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By M. J. DeMarco

Beginning in late 1985 and continuing through 1987, Bureau of Mines personnel investigated longwall chain pillar and entry design in two-and three-entry gate-road systems at a deep underground coal mine located in central Utah. To evaluate their respective stability characteristics, four chain pillars and two longwall panels within the two separate entry systems were instrumented with Bureau of Mines hydraulic borehole pressure cells to continuously monitor vertical and horizontal pillar and panel stresses through adjacent panel retreat. In addition, supplemental entry closure information was obtained from sites located in the vicinity of the instrumented pillars. The findings presented in this report demonstrate the practicality of evaluating mine pillar stability using in situ methods and support three significant conclusions regarding ground control aspects of the investigated two-entry system: (1) Total areal entry loading was considerably less for the two-entry system, as opposed to the three-entry system, (2) a smaller percentage of opened ground in the two-entry system contributed to a marked reduction in roof falls, and (3) lower areal loading in the two-entry system suggests improved ground conditions when mining the underlying seam.

Jan 1, 1988

By John M. Dower, Ralph W. Plummer, Terrence J. Stobbe, Hyunwook Kim

"The relationship between exposure to coal mine dust and the development of various respiratory diseases is well recognized. The cause of these diseases however. Is still uncertain. To study this cause-effect relationship, It Is necessary to characterize the coal mine dust In terms of the quantity of dust present and mineral content of the dust. Dust samples were collected using a Portable Continuous Aerosol Monitor (PCAM) and 4-stage cassette Impactors at various locations in an upper Freeport seam coal mine In West Virginia. The samples were analyzed using an X-ray microdiffraction film technique and energy dispersive scanning electron microscopy. This paper presents the results of the first phase of this characterization work which Includes determining the size distribution of the dust and the mineral content of the size intervals.IntroductionDiseases associated with dusts in coal mine environments continue to afflict miners in today's modem mines. These diseases still persist because, as Olishifski points out an employee rarely experiences exposures to a single environmental stress but rather to an Intricate Interplay of multiple stresses.(1) In the case of coal mining the multiple stresses are varying sizes of dust particles originating from coal imbedded minerals. Immediate roof strata bottom strata. Incombustible rock and the coal itself. The site of this Intricate Interplay Is the miner's lungs and the resulting diseases are a function of the composite dust exposures.The proper study of coal mine dust toxicity requires that the dusts used replicate existing coal and mineral dust compositions in their relevant size fractions. The purpose of this project is to develop the size and mineral content data necessary to support this ongoing toxicological effort.Existing coal mining standards and regulations also address total and respirable dust exposures. These dust terms refer to both the quality and quantity of the dust segment in the mine atmosphere. Dust quality addresses its coal and mineral content. whereas dust quantity Is described by mass per unit volume (mg/m3) The comprehensive characterization of coal mine dust exposures will enable revision of these standards and regulations to address the specific minerals and size fractions found to be toxic to human lung tissue."

Mar 1, 1989

By James R. Craig

Petroleum coke is becoming an increasingly important source of light hydrocarbon products as product crudes become heavier and of poorer quality. The use of petroleum coke to generate synthesis gas results in the formation of residual slags that are enriched in silica, alumina, sulfides, oxides, and free metals. The characterization of these slags and their con? stituent phases is an essential step in considering the ultimate use or disposal of such slags and in understanding how to alter the properties of the slags to optimize the efficiency of gasifiers. Depending upon temperatures and bulk compositions, quenched slags typically consist of silicate glasses, calcium silicates, iron-nickel oxide-sulfide masses, aluminate spinels and free metals. Whereas the glasses contain relatively uniformly dispersed metals and sulfur, the iron-nickel oxide-sulfide masses highly concentrate nickel and sulfur. The aluminate spinels very effectively concentrate vanadium and chromium, thus depleting glasses or other adjacent phases. The abundance as well as the make up of the slags strongly affects the physical behavior of the slags within the gasifiers

Jan 1, 1989

By F. Reich, S. L. Chryssoulis, K. G. Stowe

The surface chemistry of particulates from mineral processing streams can be determined by laser-probe microanalysis. The small area of analysis (2-30 micrometres) enables the surfaces of individual grains to be characterised. Conclusions are based on data acquired from a statistically significant number of grains of a given type. Maps showing the distribution of elements on the surface of mineral particulates can be obtained by time-of-flight secondary ion mass spectrometry. The importance of such analyses in understanding the response of minerals to beneficiation practices is discussed with reference to three examples. The first relates to the loss of selectivity in the differential flotation of a base-metal ore, the second to the different flotabilities of coarse- and fine-grained pentlandite from a Cu-Ni ore and the third concerns the preg-robbing effects of organic matter in a carbonaceous gold ore.

