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By Pesic. Batric

A novel chitosan-pyridoxal-epichlorohydrin was synthesized and evaluated in our laboratories. The evaluation was achieved by performing kinetic and equilibrium studies of copper sorption. The parameters examined were pH, temperature, concentration of copper, particle size and selectivity of copper sorption against iron, zinc, cadmium and cobalt. It was found that pH was the most important parameter, and sorption of copper increased with pH increase in the range pH 2.5-6.0. The low activation energy of the sorption reaction, 1 1.13 kJ/mole (2.66 Kcal/mole), showed that temperature was not an important parameter. The synthesized chitosan was selective against iron, zinc, cadmium and cobalt. The selectivity with respect to last three metals was achieved by the kinetic difference of sorption, as sorption of copper was much faster than for other metals. Iron (Fe2+) does not adsorb on chitosan. The mechanism governing the sorption of copper is intraparticle diffusion. This finding was supported by the dependance of copper sorption on the square root of time, the low activation energy, and the fit of experimental data in the diffusion through the product layer equation.

Jan 1, 1994

By C. H. Bucknam

Net carbonate value (NCV) characterization methods for acid generation potential measurement originated from studies on the Carlin Trend during the 1990's and have been subsequently standardized through cooperation of the Acid Drainage Technology Initiative Metal Mining Sector and the American Society of Testing and Materials International. The paper describes the evolution and standardization of the NCV methods, the importance of mineralogy in interpreting the results and application of the methods to implementation of the Global Acid Rock Drainage (GARD) Guide.

Jan 1, 2011

By Yonghun Jong, Chungin Lee

The main purpose of this study was to apply the artificial neural network (ANN) models to determine optimal powder factors and predict peak particle velocities, based on a series of observations and input parameters. The used blasthole pattern was V-cut. The locations of blastholes and ignition patterns remained almost constant. The input parameters were 14 geological conditions (i.e., dip, dip direction, spacing, separation, and persistence of 2 discontinuity sets, tunnel orientation, rock strength, RQD, and RMR) and 4 blasting conditions (i.e., distance between blasting points and measuring points, charge weight per delay, drilling length, and blasting efficiency). Data for the ANN application in this study were recently collected in a highway tunnel under construction in Korea. The main rock type in the site was biotitic granite. An optimum ANN model was determined by training models with collected data. The trained model was used to evaluate the prediction capability of the optimum model. It was shown that the ANN model could predict the powder factor and the peak particle velocity depended upon the selected input parameters. Particularly, the ANN model predicted more accurate peak particle velocities than those obtained by the blasting vibration equation. Moreover, the more dominant factors among the input parameters could be determined by analysis of the relative strength effect.

Jan 1, 2002

By J. Weinstein

New erosion, corrosion resistant metal, ceramic, and polymer composite technologies are being developed and marketed by Alanx Products L.P. for use in hydrocyclones, pumps, valves, and other applications in mining and minerals processing. This paper will present an overview of the ceramic/metal composite material system and properties developed, which include excellent erosion/ corrosion resistance. Wear data will be shown from a variety of laboratory tests in dry and wet conditions, in aqueous neutral and corrosive environments. Comparisons will be made with a variety of competitive materials currently used in the industries sited. Data will also be presented on field tests with pumps and hydrocyclones in hard rock mining and other abrasive/corrosive environments. Field data from North and South America, as well as Australian mining applications will be highlighted.

