Search Documents

By Dominic Howarth, Diana Drinkwater, Don McKee

"The pressures on mining and minerals education at the tertiary level are well known. Within Australia, for example, the number of undergraduate mining engineering courses with 30 or more students in each year has reduced to three (University of Queensland, University of New South Wales and Curtin University). Similar declines in both student numbers and participating institutions are evident in many other parts of the world, and notably in USA and most countries in Europe.An in depth study of the Australian sector was conducted in 1997/1998, resulting in the Back from the Brink report (Carter 1998). The Australian situation was summarised as follows.Australia’s minerals education system, in its current form, is fragile and is in no position to seize the opportunity (i.e. world leadership in minerals education) and is more likely to succumb to the threat.Current trends include:- an acute shortage of talented academic staff, as a result of University remuneration packages having become hopelessly uncompetitive with those in the minerals industry;- small student populations and high relative costs, making mineral specific courses vulnerable to closures, when Universities are under extreme cost pressures; this situation will be exacerbated if enrolments drop in response to, say, a cyclical down turn in the industry; and- under-resourcing of minerals departments because of their comparatively small size, making these departments incapable of delivering top class teaching in all aspects of their courses, despite being excellent in some areas.Most of the Australian issues identified above have direct parallels in other countries.The most common response of institutions to the threats is to seek strength, and in some cases survival, through various forms of linkages and networks. A number of these associations, which are frequently defensive in nature, are outlined in the paper."

Jan 1, 2003

By E. V. Manlapig, M. C. Harris

"The complexity of the flotation process has made the identification of an appropriate model structure, for use in the prediction of flotation circuit performance, far from obvious. Work performed under the auspices of the AMIRA P9 flotation program has indicated that the metallurgical performance achieved from a flotation cell arises from the interaction of two essentially independent property classes, namely the cell operating conditions and the properties of the cell feed stream. These observations have led to the development of a model structure that associates a constant set of flotation parameters to the streams of the circuit, which are transformed into a flotation response depending on the operating conditions within the flotation cell.A variety of alternative model structures exist within the literature which do not make this distinction between cell and stream flotation properties, and many of these models are in widespread use for flotation optimisation and design studies, both in industry and academia.In this paper, data collected from an industrial flotation circuit is used to derive the parameters associated with two different types of flotation models. Simulations performed using these models demonstrate the need to differentiate between cell and feed properties. A model that does not differentiate between these two properties fails to successfully predict the metallurgical performance of a flotation circuit after a disturbance."

Jan 1, 2003

By Olli Haavisto, Heikki Häkkänen, Tommi Kauppinen, Navid Khajehzadeh

Raman analysis is a well-established method for finding the abundant minerals in an ore sample. In this study, Raman spectroscopy is tested as a method for rapid and contactless on-line mineral analysis. Rapidness might enable on-site analysis of rock drillcore, which in turn would lead to more cost-efficient solutions in mineral exploration. This paper discusses the use of Raman analysis to identify minerals and to measure their concentration. The sample set under study consists of rock drillcore collected from Agnico-Eagle Kittilä Mine, Finland. Selected parts of the sample set are measured by Raman spectroscopy and the minerals are identified using reference spectra from a public source. Moreover, the direct measurement of concentration of different minerals with the help of Non-negative least squares (NNLS) optimisation algorithm is considered. The optimisation algorithm was constructed to form a linear combination of reference spectra which best represent the measured spectrum, or an average of measured spectra, from an ore sample. The results show that NNLS can identify abundant minerals in a given sample. Also through this method of analysis the results of a traditional point-count method can be expanded: It was observed that, due to grain size, multiple minerals consistently appear in the spectra measured over an area, which means that point-count method is not a proper way to interpret the spectra. This can be seen as a new result, as formerly the discussion has attended to other methods.