Jan 4, 1992

By Bowen Li

Copper vermiculite is a special nanomaterial with excellent antibacterial and antifungal performance. By means of ion exchange, copper vermiculite containing up to 5.8wt% copper was prepared. The chemical and mineralogical characterization of the material was investigated in this study based on the XRD, AAS, TEM and EDS analysis, as well as the calculation of crystalline parameters and crystal chemical formula. Cu2+ and Mg2+ have similar atom radius and same electrovalence. Correspondingly, the structure character of copper vermiculite is very close to that of standard Mg-vermiculite. Most of the CU21 may have occupied the interlayer cationic positions in the form of hydrate in vermiculite. However, some may have entered into octahedral coordinate positions. The values of au and bo of the copper vermiculite crystal cell have no obvious change compared to that of original vermiculite micropowder, but the Co value decreased slightly, which is desirable for the stabilization of the Cu2+ in copper vermiculite.

Jan 1, 2003

By L. K. Bandyopadhyay, P. K. Mishra, S. K. Chaulya, R. S. Singh, A. Kumar, N. Tripathi, K. Mandal

A comprehensive field study has been carried out to measure the background air quality status and identify the air pollution sources from opencast mines around a heritage site in India. Air quality modeling has been carried out to envisage dust concentration due to the existing and closed mines in the region. The predicted total PM10 and PM2.5 levels at the selected receptor locations ranged from 86.39 to 194.89 and from 34.82 to 99.55 µg/m³, respectively.

Jan 12, 2022

By R. Sellaro

It has long been understood that extended occupational exposures to respirable mine dusts can lead to chronic lung disease. In underground coal mines, CWP and silicosis are major concerns. While there have been many studies aimed at understanding total dust concentrations and silica content associated with different mining conditions (e.g., locations/occupations within a mine, cutting methods, geologic strata), little research has been completed to more comprehensively characterize respirable dust (i.e., by particle composition, size distributions, shapes). This preliminary study sought to characterize dust from an underground coal mine in Central Appalachia using scanning electron microscopy with energy dispersive x-ray (SEM-EDX). Respirable dust samples were collected from various locations in the study mine, and individual dust particles were identified and classified by mineral type. A continuous personal dust monitor was also used to estimate total respirable dust concentrations during sampling. Here we report initial results of this work, and discuss advantages and challenges of particle-level characterization of mine dusts in terms of occupational health research.

Feb 23, 2014

By J. Guerrero, O. Pavez, N. Toro, A. Nazer

In the 19th century, mining in northern Chile was of great economic importance. Today, the ruinsof the copper smelters and abundant fragments of refractory bricks from their furnaces remain. Therefractory materials have not been previously studied. the origin, physical and chemical properties, and compressive strength of 10 different samples of historical refractory bricks collected on-site were investigated. The characterization results showed that the bricks are silico-aluminous, unlike the magnesium-chromium bricks used by current foundries. It was determined that 90% of them were produced in the UK and 10% were manufactured in Chile. The phases present are mullite, quartz, cristobalite, and tridymite, and the chemical composition corresponds mainly to SiO2. The compressive strength of the historical bricks is similart to those currently used,. These results may contribute to the knowledge of the 19th century mining and metallurgical historical heritage of Chile and the UK.

Jul 5, 2023

By John W. Graydon

Incineration is an attractive alternative to the disposal of MSW in landfill sites. However, the process of incineration generates fly ash which contains significant levels of leachable heavy metals - particularly cadmium, lead, and zinc - and it is essential to manage this fly ash in an environmentally sound manner. The compositions, phases, textures, morphologies and size of fly ash particles have been studied by light microscopy, scanning electron microscopy, X-ray microanalysis, and X-ray diffraction. The detailed spatial relationships and speciation of the environmentally significant constituents have received particular emphasis. The information obtained is useful in understanding how fly ash is formed during incineration, in understanding the leaching behavior of untreated fly ash if it is disposed of in a landfill and, most importantly, in guiding the development of the best treatment strategies for fly asti to mitigate its environmental impact.