Jan 1, 1992

By J. Pizarro

Any organization that subjects its activities to a continuous improvement methodology, aiming to optimize their processes and services, must be able to adequately measure the results of the implemented changes to pursue better outcomes. This is no different for mining companies. When it comes to blasting, an accurate fragmentation analysis can correlate blast design and rock mass parameters to particle size distribution, enabling us to further analyze the correspondence of specific design patterns, applied to specific rock mass properties and the result in measured fragmentation indicators. Over time, many tools were developed for us to obtain PSD data, albeit each of them had their own shortcomings. The first ones to be developed involved photographing the muck pile including a scale object, uploading those photos to a PC, and using specialized software to analyze each one. As a result, analysts would get a PSD curve that served as reference for the performance of the blast. This method, which is still used, has major shortcomings. The most obvious one is that it is only able to capture a slice of the blast, which corresponds to the exposed section of the muck pile the analyst has access to, and even there its reach is limited to the areas that are safe for getting close enough for placing the scale, which are not many. Consequently, this is a very limited way to get a fragmentation performance assess for a blast. Currently, autonomous systems are capable of taking continuous pictures of the muck pile. Installed on a shovel, conveyor belt or crusher feed, these systems can take a continuous stream of pictures that are later analyzed automatically without the need of human intervention. These systems greatly increase the volume of data and, consequently, we have a PSD curve that is more representative of the blast performance. However, this technology still had issues when trying to sample front end loaders mining operations or getting results from underground blasting due to the inherent difficulties of these operations. New algorithms used for capturing and processing data for front end loaders can overcome the harsh environment of their operations and produce PSD data in high vibration environments and difficult mining angles. For underground mining, algorithms can be used to sample each truck exiting the mine, giving a reliable source of fragmentation analysis that can be traced back to their stope of origin. The development of this technology extends the existing system’s capabilities and helps us in our efforts to improve fragmentation results with each blast.

Jan 1, 2024

Technically speaking, the concept of NDT sounds like the "magic bullet" when faced with a questionable drilled shaft. All the Contractor or Engineer needs to do is select an NDT method, apply it, understand the details and extent of the defect and determine whether it will impact the load carrying capacity of the shaft during it’s design life. Unfortunately, it is not that simple. NDT is a tool utilized to indirectly assess the condition of the completed drilled shaft. For the most effective interpretation, NDT data should be correlated with the subsurface information, visual observation, and detailed shaft installation records. The basis for acceptance or rejection of drilled shafts should not be solely based on NDT. The parties responsible for specifying, interpreting and using the NDT results must understand the capabilities and limitations of the method to be utilized, in conjunction with the relevant subsurface conditions of the site, before selecting and specifying a system and acting on the results. This is necessary so that an appropriate NDT method can be specified and contracted. In this manner the results and roles of the responsible parties can be clearly defined.

Jan 1, 2004

By A R. McKinnon

The recently opened Hera Au-Pb-Zn-Ag mine in central New South Wales has provided an ideal opportunity to demonstrate the calculation of sulfide ore mineralogy using normative methods. Normative mineralogy applies a set of sequential rules based on the species likely to be present to assign the chemical components of a sample to their respective mineral components. The dominant sulfide mineral assemblage present at Hera is galena, iron-bearing sphalerite, chalcopyrite, pyrrhotite and pyrite. A normative technique for estimating the relative abundance of each of these species from drill hole, grade control and metallurgical assay data sets has been developed. This includes a process for deriving a gangue iron value and differentiating pyrrhotite from pyrite using sulfur/iron ratios. A calculated total sulfide volume value has been utilised at the mine to improve interpretation of lode boundaries. Normative drill hole values have also been used for domaining within the orebody, with large scale mineralogical trends evident. Dry bulk density (BD) values calculated using a normative species-weighted method show good correlation with measured BD values (R2 = 0.895) and are a significant improvement on the Pb+Zn+Cu regression method (R2 = 0.646) previously used. Application of these calculations to identify errors in assay databases is demonstrated, with specific reference to the data set for the nearby Nymagee copper deposit. Validation of block model grades is also explored and a method to improve resource estimates using direct normative mineral interpolation is proposed. The integration of the normative data into the production and metallurgical data sets at Hera is described and the relationship of the normative minerals to other economic elements such as gold and silver is discussed.CITATION:McKinnon, A R, 2017. Application of normative ore mineralogy to geological and metallurgical data sets at the Hera Au-Pb-Zn-Ag mine, New South Wales, Australia, in Proceedings Tenth International Mining Geology Conference 2017, pp 63–74 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 20, 2017