Jan 1, 2014

By A. Shibayama

Soil contamination by organic compounds is one of the most concerned issues on polluted soil. It is well known that there are limited methods to remediate the contaminated soil on site. Especially, the in-situ method for contaminated soil is too difficult to de-contaminate the organic pollutant. In this study, the fundamental ability of soil remediation, which aimed to decrease oil concentration in, in-situ process, have been researched by using a high pressure gas generated from ?crush composition? on artificially oil contaminated soil. The n-hexadecane (n-C16H34) and other organic compounds were selected as soil oil contaminators, gravimetric analysis by soxhlet extraction and GC-MS were used as qualitative and quantitative analysing methods. For the experimental examination, the influences on the difference in the concentration of n-hexadecane (and other organics), the tamping amount, position and repetition of crush composition in soil, and scale (size) of experimental model were investigated. The n-hexadecane concentration reduced by the explosive effect of crush composition showed a reasonable decrease of about 30 wt%~60 wt% compared to the initial n-hexadecane. The removed amount of n-hexadecane and distance from explosion point of the crush composition was related in scale and model of contaminated soil.

Jan 1, 2014

This study examines the surface alteration and flotation behaviour of synthetic moncheite, PtPd(BiTe)2, in the presence of pentlandite. The telluride minerals contribute around 20% ~ 30% and up to 45% of the PGM present in the Platreef ore and are considered to be slow floating as there is evidence of these minerals reporting to the tailings. It was proposed that oxidation products from other minerals and grinding media would affect the mineral surface composition and floatability thereby causing inadvertent depression of moncheite due to precipitating ions. ToF-SIMS analyses (time of flight secondary ion mass spectrometry) was used to characterise the mineral surface as well as the extent of surface alteration. Microflotation was used to deter-mine the hydrophobicity of the synthetic minerals. Conditioning of moncheite in the presence of pentlandite reduced the flotation response of the + 38 -106µm size fraction from > 99% to 56%. This was due to pentlandite dissolution products (iron and nickel hydroxy species) which formed overlayers on the mineral surfaces thereby inhibiting the adsorption of collector. In addition, further grinding of these samples, with and without pentlandite conditioning showed a negative effect on recovery due to the fineness of the particle size distribution and there was no advantage gained from any possible exposure of fresh sites in the sample.

Jan 1, 2014

By N. D. Dementieva

Based on lab and pilot-plant tests to recover gold, silver and lead of a Russian deposit, a collective and flotation concentration flow sheet with lead and sulfide concentrates was proposed. The type of the deposit is gold-sulfide-quartz-bearing. The recovery of gold, silver, and lead to a lead concentrate was 47.4%, 68.1% and 70.7%, respectively. The grade of gold and silver grade was 170 g/t and 372 g/t, respectively. The mass percent of lead, zinc and arsenic mass percent was 41.7%, 0.34% and 0.63%, respectively. The recovery of gold and silver recovery to a sulfide concentrate was 50.1% and 28.8% at the grade of gold 20.5 g/t and silver 66.2 g/t. Sulfide concentrate with arsenic mass percent ~3% was biooxidised followed by CIL and obtaining metal at the site as well as zinc concentrate from bioleaching solutions with zinc mass percent 45% at its 64% recovery. The total gold and silver recovery using a developed technology with the account of their treatment at a polymetallic plant was 92.2% and 93.7%, respectively.

