript. Several key items that must be considered and addressed during the planning phase of constructing a WSF final landform are also described. Various methods for monitoring performance of a WSF final landform are also reviewed. Key aspects associated with decommissioning a tailings WSF and waste rock pile at the former Cluff Lake uranium mine in northern Saskatchewan are included to illustrate many of the practical insights provided in this paper.

Jan 1, 2020

By W. W. Beaton

The Coxheath copper mine is situated on the north side of the Coxheath hills and opposite the French Vale, at a distance of about 10 miles southwest of Sydney, Cape Breton county. The deposit was discovered in 1880, and the first work on the property was carried out with local capital. Lacer some Boston men became interested and formed a Company to finance the undertaking. This group operated the mine intermittently for approximately 20 years, spending close to one million dollars on the undertaking. Three shafts were sunk to depths of 110, 190, and 340 feet, and further underground workings to the extent of approximately one-half mile were driven. Also, an extensive surface programme was carried out. in which many test pits and hundreds of feet of trenches were dug, Early in the summer of 1928 the Arno Mines, Limited, optioned the property and immediately started an exploration campaign. A series of trenches were dug along the parallel vein system, and over 4,000 feet of diamond-drilling was done. The results obtained were so encouraging that a mining plant was erected in the fall of chat year and No. 2 shaft was drained. A complete new plant was installed, consisting of one 120 h.p. Fairbanks-Morse Diesel engine, direct connected to a Sullivan angle compound, air compressor; an 80 h .p. Leonard boiler, which supplies power for the 7 by 11 Ingersoll-Rand hoist; and a Sullivan class C steel sharpener and oil furnace. Two 250-gallon Cameron pumps, one operated by steam and the other by air, were placed in the mine so that, in case of a break-down, the mine would not be flooded.

Jan 1, 1930

By Jun Miao, Kang Liu, Jilai Xue, Jun Zhu

CO2 emissions must be reduced by at least 50 % by 2050, and hence the technical solutions to capture and convert CO2 into value–added products should be considered. A Cobalt(III) Schiff base complex (Salen–Co(III)) has been investigated as a catalyst for synthesis of cyclic carbonate from CO2 and epichlorohydrin(ECH) with tetrabutylammonium bromide (TBAB) as co–catalyst. To recover Salen–Co(III) for the next cycling operation, it was immobilized onto zeolite 13X through excessive impregnation method. The immobilized catalyst was characterized using XRD, SEM, BET and ICP–AES techniques. Catalytic tests showed that yield of cyclic carbonate reached 90 % using 0.5 mol % Salen–Co(III) at ambient conditions. The immobilized Salen–Co(III) exhibited better catalytic activity than the homogenous one when used at the first cycle, but the yield decreased by some 20 % after five cycles.

Jan 1, 2015