By A. Bastrzyk

Text The mining and refining of minerals generates large amounts of solid waste. The waste from cleaning operations constitutes up to 90% of the total production. Although some of them can be used in mining, civil enegineering, construction, agriculture, most of them must be disposed in dumps and slurry ponds, causing major economic and enviromental problems (Alonso, 2002; Alon-so, 1999). The refuse from minerals cleaning may have considerable valuable particles content, which can be used in industry. Thus, the recovery of these particles from minerals waste by using a cleaning method effective at fine particle size, may overcome these consequences. Surfactants are used in numerous applications including emulsification and solid surface modification. In the oil agglomeration of minerals, the ionic surfactants (both anionic and cationic) are used for the hydrophobization of mineral surface and the oil-water emulsion preparation. When the cationic surfactant is injected into the oil-water mixture, surfactant molecules adsorb at the oil-water interface, changing droplets? properties. The addition of anionic surfactant to the mineral suspension was found to modify the solid-liquid interface. In this paper, the condition and mechanism of selective separation of magnesite from quartz are presented. A satisfactory was achieved with the amount of anionic collector (sodium oleate) equal to 15.2 mg/gsolid and with the amount of cationic collector 27.9 mg/gsolid for cetyltrimethylammonium bromide (CTAB) and 16.9 mg/gsolid for dodecyloammonium hydrochloride (DDAHCl) at pH 8. At these conditions, the amount of agglomerated carbonates was about 12% for CTAB and 5% for DDAHCl.

Jan 1, 2014

By Jacob Masliyah, Zhiang Zhou, Dharamdat Christendat, Tshitende Kasongo, Kevin Hyland, Zhenghe Xu, Ted Kizior, Douglas Cox

"A novel on-line visualization system, previously developed at Syncrude Canada Ltd., has been modified to characterize rising bubbles, particles and particle-bubble aggregates in a flotation process. With this system, the bubble size and rise velocity in a laboratory flotation cell can be determined. The technique allows the loading of solids on bubbles to be visualized, thereby providing an in-depth understanding of sub-processes of flotation. A step-by-step data processing procedure is presented. The applicability of the developed system to mineral flotation and bitumen extraction is discussed. Under batch flotation conditions in a laboratory Denver cell, three main bubble-particle attachment patterns are observed. They are: i) single particles attached to single bubbles, ii) particle aggregates loaded on single bubbles; and iii) a group of particles aggregated with a group of bubbles. The results demonstrate that the on-line visualization system is a powerful tool for understanding and diagnosing flotation processes.INTRODUCTIONAir (Gas) bubbles are an indispensable component in a flotation system. Both industrial practice and theoretical analysis indicate (Yoon, 1993; Diaz-penafiel and Dobby, 1994) that the size and population of bubbles are two important process parameters in modeling flotation. More recent investigations (Finch, et al., 1999; Gorain, et al., 1997) suggest that for a given flotation system, bubble surface area flux, defined as the air liquid interfacial area per unit time and unit cross-sectional area of flotation cell, showed a better correlation with the flotation rate constant. As a result, the bubble surface area flux is now being considered as a key parameter to account for the combined effect of bubble size and population in evaluating the performance of flotation machines and modeling flotation processes. However, the success of using bubble surface area flux in flotation process modeling largely depends on how accurate it can be determined or estimated (Finch, et al., 1999)."

Jan 1, 2000

By L. Munsamy, B. J. Madden

OpenRisk, an open cast risk rating system, takes into account relative differences in the importance of hazards, as experienced on each mine as a result of different combinations of geotechnical factors and mining conditions. The system is based on critical geotechnical and operational parameters that have been identified by mining personnel and rock engineers. The primary advantage of this risk rating system is that all the strip mines would use an identical system, which enables the user to compare their risk to the risk at neighbouring mines and/or other open cast mines. The system can be adjusted to meet local, mine specific requirements. This system has been made practical and easy to use. Therefore, this tool can be used by personnel from other disciplines not directly related to rock engineering. OpenRisk system has been in operation at nine Anglo Coal and other open cast mines. It adequately detects areas of high risk and generates adequate remedial solutions to reduce the risks. Awareness of the personnel has been higher at the sites that use OpenRisk. The proactive approach of OpenRisk ensures that all personnel are aware of risks in the pits and how to deal with potential risky areas.