Jan 1, 1992

By S. J. Schatzel, P. W. Jeran, W. P. Diamond, F. E. McCall, F. Garcia, J. C. LaScola, T. P. Mucho

The National Institute for Occupational Safety and Health, Office for Mine Safety and Health Research, is investigating the geologic and mining factors influencing the migration of longwall gob gas. One goal of these studies is to optimize methane drainage strategies to reduce the volume of gob gas that reaches the underground workplace. As part of this research effort, longwall gob gas flow paths in a mine operating in the Pittsburgh Coalbed, PA, were investigated using SF6 tracer gas. Tracer gas released into the ventilation airflow underground generally stayed in the bleeder system and was vented at the associated bleeder fan shafts. Tracer gas injected into an inactive (intaking) gob gas venthole migrated to the two inby producing ventholes on the study panel, indicating that all three ventholes were in communication. The tracer gas that was injected into the gob generally stayed in the gob and only migrated to the ventilation system in response to the venthole on the study panel closest to the injection hole going off production. Tracer gas flow velocities in the longwall gob reservoir and factors influencing the production performance of gob gas ventholes in the study area are also discussed.

By Sumantra Mandal

The hot deformed microstructure of the 15Cr-15Ni-2.2Mo-Ti modified austenitic stainless steel (commonly known as alloy D9) was investigated employing electron backscatter diffraction (EBSD). Hot compression tests were conducted in a Gleeble thermo-mechanical simulator at temperatures of 1173K-1373K (in steps of 100K) with a strain rate of 10 and 100 s-1 to different strains. Various kinds of deformation patterns were observed inside the deformed grains. These were inferred as the development of geometrically necessary boundaries or formation of parallel set of micro-bands. Recrystallized grains were partitioned from the deformed grains employing grain orientation spread approach. Extent of dynamic recrystallization (DRX) was found to be minimal at 1173K. DRX was predominantly found to happen at and above 1273K which increases with increase in strain. DRX nucleation and development mechanisms were discussed with respect to bulging of the parent grains and sub-grain rotation. Special emphasize is given on the role of annealing twins on DRX nucleation and subsequent expansion.

Jan 1, 2009

By D. E. Walsh

Over a period of seven years (1989-1996) the Mineral Industry Research Laboratory (MIRL) University of Alaska Fairbanks, has investigated the effects of temperature, residence time, and particle size on the degree of low-rank coal (LRC) upgrading for a non-evaporative, hydrothermal drying process, also known as hot water drying (HWD). Three Alaskan LRCs were used in this study: Usibelli coal (Seam No.4) from the Nenana Coal Field, Little Tonzona coal from near McGrath, and Beluga coal from the Beluga-Yentna field on the west side of Cook Inlet. Replicated, factorial tests were conducted. Experimental results indicate that most of the low-rank coal upgrading via HWD occurs rapidly within the first 10-20 minutes of residence time. Thereafter, the upgrading process slows down and over 100 minutes of additional residence time are required to produce similar percentage increases in coal properties to those achieved in the first 10-20 minutes. The properties of the hot water dried products were very sensitive to process temperature. Calorific value, carbon and oxygen contents, equilibrium moisture levels and Hardgrove grindabilities all appear to change linearly with temperature within the 275" C to 325" C range.

Jan 1, 1997

By C. Blais, G. L’Espérance

Characterization of second phase particles is important with regard to their influence on mechanical properties of materials. Analytical electron microscopy offers the possibility to achieve complete characterization of inclusions. Complete characterization of inclusions means quantitative evaluation of their chemistry and the stereological parameters. A characterization technique based on integrated microscopy and involving scanning electron microscopy, image analysis and energy dispersive X-ray spectrometry is presented. A discussion of the use of transmission electron microscopy and electron energy loss spectroscopy is also presented for the characterization of very small particles and compounds (>100 nm).