Sep 1, 2012

By H. Araneda

Throughout Chile?s history, mining has consistently been a leading industry in the country. The 1990s marked the beginning of a boom in Chile?s mining industry, especially in copper mining, due to both foreign and local direct investment in the sector. Mining?s contribution to the GDP was 15.6% at current prices in 2009, and it accounts for 56% of the country?s exports. Chile?s copper market share reached 35% in 2009. The investment portfolio in mining in Chile for the coming decade has been estimated at 90 billion US dollars. The acute scarcity of human resources currently experienced by the mining sector in Chile will be accentuated in the coming decade as a result of this scenario of investments. The situation is, additionally, similar to the one confronted by other countries involved in the mining industry such as Australia, South Africa, Canada, and in Latin America includes, Peru, Colombia and Brazil. A study carried out by Fundacion Chile, ¨Labor Force in the Chile Mining Industry, Diagnostic and Recommendations, 2011-2020? shows the projected labor shortage for the operation of projects in the development stage, considering only the requirements of the process of extraction, processing, and maintenance. The demand, accumulated incrementally, will be around 115,000 technically skilled workers, professionals, and qualified workers. This figure refers to the operational work force, and does not include the human resources that will be required for the prior stage of the engineering and construction of the projects (brownfield and greenfield). The demand for technically skilled workers and professions for the stages of engineering and construction of the projects that have already received investments is estimated to be 190,000 people for the period 2012-2020. The peak of the demand for engineering is 2012, with a figure that surpasses the 12,000 professionals for all of the engineering specialties. The analysis of the formation of human resources at the tertiary level (where tertiary includes technical/vocational and academic degrees at the undergraduate level) for mining and related majors demonstrates that the programs are scarce with a bias toward theoretical contents and that they are excessively long (40% longer than comparable programs in Australia, Canada, and in OECD countries). The completion rates are low, especially in the technical-vocational programs, which have a completion rate of only around 30%. Finally, the rates of attraction of technically skilled labor and professionals towards careers in mining are insufficient to reduce the identified skill gaps. In the case of university professionals such as geologists, mining engineers and engineers in metallurgy, 80-90% will work in mining. In the case of graduates of relevant majors, that cover skills also utilized by other industries, not only mining?such as maintenance workers, operators of fixed and mobile equipment, etc.?the mining sector appears to be unattractive for reasons such as shift schedules, geographical location of work sites, and other factors. On the basis of the available diagnosis a strategy for the sector has been developed (Workforce Development and Skills Strategy) whose objective is (i) to define a Mining Qualifications Framework to identify the critical roles to be filled (ii) to start, with public resources, a ¨fast-track? training program to assure the availability of at least 28,000 operators (machinery operators, truck drivers, etc.) and maintenance specialists in 2015 (iii) to promote the development of training hubs for mining with learning technologies to train technical labor and professionals on the basis of world class standards (iv) to design and implement a campaign oriented toward the perception of mining as an attractive field of employment opportunity (v) to develop curricular innovations for tertiary education programs, on the basis of international benchmarks. Keynotes: Chile, mining, copper mining, skilled human resources

Sep 1, 2012

By Y. Foucaud, C. Eswaraiah, L. Filippov

Enhanced gravity separators such as Falcon concentrator which uses additional centrifugal force, are the most common gravity concentration techniques used for fine particles processing. Hence, understanding the kinetics and separation mechanisms within these separators is of paramount interest. Recent research yielded a predictive physical model for the Falcon Ultra Fine (UF) which however does not explain some results obtained with industrial ores. This study aims to identify the mechanisms involved in Falcon UF separation with the objective of confirming or rejecting the hypotheses on which the current model is built and suggesting potential points of improvement. The Falcon UF kinetics is investigated through the processing of complex low-grade and fine-grained ores from the Altenberg tin deposit (Germany), the Tabuaço tungsten deposit (Portugal) as well as a synthetic iron ore. Saturation tests are performed on the Falcon UF by controlling the separation efficiency in terms of recovery and enrichment ratio with time or feed mass. Results show an evolution of Falcon UF performance with time in contradiction with the stationary separation hypothesis on which the physical model is based. Observation of the concentrate bed suggests the presence of erosion figures in furrows which may play locally an active role in the separation. In terms of Falcon UF separation timing, three phases can be distinguished. First, upon initial feeding of the bowl, a bed quickly grows unselectively and ultra-fine particles are ejected from the bowl until the bed reaches its final profile. Next, actual separation occurs with selective concentration of dense particles. Finally, capture sites saturate and recovery drops. The evolution of partition curves over time confirms the existence of two separation mechanisms. First, differential particles settling within the flowing film responsible for the ejection of small size particles during the whole separation cycle which is already accounted for in the physical model. The second mechanism involved may be explained by the action of lift force, neglected in the physical model, which acts preferentially on coarse particles deposited at the surface of the bed resulting in coarser particles being rejected in the tailings. Hence, the addition of a lift force component to the existing model is suggested to account for this second separation mechanism.