Jan 1, 2006

By T. M. Yegulalp

A numerical model is being developed to assess the enhancement of permeability by improved fracture connectivity by micro-hydrofracturing. A generic two-dimensional percolation model has been developed to test the impact of various field conditions on permeability. Field data from Cyprus Minerals' Mineral Park Mine has been used to establish statistical properties of the observed fracture systems. Results of statistical anlyses of the field data and examples of the use of percolation model are presented.

Jan 1, 1995

By Murdaugh W

The application of photogeological techniques and analysis of more advanced remote sensor images can be a cost and time effective tool in the search for desert placer gold deposits. Examples are given of regional analysis using standard false color composit Landsat images and conventional black and white aerial photography. The examples include identification of sites to sample to evaluate the pathways of .alluvial gold migration and identification of potential sites of concentration. The results of these studies developed an increased number of target areas and exploration in proceeding with promising results. In addition to the development of additional target concepts and identification of specific target areas data useful to evaluation of mineability can also be obtained from photogeological investigation. Some indication at least can be obtained of the existence of duricrusts and salines that may hamper mining. Identification of possible sources of water is another important task in the desert environment. In addition indications of the clay content of the material to be worked is very important because of its economic impact on operational costs and overall recovery. The application of photogeology to these questions is discussed.

Jan 1, 1988

By M. Misra

It is estimated that the volume of low -level and intermediate level contaminants present in the soil at different DOE sites is of the order of several million cubic feet. The existing remediation scheme is containerization followed by burial in Land Disposal Facilities (LDF's) which is economically unattractive warranting the need to develop alternate remediation routes. One such route is the physical separation based volume reduction approach to removing a MINIMUM AMOUNT OF CLEAN SOIL with the radioactive particles, reducing the amount of material that requires disposal. The purpose of this study was to evaluate and test the feasibility of using physical beneficiation techniques for removal of contaminants from soil. The performance criterion was to recover at least 80% of the activity in 20% or less of the original contaminated soil volume. Four different radioactively contaminated (primarily uranium and plutonium) soils from DoE sites namely LANL, INEL, Fernald Plant 1 Storage Pad (ID-B) and Mound soils were tested using gravity, magnetic, gravo-magnetic, hydrocyclonic and flotation devices. The paper is divided into the two sections. The first section presents the overview of the Heavy Metals in Contaminated Soil Treatability Project conducted at the University of Nevada, Reno (UNR) describing the salient features of a state-of-the art Soil Washing Laboratory and the technology equipments used in the test program. The second section describes the soil characterization and typical volume reduction results obtained from the UNR tests. Among the physical separation processes, only flotation processes passed the performance criterion. For the LANL and INEL soils where the contamination was contained in coarse particle size, it was possible to recover more than 80% of the activity in less than 10-20% of the original volume of the soil thus rendering 80-90% of the soil "clean". For Fernald and Mound soils where contamination was of colloidal nature, flotation based processes showed encouraging results and are recommended for further studies.