Jan 1, 1998

By N. Krishna

The utilization of Electrochemical Impedance Spectroscopy (EIS) in conjunction with Atomic Force Microscopy (AFM) is a powerful surface characterization technique to study the role of sulfur formation during acidic oxidation of chalcopyrite. It has been established that the chalcopyrite dissolution kinetics is controlled by the formation of passive sulfur layer during leaching. The objective of the study was to characterize the intermediate sulfur layer formation at different oxidation conditions in acidic solution. The chalcopyrite samples were subjected to anodic oxidation and the oxidation process was analyzed using impedance spectroscopy. The sulfur growth on the chalcopyrite surface during oxidation was further analyzed using Atomic Force Microscope for sulfur roughness and grain size, peak height and sulfur growth.

Jan 1, 1999

By Robert L. Parsons

This paper describes the results of a detailed analysis of a loess deposit at the deep foundations test site established by the Kansas Department of Transportation. Multiple CPT, SPT, and pressuremeter tests were conducted as part of the investigation. This paper includes an evaluation of the effectiveness of common correlations used with the CPT, SPT when used for classification of loess and estimating its properties. Results show that common correlations must be used with caution as significant errors in estimation may result from using methods developed for other soil types. Laboratory testing included direct shear, triaxial, collapse, and consolidation testing, with many of the tests conducted on both vertically and horizontally oriented samples to evaluate anisotropic behavior. The results showed that strength properties could be considered to be isotropic.

Jan 1, 2009

By Susanne Pignolet-Brandom

Fourteen samples of crushed Duluth Complex rock were characterized by the QEM?SEM automated scanning electron microscope image analysis system to evaluate the application of the system to mining waste rock characterization. The system can reliably distinguish the iron sulfides, the copper-iron sulfides and the nickel-iron sulfides. Calcite was distinguished from all other minerals except fluorite. The volumetric abundances were verified by comparing elemental abundances calculated using the QEM"SEM volumetric percentages and appropriate mineral compositions with elemental abundances determined by standard laboratory procedure. The pH and sulfate concentrations of rinse water from laboratory leach experiments correlated well with the mineralogical data.

Jan 1, 1989

By C. W. Whitten

Solis from an abandoned Pb battery processing facility were characterized prior to the selection of the extraction technique. Reflected light microscopy and electron beam methods were used to locate Pb-bearing phases and to quantify the compositions of the phases. It was found that the soils are composed primarily of quartz and feldspars with minor amounts of iron and titanium oxides. Lead is primarily present as an oxide or sulfate that is associated with the silicate minerals. Specific phases identified were PbO; Pb02; cerrusite, PbCO3; angleslte, PbSO4; galena, PbS; and magnetoplumbite, 2PbO3Fe2O3; or plumboferrite PbO2Fe2O3?

Jan 1, 1989

By M. Schreiner, J. Brune, D. Theisen, C. S. -J. Tsai

This study reports that routine mining activities could produce a high number of nanometer sized particles which have not been well characterized and may represent an unacknowledged exposure present in the mining environment. A preliminary survey of the particle emission from the feed-leg drilling activity was conducted in the excavations of an experimental mine. The level of particulate exposure was monitored by real time direct reading instruments include a NanoScan scanning mobility particle sizer (measurement range 10-420 nm) and an optical particle sizer (measurement range 0.3-10 μm). Particulate morphological and structural examination was conducted through transmission and scanning electron microscopy and x-ray dispersive analysis of samples collected by a thermophoretic sampler, and a novel nanoparticle sampler. The real time instrument data revealed high concentrations (> 3.5 x 106 particles/cm3) of ultrafine/nanoparticles generated from the drilling activity. Analysis of particle sampler specimens with energy-dispersive x-ray spectroscopy showed a large amount of submicron silica, spherical primary particles and agglomerated soot particles rich in carbon. Exposure to particles in the nanometer size from various sources within the mining environment may be associated with the poorly understood rise in respiratory and systemic disease among miners. INTRODUCTION Exposures to mine dust have been measured and evaluated for decades. Exposures to aerosolized dust such as coal or silica particles can cause lung and other diseases (1-7). One way that The Mine Safety and Health Administration (MSHA) characterizes inhalation exposures within the mining environment is through measuring the respirable dust mass concentration within the breathing zone of workers (8). Respirable particulate matter (RPM) is of great concern due to its ability to deposit in the alveolar region of the lungs (9-10) where it can affect respiratory function. Interventions championed by MSHA have greatly reduced the prevalence of coal workers pneumoconiosis (CWP) and progressive massive fibrosis (PMF). Although great progress has been made, the prevalence of CWP and PMF appears to be trending upwards and the measured increase in prevalence is not elucidated in RPM measurements (11-12). Though the presence and risk associated with ultrafine particles such as emission from diesel engine within the mining environment has been previously established (13-14). There is suspicion within the mining industry that this resurgence of lung disease may be due to very fine particulate matter from various source that is not properly characterized by current sampling methods. Nanometer sized particles, in the range of ultrafine particles, fall within the RPM size range and have been found to deposit in all regions of the respiratory tract (15). Nanoparticles are commonly accepted as particles that are greater than 1 nm in two or three dimensions but smaller than 100 nm (16). Once in the lungs, nanoparticles can enter the blood stream (17) and selectively affect other target organs such as the heart, liver, bone marrow, lymph nodes, spleen, and brain (15,18-19). The size of nanoparticles has been shown to correlate with their translocation behavior on secondary target organs (20-21). There is strong evidence that the clearance mechanisms used to rid the lungs of particulate matter are not as effective on nanometer sized particles, leading to a greater fraction of never-cleared particles which may enhance disease development (20). Research has demonstrated that nanometer sized particles have unique properties (22) whose adverse health impact is greater than what has been found with micrometer sized particles of the same type (23-26). The large ratio of surface area to mass compared to larger particles is believed to make nanoparticles a greater hazard. Utilizing mass to measure these types of exposure will be very difficult to accurately characterize the quantity of