Jan 1, 2018

By P. Coghill, P. Revell

"Geo-sensing is the ability to routinely measure or infer rock properties at a range of scales using non-destructive scanning devices. These devices can provide information and data flows to support integrated decision making across the minerals value chain. Geo-sensing has been used for many years in minerals exploration using technologies such as satellite imaging and airborne geophysics but to date the use of sensing technologies in between the mine and mill has been very limited. The aim of this research is to develop new mineral sensing technologies that can enable grade engineered ore streams through the rejection of low value gangue or deleterious elements either in the pit or during transfer to the mill. This paper focusses on the research and development being carried out by the Cooperative Research Centre for Optimising Resource Extraction (CRC ORE) and its associated members on new sensing technologies. At the start of their development these technologies were classified on the Technology Readiness Level scale at 3 (TRL3), equivalent to a proof of concept. Laboratory testing and design is aimed at progressing these sensing technologies to TRL5 which is ready for testing at an end users site. New data obtained during the laboratory testing and design phases are presented in the paper demonstrating performance specifications such as detection limits and measurement speed which can be used to infer the pod size of gangue that can be rejected at scale. Grade Engineering® and coarse gangue rejection are considered as key drivers for the mining industry to address the higher mining, processing and environmental costs associated with ore bodies with declining grades. This is an industry wide problem and the development of mineral sensors is seen as key enabling technologies for Grade Engineering® and coarse gangue rejection. The technologies presented in this paper enhance value through early decision making of ore quality and improve the overall resource value case through improved grade and throughput engineering."

Jan 1, 2018

By M. Etelapaa

A new approach to controlling the process of selective flotation of sulphide minerals from pyrite in a lime environment is covered in the presentation. Advantages of process control based on the electrochemical potential of slurry controlled by ?? ? electrode are proved and compared to conventional methods of ?? ? metering and conductometry. Keywords: flotation, electrochemical potential, automation dosing system, neural network

Sep 1, 2012

By L. C. Zhou

The floatability of andalusite and associated minerals are studied and their action mechanisms of andalusite and associated minerals with collector alkyl benzene sulphonate are also studied. Through the mensuration of electrical potential and the infrared spectroscopy, as well as desorption tests, it is confirmed that the interaction of andalusite with sodium dodecyl benzene sulphonate (SDBS), is in addition to physical adsorption, but also is chemical adsorption. The study results of the pure minerals are used for the flotation of actual andalusite mineral. By flotation from contain-ing 45.68% andalusite ore, the fine andalusite concentrate is gained which Andalusite grade is 85.88%, containing Al2O355.29% and Fe2O3 less than 1.5%.

Jan 1, 2014

By J. A. Venter

Mineralogical studies indicate the Pt-Pd-Bi-Te class to react poorly on the flotation stimuli and indications are that these minerals are slow floaters. However, recent studies performed on a number of minerals from this class indicated strong interactions with potassium ethyl xanthate resulting in the formation of dixanthogen (only one of several xanthate species). The poor flotation response is not a result of poor interaction of xanthate with the surface. It is proposed that the oxidation products of sulfides in the process water interact with the PGM surface. To test this, the effect of thiosulfate (an important oxidation product of sulfides) was investigated by employing electrochemical measurements and FTIR spectroscopy. The electrochemical investigations indicate no strong effect of thiosulfate on the interaction of xanthate with the minerals surface as well as the reduction of oxygenthiosulfate is likely not responsible for the poor flotation response of these minerals in industrial plants.