Jan 1, 1995

By M. J. Beus, B. Stewart, S. Iverson

Synopsis U.S. Mine Safety and Health Administration (MSHA) accidents statistics have identified ore-pass hazards as a significant safety problem in U.S. underground metal mines. The statistics show that nearly 75% of injuries are directly or indirectly related to pulling or freeing of ore-pass chutes, the use of hand tools in ore passes, fails of broken rock in ore passes and structural failures of chutes or gates and ore-pass walls. Researchers at the Spokane Research Laboratory of the National Institute for Occupational Safety and Health (NIOSH) are investigating hazards in and around ore passes in hard rock mines. Risk assessment methods, such as fault-tree analysis, have been employed to identify the most probable causes of orepass failures, define research priorities and analyse the factors that result in malfunctioning and unsafe ore passes. Static and dynamic loads are being measured in a laboratory setting with the use of a reduced-scale orepass mock-up. Field tests are being initiated in mine ore passes to determine static and dynamic loads. Data from the test ore passes are being compared with data from the mine to characterize true system behaviour. Computer modelling with the use of closed-form solutions, finite-element analyses and a newly developed particle flow code predicts static and dynamic leads from the flow and the impact of ore and waste in the ore pass. Preliminary results indicate that dynamic impacts from ore and waste rock might be considerably greater than expected. The total static load is substantially less than is typically used fur the structural design of chute and gate support members. It is suggested that damping factors, normal and shear stiffness and mass frictional characteristics have a significant effect on particle flow and resulting impact loads. This is being verified with the use of results from laboratory tests, field tests and particle flow analyses. Ore passes are vertical or steeply inclined openings in a rock mass through which ore and waste are transported and where they mar also be stored. A typical underground mining system is shown in Fig. 1. The arrows indicate the locations of ore passes and loading pockets and their relative configurations. The control of material flow is potentially one of the most hazardous operations in underground mining. According to MSHA data. most of the ore pass-related accidents in the U.S.A. are associated with the loading-unloading cycle and removal of blockages from ore passes. In particular, attempts to free ore hang-ups have resulted in multiple fatalities. The hazards are obvious; there is uncertainty as to when the ore will break loose and miners are unable to escape falling rock to a safe location. Although ore passes and chutes and gate systems for underground metal and non-metal mines roust meet the requirements specified in the U.S. Code of Federal Regulations (CFR). Parts 57 and 75, recent structural failures of ore-pass linings and gates have underlined the lack of adequate ore-pass design standards available to both MSHA enforcement staff and mine engineers. Because of the importance of an ore pass to the safe operation of a mine design criteria need to be assessed and new guidelines developed. Researchers at the Spokane Research Laboratory of the Nationals Institute for Occupational Safety and Health (NIOSH) are investigating hazards in and around ore passes in hard rock mines and studying design criteria for ore passes. The near-term goal is to conduct laboratory and field experiments and computer modelling to evaluate the ore-pass design criteria currently used. Literature searches, field site

By Nick M. Withers, Suthagarann Visvalingam, Cillian Mc Colgan

The level crossings removal project in Victoria is removing 75 level crossings across Melbourne to improve safety by separating trains from traffic, with other benefits such as reduced congestion, an upgraded road network, connected communities and support of urban regeneration. The level crossing at Station Street in Carrum forms part of the scope being delivered by the Southern Program Alliance (SPA), which is delivering level crossing removal works associated with the Frankston Train Line. At Station Street, a rail viaduct consisting of 19 spans and totalling approximately 545 m in length is under construction to remove the former level crossing. The viaduct consists of two parallel reinforced concrete Utrough girders and steel trough girders, one for each rail line. The foundations of the rail viaduct are founded on groups of Continuous Flight Auger (CFA) piles. The characterisation of geological units encountered at Carrum for the foundation design has been based on insitu testing and interpretation of test results from high strain dynamic pile testing (PDA) and Case Pile Wave Analysis Program (CAPWAP) from the Seaford Road Bridge, located approximately three kilometres South of Carrum, in similar ground conditions. By conducting pile load-deformation analyses based on pile testing significant savings were made for the client compared to the original design which was based on more traditional empirical correlations. This paper discusses the pile design methodology adopted using pile test data for this viaduct foundation. The results of this assessment are also compared to existing empirical correlations, and the limitations are discussed. The performance of the adopted pile design methodology using pile test data at Carrum rail viaduct is also discussed.