Jan 1, 2019

By M. Choy, A. Kadiayi, E. Magdzinski

"Design of engineering controls to limit occupational noise exposure rely on accurate calculation inputs. Sound in mines can carry considerable distances. Mine ventilation engineers rely on noise propagation calculations to estimate silencer performance criteria for key mine fan installations that are often in proximity to occupied areas of a mine and can remain in service for decades. The blasted and rockbolted walls of hard rock mining tunnels have unique acoustical properties. Underground testing in an operating metal mine in Sudbury, Canada was performed and results processed to characterize noise propagation in mines, with the goal of improving the accuracy of noise calculations.INTRODUCTIONAs mine operators continue to improve and promote workplace safety, addressing noise at fixed infrastructure locations is observed as increasingly common. Underground fans are important to consider in this context, as they are typically loud, in proximity to occupied and sensitive workplaces, and operate nearly continuously. Predicting noise propagation from ventilation fans within underground mines has long been a challenge, with few available resources documenting acoustical properties as calculation inputs. Other factors in addition to rock face absorption properties include tunnel geometry and distance from the fan, which play critical roles in characterizing the noise level at any given point away from the fan. By understanding and establishing methods to better predict noise dissipation along underground mining tunnels, engineers can design noise controls with a greater degree of precision and confidence to effectively protect workers from over exposure to noise.This paper investigates classical methods of predicting reverberant room and direct field noise propagation. These prediction methods are then compared to noise measurements taken within the Fraser Mine of Glencore’s Sudbury Integrated Nickel Operations (Sudbury INO) Measurements were taken at a depth of ~881 m (2,889 ft), along an ~300 m (984 ft) long blasted hard rock mining tunnel. The noise along the mine tunnel resulted from the intakes of two 900 kW (1,200 hp) ventilation fans with a combined exhaust capacity of 300 m3/s (630,000 cfm)."

Jan 1, 2019

By Fejes A. J

The U.S. Bureau of Mines installed surface and subsurface instruments at a mine site in Colorado to monitor and characterize the overburden response to longwall mining. Instrumentation included a time-domain reflectometry (TDR) cable, a multiple-point borehole extensometer (MPBX), vertical- deformation surface monuments, and in-mine pressure cells for monitoring abutment, pillar, and gob loads with respect to the longwall face position. The purpose of the study was to collect data that could be analyzed to correlate the design of the mine layout to the resulting overburden failure response. Determining the extent of caving and fracturing is important in the and and semiarid Western United States because of the possible consequences to the fragile underground hydrologic systems upon which the land owners and users depend. This study is unique from past investigations because the overburden contains massive sandstone members that impose special conditions on the caving process and pressure redistribution above the longwall panels. This paper presents the results of this correlation study.

Jan 1, 1992