Jan 1, 2014

By M. S. Eygi

This study covers the investigations based on the electrokinetic and rheological properties to explain the interactions between kaolin minerals and commercially available polyelectrolyte in anionic character. Additional adsorption test were also conducted to support the interaction mechanism. Adsorption tests showed that adsorption densities decrease by increasing the solid content. In-creasing the solids contents from 1% to 30% by weight resulted in the decrease on adsorption from 2.14 mg/g to 1.85 mg/g. Because of its difficulty, the solids ratio at 70% was not studied. However, following to trend of the curve plotted adsorption density-solid ratio, an estimation was made and adsorption density at 70% solid content was extracted from the curve as 1.75~1.80 mg/g. The electrokinetic studies pointed out that the presence of polyelectrolyte increase the zeta potential of kaolin from 40 mV to 60 mV which is reasonable conditions to disperse and stabilize the kaolin slurry and lower the viscosity. When these result of the different tests are combined and considered together, 2 mg/g polyelectrolyte concentration was noted as optimal concentration where adsorption density, viscosity and zeta potential of the slurries give maxima and remain constant after this concentration.

Jan 1, 2014

It is well known that the crushing and grinding steps in the mineral processing of ores represent a substantial proportion of total energy, cost and carbon emission in mining. For instance a recent study calculated that 36% of the energy consumed by gold and copper producing mines in Australia was attributable to comminution (Ballantyne et al, 2012). Understanding this component of a business is essential in a world seeking to lower production costs, improve earnings and reduce its carbon footprint. The issue commands the attention and support of industry leaders in the mining sector, government, equipment manufacture, engineering design and research organizations. Furthermore, several researchers have often stated that globally, comminution processes consume between 3-4% of the world?s electrical energy production (Daniel and Lewis-Gray, 2011). In 2009-10, Australia?s Federal Government Energy Efficiency Opportunity (EEO) participants in the mining sector used 336.5 PJ, representing approximately 6 percent of Australia's total energy use. It is evident that the current practices of breaking rocks in tumbling mills are relatively inefficient (Fuerstenau and Abouzeid, 2002). Research and improved engineering design has established that a range of improved blasting, crushing and grinding techniques and flow sheets may lower project costs and carbon footprint. These include relatively simple process flow sheet strategies such as gangue rejection or pre-concentration prior to size reduction, a better combination of grinding technologies (both current and new systems), and selection of coarser grind sizes where ore and waste mineralogy allow. Yet, despite this systematic and detailed research, the industry remains somewhat reluctant to implement these strategies. CEEC (Coalition for Eco-Efficient Comminution) was established in 2011 to support knowledge sharing and change in an area of high-energy consumption for the global mineral industry. CEEC is a not-for-profit industry company, funded by grants from world wide industry companies, whose mission is to accelerate knowledge and technology transfer in the field of energy-efficient comminution. The key benefit to the mining sector arising from CEEC?s activities will be an increase in the rate at which more energy-efficient comminution data sets, processes, and technologies are developed, demonstrated, shared and applied. This will contribute directly to the industry?s target of reducing operating costs and carbon emissions. CEEC International Ltd and JKTech Pty Ltd teamed together to facilitate the inaugural CEEC Workshop, in June 2012. The purpose of the workshop was to produce a roadmap to provide guidelines for how (1) operations can achieve best EEC practice in the short to medium term, in collaboration with vendors, engineering companies and other service providers, and (2) what R&D is needed to achieve paradigm change in EEC in the medium to long term, e.g. 75% reduction in comminution energy in 10 years.

Sep 1, 2012

By ?. S. Yusupov, V. P. Isupov, N. Z. Lyakhov, A. G. Vladimirov, S. A. Kondratiev