Nov 1, 2022

By P. R. Taylor

A review of the advantages and disadvantages of plasma technology for metal and mineral wastes is presented. Examples of the use of plasma systems are given and possible future uses are outlined. Among the potential uses are treatment of electric arc furnace (EAF) dusts, the vitrification of nuclear wastes and the removal of toxic metals. Over the past few decades, plasma technology has been studied for potential applications over a wide range of metals/materials processing areas. One promising area of plasma technology applications is the treatment of industrial hazardous waste. The potential generation of hazardous and toxic waste by various industries has become a matter of public and political awareness. Environmental regulations have put stringent toxicity emission limits on disposable waste streams. An intensive research effort is currently underway in the area of hazardous waste treatment.

Jan 1, 1994

By I. Abdullayev, M. Soberano Capistran, J. Garcia

The application of post-tensioning in segmental structures was introduced in the early 1900s and has been successfully applied in different types of structures including immersed tunnels, bridges, buildings, metro stations, and stadiums. There are, however, only five known circular concrete tunnel projects where the post-tensioning approach has been adopted. This paper discusses the application of post-tensioning to mitigate the high internal operating pressures in an effluent outfall tunnel project 7 miles, 11.3 km long, currently under construction for the Los Angeles County Sanitation Districts, LACSD. This project will be the first use of post- tensioned segmental concrete tunnel linings in North America.

Jun 23, 2024

By M. Schultz

The cost of remediation often drives the selection of the preferred remedial alternative at hazardous waste sites. The use of probabilistic cost/risk analyses can aid in predicting costs of remedial alternatives. Three types of information are discussed in performing cost/risk analyses: (1) data on the quantity of contamination versus the contaminant concentration; (2) unit costs of remediation for the remedial alternatives; and (3) risk to contaminant concentration relationships. Cost/risk evaluations are performed on a site-by-site basis, to account for combined risks of different contaminants and differences in quantity to be remediated versus contaminant concentration. The cost/risk analysis produces a graph of risk versus cost for each of the remedial alternatives. These costs are then compared to facilitate selection of a preferred alternative. An example of comparison of alternatives is illustrated for a historic coal gasification site.

Jan 1, 1992

Probabilistic seismic hazard analyses (PSHA) have now gained wide acceptance in the development of design criteria for major projects. When used with regional criteria the procedures have also allowed the preparation of more rational seismic zoning maps. Seismic zoning maps using various levels of results from PSHA studies around the Pacific Rim now include Canada, Indonesia, New Zealand and the United States. Some Pacific Rim countries such as Chile where the seismic exposure is dominated by subduction events have no subdivision into separate zones.Approaches to risk based zoning are being considered in several Pacific Rim countries including Australia. Australian studies must face problems similar to parts of the Eastern United States where seismic activity is low with irregular and infrequent occurrences of moderately large earthquakes. The perception of the seismic exposure by both regulatory agencies and the public at large is different when considering areas of low seismicity. There is therefore a need to make different interpretations of the results of PSHA studies in these areas of low seismicity. The aim of this paper is to explore some of these differences by comparing the results from two site specific studies from areas with widely differing seismic activity rates.

Jan 1, 1990

By Habib Zughbi, Paul Zulli

"A key step towards sustainability in iron and steelmaking is to optimise the use of raw materials and energy consumption, and consequently minimise CO2 emissions. Models based on a Process Integration (PI) approach play a key role in evaluating various scenarios and the impact of introducing changes in raw materials and operational conditions on the overall energy consumption and CO2 emissions. BlueScope uses a PI based comprehensive model for its Port Kembla Steelworks (PKSW), called the Integrated Steelworks Energy and Emissions Model (ISEEM). ISEEM is tightly coupled to the configuration of PKSW. It is based on mass and energy balances as well as thermodynamic relationships. ISEEM is a steady-state model and is used to predict overall and detailed unit-by-unit energy consumptions and CO2 emissions. It is also used for plant-based scenario modelling. This paper investigates the impact of major changes to PKSW configuration, including the shutting down of a blast furnace and cokemaking battery, on the energy consumption and CO2 emissions of the plant. It discusses some of the issues involved in updating the model and some identified opportunities."

Jan 1, 2015