"Considering the shortage of lithium reserves, the desirability has been shown of studying the possibility of processing into spodumene concentrates the concentration tailings and low-grade ore reserves at Transbaikalian Mining and Processing Project (ZabGOK). The mineral and chemical composition and the particle size distribution of the mineral feed, separability and recoverability of spodumene have been studied, forming the basis for the development of a concentration process and flowsheet for the studied mineral resource. Prospects have been established for impact ore grinding in a disintegrator, the efficiency of mechanochemical processes has been shown in the separation of quartz and feldspar and the recovery of lithium from concentrates.INTRODUCTION Lithium is widely used in various industries - nuclear power engineering, defense technology, power generation, ceramics, special-purpose glass and other technologies. The increasing demand for lithium and its compounds (lithium carbonate and hydroxide) for use in the manufacture of high-tech products (lithium-based materials for chemical sources of electric power and electrochemical energy) explains the need for establishing a sustainable raw material base (Mohr et al. 2012; Moores, 2007). The main sources of lithium are spodumene pegmatites (Vladimirov et al. 2012; Garret, 2004), brines (salars), and hydromineral materials (Garret, 2004; Zeng and Liu, 2009; Kotsupalo and Ryabtsev, 2008). However, in view of the absence in Russia of extractable hydromineral resources of lithium, the practical significance of spodumene ores remains decisive. Russia controls some of the world’s largest reserves of rare-metal pegmatites holding over 8 million tons of Li2O: approximately 7 million tons on the Kola peninsula and 1 million tons in the Sayan mountains. The main lithium mineral in pegmatites is spodumene LiAlSi2O6 containing 8.1% Li2O. It can be efficiently recovered by gravitational concentration and flotation. However, most of the deposits are located in remote areas and none is currently developed. In this connection, special research is focused on technogenic raw materials, which are increasingly seen as a solution to the resource base problem (Chanturia, 2008, Kurkov and Kotova, 2007)."

Jan 1, 2018

In the present work, the flotation behaviours of zircon, rutile and ilmenite using sodium oleate as collector in absence and presence of depressants were thoroughly investigated. The maximum in the flotation recovery of any of the above minerals falls within similar pH ranges. A range of inorganic and polymer depressants were examined in order to improve the separation of zircon from rutile and ilmenite. Optimum values of conditioning pH and depressant concentration to achieve maximum recovery and best selective floatability of zircon were obtained. Selective flotation of zircon from Ti-bearing minerals was anticipated from single mineral experiments under different pH values, depressant and collector conditions.

Jan 1, 2014

By Saeed Farrokhpay

It is known that the grinding condition has a major effect on the beneficiation characteristics of the minerals in subsequent processing, in particular, flotation. In the flotation process, particles surface and their condition can significantly influence collector adsorption and flotation performance. For example, particle shape and its surface roughness occurred during grinding may influence flotation characteristics of a specific ore. In fact, adsorption of different cationic and anionic species on mineral surfaces can be varied depending on the selected comminution procedure. The flotation performance of sulphide minerals can be detrimentally affected by the surface oxidation. The amount of surface oxidation may reduce the hydrophobicity of the mineral and makes adsorption of collectors less selective. Improved liberation may generally result in improved flotation recovery. However, this may result in finer grinding and slimes, and consequently, reduce the overall flotation recovery. This paper discusses the effect of wet and dry grinding on copper flotation of a complex Cu-Pb-Zn ore. Industrially, wet grinding is preferred due to its higher energy efficiency and owing to downstream processing requirements. In this study, series of flotation tests were conducted,and surface analysis (XPS and ToFSIMS) were performed after wet or dry grinding at two different P80 values. Mineralogical study was also conducted to investigate the liberation of valuable minerals after grinding. A higher copper flotation recovery was found for wet grinding. However, the copper recovery was increased by further grinding in both conditions (wet and dry). The results showed a higher collector adsorption on copper mineral surfaces after wet grinding. The surface analysis also revealed that the ore is slightly more oxidized after dry grinding probably due to higher temperature during dry grinding.

Sep 1, 2012

By L. W. Luo

Zeolite in some regions or countries of the world have been the subjects of materials for environmental remediation involving the use of removal to heavy metal ions and some organic pollutant as a sorbent because of its capacious ions exchange and huge surface area. This article addresses the equilibrium and kinetics for manganese adsorption using zeolite modified by hexadecyl trimethyl ammonium bromide (HTMAB) as a sorbent material over a range of pH between 3.4~7.2 with eight different Mn(?) solution concentrations. PHzpc (pH of zero point charge) of the sorbent was examined according to the method proposed by Tripathy and Kanungo, and a value of 6.91 was obtained. The experimental data fit langmuir?s model for the majority of pH and Mn(?) solution concentrations tested (0.92<R2<0.97). The maximal adsorption capacity, qm ascending with pH between 3.4~7.2, rise from 15.01mg?g-1 at 3.4 to 19.46 mg?g-1 at 7.2. Besides, the constant of Freundlich Kf have the same trend with qm, increases with pH ascending. And the sorption intensity, represented by parameter 1/n in Freundlich?s model, is favorable in entire range of metal ions concentration studied. Finally, kinetics data accurately fit to pseudo-second order which indicate that there must be sorption of Mn(?) behavior occurring on inner-sphere of the sorbent.

Jan 1, 2014

By Wei Sun, Ruolin Wang, Jianjun Wang, Xiaodong Li, Honghu Tang, Yuehua Hu, Anh V. Nguyen, Haisheng Han, Kefeng Chen, Zhao Wei

It is difficult to separate scheelite especially from fluorite with fatty acid collectors because the adsorption mechanism of these collectors occurs through chemisorption of the oleate ion onto the mineral surface. A simplified flotation process using Pb-BHA complexes was developed to replace the energy-inefficient Petrov’s process of using a fatty acid, increasing the recovery of scheelite and reducing the cost. The relationship between surface chemical properties (crystal chemistry, solubility, and Zeta potential) of minerals and flotation by using a fatty acid or Pb-BHA complexes was studied in detail to provide new insights into the selective separation mechanism. The results indicate that the scheelite surface exposes more O atoms than Ca and that they are negatively charged due to the anisometric dissolution of Ca and WO4, which provides the possibility for separation using selective interfacial reaction. The FTIR and Zeta potential results indicate that both chemical and electrostatic adsorption play an important role in the adsorption of Pb-BHA complexes on the scheelite surface. The XPS results of the atomic composition and binding energies confirmed the presence of the adsorbed Pb-BHA complexes and that O and Ca may be the active adsorption sites. Therefore, scheelite was able to be collected by forming either a Ca-O-Pbcollector or W-O-Pb-collector (BHA). However, fluorite was only able to be collected by a fatty acid collector and colloidal [H2SiO3]n -, and a high temperature was needed improve the selective desorption of the adsorbed fatty acid collector by forming Ca-[H2SiO3]n - on the fluorite surface, resulting in serious problems in industry. However, the Pb-BHA complexes significantly contribute to improving the recovery of scheelite minerals, simplifying the flotation process, and circulation of the residual reagents and water. The new process has been applied in Shizhuyuan Mine, and improved the recovery by almost 10%.

Jan 1, 2018

By Graeme Heyes, Warren J. Bruckard, Michael A. Somerville

"A limited series of laboratory batch flotation tests was conducted on a suite of calcium-ferrite-based slags made in laboratory smelting trials. The smelting tests were conducted as part of a wider CSIRO Minerals’ research project aimed at developing a single-stage continuous copper-making process. The objective of the flotation work was to maximise copper recovery and iron rejection from slags made in the process.The slags treated included a reduced low copper slag, an oxidised high copper slag composite, and a very reduced low copper self-pulverising slag. The copper content of the slags varied from 2.9% to 14% Cu. The copper was present as metallic copper, oxide copper and copper-calcium ferrite phases with the phase mix related to smelting conditions. The slags were crushed, ground, wet-screened at 355 or 210 µm to remove coarse metallic particles of copper, and floated at natural pH (about pH 11) using reagents and conditions appropriate for the selective recovery of the copper phases.In rougher/scavenger tests on the reduced low copper and self-pulverising slags copper recoveries above 92% were obtained with copper enrichment ratios varying between 2.3 and 2.9. For the oxidised high copper slag copper recoveries were poorer - only 47% of the copper was recovered with an enrichment ratio of 3.3. The presence of the slow floating copper-ferrite phases in the slags limited further (selective) copper recovery. Ageing of the high copper slag, that is, a significant delay between grinding and flotation, resulted in a deterioration of the copper flotation response.The critical parameter affecting the flotation of copper from direct converting slags was found to be the form of the copper in the slag. Slags containing a higher proportion of the more desirable form of copper for flotation will provide the best opportunity for high copper recoveries to be consistently obtained, allowing improvements in the economics of the overall copper-making process."

Jan 1, 2003